2015/2016:

: + +

3:

40 ( :)
- 1 60 ( 100g
6g )CH3COOH
- d=1.05
- 2 50 Va=20 mL NaOH
Cb=0.05moL/L PH Vbe=8.4mL PHe=8.1
Vb=4.2mL PH=4.8
- .
-
- PH .


8.1 10

- .

4.4
3.1

- 60

6.4
4.8

CH3COOH/CH
- Ka 3COO
)(aq
M H =1g/moL
)(aq
-
M O=16g/moL
- PH

M C=12g/moL

40 ( :)

) ( K(aq
)+ (aq
.1 t=0 V1 =200mL ) I
2)(2(aq
C1=0.4moL V2 =200mL ) K + S2O8

)(aq

C2
)

)
) X ] [I-
.2 )[I - ]=f(t
)
) Xmax
)(aq

)(aq

) C2
)

])1 [I-(aq
V= - dt
2

t=0
.3 X (t) = Ax +b
bA
22-

) )(S2O8 /SO4 ) (I2(aq)/I(aq

)(aq
)(aq

1 2

 04 (:)
.1 L r R=100
E K t=0
) i
)dUB(t) 1 (t
= + UB
) ) UB(t

dt

) UB(t) =(E-ri )e-(1/)t +ri i

.2 ) UB(t

) E R=4r r
) t=0
0

t=(+ )

) L
)
04(: )
1
A
)1 210zPo 82Pb
) z A
)2 N0 t=0 ) N(t
t
240
0.30

200
0.37

160
0.45

120
0.55

80
0.67

40
0.82

0
1

) Ln e
)(
) )-Ln 0 =f(t
)
)
) ( )
) t 12 ( )
) t=5 =0.01

)N(t
N0

2 2

)t (Jours
)(
N0
)(
-Ln 0