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V (mV)

R ()

1.3

E (mV) V (mV) Vc (mV) i (mA/cm2)


-500
-6.0
-4.7
-0.50
-490
-5.3
-4.0
-0.43
-480
-4.8
-3.5
-0.37
-470
-4.2
-2.9
-0.31
-460
-3.9
-2.6
-0.28
-450
-3.7
-2.4
-0.26
-440
-3.4
-2.1
-0.22
-430
-3.2
-1.9
-0.20
-420
-3.1
-1.8
-0.19
-410
-2.9
-1.6
-0.17
-400
-2.8
-1.5
-0.16
-390
-2.7
-1.4
-0.15
-380
-2.6
-1.3
-0.14
-370
-2.5
-1.2
-0.13
-360
-2.5
-1.2
-0.13
-350
-2.4
-1.1
-0.12
-340
-2.3
-1.0
-0.11
-330
-2.3
-1.0
-0.11
-320
-2.3
-1.0
-0.11
-310
-2.2
-0.9
-0.10
-300
-2.2
-0.9
-0.10
-290
-2.2
-0.9
-0.10
-280
-2.1
-0.8
-0.09
-270
-2.1
-0.8
-0.09
-260
-2.0
-0.7
-0.07
-250
-2.0
-0.7
-0.07
-240
-2.0
-0.7
-0.07
-230
-1.9
-0.6
-0.06
-220
-1.8
-0.5
-0.05
-210
-1.7
-0.4
-0.04
-200
-1.6
-0.3
-0.03
-190
-1.4
-0.1
-0.01
-180
-1.0
0.3
0.03
-170
-0.4
0.9
0.10
-160
0.4
1.7
0.18
-150
1.5
2.8
0.30
-140
3.0
4.3
0.46
-130
5.7
7.0
0.75
-120
9.2
10.5
1.12
-110
13.3
14.6
1.56
-100
16.5
17.8
1.90
-90
18.1
19.4
2.07
-80
17.0
18.3
1.96

Log|i|
-0.2987
-0.3688
-0.4267
-0.5084
-0.5558
-0.5906
-0.6486
-0.6921
-0.7155
-0.7667
-0.7947
-0.8247
-0.8569
-0.8916
-0.8916
-0.9294
-0.9708
-0.9708
-0.9708
-1.0166
-1.0166
-1.0166
-1.0677
-1.0677
-1.1257
-1.1257
-1.1257
-1.1927
-1.2718
-1.3688
-1.4937
-1.9708
-1.4937
-1.0166
-0.7404
-0.5237
-0.3373
-0.1257
0.0504
0.1935
0.2796
0.3170
0.2916

10

E (mV) V (mV) Vc (mV) i (mA/cm2)


-40
10.1
11.4
1.22
-30
9.6
10.9
1.17
-20
9.4
10.7
1.14
-10
9.7
11.0
1.18
0
10.3
11.6
1.24
10
11.7
13.0
1.39
20
13.8
15.1
1.61
30
17.0
18.3
1.96
40
21.1
22.4
2.40
50
25.2
26.5
2.83
60
27.8
29.1
3.11
70
28.0
29.3
3.13
80
26.0
27.3
2.92
90
22.0
23.3
2.49
100
18.6
19.9
2.13
110
14.9
16.2
1.73
120
11.5
12.8
1.37
130
8.8
10.1
1.08
140
6.2
7.5
0.80
150
4.3
5.6
0.60
160
2.7
4.0
0.43
170
1.4
2.7
0.29
180
0.5
1.8
0.19
190
-0.2
1.1
0.12
200
-0.5
0.8
0.09
210
-0.7
0.6
0.06
220
-0.8
0.5
0.05
230
-0.9
0.4
0.04
240
-0.9
0.4
0.04
250
-1.0
0.3
0.03
260
-1.0
0.3
0.03
270
-1.1
0.2
0.02
280
-1.1
0.2
0.02
290
-1.1
0.2
0.02
300
-1.1
0.2
0.02
310
-1.1
0.2
0.02
320
-1.1
0.2
0.02
330
-1.1
0.2
0.02
340
-1.2
0.1
0.01
350
-1.2
0.1
0.01
360
-1.2
0.1
0.01
370
-1.2
0.1
0.01
380
-1.2
0.1
0.01

