Cambio de volumen molar a volumen total:

V x1 V1 x2 V2 x1 x2 (45 x1 25 x2 )
n V V t n1 V1 n2 V2

45 n12 n2 25 n1 n22

n2
n2

n1 V1 n2 V2 45 n12 n2 25 n1 n22

n
n
n3
n3

cm3
mol

cm3

Obtencin de la expresin para el volumen molar parcial de (1):

nV

n1

2
2 n 2 n1 2 n12 n
2 n 2 n1 n

25
n
2

n4
n4

V 1 110 0 45 n2
n2

110 90 x1 x2 90 x12 x2 25 x22 50 x1 x22 110 90 x1 x2 (1 x1 ) x22 (25 50 x1 )

110 90 x1 x22 x22 (25 50 x1 ) 110 x22 (90 x1 25 50 x1 )
110 x22 ( 40 x1 25)
Obtencin de la expresin para el volumen molar parcial de (2):

45 n12 n2 25 n1 n22

cm3
2
2
n
n
2
n 2 n2 n
2 n 2 n2 2n22 n
V 2 0 90 45 n12

25
n
1

n4
n4

n V V t n1 V1 n2 V2
nV

n2

n1

90 45 x12 90 x12 x2 50 x1 x2 50 x1 x22 90 x12 ( 45 90 x2 ) 50 x1 x2 (1 x2 )

90 x12 (45 90 x2 ) 50 x12 x2 90 x12 ( 45 90 x2 50 x2 )
90 x12 (45 40 x2 )
Para

x1 0.4

x2 1 x1

x2 0.6
3

V 110 x1 90 x2 x1 x2 ( 45 x1 25 x2)
2

Vmp1 110 x2 ( 40 x1 25)

2

Vmp2 90 x1 ( 45 40 x2)

Vmp1 124.76

cm

mol
3

Vmp2 93.36

Comprobando por la regla de adicionabilidad:

x1 Vmp1 x2 Vmp2 105.92

V 105.92

cm

mol

cm

mol

V1 110

n1

n1V1
V1

n n1 n2

cm

mol

cm

V2 90

moles de 1

n1 6.8182

n2

moles de solucin

n 23.4848

n1V1 750

mol

n2V2 1500

cm

n2V2

n2 16.6667

V2

x1

n1

x1 0.2903

Volumen molar de solucin preparada:

3

V 110 x1 90 x2 x1 x2 ( 45 x1 25 x2)

Volumen total de solucin:

Vt n V

cm

V 102.1537

mol
3

Vt 2399.0635

cm

a)
V 1 110 x22 ( 40 x1 25)
V 2 90 x12 (45 40 x 2 )
b)

Regla de adicionabilidad:

V x1 Vmp1 x2 Vmp2

? x1 110 x22 (40 x1 25) x 2 90 x12 (45 40 x2 )

? 110 x1 40 x12 x22 25 x1 x22 90 x2 45 x12 x 2 40 x12 x 2 22

V 110 x1 90 x2 x1 x2 (45 x1 25 x2

cm

moles de 2
n2
x2
x2 0.7097
n

c)

Ecuacin de Gibbs-Duhen

d Mi 0

x1 d V 1 x2 d V 2 0

x1

d Mi 0
dV 1
dV 2
x2
0
dx1
dx1

dV 1
0 x22 (40) (40 x1 25) 2 x2 40 x22 80 x1x2 50 x2
dx1

dV 2
0 x12 (40) (45 40 x2 ) 2 x1 40 x12 90 x1 80 x1 x2
dx1

x1 40 x22 80 x1 x2 50 x2 x 2 40 x12 90 x1 80 x1 x2 ?
40 x1 x22 80 x12 x2 50 x1 x2 40 x12 x2 90 x1 x2 80 x1 x 22 ?
40 x1 x2 40 x 12 x2 40 x1 x 22 ?
40 x1 x2 (1 x1 x 2) ?
40 x1 x2 (0) ?
00

d)

dV 1
dx1

x1 0

x1
i

i1

x2 1 x1
i

10

V 110 x1 90 x2 x1 x2 45 x1 25 x2
i

i 2 40x1i 25

Vmp1 110 x2
i

40 x1 90 x1 80 x1 x2 0

x2 1

x1 0

i 1 11

40 x2 80 x1 x2 50 x2 0

x2 0

x11

dV 2
dx1
e)

x1 1

Vid 110 x1 90 x2

i 2 45 40x2i

Vmp2 90 x1
i

cm

mol

TABLA DE VALORES
i

x1

1
2
3
4
5
6
7
8
9
10
11

Vid

Vmp1
i

Vmp2
i

90

90

135

90

0.1

94.43

92

133.49

90.09

0.2

98.64

94

131.12

90.52

0.3

102.51

96

128.13

91.53

0.4

105.92

98

124.76

93.36

0.5

108.75

100

121.25

96.25

0.6

110.88

102

117.84

100.44

0.7

112.19

104

114.77

106.17

0.8

112.56

106

112.28

113.68

0.9

111.87

108

110.61

123.21

110

110

110

135

GRAFICA
140
135
130
Vi
Vidi

125
120

Vmp1i115
Vmp2i110
105
100
95
90

0.1

0.2

0.3

0.4

0.5
x1i

0.6

0.7

0.8

0.9