Component

NH3

Cp Constant
A

Tb (K)

Tc (K)

Hvap
Hf
(kJ/kmol) (kJ/kmol)

27.315 2.38E-02 1.71E-05

###

239.65

405.6

23362

-45900

N2

31.150

2.68E-05

###

63.25

126.2

5581

H2

27.143 9.27E-03

###

7.65E-09

20.35

33.2

904

###

B.2.1 Energy Balance around Mixer, M-1

Stream 18

Stream 3

Stream 1
Stream 2
M-1
Operating condition :
Stream
1
2
3
18

Temperature Temperature Pressure 4

3
(C)
2 (K)1 M-1 (atm)
25.00
25.00
-22.81
-41.86

298.15
298.15
250.34
231.30

60.00
60.00
59.97
59.97

Phase
Vapor
Vapor
Vapor
Vapor

Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
Stream
Component
(inlet)

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

HV
(kJ/hr)

N2

380.1200

0.0000

0.0000

H2

1140.3000

0.0000

0.0000

18

NH3

46.0400

-2313.3687

-45900

-2219743.4957

N2

849.6100

-1954.0110

-1660147.3229

H2

2572.0000

-1923.3943

-4946970.2288

Total

-8826861.0474

Stream
Component
(outlet)
3

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

HV
(kJ/hr)

NH3

46.0400

-1668.1522

-45900

-2190037.7270

N2

1230.5000

-1396.4576

-1718341.0159

H2

3712.4000

-1377.1397

-5112493.2706

Total

-9020872.0135

Heat duty (kJ/hr) = -194010.97 kJ/hr

T (K)

31.150

-1.356E-02

2.679E-05

-1.168E-08

298.1500

27.143

9.27E-03

-1.38E-05

7.65E-09

298.1500

27.315

2.38E-02

1.71E-05

-1.18E-08

231.2950

31.150

-1.36E-02

2.68E-05

-1.17E-08

231.2950

27.143

9.27E-03

-1.38E-05

7.65E-09

231.2950

T (K)

27.315

2.38E-02

1.71E-05

-1.18E-08

250.3400

31.150

-1.36E-02

2.68E-05

-1.17E-08

250.3400

27.143

9.27E-03

-1.38E-05

7.65E-09

250.3400

To (K)

298.15
298.15
298.15
298.15
298.15

To (K)

298.15
298.15
298.15

B.2.2 Balance around Compressor, C-2

Stream 3

Stream 4

Operating condition :
Stream
3
4

C-2

Temperature Temperature
(C)
(K)

-22.81
108.15

E-1

250.34
381.30

Pressure
2 (atm)

Phase

59.97
172.74

Vapor
Vapor

Assumption :
1. Adiabatic compressing (no heat loss in process of compressing)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
CpdT
Hf
(kJ/kmole) (kJ/kmole)

HV
(kJ/hr)

Stream
(inlet)

Component

Flowrate
(kmole/hr)

NH3

46.0400

-1668.1522

-45900

-2190037.7270

N2

1230.5000

-1396.4576

-1718341.0159

H2

3712.4000

-1377.1397

-5112493.2706

Total

-9020872.0135

CpdT
Hf
(kJ/kmole) (kJ/kmole)

HV
(kJ/hr)

Stream
(outlet)

Component

Flowrate
(kmole/hr)

NH3

46.0400

3069.8481

-45900

-1971900.1954

N2

1230.5000

2426.8046

2986183.0846

H2

3712.4000

2411.0888

8950925.9232

Total

9965208.8123

Heat duty (kJ/hr) = 18986080.83 kJ/hr

T (K)

27.315

2.38E-02

1.71E-05

-1.18E-08

250.3400

31.150

-1.36E-02

2.68E-05

-1.17E-08

250.3400

27.143

9.27E-03

-1.38E-05

7.65E-09

250.3400

T (K)

27.315

2.38E-02

1.71E-05

-1.18E-08

381.3000

31.150

-1.36E-02

2.68E-05

-1.17E-08

381.3000

27.143

9.27E-03

-1.38E-05

7.65E-09

381.3000

To (K)

298.15
298.15
298.15

To (K)

298.15
298.15
298.15

E-13-02

Stream 4

Stream 5
X-3

Operating condition :

Stream

Temperature
(C)

Temperature
X-1 (K)

Pressure
(atm)

Phase

F
E

960.00
380.00

1233.15
653.15

44.00
44.00

Vapor
Vapor

Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
CpdT
Hf
(kJ/kmole) (kJ/kmole)

Stream
(inlet)

