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FIITJEEMOCKTEST3

IITJEE2011
PAPERI
Time:3hours

MaximumMarks:240

INSTRUCTIONS:
A. General
1. ThisbookletisyourQuestionPapercontaining60questions.
2. Blankpapers,clipboards,logtables,sliderules,calculators,cellularphones,pagersand
electronicgadgetsinanyformarenotallowedtobecarriedinsidetheexaminationhall.
3. FillintheboxesprovidedforNameandEnrolmentNo.
4. The answer sheet, a machinereadable Objective Response (ORS), is provided
separately.
5. DONOTTAMPERWITH/MULTILATETHEORSORTHEBOOKLET.
B. FillingintheOMR:
6. TheinstructionsfortheOMRsheetaregivenontheOMRitself.
C. MarkingScheme:
7. ForeachquestioninSectionI,youwillbeawarded3marksifyouhavedarkenedonly
thebubblecorrespondingtothecorrectanswerandzeromarkifnobubblesaredarkened.
Inallothercases,minusone(1)markwillbeawarded.
8. ForeachquestioninSectionII,youwillbeawarded4marksifyouhavedarkenedonly
thebubblecorrespondingtothecorrectanswerandzeromarkifnobubblesaredarkened.
Inallothercases,minusone(1)markwillbeawarded.
9. For each question in Section III, you will be awarded 4 marks if you darken only the
bubblecorrespondingtothecorrectanswerandzeromarkifnobubblesaredarkened.In
allothercases,minusone(1)markwillbeawarded.
10. ForeachquestioninSectionIV:youwillbeawarded2marksforeachrowinwhichyou
havedarkenedthebubble(s)correspondingtothecorrectanswer.Thus,eachquestionin
this section carries a maximum of 8 marks. There is No negative marks awarded for
incorrectanswer(s)inthissection.
Dontwrite/markyouranswersinthisquestionbooklet.
Ifyoumarktheanswersinquestionbooklet,youwillnotbeallowedtocontinuetheexam.
NAME:
ENROLLMENTNO.:

PAPERI

MOCKTEST2011P(I)PMC(VSB)2

PARTI:PHYSICS
SECTIONI
SingleCorrectChoiceType
Thissectioncontains8multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONLYONEiscorrect.
1.

Twoboats,AandB,startoffsimultaneouslyfromthesamepoint
fromthebankofariver.Amoveswithauniformvelocityof4m/s
relativetowaterperpendiculartothebank,andBstartsfromrest
withanaccelerationof5m/s2w.r.t.waterinthedirectionshownin
figure. If the speed of water current be u = 2 m/s, then find the
separationbetweentheboatsatthemomentwhentheyareat
equaldistancefromthebank.Assumesufficientwidthoftheriver.
(A)4m
(B)9m
(C)8m

(D)6m

2.

Considerthecircuitshowninfigureristhewindingresistanceofeachof
the two coils. If switch S is closed at t = 0, effective resistance in the
circuitatt=0is
R
R
(A) 4
(B) 2
(C)R
(D)4R

3.

AsmoothsphereofradiusRismadetotranslateinastraightlinewithaconstantaccelerationa.A
particlekeptontopofthesphereisreleasedfromtherewithzerovelocitywithrespecttothesphere.
Thespeedoftheparticlewithrespecttothesphereasafunctionoftheangleitslides,whenis
small,isgivenby(given:R=1/2ma=1m/s2)
(A) v
(B) v 5
(C) v 7
(D) v 11

4.

A500resistorandacapacitorCareconnectedinseriesacross50Hzacsupplymains.Ther.m.s.
potentialdifferencerecordedonhighimpedancevoltmetersareV1=120V(acrossresistor)andV2=
160V(acrosscapacitor).Whatisthepowertakenfromthesupplymains?
(A)48W
(B)200W
(C)28.8W
(D)14.4W
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)3

5.

