PLANT LOAD:

NG:
PROCESS AIR:
S/C:
NG/AIR:
H2 Recycle:

100 %
44297 Nm3/hr
45000 Nm3/hr
3.3
0.73
1800 Nm3/hr

Production:
C

FEED GAS:
FUEL GAS:

34551.66
9745.34

mt/day

H2 recycle
H2
N2
CO
CO2
CH4

1332
378
54
18
18

Total

1800

R-11-02
NG FEED
N2
CO2
CH4
C2H6
C3H8
C4H10
C5H12
Total:

120.93081
276.41328
33369.993
701.3987
62.192988
13.820664
6.910332
34551.66 Nm3/hr

Nm3/hr
Nm3/hr

Gas Vent
N2
CO2
O2
H2O
CO
Total

Steam:

113918.4 Nm3/hr

H-13-01
(Primary Reformer)

11-02

H2
N2
CO
CO2
CH4
C2H6
C3H8
C4H10
C5H12

1332
498.9308
54
294.4133
33387.99
701.3987
62.19299
13.82066
6.910332

Total:

36351.66 Nm3/hr

x1:
x2:
x3:
x4:
x5:
x6:

26741.81
25825.32
784.3227
82.92398
20.731
6.910332

FUEL GAS

N2
CO2
CH4
C2H6
C3H8
C4H10
C5H12
Total:

34.10869
77.96272
9412.049
197.8304
17.54161
3.898136
1.949068
9745.34

Process Air
N2
O2
CO2
Ar

35100
9450
45
405

Total:

45000 Nm3/hr

R-13-01
(Secondary Reformer Combustion)

01
former)

AIR

H2
N2
CO
CO2
CH4
H2O

80576.13
498.9308
26795.81
272.8133
8346.998
87219.8

Total:

203710.5 Nm3/hr

x1:

3150

N2
O2
CO2
Ar
Total:

R-13-01
(Secondary Reformer)

H2
N2
CO
CO2
CH4
H2O
Ar

80576.13
35598.93
20495.81
9722.813
5196.998
93519.8
405

Total:

245515.5 Nm3/hr

x1:

4417.449

H2
N2
CO
CO2
CH4
H2O
Ar

84993.58
35598.93
20495.81
14140.26
779.5497
89102.35
405

Total:

245515.5

R-14-01
(HTS)

x1:

Nm3/hr

15371.85

R-14-02
(LTS)

H2
N2
CO
CO2
CH4
H2O
Ar

100365.4
35598.93
5123.951
29512.12
779.5497
73730.5
405

Total:

245515.5 Nm3/hr

x1:

To UREA PLANT:
H2
N2
CO2
H2O
Total:

R-14-02
(LTS)

1024.79

BENFIELD

H2
N2
CO
CO2
CH4
H2O
Ar

101390.2
35598.93
4099.161
30536.91
779.5497
72705.71
405

Total:

245515.5 Nm3/hr
Water Remove:

0.98

o UREA PLANT:

0.94

202.7804
35.59893
28704.69
2181.171
31124.24 Nm3/hr

Water Remove:

0.78

V-15-04

R-25-01

H2
N2
CO
CO2
CH4
H2O
Ar

101187.4
35563.33
4099.161
1832.214
779.5497
1410.491
405

H2
N2
CO
CO2
CH4
H2O
Ar

Total:

145277.2 Nm3/hr

Total:

101187.4
35563.33
4099.161
1832.214
779.5497
310.308
405
144177 Nm3/hr

x1:
x2:

R-25-02

R-25-01

824.4965
3074.371

H2
N2
CO
CO2
CH4
H2O
Ar
CH3OH

86416.47
35563.33
1024.79
1007.718
779.5497
1134.804
405
3898.867

Total:

130230.5 Nm3/hr

x1:
x2:

806.1743
717.3532

Methanol remove:
Water remove:

0.99
0.94

Methanol Separator

H2
N2
CO
CO2
CH4
H2O
Ar
CH3OH

81128.53
35563.33
307.4371
201.5436
779.5497
1940.979
405
5422.395

Total:

125748.8 Nm3/hr

CH3OH
H2O

5368.171
1824.52

Total

7192.691 Nm3/hr

R-17-01

H2
N2
CO
CO2
CH4
H2O
Ar
CH3OH

81128.53
35563.33
307.4371
201.5436
779.5497
116.4587
405
54.22395

Total:

118556.1 Nm3/hr

x1:
x2:
x3:

307.4371
201.5436
54.22395

H2
N2
CH4
H2O
Ar

79345.82
35563.33
1342.754
881.2069
405

Total:

117538.1

Nm3/hr

Primary reformer
CO2 + H2 --> CO + H2O
CH4 + 2H2O <--> CO2 + 4H2
C2H6 + 2H2O <--> CH4 + CO2 + 3H2
C3H8 + 2H2O <--> C2H6 + CO2 + 3H2
C4H10 + 2H2O <--> C3H8 + CO2 + 3H2
C5H12 + 2H2O <--> C4H10 + CO2 + 3H2

fCO2:
fCH4:
fC2H6:
fC3H8:
fC4H10:
fC5H12:

0.4
0.75
1
1
1
1

fCH4:
fC2H6:
fC3H8:
fC4H10:
fC5H12:

1
1
1
1
1

fO2:

Burner in H-13-01
CH4 + 2O2 --> CO2 + 2H2O
C2H6 + 5/2O2 --> 2CO + 3H2O
C3H8 + 7/2O2 --> 3CO + 4H2O
C4H10 + 9/2O2 --> 4CO + 5H2O
C5H12 + 11/2O2 --> 5CO + 6H2O
Combustion Top of Secondary Reformer
CH4 + 2CO + 3O2 --> 3CO2 + 2H2O
Reaction in Secondary Reformer
CH4 + H2O <--> CO2 + H2

fCH4:

0.85

fCO:

0.75

fCO:

0.2

HTS
CO + H2O <--> CO2 + H2
LTS
CO + H2O <--> CO2 + H2
Methanol 1
CO2 + 3H2 <--> CH3OH + H2O
CO + 4H2 <--> CH3OH

fCO2:
fCO:

0.45
0.75

fCO2:
fCO:

0.8
0.7

Methanol 2
CO2 + 3H2 <--> CH3OH + H2O
CO + 4H2 <--> CH3OH
Methanator
CO + 3H2 <--> CH4 +H2O
CO2 + 4H2 <--> CH4 + 2H2O
CH3OH + H2 <--> CH4 + H2O

fCO:
fCO2:
fCH3OH:

1
1
1

x1:
x2:
x3:
x4:
x5:
x6:

26741.81
25825.32
784.3227
82.92398
20.731
6.910332

x1:
x2:
x3:
x4:
x5:

x1:

3150

x1:

4417.449

x1:

15371.85

x1:

1024.79

x1:
x2:

824.4965
3074.371

x1:
x2:

806.1743
717.3532

x1:
x2:
x3:

307.4371
201.5436
54.22395