11/07/2015 11:53:21

Sample Information
: Admin
: 11/07/2015 11:37:05 AM
: Unknown
:1
: HYDROGEN
: 00329
: [1]=1
:1
:1
:1
: 1.00
: C:\GCMSsolution\Data\Project1\HYDROGEN003.qgd
: C:\GCMSsolution\Data\Project1\HYDROGEN003.qgd
: C:\GCMSsolution\Data\Project1\HYDROGEN.qgm
: C:\GCMSsolution\Data\Project1\HYDROGEN.qgm
:
: C:\GCMSsolution\System\Tune1\10042014.qgt
: Admin
: 11/07/2015 11:42:22 AM
Chromatogram HYDROGEN C:\GCMSsolution\Data\Project1\HYDROGEN003.qgd

Analyzed by
Analyzed
Sample Type
Level #
Sample Name
Sample ID
IS Amount
Sample Amount
Dilution Factor
Vial #
Injection Volume
Data File
Org Data File
Method File
Org Method File
Report File
Tuning File
Modified by
Modified

5000000

2-Propanone, 1-methoxy- (CAS)/1.846

10000000

1-Butanol, 2-methyl- (CAS)/1.574

PROPENE 3,3,3-D3/1.315
Ethene, 1,1-difluoro- (CAS)/1.340
N-Methylenehydrazinium/1.370

Intensity
C:\GCMSsolution\Data\Project1\HYDROGEN003.qgd
14,305,571

TIC

0
1.1

Peak#
1
2
3
4
5

2.0

R.Time
1.315
1.340
1.370
1.574
1.846

Area
36484971
14818973
45102947
265437390
79057912
440902193

3.0

Area%
8.28
3.36
10.23
60.20
17.93
100.00

Height
8403053
8484262
8591884
13880571
9301875
48661645

4.0

5.0

Peak Report TIC

Name
PROPENE 3,3,3-D3
Ethene, 1,1-difluoro- (CAS)
N-Methylenehydrazinium
1-Butanol, 2-methyl- (CAS)
2-Propanone, 1-methoxy- (CAS)

Library
<< Target >>
Line#:1 R.Time:1.315(Scan#:44) MassPeaks:241
RawMode:Averaged 1.310-1.320(43-45) BasePeak:44.85(1067828)
BG Mode:Calc. from Peak Group 1 - Event 1 Q3 Scan
100
45
90
80
70
60
50
40
30
20
10
46 60
78 91 108
137 151
172 191
212

298 313

331 343

10
40
70
100
130
160
190
220
250
280
310
Hit#:7 Entry:164 Library:Wiley9.lib
SI:98 Formula:C3H3D3 CAS:1517-51-7 MolWeight:42 RetIndex:0
CompName:PROPENE 3,3,3-D3 $$ PROPENE-3,3,3-D3 $$ 3,3,3-TRIDEUTEROPROPENE
100
45
90
80
70
60
41
50
40
30
27
20
10 13

340

10

40

70

100

130

160

190

220

<< Target >>

Line#:2 R.Time:1.340(Scan#:49) MassPeaks:212
RawMode:Averaged 1.335-1.345(48-50) BasePeak:44.85(354185)
BG Mode:Calc. from Peak Group 1 - Event 1 Q3 Scan
100
45
90
80
70
60
50
40
30
20
10
47 56
83
102 119 135 152 168 184
209
10

40

70

100

130

160

190

235

265 279

250

227 238

220

280

265 280

250

310

297

280

1/2

386

370

404

400

431 445 461

430

482 493

460

490

D
D

340

318 331341

310

364

340

370

363

370

400

385

402 415

400

430

440

430

460

458

460

490

478 494

490

5.2
min

11/07/2015 11:53:21

Hit#:3 Entry:926 Library:Wiley9.lib

SI:97 Formula:C2H2F2 CAS:75-38-7 MolWeight:64 RetIndex:0
CompName:Ethene, 1,1-difluoro- (CAS) $$ 1,1-Difluoroethene $$ 1,1-Difluoroethylene $$ Genetron 1132a $$ Vinylidene fluoride $$ Vinylidene difluoride $$ Ethylene, 1,1-difluoro- $$ CH2=CF2
100
27
90
80
F
70
60
50
40
39
30
F
20
10 14
10

40

70

100

130

160

190

220

<< Target >>

Line#:3 R.Time:1.370(Scan#:55) MassPeaks:238
RawMode:Averaged 1.365-1.375(54-56) BasePeak:44.85(379994)
BG Mode:Calc. from Peak Group 1 - Event 1 Q3 Scan
100
45
90
80
70
60
50
40
30
20
10
53
77 9198
121 133 144 155 171 183 200 211
10
40
70
100
130
160
190
220
Hit#:2 Entry:248 Library:Wiley9.lib
SI:95 Formula:CH5N2 CAS:0-00-0 MolWeight:45 RetIndex:0
CompName:N-Methylenehydrazinium
100
29 45
90
80
70 17
60
50
40
30
20
10
10

40

70

100

130

160

190

220

<< Target >>

Line#:4 R.Time:1.575(Scan#:96) MassPeaks:208
RawMode:Averaged 1.570-1.580(95-97) BasePeak:56.05(1670217)
BG Mode:Calc. from Peak Group 1 - Event 1 Q3 Scan
100
90
55
80
70
60
50
45
40
30
20
10
70
91
110
136146 157 176
207217

250

237

280

255 270

250

287

280

310

370

400

314 330 341 356 370

390 402

310

340

340

370

400

430

424

460

442 457

430

490

476

460

501

490

N+
H2N
250

280

241 253

277 288

310

320

340

337

370

361

400

387 401

430

426

460

446

490

467

486 497

10
40
70
100
130
160
190
220
250
280
310
340
370
400
430
460
490
Hit#:4 Entry:4792 Library:Wiley9.lib
SI:82 Formula:C5H12O CAS:137-32-6 MolWeight:88 RetIndex:0
CompName:1-Butanol, 2-methyl- (CAS) $$ 2-Methyl-1-butanol $$ sec-Butylcarbinol $$ 2-Methyl-n-butanol $$ Active amyl alcohol $$ 2-Methylbutyl alcohol $$ Primary active amyl alcohol $$ Acti
100
29
90
80
56
70
60
OH
50
70
40
55
27
30
20
10
86
10

40

70

100

130

160

190

220

<< Target >>

Line#:5 R.Time:1.845(Scan#:150) MassPeaks:241
RawMode:Averaged 1.840-1.850(149-151) BasePeak:44.95(206757)
BG Mode:Calc. from Peak Group 1 - Event 1 Q3 Scan
100
45
90
80
70
60
50
40
58
30
55
20
70
10
181 191201 217
96 109
130 146156

250

238

280

260

281

310

298 311

340

328 343

370

370

400

390

430

417

460

433 444

490

464 476

496

10 30 50 70 90 110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 410 430 450 470 490
Hit#:2 Entry:4561 Library:Wiley9.lib
SI:86 Formula:C4H8O2 CAS:5878-19-3 MolWeight:88 RetIndex:0
CompName:2-Propanone, 1-methoxy- (CAS) $$ CH3COCH2OCH3 $$ Methoxyacetone $$ Methoxy-2-propanone $$ 1-Methoxyacetone $$ Methoxymethyl methyl ketone $$ 1-Methoxy-2-propano
100
45
90
80
70
60
O
50
58
40
30
O
20 15 29
10 13
88
71
10

30

50

70

90

110 130 150 170 190 210 230 250 270 290 310 330 350 370 390 410 430 450 470 490

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