Component

Flowrate
(kmole/hr)

E-13-20
all vapor

CH4
N2

442.5204
3057.8185

29197.5995

-45900
0

H2
H20
CO
CO2

7083.5874
32436.2726
2361.1958
427.64331048

27917.5582
35957.0056
29523.0589
46440.8344

0
-242000
-110620
-393770

O2

30899.5404

0
Total

Stream
(outlet)
E-13-20
all vapor

Component
CH4
N2
H2
H20
CO
CO2
O2

Flowrate
(kmole/hr)
442.5204
3057.8185
7083.5874
32436.2726305561
2361.1958035839
427.64331048
0

Heat Duty = -993038540.3651

CpdT
Hf
(kJ/kmole) (kJ/kmole)
16149.5545 -45900
10511.7756
0
10374.4796
0
12501.6925 -242000
10579.2619 -110620
15465.6845 -393770
10980.8273
0
Total
kJ/hr

on for component k at Treference

HV

(kJ/hr)

-20311686.4133
89280959.4453

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

197756463.6329
-6683266741.1123
-191485757.1109
-148532994.2070

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.60E-005

0.0000
-6756559755.7652

28.106

-3.68E-006 1.746E-005

HV

(kJ/hr)

-13165179.0830
32143101.7277
73488532.8203
-7444069670.6570
-236215771.0849
-161779309.8534
0.0000
-7749598296.1302

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

27.143

9.27E-03

-1.38E-05

32.243
30.869
19.795
28.106

0.001924
-0.01285
0.073436
-4E-006

1.1E-005
2.8E-005
-6E-005
1.7E-005

T (K)

To (K)

1233.1500
-1.17E-08 1233.1500

298.15
298.15

1233.1500
-3.60E-09 1233.1500
-1.27E-008 1233.1500
1.715E-008 1233.1500

298.15
298.15
298.15
298.15

1233.1500

298.15

-1.13E-08
7.65E-09

-1.07E-008

T (K)

653.1500
-1.17E-08 653.1500
7.65E-09 653.1500
-4E-009 653.1500
-1E-008 653.1500
1.7E-008 653.1500
-1E-008 653.1500
-1.13E-08

To (K)

298.15
298.15
298.15
298.15
298.15
298.15
298.15

B.2.4 Balance around Reactor, R-4

Stream 5

Stream 6

R-4
Operating condition :
Stream
5
6

Temperature
1 Temperature (K)
2
R-1
(C)
380.00
430.00

653.15
703.15

Pressure
(atm)

Phase

44.00
44.00

Vapor
Vapor

Note that the heat of reaction is automatically incuded in calculating the stream enthalpy
Assumption :
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
Stream
(inlet)

Component

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

E-13-20
all vapor

CH4
N2

442.5204
3057.8185

16149.5545
10511.7756

0
0

H2
H20
CO
CO2

7083.5874
32436.2726
2361.1958
427.64331048

12501.6925
10579.2619
15465.6845

0
-242000
-110620
-393770

O2

10980.8273

Stream
(Outlet)
R-14-01
all vapor

Component
CH4
N2

Flowrate
(kmole/hr)
44.2520
3057.8185

0
Total

CpdT
Hf
(kJ/kmole) (kJ/kmole)
12043.4070
0
11847.9631
0

H2
H20
CO
CO2
O2

8736.4245
30783.4356
708.3587
2080.480372989
0

Heat Duty = 30220861.6159

14365.7384
12130.0295
17924.5785
12621.3452
0.0000

kJ/hr

0
-242000
-110620
-393770
0
Total

y incuded in calculating the stream enthalpy

tion for component k at Treference

HV

(kJ/hr)

7146507.3303
32143101.7277

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

0.0000
-7444069670.6570
-236215771.0849
-161779309.8534

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.602E-005

0.0000
-7802775142.5372

28.106

HV

(kJ/hr)

532945.3297
36228920.5205

-3.680E-006 1.746E-005

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

27.143

9.27E-03

-1.38E-05

125505188.2085
-7076187427.3938
-65661612.0481
-792972295.5381
0.0000
-7772554280.9214

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.602E-005

28.106

-3.680E-006 1.746E-005

T (K)

To (K)

-1.13E-08

653.1500
653.1500

298.15
298.15

1.715E-008

653.1500
653.1500
653.1500
653.1500

298.15
298.15
298.15
298.15

-1.065E-008

653.1500

298.15

T (K)

To (K)

