Bateria de Vanadio

PARMETROS
H_cell 0.035[m] Cell height
wCell 0.0285[m] Cell depth
L_e 0.004[m] Electrode thickness
L_m 203e-6[m] Membrane thickness
DV2 2.4e-10[m^2/s] V(2+) diffusion coefficient
DV3 2.4e-10[m^2/s] V(3+) diffusion coefficient
DV4 3.9e-10[m^2/s] VO(2+) diffusion coefficient
DV5 3.9e-10[m^2/s] VO2(+) diffusion coefficient
DH 9.312e-9[m^2/s] H(+) diffusion coefficient
DSO4 1.065e-9[m^2/s] SO4(2-) diffusion coefficient
DHSO4 1.33e-9[m^2/s] HSO4(-) diffusion coefficient
v 30[ml/min]/(wCell*L_e) Inlet velocity
T 293.15[K] Cell temperature
sigma_e 66.7[S/m] Electrode conductivity
epsilon 0.93 Electrode porosity
a 35e4[m^2/m^3] Electrode specific area
E0_pos 1.004[V] Standard potential, positive reaction
k_pos 2.5e-8[m/s] Rate constant, positive reaction
alpha_pos 0.55 Transfer coefficient, positive reaction
E0_neg -0.255[V] Standard potential, negative reaction
k_neg 7e-8[m/s] Rate constant, negative reaction
alpha_neg 0.45 Transfer coefficient, negative reaction
beta 0.25 Dissociation constant
kd 1e4[mol/(m^3*s)] HSO4(-) dissociation rate constant
aHm 1.99 Membrane proton activity
sigma_m 10[S/m] Membrane conductivity
cV2_0 156[mol/m^3] V(2+) initial concentration

cV3_0 884[mol/m^3] V(3+) initial concentration

cV4_0 884[mol/m^3] VO(2+) initial concentration
cV5_0 156[mol/m^3] VO2(+) initial concentration
cH_0_neg 4447.5[mol/m^3] H(+) initial concentration, negative electrode
cH_0_pos 5097.5[mol/m^3] H(+) initial concentration, positive electrode
cHSO4_0_neg 2668.5[mol/m^3] HSO4(-) initial concentration, negative electrode
cHSO4_0_pos 3058.5[mol/m^3] H"O4(-) initial concentration, positive electrode
i_avg -100[mA/cm^2] Average current density

VARIABLES NEGATIVAS
aV3 max(cV3/1[mol/l],eps) V(3+) activity
aV2 max(cV2/1[mol/l],eps) V(2+) activity
aH max(cH_neg/1[mol/l],eps) H(+) activity
aHSO4 max(cHSO4_neg/1[mol/l],eps) HSO4(-) activity
aSO4 max(cSO4_neg/1[mol/l],eps) SO4(2-) activity
Eeq_neg Nernst(E0_neg,T,aV3/aV2) Equilibrium potential
i0_neg F_const*k_neg*aV2^(1-alpha_neg)*aV3^alpha_neg*1[mol/l] Exchange current
density
rd kd*((aH-aHSO4)/(aH+aHSO4)-beta) dissociation rate
phil phil_neg Electrolyte potential (for postprocessing)
phis phis_neg Electrode potential (for postprocessing)

POSITIVE VARIABLES
aV4 max(cV4/1[mol/l],eps) VO(2+) activity
aV5 max(cV5/1[mol/l],eps) VO2(+) activity
aH max(cH_pos/1[mol/l],eps) H(+) activity
aHSO4 max(cHSO4_pos/1[mol/l],eps) HSO4(-) activity
aSO4 max(cSO4_pos/1[mol/l],eps) SO4(2-) activity
Eeq_pos Nernst(E0_pos,T,aV5*aH^2/aV4) Equilibrium potential
i0_pos F_const*k_pos*aV4^(1-alpha_pos)*aV5^alpha_pos*1[mol/l] Exchange current
density
rd kd*((aH-aHSO4)/(aH+aHSO4)-beta) dissociation rate
phil phil_pos Electrolyte potential (for postprocessing)
phis phis_pos Electrode potential (for postprocessing)