AstringiswoundonacylinderofunitmassandradiusR.Oneendofthestringiscontinuouslypulled
verticallyupwardssuchthatasthestringunwinds,thecylinderspins,butitsaxisremainshorizontalat
thesamelevel.Tensionintheverticalportionofthestringis
(A)2g
(B)3g
(C)6g
(D)g

6.

Adoubleslitofseparation1.5mmisilluminatedbywhitelight(40008000).Onascreen120cm
away,colouredinterferencepatternisformed.Ifapinholeismadeonthisscreenatadistanceof3
mmfromthecentralwhitefringe,somewavelengthswillbeabsentinthetransmittedlight.Findthe
secondlongestwavelength(in)whichwillbeabsentinthetransmittedlight.
(A)6818
(B)5769
(C)5800
(D)4421

7.

AsolidconeofheightHandbaseradiusH/2floatsinaliquidofdensity.It
ishangingfromtheceilingwiththehelpofastring.Theforcebythefluidon
thecurvedsurfaceoftheconeis(P0:atmosphericpressure)
P gH
P gH
H2 0
H2 0

4
3
6

4
(A)
(B)
H2 P0

gH
4
4

(C)

8.

H2
P0 gH
(D) 4

The electron in a hydrogen atom makes a transition n1 n2 where n1 and n2 are the principle
quantumnumbersofthetwostates.AssumeBohrmodelisvalidinthiscase.Thefrequencyofthe
orbitalmotionoftheelectronintheinitialstateis1/27ofthatinthefinalstate.Thepossiblevaluesof
n1andn2are
(A)n1=6,n2=3
(B)n1=4,n2=2
(C)n1=8,n2=1
(D)n1=3,n2=1
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)4

SECTIONII
MultipleCorrectChoiceType
Thissectioncontains4multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONEORMOREmaybecorrect.
9.

Suppose two particles 1 and 2 are projected in vertical


plane simultaneously. Their angles of projection are 30
and , respectively, with the horizontal. Suppose they
collideafteratimetinair.Then

4
sin1
5 andtheywillhavethesamespeedjustbeforethecollision
(A)
4
sin1
5 andtheywillhavedifferentspeedsjustbeforethecollision
(B)
(C)x<1280 3 960m
(D)itispossiblethattheparticlescollidewhenbothofthemareattheirhighestpoint.
10.

Energyliberatedinthedeexcitationofhydrogenatomfromthirdleveltofirstlevelfallsonaphoto
cathode.Laterwhenthesamephotocathodeisexposedtoaspectrumofsomeunknownhydrogen
like gas, excited to second energy level, it is found that the de Broglie wavelength of the fastest
photoelectronsnowejectedhasdecreasedbyafactorof3.Forthisnewgas,differenceofenergiesof
second Lyman line and first Balmer line is found to be three times the ionization potential of the
hydrogenatom.Selectthecorrectstatement(s):
(A)Thegasislithium
(B)Thegasishelium
(C)Theworkfunctionofphotocathodeis8.5eV
(D)Theworkfunctionofphotocathodeis5.5eV

11.

A smooth hemispherical bowl 30 cm in diameter rotates with angular speed about an axis of
symmetry.AparticlePofweight0.5kgfisobservedtoremainatrestrelativetothebowlataheight
of10cmabovethebase.IfNistheforceextendedbytheparticleonthebowl,then
(A)w=4.5rad/s
(B)N=1.5kgf
(C)Whenwisincreasedto9rad/s,Nbecomes3.0kgf
(D)Whenwisincreasedto9rad/s,Nbecomes0.5kgf
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)5

12.