-1.13E-08

703.1500
703.1500
703.1500

298.15
298.15
298.15

-1.17E-08
7.65E-09
-3.60E-09
-1.272E-008

-1.17E-08
7.65E-09

-3.60E-09
-1.272E-008
1.715E-008
-1.065E-008

703.1500
703.1500
703.1500
703.1500

298.15
298.15
298.15
298.15

B.2.5 Balance around Expander, E-5

Input

Output
E-14-01

Operating condition :
Stream
Input
Output

Temperature
Temperature (K)
(C)
430.00
215.00

703.15
488.15
E-1

Pressure
(atm)

Phase

44.00
44.00

Vapor
Vapor

Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 C
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
Stream
(Inlet)

Component

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

R-14-01
all vapor

CH4
N2

44.2520
3057.8185

18978.2663
12043.4070

0
0

H2
H20
CO
CO2

8736.4245
30783.4356
708.3587
2080.4803729887

11847.9631
14365.7384
12130.0295
17924.5785

0
-242000
-110620
-393770

O2

12621.3452

0
Total

Stream
(Outlet)
R-14-01

Component
CH4

Flowrate
(kmole/hr)
44.2520

CpdT
Hf
(kJ/kmole) (kJ/kmole)
7771.5860
0

all vapor

N2

3057.8185

5564.9317

H2

8736.4245
30783.4356
708.3587
2080.4803729887
0

5530.1093
6541.9409
5584.8619
7779.0204
5732.4316

0
-242000
-110620
-393770
0
Total

H20
CO
CO2
O2

Heat Duty = -342088698.6135

kJ/hr

ion for component k at Treference

HV

(kJ/hr)

839827.0035
36826552.5660

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

103508834.5676
-7007364626.1915
-69766231.5459
-781939022.6231

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.60E-005

0.0000
-7717894666.2235

28.106

HV

(kJ/hr)

343908.5339

-3.68E-006 1.746E-005

19.251

5.21E-02

1.20E-05

17016551.0839

31.150

-1.36E-02

2.68E-05

48313382.3524
-7248207991.4365
-74402558.2032
-803046657.1676
0.0000
-8059983364.8370

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.60E-005

28.106

-3.68E-006 1.746E-005

T (K)

To (K)

703.1500
-1.17E-08 703.1500

298.15
298.15

703.1500
-3.60E-09 703.1500
-1.27E-008 703.1500
1.715E-008 703.1500

298.15
298.15
298.15
298.15

-1.07E-008

703.1500

298.15

T (K)

To (K)

-1.13E-08

488.1500

298.15

-1.13E-08
7.65E-09

-1.17E-08

488.1500

298.15

7.65E-09

488.1500
488.1500
488.1500
488.1500
488.1500

298.15
298.15
298.15
298.15
298.15

-3.60E-09
-1.27E-008
1.715E-008
-1.07E-008

Input

Output
X-6

Operating condition :
Stream
Input
Output

Temperature
Temperature (K)
(C)
215.00
230.00

488.15
503.15

Pressure
(atm)

Phase

44.00
44.00

Vapor
Vapor

Assumption :
1. Reference temperature : 25 C
2. Estimated = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at T
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(Inlet)

Component

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

R-14-01
all vapor

CH4
N2

44.2520
3057.8185

7771.5860
5564.9317

0
0

H2
H20
CO
CO2

8736.4245
30783.4356
708.3587
2080.480372989

5530.1093
6541.9409
5584.8619
7779.0204

0
-242000
-110620
-393770

O2

5732.4316

0
Total

Stream
(Ounlet)
R-14-01
all vapor

Component
CH4
N2

Flowrate
(kmole/hr)

CpdT
Hf
(kJ/kmole) (kJ/kmole)

44.2520

8471.3421

3057.8185

6008.7578

H20
CO
CO2
O2

9373.9473
30145.9127
70.8359
2718.003239956
0

5969.3061
7072.2178
6031.9129
8446.8093
6198.8796

0
-242000
-110620
-393770
0
Total

Heat Duty =

-2142791.3419

kJ/hr

H2

tion for component k at Treference

en (N2), heat of vaporization

HV

(kJ/hr)

343908.5339
17016551.0839

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

48313382.3524
-7248207991.4365
-74402558.2032
-803046657.1676

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

0.0000
-8059983364.8370

28.106

-3.68E-006 1.746E-005 -1.07E-008

HV

(kJ/hr)

374874.1722

19.251

5.21E-02

1.20E-05

-1.13E-08

18373690.8234

31.150

-1.36E-02

2.68E-05

-1.17E-08

55955960.9754
-7082112412.7591
-7408588.5694
-1047309680.8215
0.0000
-8062126156.1789

