JR & ER - Eng. PC

Dear Students,
As you are proceeding for Deepawali Vacations, you are looking forward to free time, fun and
frolic with family and friends. I, on the behalf of my department, wish you all the joy and
happiness in this festival period.
Deepawali is a festival of lights. We lighten lamps to drive away the darkness of moonless
night of Deepawali. Do not forget, it is also a very crucial period for you when you can pull out
some time for your revision. Devote your mornings and afternoons to academics (self-study)
while evening should be reserved for pure enjoyment. Do not plan any study in evening
duration, just enjoy freely and have a good time if you have studied properly in the morning.
As you lighten the lamps of Deepawali, also lighten the lamp of knowledge in your heart. I am
offering you unlighted deepaks in the form of Chemistry problems. Lighten them with the fire
of your mind, and solve them all to celebrate true deepawali.
May your interest in your subject intensify. May you learn to work hard with consistency. May
you always maintain your focus. May you be true to yourself. May Ma Saraswati bless you
with all that is desirable. This is a blessing from my heart.
With affection,
Shishir Mittal,
VP(SW) and HoD (Chemistry),
Resonance.
ORGANIC CHEMISTRY
IUPAC NOMENCLATURE
Instruction :
1.
2.
3.
4.
The test is of 1 hour duration.

The Test Booklet consists of 30 questions. The maximum marks are 120.
Each question is allotted 4 (four) marks for correct response.
Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each
question. [one fourth (1)] marks will be deducted for indicating incorrect response of each
question.
________________________________________________________________________________________
Straight Objective Type

This section contains 30 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out
of which ONLY ONE is correct. Each question carry (4, 1) Marks.
________________________________________________________________________________________
1.
What is correct about methyl butane and 2-methyl pentane.

(1) Both have same empirical formula.
(2) Both have same molecular formula.
(3) Both have same general formula.
(4) Both have same number of carbon atoms
2.
Which of the following has CnH2n general formula ?

(1)
3.
(2)
5.
(4)
Degree of unsaturation of the following compound is :
(1) 6
4.
(3)
(2) 7
(3) 5
(4) 8
Number of 3 and 2 carbon atoms in iso-octane is

(1) 2, 2
(2) 2, 3
(3) 1, 1
(4) 1, 2
compound is :
(1) Unsaturated homocyclic

(3) Saturated heterocyclic
6.
(2) Aromatic heterocyclic

(4) Unsaturated heterocylic
What is correct IUPAC name of
(1) 4-Methyl-2,6-dibromo-2-chloro-5-fluoroheptane
(2) 4-Methyl-2-chloro-2,6-dibromo-5-fluoroheptane
(3) 2,6-Dibromo-2-chloro-5-fluoro-4-methylheptane
(4) 4-Methyl-6-chloro-2,6-dibromo-3-fluoroheptane
7.
The correct IUPAC name of the following compound is :

H
OCH3 NO2
Cl C C C Et
CH3 Br
(1) 2-Bromo-1-chloro-3-ethyl-2-methoxy-1-methyl-3-nitropropane
(2) 3-Bromo-2-chloro-3-methoxy-4-nitrohexane
(3) 3-Bromo-2-chloro-4-ethyl-3-methoxy-4-nitrobutane
(4) 4-Bromo-5-chloro-4-methoxy-3-nitrohexane
14
Page # 14
8.
In the structure
word root changes by replacing the value of R. What will be R.
(2) CH CH3
|
Cl
(1) CH3
9.
(3) CH=CH2
(4) CH2CH2CH2CH3
Select the strucuture with correct numbering in the chain :
NO2
4
3 2
1
(2) H3C C CH2 CH3
(1)
Br
7
2
(3) 1
10.
6
(4)
13.
14.
15.
16.
Correct IUPAC name of the following compound is :

Br
(2) 4-Bromo-5-ethenylhepta-1,3,6-triene
(4) 4-Bromo-3-ethylidenehepta-1,4,6-triene
What is the structure of 4-Methylhex-5-en-3-thiol.

(1)
12.
1
4
(1) 4-Bromo-5-ethylidenehepta-1,3,6-triene
(3) 4-Bromo-3-ethenylhepta-1,4,6-triene
11.
(2)
(3)
(4)
Structural formula of 3Ethynyl1,4pentanediol is :

(1)
(2)
(3)
(4) None of these
The IUPAC name of CH3CH2COCH(CH3)2 is :

(1) Isopropylethyl ketone
(3) 4-Ethylisopropyl ketone
(2) 2-Ethyl-3-pentanone
(4) 2-Methyl-3-pentanone
IUPAC name of CH3CH2CHO is

(1) Propionaldehyde
(2) Ethyl aldehyde
(3) Propanol
IUPAC name of CH3 CH COCl is :

|
CH2CH3
(1) Butan-2-yl chloride
(3) 3-Methyl butanyl chloride
(2) 2-Methylbutanoyl chloride

(4) 2-Ethylpropanoyl chloride
(4) Propanal
The IUPAC name of CH3 C CH2 CONH2 is :

||
O
(1) 3-Oxobutanamide
(2) 4-Oxobutanamide
(3) 2-Oxobutanamide
(4) 2-Acetyl ethanamide
15
Page # 15
17.
Structure of the 2,2-Dimethylbutane dioic acid :

