1.

1.
11.

11.
3.

3.
33.
33.
32.
32.
22.

22.
19.

19.
42.

42.
14.

The series limit values are 8208 and 22800 for the quantum numbers n 1 and n2 in the
atomic spectrum of hydrogen. What is the wavelength for the radiation emitted for the
transition n2 n1 in ?
(A)15282
(B) 12258
(C) 12825
(D)15822
C
An open vessel containing air at 10C is heated to T K. It is found that 60% of the air is
expelled. Calculate T. Assume that air behaves like an ideal gas and that the volume
change of the vessel may be neglected.
(A) 856 K
(B) 865 K
(C) 658 K
(D) 568 K
C
The temperature at which gas must be cooled before it can be liquefied by compression
is called
(A) Boyle temperature
(B) critical temperature
(C) liquefication temperature
(D) temperature
D
Kaolin, Talc and mica belong to a class of silicates called
(A) chains silicates
(B) sheet silicates
(C) cyclic silicates
B
Which substance would you expect to have the highest boiling point?
(A) Cl2
(B) BrCl
(C) HCI
D

(D) amphiboles

(D) NaCl

What is the emf of a cell containing two hydrogen electrodes, the negative one in contact
with 106 M OH and the positive one in contact with a 0.1 M CH3 COONH4 solution?
Given: PKa (CH3COOH) = 4.74 and pKa (NH4+) = 9.26.
(A) 0.059 V
(B) + 0.0295 V
(C) 0.0295 V
(D) + 0.059 V
D
Reduction potential of half cell Ag I AgI (aq) saturated
(E0Ag / Ag 0.8 V, K SP of Agl is 10 16 ) is .. V
(A) 0.328
D

(B) 1.272

(C) 0.328

C(s) + O2(g) CO2(g); H = 94.3 kcal/mol

1
CO(s) + O2(g) CO2(g); H = 67.4 kcal/mol
2
O2(g) 2O(g);
H = 117.4 kcal/mol
CO(s) C(g) + O(g); H = 230.6 kcal/mol
Calculated H for C(s) C(g) in kcal/mol.
(A) 171
(B) 154
(C) 117
D
Which is definite property?
(A) internal energy
(B) entropy
(C) both
(A)
(B)
(C)

(P) 0.144

(D) 145

(D) none
(D)

14.
38.

38.
36.

C
The solubility product of AgCI in water is 1.7 x 10 10 and that of Ag2CrO4 is 9 x 1012 at
25C. A solution of KCI (0.1 M) containing K 2Cr2O4 (0.001 M) is titrated against AgNO 3
solution (0.1 M) added from a burette. To what value will the [Cl ] decrease by
precipitation of AgCI before Ag2CrO4 just gets precipitated?
(A) 2.167 x 105 M
(B) 2.716 x 105 M
(C) 1.267 x 106 M
(D) 1.762 x 106
M
C

41.
44.

pKa for formic acid = 3.75. A buffer solution containing sodium formate and formic acid in
the concentration ratio 4 : 1 has a pH at which an acid-base indicator, (a weak acid)
shows a colour half-way between those of its acid and conjugate base forms, what is K a
for the indicator?
(A) 5.545 x 104
(B) 4.445 x 105
(C) 5.556 x 106
(D) 4.212 x 104
B
The rate of chemical reaction increases,
(A) If the temperature is decreased
(B) If the concentration of the reactants is decreased
(C) If the concentration of the reactants is increased
(D) with time
C
The rate of reaction A
F increases by a factor of 5.18, when the concentration of A

44.

is tripled. What is the order of A?

(A) 3/4
(B) 2/3
C

36.
41.

(C) 3/2

(D) 2.5