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

28.106

44.25204
30145.91
70.83587
9373.947
2718.003
0
3057.818

-3.68E-006 1.746E-005 -1.07E-008

CH4
H2O
CO
H2
CO2
O2
N2

T (K)

To (K)

488.1500
488.1500

298.15
298.15

488.1500
488.1500
488.1500
488.1500

298.15
298.15
298.15
298.15

488.1500

298.15

T (K)

To (K)

503.1500

298.15

503.1500

298.15

503.1500
503.1500
503.1500
503.1500
503.1500

298.15
298.15
298.15
298.15
298.15

B.2.9 Balance around Expander, E-9

Stream 11

Stream 12

E-9
Operating condition :
Stream

Temperature
(C)

11
12

230.00
99.00

Temperature (K)

Pressure
(atm)

Phase

503.15
372.15

44.00
44.00

Vapor
Mixture

E-1

Assumption :
1. Adiabatic expending (no heat loss in process of expanding)
2. Reference temperature : 25 C
3. Estimated = 0.38
4. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(Ounlet)
R-14-01
all vapor

Stream
(outlet)

Component Flowrate (kmole/hr)

CpdT
(kJ/kmole)

Hf
(kJ/kmole)

CH4
N2

44.2520
3057.8185

8471.3421
6008.7578

0
0

H2
H20
CO

9373.9473
30145.9127
70.8359

5969.3061
7072.2178
6031.9129

0
-242000
-110620

CO2
O2

2718.0032399564
0

8446.8093
6198.8796

-393770
0
Total

Component

Flowrate (kmole/hr)

CpdT
(kJ/kmole)

Stream
(outlet)

Component

4. Energy consume calculated as

CH4
follow :
N2
H2
H20
CO
CO2
O2

Component
CH4
N2
H2

Liquid

Vapor

CpdT
(kJ/kmole)

0.0000

44.2520

8471.3421

0.0000
3057.8185 6008.7578
0.0000
9373.9473 5969.3061
29542.9944470581 602.918254 7072.2178
0
70.83587411 6031.9129
0
2080.480373 8446.8093
0

6198.8796

Hvap(Tb)
(kJ/kmole)
8185
5581

Hvap(T)
(kJ/kmole)
-11231.6471
-10314.9061

HL
(kJ/hr)
0
0

H20
CO
CO2
O2

904
40683
6046
17166
6824

Heat Duty=

-926912639.4517

-3134.9945
0
40739.3272 -8.1E+009
-10857.9594
0
-14316.8804
0
-10834.4473
0
Total
-8.1E+009

for component k at Treference

N2), heat of vaporization

HV

(kJ/hr)

374874.1722
18373690.8234

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

55955960.9754
-7082112412.7591
-7408588.5694

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005

-1.272E-008

-1047309680.8215
0.0000
-8062126156.1789

19.795

0.073436

-5.602E-005 1.7153E-008

Hf (kJ/kmole)

28.106

-3.680E-006 1.746E-005

-1.065E-008

Hf (kJ/kmole)

19.251

5.21E-02

1.20E-05

-1.13E-08

0
0
-242000
-110620
-393770

31.150

-1.36E-02

2.68E-05

-1.17E-08

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005

-1.272E-008

19.795

0.073436

-5.602E-005 1.7153E-008

28.106

HV

(kJ/hr)

-3.680E-006 1.746E-005

-1.065E-008

flowrate
liquid
0.0000
0.0000

Tb (K)

Tc (K)

T (K)

31371605.771484
18373690.823439

111.65
77.35

190.6
126.2

372.1500
372.1500

55955960.975368
-141642248.25518
-7408588.569384
-801657335.56119
0
-845006914.81547

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

372.1500
0.0000
372.1500 29542.9944
372.1500
0
372.1500
0
372.1500
0

T (K)

To (K)

503.1500
503.1500

298.15
298.15

503.1500
503.1500
503.1500

298.15
298.15
298.15

503.1500
503.1500

298.15
298.15

T (K)

To (K)

503.1500

298.15

503.1500
503.1500
503.1500
503.1500
503.1500

298.15
298.15
298.15
298.15
298.15

503.1500

298.15

flowrate
Cp
vapor
3703.263 8471.342
3057.818 6008.758
9373.947
602.9183
70.83587
2080.48
0