Log|i|
0.0861
0.0666
0.0586
0.0706
0.0936
0.1431
0.2082
0.2916
0.3794
0.4524
0.4931
0.4961
0.4654
0.3965
0.3280
0.2387
0.1364
0.0335
-0.0958
-0.2226
-0.3688
-0.5394
-0.7155
-0.9294
-1.0677
-1.1927
-1.2718
-1.3688
-1.3688
-1.4937
-1.4937
-1.6698
-1.6698
-1.6698
-1.6698
-1.6698
-1.6698
-1.6698
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708

-70
-60
-50

14.3
12.1
10.8

15.6
13.4
12.1

1.67
1.43
1.29

0.2223
0.1563
0.1120

390
400
410

-1.2
-1.2
-1.2

0.1
0.1
0.1

0.01
0.01
0.01

-1.9708
-1.9708
-1.9708

1600
1500
1400
1300
1200
1100
1000
900
800
700

E (mV)

600
500
400
300
200
100
0
-1
0
-100

10

-200
-300
-400
-500
-600

i (mA/cm2)

11

12

13

14

15

A (cm2)

v (mV/s)

0.935

E (mV) V (mV) Vc (mV) i (mA/cm2)


420
-1.2
0.1
0.01
430
-1.2
0.1
0.01
440
-1.2
0.1
0.01
450
-1.2
0.1
0.01
460
-1.2
0.1
0.01
470
-1.2
0.1
0.01
480
-1.2
0.1
0.01
490
-1.2
0.1
0.01
500
-1.2
0.1
0.01
510
-1.2
0.1
0.01
520
-1.2
0.1
0.01
530
-1.2
0.1
0.01
540
-1.2
0.1
0.01
550
-1.2
0.1
0.01
560
-1.2
0.1
0.01
570
-1.2
0.1
0.01
580
-1.2
0.1
0.01
590
-1.2
0.1
0.01
600
-1.2
0.1
0.01
610
-1.2
0.1
0.01
620
-1.2
0.1
0.01
630
-1.2
0.1
0.01
640
-1.2
0.1
0.01
650
-1.2
0.1
0.01
660
-1.2
0.1
0.01
670
-1.2
0.1
0.01
680
-1.2
0.1
0.01
690
-1.2
0.1
0.01
700
-1.2
0.1
0.01
710
-1.2
0.1
0.01
720
-1.2
0.1
0.01
730
-1.2
0.1
0.01
740
-1.2
0.1
0.01
750
-1.2
0.1
0.01
760
-1.2
0.1
0.01
770
-1.2
0.1
0.01
780
-1.2
0.1
0.01
790
-1.1
0.2
0.02
800
-1.1
0.2
0.02
810
-1.1
0.2
0.02
820
-1.0
0.3
0.03
830
-1.0
0.3
0.03
840
-1.0
0.3
0.03

Log|i|
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.9708
-1.6698
-1.6698
-1.6698
-1.4937
-1.4937
-1.4937

0.5

E (mV) V (mV) Vc (mV) i (mA/cm2)


880
-1.0
0.3
0.03
890
-1.0
0.3
0.03
900
-0.9
0.4
0.04
910
-0.9
0.4
0.04
920
-0.9
0.4
0.04
930
-0.9
0.4
0.04
940
-0.9
0.4
0.04
950
-0.8
0.5
0.05
960
-0.8
0.5
0.05
970
-0.8
0.5
0.05
980
-0.7
0.6
0.06
990
-0.6
0.7
0.07
1000
-0.6
0.7
0.07
1010
-0.5
0.8
0.09
1020
-0.5
0.8
0.09
1030
-0.4
0.9
0.10
1040
-0.3
1.0
0.11
1050
-0.3
1.0
0.11
1060
-0.2
1.1
0.12
1070
0.0
1.3
0.14
1080
0.2
1.5
0.16
1090
0.4
1.7
0.18
1100
0.6
1.9
0.20
1110
1.0
2.3
0.25
1120
1.2
2.5
0.27
1130
1.8
3.1
0.33
1140
2.1
3.4
0.36
1150
3.4
4.7
0.50
1160
4.2
5.5
0.59
1170
5.8
7.1
0.76
1180
7.9
9.2
0.98
1190
9.0
10.3
1.10
1200
10.7
12.0
1.28
1210
13.6
14.9
1.59
1220
16.4
17.7
1.89
1230
18.7
20.0
2.14
1240
21.3
22.6
2.42
1250
23.8
25.1
2.68
1260
26.5
27.8
2.97
1270
29.2
30.5
3.26
1280
31.8
33.1
3.54
1290
34.4
35.7
3.82
1300
37.2
38.5
4.12

