2015/2016:

: + +

3:

40 ( :)
- 1 60 ( 100g
6g )CH3COOH
- d=1.05
- 2 50 Va=20 mL NaOH
Cb=0.05moL/L PH Vbe=8.4mL PHe=8.1
Vb=4.2mL PH=4.8
- .
-
- PH .


8.1 10

- .

4.4
3.1

- 60

6.4
4.8

CH3COOH/CH
- Ka 3COO
)(aq
M H =1g/moL
)(aq
-
M O=16g/moL
- PH

M C=12g/moL

40 ( :)

) ( K(aq
)+ (aq
.1 t=0 V1 =200mL ) I
2)(2(aq
C1=0.4moL V2 =200mL ) K + S2O8

)(aq

C2
)

)
) X ] [I-
.2 )[I - ]=f(t
)
) Xmax
)(aq

)(aq

) C2
)

])1 [I-(aq
V= - dt
2

t=0
.3 X (t) = Ax +b
bA
22-

) )(S2O8 /SO4 ) (I2(aq)/I(aq

)(aq
)(aq

1 2

 04 (:)
.1 L r R=100
E K t=0
) i
)dUB(t) 1 (t
= + UB
) ) UB(t

dt

) UB(t) =(E-ri )e-(1/)t +ri i

.2 ) UB(t

) E R=4r r
) t=0
0

t=(+ )

) L
)
04(: )
1
A
)1 210zPo 82Pb
) z A
)2 N0 t=0 ) N(t
t
240
0.30

200
0.37

160
0.45

120
0.55

80
0.67

40
0.82

0
1

) Ln e
)(
) )-Ln 0 =f(t
)
)
) ( )
) t 12 ( )
) t=5 =0.01

)N(t
N0

2 2

)t (Jours
)(
N0
)(
-Ln 0

: + +

=1.05
=50

PH PH
CH3COOH+OH-CH3COOH+H2O
CaVa=CbVbe Ca=0.021mol/l
C=Ca.50=1.05mol/l

PKa=PH1/2=4.8 Ka=10-4.8=1.58 10-5
PHe

PH

I2+ 2 SO4-2

mmol
200C2
0
0
200C2-X
X
2X
200C2-Xmax Xmax 2Xmax

80
80-2X
80-2Xmax

[ I ] =(80-2X)/0.4=(200-5X )mmol/l

] [ I

2 08 S

0.25
0.50
0.25
0.25
0.25
0.25
0.25
0.50
0.50
0.50
0.50

0.25 2I-I +2e

2
0.25 S O -2+2e2SO -2
2 8
4
0.25 2I-+ S O -2I +2 SO -2
2 8
2
4
2I-+

S2O8-2

2015/2016

] [I

0.50

0.25
0.25
0.25
0.50

0.25
Ub+UR=E
(dub/dt)+(duR/dt)=0
0.50 du +(1/R)(di /dt)= 0
Ub= L(di/dt)+ri di/dt
b
di/dt=(Ub-ri)/L
Ub+Ri=E i=(E-Ub)/R
0.50 ( dU / dt) +(1/)U =Er/L
b
b
dub/dt=-1/(E-ri0)e-(1/)t
Ub/=1/(E-ri0)e-(1/)t +ri0/
0.25
=dub/dt+ Ub/=ri0/
=) ()/
0.25
0.50 E=10v Ri0=8v ri0=2v Ri0/ri0=4 R=4r r=25
)t=0)= -1/(E-ri0()=-E/t=( dub/dt 0.50
0.25 t=( )/ =( )t=0.8ms
=0.50
L=0.1H
El=(1/2)Li02=0.0032j

206

S 2 082 /V

)/(VS)+cts+(2X

).X/Vs (X)+cts

2
8

=(0.04-2X) I-

Ln(Nt/N0)=-Ln(0.5NO /N0) =-Ln0.5=0.69

0.50
-Ln(Nt/NO)=0.69=0.7
t =138j 0.25

0.25
)-(5/
Nt/NO=e
=e-5=0.01

b
S/mol . m

0.50

=(-2 I +2 S 2 0
-

=AX+b

S/m

0.25
1.25

I
1/2

0.25
0.25
0.50

84 Po
82 Pb+ 2
-Ln(Nt/N0) 0 0.2 0.4 0.6 0.8 1.0 1.2

-t/
0.25 N(t)=N0e
0.50 -Ln(Nt/N0)=-(1/)t+LnN0=-at+b
=5.10-3 S-1=0.50 =a
0.25 37 0/
0
0.25 =200j
0.25 50 0/

Xmax=20mmol f=( 80-2Xmax)/0.4=100

200C
C2=0.1mol/l
2-Xmax=0
0 .25
)0.50 Vv=(1/Vs)(dx/dt)=(1/Vs)(80- nI /2)=-1/2(d [I ]/dt
(/2=35.71mmol/min.l ) =Vv

=[I-] I-+[K+] K++[ S 2 082 ] S 2 082

210

0.50