5969.306
7072.218
6031.913
8446.809
6198.88

Hf
0
0
0
-242000
-110620
-393770
0

B.2.8 Balance around Exchanger, X-8

Stream 9

Stream 11
X-8

Operating condition :
Stream
9
11

Temperature Temperature
(C)
(K)
99.0000
99.0000

372.1500
372.1500

Pressure
(atm)
X-1

Phase

44.0000
44.0000

Mixture
Mixture

Assumption :
1. Reference temperature : 25 C
2. Estimated = 0.38
3. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
(inlet)
0

Component
CH4
N2
H2
H20
CO
CO2
O2

Flowrate (kmole/hr)
Liquid
0.0000
0.0000

Vapor
44.2520
3057.8185

0.0000
9373.9473
29542.99445 602.918254
0
70.83587411
0
2080.480373
0

CpdT
(kJ/kmole)
2.79E+03
2.16E+03
2.14E+03
2.51E+03
2.16E+03
2.87E+03
2.20E+03

Hvap(Tb)
(kJ/kmole)

Hvap(T)
(kJ/kmole)

HL (kJ/hr)

CH4
N2

8185

-11231.6471

5581

-10314.9061

H2

904
40683
6046
17166
6824

-3134.9945
40739.3272
-10857.9594
-14316.8804
-10834.4473
Total

0
-8278764856
0
0
0
-8278764856

Component

H20
CO
CO2
O2

Stream
(outlet)
0

Component
CH4
N2
H2
H20
CO
CO2
O2

Component
CH4
N2
H2
H20
CO
CO2
O2

Flowrate (kmole/hr)
Liquid
Vapor
0.0000
44.2520
0.0000
3057.8185
0.0000
9373.9473
29542.99445 602.918254
0
70.83587411
0
2080.480373
0
0

Hvap(Tb)
(kJ/kmole)
8185
5581

Hvap(T)
(kJ/kmole)
-11231.6471
-10314.9061

904
40683
6046
17166
6824

-3134.9945
40739.3272
-10857.9594
-14316.8804
-10834.4473
Total

Heat Duty =

197236945

CpdT
(kJ/kmole)
8471.3421405
6008.757846
5969.3060932
7072.2178166
6031.9129223
8446.8092748
6198.879581

HL (kJ/hr)
0
0
0
-8144031881
0
0
0
-8144031881

Stream 11

on for component k at Treference

(N2), heat of vaporization

Hf (kJ/kmole)

0
0

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

0
-242000
-110620
-393770

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

28.106

-3.68E-006 1.746E-005 -1.07E-008

HV

(kJ/hr)

Tb (K)

Tc (K)

T (K)

123258.299362448

111.65

190.6

372.1500

6603199.80444289

77.35

126.2

372.1500

20106617.9001382
-144391900.81766
-7682679.8816589
-813266111.178249
0
-938507615.87362

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

372.1500
372.1500
372.1500
372.1500
372.1500

0
0

19.251

5.21E-02

1.20E-05

31.150

-1.36E-02

2.68E-05

0
-242000
-110620
-393770
0

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

30.869

-0.01285

2.789E-005

19.795

0.073436

-5.60E-005

Hf (kJ/kmole)

HV

(kJ/hr)

28.106

-3.68E-006 1.746E-005

Tb (K)

Tc (K)

T (K)

374874.172238171
18373690.8234388

111.65
77.35

190.6
126.2

372.1500
372.1500

55955960.9753684
-141642248.25518
-7408588.569384
-801657335.56119
0
-876003646.41471

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

372.1500
372.1500
372.1500
372.1500
372.1500

T (K)

To (K)

372.1500
372.1500

298.15
298.15

372.1500
372.1500
372.1500
372.1500

298.15
298.15
298.15
298.15

372.1500

298.15

flowrate
liquid
vapor

Cp

Hf

0.0000

44.2520

2785.37

0.0000

3057.818 2159.448

0.0000 9373.947 2144.947

0
29542.99 602.9183 2511.645 -242000
0
70.83587 2162.527 -110620
0
2080.48 2866.956 -393770
0
0
2195.433
0

T (K)

To (K)

503.1500
-1.17E-08 503.1500

298.15
298.15

503.1500
503.1500
503.1500
503.1500
503.1500

298.15
298.15
298.15
298.15
298.15

-1.13E-08
7.65E-09
-3.60E-09

-1.27E-008
1.715E-008
-1.07E-008

flowrate
Cp
liquid
vapor
0.0000
44.2520 8471.342
0.0000 3057.818 6008.758

Hf
0
0

0.0000 9373.947 5969.306

0
29542.99 602.9183 7072.218 -242000
0
70.83587 6031.913 -110620
0
2080.48 8446.809 -393770
0
0
6198.88
0