Anelectronandaprotontravelatequalspeedsaroundcircularorbitsinthesameuniformmagnetic
fieldasindicated(nottoscale)inthefollowingdiagram.Thefieldisintothepageonthediagram.The
electrontravels_______aroundthe__________circleandtheprotontravels_________aroundthe
________circle.
(A)clockwise,smaller,counterclockwise,larger
(B)counterclockwise,larger,counterclockwise,smaller
(C)clockwise,larger,counterclockwise,smaller
(D)counterclockwise,larger,clockwise,smaller

SECTIONIII
ParagraphType
Thissectioncontains2paragraphs.Baseduponeachoftheparagraph3multiplechoicequestionshave
to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
ParagraphforQuestionNos.13to15
Insideauniformsphericalshellofmass4mandradius4R,asolidsphereofmass2mandradiusRiskept.
Thesolidsphereisofuniformdensity.Thecentreofthesolidsphereisdisplacedby2Rw.r.t.thecentreof
shell.
13.

Whatistheratioofgravitationalfieldintensityatthecentreoftheshelltothatatthesurfaceofsolid
sphere?
(A)1/2
(B)2
(C)1/4
(D)4

14.

Whatistheratioofgravitationalfieldpotentialatthecentreoftheshelltothatatthecentreofsolid
sphere?
(A)1/2
(B)2
(C)1/4
(D)4

15.

Aparticleofverysmallmassm0isshiftedfromcentreofshelltoanypointonthesurfaceofthesolid
sphere.Whatistheworkdonebygravitationalforcesinthisprocess?
Gmm0
Gmm0
Gmm0
Gmm0

R
R
R

(A)
(B)
(C)2
(D)2 R
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)6

ParagraphforQuestionNos.16to18
The singly ionised helium gas in Geissler tube is excited to the state of potential energy of 1.7 eV. The
radiationsfromthetubearemadetoilluminateacleanmetalsurfaceofworkfunction8eV.[Radiationsare
almostofsameintensityirrespectiveoftheirwavelengths]
16.

Thenumberofmonochromaticradiationsthatinducephotoelectronemissionis
(A)six
(B)five
(C)four
(D)three

17.

ThedeBrogliewavelengthofphotoelectronsliesintherange
(A)1.8 8.24
(B)3.8 4.3
(C)1.33 1.8
(D)8.24 4.3

18.

AschematicgraphofappliedvoltageVversusphotoelectriccurrentIisasfollows:

(A)

(B)

(C)

(D)

SECTIONIV
MatrixMatchType
Thissectioncontains2questions.Eachquestionhasfourstatements(A,B,CandD)givenColumnIand
fivestatements(p,q,r,sandt)inColumnII.AnygivenstatementinColumnIcanhavecorrectmatching
withoneormorestatement(s)giveninColumnII.Forexample,ifforagivenquestion,statementBmatches
willthestatementsgiveninqandr,thenforthatparticularquestion,againststatementB,darkenthebubbles
correspondingtoqandrintheORS.
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)7

19.

20.

Eisthetotalenergy(KE+PE)ofasatelliteorbitingaroundtheearth.Matchthecolumns:
ColumnI
ColumnII
(A)

E>0

(p)

ellipticalorcircularorbitofsatellite

(B)

E<0

(q)

escapesfromthegravitationalpullofearth

(C)

Evaries

(r)

orbitofvariableradius

(D)

E=0

(s)

mayormaynothaveconstantspeed

(t)

orbitofconstantradius

MatchcolumnIofpropertieswithcolumnIlofreactions:
ColumnI
(A)

Massofproductsformedislessthantheoriginalmass
ofthesystemin

ColumnII
(p)

decay

(B)

Bindingenergypernucleonincreasein

(q)

decay

(C)

Massnumberisconservedin

(r)

nuclearfission

(D)

Chargenumberisconservedin

(s)

nuclearfusion

(t)

decay

Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)8

PARTII:MATHEMATICS
SECTIONI
SingleCorrectChoiceType
Thissectioncontains8multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONLYONEiscorrect.
21.

fisfunctiondefinedontheinterval[1,1]suchthatf(sin2x)=sinx+cosx.

