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RESULTS
Experiment A:
Aqueous Layer
Propioni
Organic Layer X
c acid
Titrate of
added
M/10NaOH
(mL)
(mL)
70.70
44.40
48.50
19.25
13.00
7.40
Concentrati
on (M)
Titrate of
M/10NaOH
k=
Concentrati
y
x
on (M)
(mL)
Experiment C:
Flow rate of
aqueous phase
Avg
Feed
24
22
12.5
28
25
20
2.0
1.5
1.5
8.5
10
9.7
19.5
Avg
Raffinate
Extract
8.0
CALCULATIONS
1.0
2.0
0.5
2.0
0.5
2.0
=
0.67
Avg
=2
Avg =
24.33
Avg =
1.67
Avg =
9.4
For experiment A
Calculation of concentration:
M1V1 = M2V2
M1 = concentration of NaOH
M2 = concentration of
propionic acid
Y : Concentration of solute in
extract phase (Upper)
X: Concentration of solute in
raffinate phase (Bottom)
V1 = volume of NaOH
V2 = volume of propionic acid
Aqueous (Y)
Organic (X)
Distribution
Coefficient,K
K=
5.0
M1V1 = M2V2
(0.1M)(70.7 10-3L)=(M2)
(5.0 10-3L)
M2= 1.414M
M1V1 = M2V2
(0.1M)(44.4 103
L)=(M2)(5.0 10-3L)
M2= 0.888 M
Y
X
1.414 M
0.888 M
= 1.592
3.0
M1V1 = M2V2
(0.1M)(48.5 10-3L)=(M2)
(3.0 10-3L)
M2= 1.617M
M1V1 = M2V2
(0.1M)(19.25 103
L)=(M2)(3.0 10-3L)
M2= 0.642 M
K=
Y
X
1.617 M
0.642 M
= 2.519
K=
1.0
M1V1 = M2V2
(0.1M)(13 10-3L)=(M2)
(1.0 10-3L)
M2= 1.3M
M1V1 = M2V2
(0.1M)(7.4 10-3L)=(M2)
(1.0 10-3L)
M2= 0.74M
Y
X
1.30 M
0.74 M
= 1.757
For experiment C
Formulae used;
1. M1V1 = M2V2
Where:
M1 = concentration of NaOH
M2
=
concentration
propionic acid
of
V1 = volume of NaOH
V2 = volume of propionic acid
6. Packing dimension:
Length = 1.2 m
Diameter = 50 mm
4. K = Y1/X*
Radius =
50 10
2
)=
0.025m
= 2.356 10-3 m3
Feed:
M1V1= M2V2
(0.1M)(19.5 mL) = M2 (10 mL)
M2 =0.195M of propionic acid
(the X1)
Raffinate:
M1V1 = M2V2
(0.1M)(0.67 mL)= M2 (10 mL)
M2=0.0067M of propionic acid
(the X2)
Extract:
M1V1 = M2V2
(0.1M)(2.0 mL)= M2 (10 mL)
M2=0.02M of propionic acid
(the Y1)
Mass Balance:
= 0.00062139 kg/s
Propionic Acid extracted from the aqueous phase (extract)
= Vw (Y1 Y2 )
since Y2 = 0.0
= 0.0033 (0.02 0)
= 0.000066 kg/s
1.592+2.519+1.757
3
K=
X* =
Y1
X
; X* =
0.0 2
1.956
= 1.956
Y1
K
= 0.0102 M
(X 1X 2)
ln( X 1 /X 2)
(0.1950.0 067)
0.195
ln(
)
0.0067
= 0.0559
Mass transfer coefficient =
= 14851
= 14.851
Feed:
M1V1= M2V2
(0.1M)(24.33 mL) = M2 (10 mL)
M2 =0.2433M of propionic acid
(the X1)
Raffinate:
M1V1 = M2V2
(0.1M)(1.67 mL)= M2 (10 mL)
M2=0.0167M of propionic acid
(the X2)
Extract:
M1V1 = M2V2
(0.1M)(9.4 mL)= M2 (10 mL)
M2=0.94M of propionic acid
(the Y1)
Mass Balance:
since Y2 = 0.0
= 0.0033 (0.94 0)
= 0.003102 kg/s
1.592+2.519+1.757
3
K=
X* =
Y1
X
; X* =
0.94
1.956
= 1.956
Y1
K
= 0.4806 M
(X 1X 2)
ln( X 1 /X 2)
(0.24330.0167)
0.2433
ln(
)
0.0167
= 0.0846
Mass transfer coefficient =
1.956
2.356 103 0.0846
= 9813
= 9.813