B.2.7 Balance around Flash, F-7

Stream 9

Stream 8

F-7

Stream 10
Operating condition :

F-1

Temperature Temperature
Stream
(C)
(K)
8
99.00
372.15
9
65.00
338.15
10
65.00
338.15

Pressure (atm)

Phase

44.00
44.00
44.00

Vapor
Vapor
Vapor

Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc
Stream
Component
(inlet)
0

CH4
N2
H2
H20

Flowrate (kmole/hr)
Liquid
0.0000
0.0000

Vapor
44.2520
3057.8185

0.0000
0

9373.9473
602.9182540216

CpdT
Hf
(kJ/kmole) (kJ/kmole)
2.79E+03
2.16E+03

0
0

2.14E+03
2.51E+03

0
-242000

CO
CO2
O2

0
0
0

70.8358741075 2.16E+03
2080.4803729887 2.87E+03
0
2.20E+03

-110620
-393770
0
Total

Flowrate (kmole/hr)
Liquid
Vapor

CpdT
Hf
(kJ/kmole) (kJ/kmole)

CH4
N2

0.0000

44.2520

1467.3003

0.0000

3057.8185

1166.9404

H2

0.0000
0
0
0
0

9373.9473
602.9182540216
70.8358741075
2080.4803729887
0

1157.6681
1352.343
1167.8585
1521.4177
1181.2012

0
-242000
-110620
-393770
0

Hvap(Tb)
(kJ/kmole)
8185
5581

Hvap(T)
(kJ/kmole)
-10380.5837
-9747.9252

HL
(kJ/hr)
0
0

HV
(kJ/hr)
64931.03
3568292

904
40683
6046
17166
6824

-3011.5642
42583.5389
-10243.5874
-10998.5522
-10156.8953
Total

0
0
0
0
0
0

10851919
-1.5E+008
-7753138
-8.2E+008
0
-9.5E+008

Heat Duty=

-15916721.9476

Stream
Component
(outlet)

H20
CO
CO2
O2

Component
CH4
N2
H2
H20
CO
CO2
O2

HV

(kJ/hr)

To (K)

123258.2994
6603199.8044

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

372.1500
-1.17E-08 372.1500

298.15
298.15

20106617.9001
-144391900.8177

27.143

9.27E-03

-1.38E-05

32.243

1.92E-03

1.06E-05

372.1500
-3.60E-09 372.1500

298.15
298.15

7.65E-09

T (K)

-7682679.8817
-813266111.1782
0.0000
-938507615.8736

30.869
19.795
28.106

372.1500
0.073436 -5.60E-005 1.715E-008 372.1500
-3.68E-006 1.746E-005 -1.07E-008 372.1500
-0.01285

2.789E-005 -1.27E-008

298.15
298.15
298.15

T (K)

19.251

5.21E-02

1.20E-05

-1.13E-08

338.1500

31.150

-1.36E-02

2.68E-05

-1.17E-08

338.1500

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

338.1500
338.1500
338.1500
338.1500
338.1500

28.106

-3.68E-006 1.746E-005 -1.07E-008

Tb (K)

Tc (K)

T (K)

111.65
77.35

190.6
126.2

338.1500
338.1500

flowrate
liquid
vapor
0.0000 44.25204
0.0000 3057.818

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

338.1500
338.1500
338.1500
338.1500
338.1500

0.0000
0
0
0
0

9373.947
602.9183
70.83587
2080.48
0

To (K)

298.15
298.15
298.15
298.15
298.15
298.15
298.15

Cp

Hf

1467.3
1166.94

0
0

1157.668
0
1352.343 -242000
1167.859 -110620
1521.418 -393770
1181.201
0

B.2.10 Balance around Flash, F-10

Stream 13

Stream 12

F-10

Stream 14
Operating condition :

1
Temperature
Stream
(C)
12
65.00
13
35.00
14
35.00

F-1

2
Temperature (K) 3Pressure (atm)
338.15
308.15
308.15

44.00
43.97
43.97

Phase
Vapor
Mixture
vapor

Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

CH4
N2

44.2520
3057.8185

CpdT
(kJ/kmole)
1467.3003
1166.9404

H2

9373.9473

1157.6681

Stream
Component Flowrate (kmole/hr)
(inlet)
R-14-01
all vapor

Hf
(kJ/kmole)
0
0
0

HV

(kJ/hr)