,
Statement1:Ifx 4 4 ,thenf(tan2x)=secx
Statement2:f(x)= 1 x ,x[1,1].
(A)Statement1istrue,statement2istruestatement2isacorrectexplanationforstatement1
(B)Statement1istrue,statement2istruestatement2isnotacorrectexplanationforstatement1
(C)Statement1istrue,statement2isfalse
(D)Statement1isfalse,statement2istrue

22.

InatriangleABC,A=30,BC=2+ 5 ,thenthedistanceofthevertexAfromtheorthocenterof
thetriangleis
1
2 5 3
3 1
2
(A)1
(B)
(C) 2 2
(D)

23.

y 2 xy x 2
a
b
c
Thedeterminant a b c isequalto
bx ay cx by
(A) bx ay cx by
bx cy ax by
(C) bx cy ax by

24.

ax by bx cy
(B) ax by bx cy
ax by bx cy
(D) ax by bx cy

AlinemeetsthecoordinateaxesatAandB.AcircleiscircumscribedaboutthetriangleOAB.Ifd1
andd2arethedistancesofthetangenttothecircleattheoriginOfromthepointsAandB,
respectively,thediameterofthecircleis
d1d2
d1 d2
d1 2d2
2
(A) d1d2
(B)
(C)d +d
(D) d1 d2
1

Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)9

25.

26.

Thenumberof3digitsinwhichthedigitathundredthsplaceisgreaterthantheothertwodigitsis
(A)285
(B)281
(C)240
(D)204

1 1
1 1
A2
1 2
1 0 .ThesumoftheelementsofA,is
Aisa22matrixsuchthat and
(A)1
(B)0
(C)2
(D)5

27.

Thevalueof20C0+20C1+20C2+20C3+20C4+20C12+20C13+20C14+20C15equalsto
20 C10 20 C9
20 C10 2 20 C9

2
2

19
19

(A)2
(B)2
219 20 C10

(C)
(D)noneofthese

28.

Whichofthefollowingconditionsimplythattherealnumberxisrational?
I.x1/2isrational
II.x2andx5arerational
III.x2andx4arerational
(A)IandIIonly
(B)IandIIIonly
(C)IIandIIIonly
(D)I,IIandIII

SECTIONII
MultipleCorrectChoiceType
Thissectioncontains4multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONEORMOREmaybecorrect.
1

29.

30.

f(x)
Thefunctionfiscontinuousandhasthepropertyf(f(x))=1xforallx[0,1]andJ= 0
dx.
Thenwhichofthefollowingis/aretrue?
1
1 3
f f
4
4
2

(A)
=1
(B)thevalueofJequalto
/2
sin x dx
1 2
f f

3
0
3
3
sin x cos x hasthesamevalueofJ
(C) =1
(D)
IntriangleABC,ifsinA+sinB+sinC1,then
(A)atleastoneofA,B,Cmustexceed150
(B)atleastoneofA,B,Cmustbelessthan30
(C)sumofatleasttwoanglesmustbelessthan30
(D)allthreeanglesareacute
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)10

31.

32.

Letunitvectors a and b beperpendicularandunitvector c beinclinedatanangletoboth a and b



c a b a b
.If
,then
1 cos 2
2
(A)=
(B)122=2
(C)2=
(D)22=2

Acontinuousfunctionf(x)onRRsatisfiestherelationf(x)+f(2x+y)+5xy=f(3xy)+2x2+1for
x,yR,thenwhichofthefollowinghold(s)good
(A)fismanyone
(B)fhasnominima
(C)fisneitheroddnoreven (D)fisbounded

SECTIONIII
ParagraphType
Thissectioncontains2paragraphs.Baseduponeachoftheparagraph3multiplechoicequestionshave
to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
ParagraphforQuestionNos.33to35
Aplayertossesacoinandscoresonepointforeveryheadandtwopointsforeverytailthatturnsup.He
playsonuntilhisscorereachesorpassesn.Pndenotestheprobabilityofgettingascoreofexactlyn.
33.
ThevalueofPnisequalto
1
1
1
(A) 2 [Pn1+Pn2]
(B) 2 [2Pn1+Pn2]
(C) 2 [Pn1+2Pn2]
(D)noneofthese

34.