Log|i|
-1.4937
-1.4937
-1.3688
-1.3688
-1.3688
-1.3688
-1.3688
-1.2718
-1.2718
-1.2718
-1.1927
-1.1257
-1.1257
-1.0677
-1.0677
-1.0166
-0.9708
-0.9708
-0.9294
-0.8569
-0.7947
-0.7404
-0.6921
-0.6091
-0.5729
-0.4794
-0.4393
-0.2987
-0.2304
-0.1196
-0.0070
0.0420
0.1084
0.2024
0.2772
0.3302
0.3833
0.4289
0.4732
0.5135
0.5490
0.5819
0.6146

-1.0
-1.0
-1.0

0.3
0.3
0.3

0.03
0.03
0.03

-1.4937
-1.4937
-1.4937

v = 0.5 mV/s

15

16

17

18

19

1310
1320
1330

40.1
43.3
46.7

41.4
44.6
48.0

4.43
4.77
5.13

0.6462
0.6785
0.7104

E (mV)

850
860
870

20
-2.4

-2.1

-1.8

-1.5

-1.2

-0.9

E (mV)
1340
1350
1360
1370
1380
1390
1400
1410
1420
1430
1440
1450
1460
1470
1480
1490
1500
1510
1520
1530
1540
1550
1560
1570
1580
1590
1600
1610
1620
1630
1640
1650
1660
1670
1680
1690
1700
1710
1720
1730
1740
1750
1760

V (mV) Vc (mV) i (mA/cm2)


50.5
51.8
5.54
53.8
55.1
5.89
57.5
58.8
6.29
61.5
62.8
6.72
65.8
67.1
7.18
69.0
70.3
7.52
74.1
75.4
8.06
78.2
79.5
8.50
83.0
84.3
9.02
88.9
90.2
9.65
94.1
95.4
10.20
97.5
98.8
10.57
104.5 105.8
11.32
102.1 103.4
11.06
116.0 117.3
12.55
122.6 123.9
13.25
128.5 129.8
13.88
136.0 137.3
14.68
143.0 144.3
15.43
152.0 153.3
16.40
161.0 162.3
17.36
170.0 171.3
18.32
181.0 182.3
19.50
191.0 192.3
20.57
202.0 203.3
21.74
213.0 214.3
22.92
225.0 226.3
24.20
238.0 239.3
25.59
252.0 253.3
27.09
266.0 267.3
28.59
280.0 281.3
30.09
295.0 296.3
31.69
312.0 313.3
33.51
336.0 337.3
36.07
354.0 355.3
38.00
371.0 372.3
39.82
390.0 391.3
41.85
410.0 411.3
43.99
428.0 429.3
45.91
447.0 448.3
47.95
467.0 468.3
50.09
499.0 500.3
53.51
515.0 516.3
55.22

Log|i|
0.7435
0.7703
0.7986
0.8271
0.8559
0.8761
0.9066
0.9296
0.9550
0.9844
1.0087
1.0239
1.0537
1.0437
1.0985
1.1223
1.1425
1.1669
1.1885
1.2147
1.2395
1.2629
1.2900
1.3132
1.3373
1.3602
1.3839
1.4081
1.4328
1.4562
1.4784
1.5009
1.5251
1.5572
1.5798
1.6001
1.6217
1.6433
1.6619
1.6808
1.6997
1.7284
1.7421

1770
1780
1790
1800

533.0
556.0
576.0
594.0

534.3
557.3
577.3
595.3

57.14
59.60
61.74
63.67

1.7570
1.7753
1.7906
1.8039

1900
1800
1700
1600
1500
1400
1300
1200
1100
1000
900
800
700
v = 0.5 mV/s

600
500
400
300
200
100
0
-0.9

-0.6

-0.3

-100
-200
-300
-400
-500

-600
Log|i|

0.0

0.3

0.6

0.9

1.2

1.5

1.8

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