64931.0304
3568291.8506
10851919.4116

H20
CO
CO2
O2

Stream
Component
(outlet)
=

602.9182540216
70.8358741075
2038.870765529
0

1352.3430
1167.8585
1521.4177
1181.2012

Flowrate (kmole/hr)

-242000
-110620
-393770
0
Total

-145090865.1726
-7753138.1142
-799744167.2905
0.0000
-938103028.2847

CpdT
(kJ/kmole)

Hf (kJ/kmole)

358.38051
291.76021

0
0

Liquid
0.0000
0.0000

Vapor
44.2520
3057.8185

H20
CO
CO2

0.0000
602.9182540216
0
0

9373.9473
0
70.835874108
2038.8707655

288.9882
336.96082
291.82559
373.86426

0
-242000
-110620
-393770

O2

294.12727

Hvap(T)
(kJ/kmole)
-9521.5899
-9198.6749

HL
(kJ/hr)
0
0

15859.0689087537
892149.76820625

-2895.3539
44108.9102
-9646.6056
-4856.4990
-9490.9403
Total

0
-1.7E+008
0
0
0
-1.7E+008

2708960.12583864
0
-7815192.67314669
-802083880.427255
0
-806282104.137448

CH4
N2
H2

Component Hvap(Tb) (kJ/kmole)

CH4
N2

8185
5581

H2
H20
CO
CO2
O2

904
40683
6046
17166
6824

Heat Duty=

-40476200.6199

HV

(kJ/hr)

T (K)

To (K)

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

338.1500
338.1500

298.15
298.15

27.143

9.27E-03

-1.38E-05

7.65E-09

338.1500

298.15

32.243

1.92E-03

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

28.106

1.06E-05

-3.60E-09

-3.68E-006 1.746E-005 -1.07E-008

338.1500
338.1500
338.1500
338.1500

298.15
298.15
298.15
298.15

T (K)

To (K)

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

308.1500
308.1500

298.15
298.15

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

308.1500
308.1500
308.1500
308.1500

298.15
298.15
298.15
298.15

-3.68E-006 1.746E-005 -1.07E-008

308.1500

298.15

28.106

flowrate
liquid
vapor
0.0000
44.2520
0.0000
3057.8185

Tb (K)

Tc (K)

T (K)

Cp

111.65
77.35

190.6
126.2

308.1500
308.1500

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

308.1500 0.0000
9373.9473 288.9882
308.1500 602.9183
0
336.9608
308.1500
0
70.83587411 291.8256
308.1500
0
2038.870766 373.8643
308.1500
0
0
294.1273

358.3805
291.7602

Hf
0
0
0
-242000
-110620
-393770
0

B.2.11 Balance around Mixer, M-11

Stream 14
Stream 15
Stream 10
M-11
Operating condition :

Temperature Temperature
2
Stream
(C)
(K)
M-1
10
35.00
308.15
14
35.00
308.15
15
-23.29
249.86

Pressure
(atm)
44.00
43.97
59.97

Phase
Vapor
vapor
Mixture

Assumption :
1. Reference temperature : 25 C
2. Energy consume calculated as follow :
Q = Qoutlet stream - Qinlet stream
= Hk(out) - Hk(in)
where Q = Heat duty
Hk(out) = nk(out)Hf,k(out) + nk(out) Cp,kdT
Hk(in) = nk(in)Hf,k(in) + nk(in) Cp,kdT
where nk = flowrate of component k
Hf,k = heat of formation for component k at Treference
4. Estimated = 0.38
5. For component Hydrogen (H2) and Nitrogen (N2), heat of vaporization
at operating temperature is assumed 0 kJ/hr because Toperating > Tc

Stream
Component
(inlet)
Operating conditionCH4
:
N2
H2
H20

Flowrate (kmole/hr)
CpdT
Hf
(kJ/kmole) (kJ/kmole)
Liquid
Vapor
0.0000
44.2520 358.38051
0
0.0000
3057.8185 291.76021 -45900
0.0000
602.918254

9373.9473 288.9882
0
336.96082

0
-242000

CO

70.8358741 291.82559

-110620

CO2
O2

0
0

2038.87077 373.86426
0
294.12727

-393770
0

Component

Hvap(Tb)
(kJ/kmole)

Hvap(T)
(kJ/kmole)

HL
(kJ/hr)

HV
(kJ/hr)

CH4
N2

8185

-9521.5899

15859.069

5581

-9198.6749

892149.77

H2

904
40683
6046
17166
6824

-2895.3539
0
2708960
44108.9102 -1.7E+008
0
-9646.6056
0
-7815193
-4856.4990
0
-8.0E+008
-9490.9403
0
0
Total
-1.7E+008 -8.1E+008