35.

1
ThevalueofPn+ 2 Pn1isequalto
1
2
(A) 2
(B) 3

(C)1

(D)noneofthese

Whichofthefollowingisnottrue?
2
2
(A)P100> 3
(B)P101< 3

2
(C)P100,P101> 3

(D)noneofthese

Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)11

ParagraphforQuestionNos.36to38
Supposeacubicpolynomialf(x)=x3+px2+qx+72isdivisiblebybothx2+ax+bandx2+bx+a(wherea,
b,p,qareconstantsandab)
36.
37.
38.

Thevalueofpis
(A)1

(B)1

(C)2

(D)noneofthese

Thevalueofqis
(A)70

(B)55

(C)73

(D)101

Thesumofsquareofrootsoftheequationf(x)=0is
(A)150
(B)146
(C)251

(D)300

SECTIONIV
MatrixMatchType
Thissectioncontains2questions.Eachquestionhasfourstatements(A,B,CandD)givenColumnIand
fivestatements(p,q,r,sandt)inColumnII.AnygivenstatementinColumnIcanhavecorrectmatching
withoneormorestatement(s)giveninColumnII.Forexample,ifforagivenquestion,statementBmatches
willthestatementsgiveninqandr,thenforthatparticularquestion,againststatementB,darkenthebubbles
correspondingtoqandrintheORS.
39.
(A)

(B)

Matchthefollowing
ColumnI
aR,thennumberofdistinctrealsolutionsofx2|x|+a=0canbe
a1 b1x a1x b1 c1
a2 b2 x a2 x b2 c 2
IfxR,ai,bi,ciRfori=1,2,3and a3 b3 x a3 x b3 c 3 =0x=

ColumnII
p.
1
q.
2

Let(1+x2)2(1+x)n= k 0 ak x .Ifa1,a2anda3areinarithmetic
progression,thenpossiblevalue/valuesofnis/are
Thevalueofxforwhichsin+ 3 cos=6xx211,04,xR
holds

r.

s.

t.

n 4

(C)
(D)

40.

(A)
(B)
(C)
(D)

x2 y2
2 2
ThetangentsdrawnfromapointPtotheellipse a b
axis.
ColumnI
c
If+= 2 (cN)
Iftantan=c[wherecR],thenlocusofPcanbe
Iftan
+tan=c{wherecR},thenlocusofPcanbe
Ifcot+cot=c{wherecR},locusofPcanbe

Spaceforroughwork

=1makeangleandwiththemajor
p.

ColumnII
circle

q.
r.
s.

ellipse
hyperbola
pairofstraightlines

t.

rectangularhyperbola

MOCKTEST2011P(I)PMC(VSB)12

PARTIII:CHEMISTRY
SECTIONI
SingleCorrectChoiceType
Thissectioncontains8multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONLYONEiscorrect.
41.
Whichofthefollowinghasthemaximumvalueofanglestrain?
(A)cyclopropane
(B)cyclopentane
(C)cyclobutane
(D)cyclohexane
42.

Themaximumdifferenceincovalentradiiisforthefollowingpairsofelements:
(A)ZrandHf
(B)MoandW
(C)LaandY
(D)PdandPt

43.

Thepackingfractionforaparticularunitcellisgivenbythefollowingequation:
8 3
r
3
64
r3

3
3

Identifythetypeoftheunitcell
(A)bcc
(B)fcc
(C)simplecubic
(D)noneofthese

44.

Inthemoststableelements,thenumberofprotonsandneutronsare
(A)oddodd
(B)eveneven
(C)oddeven

45.