H20
CO
CO2
O2

Stream
Component
(inlet)
0
CH4
N2
H2
H20
CO
CO2
O2

Component
CH4
N2
H2
H20
CO
CO2
O2

Flowrate (kmole/hr)
CpdT
Hf
Liquid
Vapor
(kJ/kmole) (kJ/kmole)
0.0000
44.2520 358.38051
0
0.0000
3057.8185 291.76021
0
0.0000
9373.9473 288.9882
602.918254
0
336.96082
0
70.8358741 291.82559
0
2038.87077 373.86426
0
0
294.12727

Hvap(Tb)
(kJ/kmole)
8185
5581
904
40683
6046
17166
6824

Hvap(T)
(kJ/kmole)
-9521.5899
-9198.6749

HL
(kJ/hr)
0
0

0
-242000
-110620
-393770
0

HV
(kJ/hr)
15859.069
892149.77

-2895.3539
0
2708960
44108.9102 -1.7E+008
0
-9646.6056
0
-7815193
-4856.4990
0
-8.0E+008
-9490.9403
0
0
Total
-1.7E+008 -8.1E+008

Heat Duty =

T (K)

To (K)

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

308.1500
308.1500

298.15
298.15

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

308.1500
308.1500

298.15
298.15

30.869

-0.01285

2.789E-005 -1.27E-008

308.1500

298.15

19.795

0.073436

-5.60E-005 1.715E-008

308.1500
308.1500

298.15
298.15

28.106

-3.68E-006 1.746E-005 -1.07E-008

flowrate
liquid
vapor

Tb (K)

Tc (K)

T (K)

111.65

190.6

308.1500

0.0000

77.35

126.2

308.1500

0.0000

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

308.1500 0.0000 9373.9473 288.9882

0
308.1500 602.9183
0
336.9608 -242000
308.1500
0
70.8358741 291.8256 -110620
308.1500
0
2038.87077 373.8643 -393770
308.1500
0
0
294.1273
0

T (K)

To (K)

19.251

5.21E-02

1.20E-05

-1.13E-08

31.150

-1.36E-02

2.68E-05

-1.17E-08

308.1500
308.1500

298.15
298.15

27.143

9.27E-03

-1.38E-05

7.65E-09

32.243

1.92E-03

1.06E-05

-3.60E-09

30.869

-0.01285

2.789E-005 -1.27E-008

19.795

0.073436

-5.60E-005 1.715E-008

308.1500
308.1500
308.1500
308.1500
308.1500

298.15
298.15
298.15
298.15
298.15

28.106

-3.68E-006 1.746E-005 -1.07E-008

Cp

Hf

358.3805

3057.8185 291.7602

44.2520

flowrate
Cp
liquid
vapor
0.0000
44.2520 358.3805
0.0000 3057.8185 291.7602

Tb (K)

Tc (K)

T (K)

Hf

111.65
77.35

190.6
126.2

308.1500
308.1500

20.35
373.15
81.65
194.65
90.15

33.2
647.3
132.9
304.2
154.6

308.1500 0.0000 9373.9473 288.9882

0
308.1500 602.9183
0
336.9608 -242000
308.1500
0
70.8358741 291.8256 -110620
308.1500
0
2038.87077 373.8643 -393770
308.1500
0
0
294.1273
0

0
0

Equipment Energy Balance

Bil
1
2
3
4
5
6
7

Process EquipmentHeat Duty (kJ/hr)

E-14-01
-342088698.61
LTS R-14-02
-2142791.3419
E-14-02
-926912639.45
V-15-01
197236945.02
C-15-01
-15916721.948
E-15-02
-40476200.62
V-15-02
0
Total
-1130300107

Stream
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

Manual
(kJ/hr)
0
0
-9020872.01350509
9965208.8123242
-7444069670.65697
#REF!
#REF!
#REF!
#REF!
#REF!
#VALUE!
#VALUE!
#REF!
#REF!
#VALUE!
#REF!
#REF!

Simulation
(kJ/hr)
178430
1128300
-2649300
17961000
68530000
62200000
50548000
-19635000
-2472700
-17162000
-3326900
-5461400
-4395500
-1065900
-18228000
-269.06
-18228000
-3956000
-439550

Error (%)
100
100
-240.50021
44.5175168
10962.4977
#REF!
#REF!
#REF!
#REF!
#REF!
#VALUE!
#VALUE!
#REF!
#REF!
#VALUE!
#REF!
#REF!