(D)evenodd

Forhydrocarbons,heatofcrackingisdefinedasHat298.15Kand101.325kPaforthefollowing
process.
m

CnHm 2n H2 g nCH4 g
2

Heatofcrackingforethaneis65.2kJandforpropaneis87.4kJ.
CalculateHforthefollowingreaction:
CH4(g)+C3H8(g)2C2H6(g)
(A)+43kJ
(B)22.2kJ
(C)44.4kJ
(D)21.5kJ
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)13

46.

25mLofamixtureofsodiumhydroxideandsodiumcarbonaterequires25mLofHClwhentitrated
withN/10HClusingphenolphthaleinasindicator.Thesamevolumeofthemixturewhentitratedwith
sameHClusingmethylorangeasindicatorrequired30mLofHCl.Calculatetheamountofsodium
hydroxideinhalflitreofthismixture.
(A)3.2g
(B)1.6g
(C)4.8g
(D)6.4g

47.

Whatistheproductformedwhenbenzeneisreducedwithlithiuminliquidammonia?
(A)

48.

(B)

(C)

(D)

NefCarbonylSynthesisisapplicabletothefollowing:
(A)Amines
(B)nitrocompounds
(C)isocyanides

noreaction

(D)cyanides

SECTIONII
MultipleCorrectChoiceType
Thissectioncontains4multiplechoicequestions.Eachquestionhas4choices(A),(B),(C)and(D)outof
whichONEORMOREmaybecorrect.
49.

Whichofthefollowingstatement/sarecorrectforanelectronthathasn=4andm=2?
(A)Electronmaybeindorbital
(B)Electronisin4thprincipleshell
(C)Electronmaybeinporbital
(D)Electronmusthavespinquantumnumber+1/2.

50.
Theether

(A)

51.
52.

CH2I

(B)

CH2

whentreatedwithHIproduces

CH2OH

(C)

Thecompoundwhichhaszerodipolemomentis/are
(A)CH2Cl2
(B)BF3
(C)NF3

(D)

OH

(D)PF2Cl3

Anaqueoussolutionofphosphoricacid(H3PO4)beingtitratedhasmolarityequalto0.25M.Whichof
thefollowingcouldbenormalityofthissolution?
(A)0.25N
(B)0.50N
(C)0.75N
(D)1.00N
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)14

SECTIONIII
ParagraphType
Thissectioncontains2paragraphs.Baseduponeachoftheparagraph3multiplechoicequestionshave
to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
ParagraphforQuestionNos.53to55
Thecarbonmetalbondincarbonylsmayberepresentedasthedonationofanelectronpairfromcarbonto
the metal M C O. This original bond is weak. A stronger second bond is formed by back bonding,
sometimescalleddativebonding.Thisarisesfromsidewaysoverlapofafulldxyorbitalonethemetalwith
the empty antibonding *2y orbital of the carbon, thus forming a M C bond. The total bonding is thus
M=C=O.ThedriftofelectrondensityfromMtoCmakestheligandmorenegative,whichinturnenhances
itsdonatingpower.ThusCOformsweakbondstoLewisacids(electronpairacceptors)suchasBF3asonly
bonding is involved. In contract, CO forms strong bonds to transition metals where both and bonding
canoccur.OtheracceptorligandsincludeCN,RNCandNO+.Comparingtheseligands,thestrengthsofthe
bondsareintheorderCN>RNC>CO>NO+,whilsttheiracceptorpropertiesareinthereverseorder.
53.

Incarbonmonoxidemolecule,theatomwhichhasalonepairofelectronsis
(A)carbonatom
(B)oxygenatom
(C)bothofthem
(D)noneofthem

54.

Carbonmonoxideformsmetalcarbonylcompoundswiththefollowingmetal/s:
(A)manganese
(B)iron
(C)nickel
(D)allofthese

55.

Whichofthefollowingisnotaconsequenceofbackbondinginmetalcarbonyls?
(A)BondlengthinCOincreases
(B)BondorderofCOdecreases.
(C)Newelectronenterstheantibondingorbital.
(D)Electrondensityincreasesonthemetal.
Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)15

ParagraphforQuestionNos.56to58
The trend of metallic properties is less obvious in group 17. Increasing stability of positive ions shows an
increasingtendencytobasicormetalliccharacter.Fluorineisthemostelectronegativeelementandhasno
basic properties. Iodine dissolve in oleum and other strongly oxidizing solvents forming bright blue
(paramagnetic) solutions containing [I2]+. [Br2]+ is also formed in oleum and is bright red coloured and
paramagnetic.[Cl2]+hasbeenspectroscopicallyindischargetubes.Manycrystallinecompoundscontaining
[I2]+ or [Br2]+ have been prepared. Many other compounds containing cations like [Cl3]+, [Br3]+ and [I3]+ have
beenprepared.
56.

57.

58.

Whichofthefollowinghalogensisthemostbasicinnature?
(A)fluroine
(B)iodine
(C)bromine

(D)chlorine

Theshapesof I3 and I3 ,respectively,are


(A)linear,bent
(B)bent,bent
(C)linear,linear

(D)bent,linear

Thebondlengthin Br2 cationis2.15 A ascomparedwiththebondlengthinBr2,whichis2.27 A .


Thisdefinitelyshowsthat
(A)Theelectronisremovedfromabondingorbital
(B)Theelectronisremovedfromanantibondingorbital.
(C)Theelectronisshiftedfromabondingorbitaltoanantibondingorbital.
(D)Theelectronisshiftedfromanantibondingorbitaltoabondingorbital.

Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)16

SECTIONIV
MatrixMatchType
Thissectioncontains2questions.Eachquestionhasfourstatements(A,B,CandD)givenColumnIand
fivestatements(p,q,r,sandt)inColumnII.AnygivenstatementinColumnIcanhavecorrectmatching
withoneormorestatement(s)giveninColumnII.Forexample,ifforagivenquestion,statementBmatches
willthestatementsgiveninqandr,thenforthatparticularquestion,againststatementB,darkenthebubbles
correspondingtoqandrintheORS.
59.

60.

Matchthefollowing
ColumnI
(A) 106gsodiumcarbonate
(B) 66gH3PO2
(C) 126gofcrystallineoxalicacid
(D) 158gofNa2S2O3inreactionwithI2

ColumnII
(p)
(q)
(r)
(s)
(t)

1mole
2gequivalents
2moles
4gequivalents
1gequivalent

Matchthefollowing
ColumnI
Cl
(A)

ColumnII
(p)

More reactive than benzene towards ES


reactions

(q)

Less reactive than benzene towards ES


reaction

(r)

Doesnthaveacidicnature

(s)

GivesoandpproductsinES

(t)

GivesmproductsinES

OH
(B)

OCH3
(C)

CHO
(D)

Spaceforroughwork

MOCKTEST2011P(I)PMC(VSB)17

FIITJEEMOCKTEST3
IITJEE2011
PAPERI
ANSWERS
PHYSICS
1.

2.

3.

4.

5.

6.

7.

8.

9.

B,C,D

10.

B,C

11.

A,B

12.

13.

14.

15.

16.

17.

18.

19.

Aq,Bp,s,Cr,Dq

20.

Ap,q,r,s,Bp,q,r,s,Cp,q,r,s,Dp,q,r,s,

MATHS
21.

22.

23.

24.

25.

26.

27.

28.

29.

A,B,D

30.

A,C

31.

B,C

32.

A,B

33.

34.

35.

36.

37.

38.

39.

Aq,r,sBp,tCq,r,sDr

40.

Ar,s,tBp,q,r,s,tCr,sDr,s

CHEMISTRY
41.

42.

43.

44.

45.

46.

47.

48.

49.

A,B

50.

A,D

51.

B,D

52.

A,B,C

53.

54.

55.

56.

57.

58.

59.

Ap,qBp,tCp,qDp,t

60.

Aq,r,sBp,sCp,r,sDq,r,t

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