(1)
18.
(2)
The IUPAC name of
(3)
(4)
is
(1) 4-Cyano-2-chlorocyclohex-5-enamide
(3) 4-Cyano-6-chlorocyclohex-2-enamide
(2) 4-Cyano-2-chlorocyclohex-5-ene carboxamide

(4) 4-Cyano-6-chlorocyclohex-2-ene carboxamide
19.
What is the correct IUPAC name for CH3 CH CH CH CH2 C N

|
CH3
(1) 5-Methylhex-3-enenitrile
(2) 5-Cyanomethylpent-2-ene
(3) 4-Isopropylbut-3-enenitrile
(4) None of above
20.
IUPAC name of
is
(1) Methyl 2-aminopropanoate
(3) 2-aminomethylethane carboxylate
21.
(2) 2-aminomethylpropanoate
(4) Methyl 2-aminocyanoethane carboxylate
The IUPAC name of
is :
(1) Ethyl 3-chlorocarbonyl-2, 3-dimethylpropanoate

(2) Ethyl 3-chlorocarbonyl-2-methylbutanoate
(3) Ethyl 2, 3-dimethyl-3-chlorocarbonylpropanoate
(4) Ethyl 2-methyl-3-chlorocarbonylbutanoate
22.
IUPAC name of
is
(1) Ethyl 3-Oxobutanoate

(3) Ethyl 3-Carboxy-2-methylpropanal
23.
24.
IUPAC name of
(1) 1-Ethanoyloxyethane-1-sulphonic acid
(3) 2-Ethanoyloxyethane-1-sulphonic acid
is :
(2) 1-Ethanoyloxypropane-1-sulphonic acid.
(4) 3-Ethanoyloxy-1-sulphoethane
What is the correct IUPAC name for

(1) Cyclopentanoic anhydride
(3) Dicyclopentanoic anhydride
25.
(2) Ethyl 3-Formylbutanoate

(4) Ethyl 2-Formylbutanoate
(2) Cyclopentane carboxylic anhydride

(4) Dicyclopentane carboxylic anhydride
Which is the correct structure of compound Propyl cyclobutane carboxylate

O
O
(1)
OCCH2CH2CH3
O
(3)
COCH2CH2CH3
COCH2CH2CH3
(2)
O
(4)
COCH(CH3)2
16
Page # 16
26.
The IUPAC name of
is :
(1) 3-Hydroxy-2-oxobutanedioic anhydride

(2) 2-Hydroxy-3-oxobutanedioic anhydride
(3) 2-Oxo-3-hydroxybutane dicarboxylic anhydride
(4) 2-Hydroxy-3-oxoethane dicarboxylic anhydride
27.
What is the IUPAC name of

(1) 5-Chloro-3-hydroxybenzenecarboxylic acid.
(2) 3-Hydroxy-5-chlorobenzenecarboxylic acid.
(3) 3-Chloro-5-hydroxybenzenecarboxylic acid.
(4) 1-Carboxy-3-chlorobenzen-1-ol
28.
Which is the correct IUPAC name of the following compound :
(1) 4-Methyl-5-bromonitrobenzene
(3) 3-Bromo-4-methyl-1-nitrobenzene
29.
The correct IUPAC name of the compound :

CHO
NO2
OCH3
(1) 2-Formyl-5-methoxynitrobenzene
(3) 4-Methoxy-2-nitrobenzaldehyde
30.
(2) 4-Formyl-3-nitroanisole
(4) 4-Methoxy-6-nitrobenzaldehyde
Which has correct IUPAC numbering :

(1)
(2)
(3)
(4) None of these
OBJECTIVE RESPONSE SHEET (ORS)
17
Page # 17
ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

Instruction :
1.
2.
3.
4.

question.
________________________________________________________________________________________

________________________________________________________________________________________
1.
In position isomers :
(1) Nature of Functional group changed
(3) Position of multiple bond changed
(2) Length of parent or side chain changed

(4) None of these
2.
The structures (CH3)2CHCH2Br and CH3(CH2)3Br shows :

(1) position isomers
(2) chain isomerism
(3) functional isomerism
(4) None of these
3.
Which of the following are chain isomer :

(1) Hexane and Heptane
(3) 2-Methyl pentane and 3-Methyl pentane
(2) 1,1-Dichloroethane and 1,2-Dichloroethane

(4) Pentane and neopentane
4.
1,1-Dimethylcyclopropane and 1,2-Dimethylcyclopropane are :

(1) Positional isomer
(2) Metamer
(3) Functional isomer
(4) Chain isomer
5.
Diethylether and Methylpropyl ether are

(1) Positional isomers
(3) Metamers
(2) Functional isomers

(4) Chain isomers
6.
The isomerism exhibited by alkyl cyanide and alkyl isocyanide is :

(1) Functional isomerism
(2) Positional isomerism
(3) Chain isomerism
(4) Metamerism
7.
Methyl propanoate and ethyl ethanoate are :

(1) Functional isomers
(2) Metamers
(3) Chain isomers
(4) Homologues.
8.
Which of the following pairs are not isomeric compounds :

(1) Ethyl ethanoate and Methyl propanoate
(2) Butanone and Butanal
(3) Ethoxy propane and Propoxy ethane
(4) Methoxy methane and Ethanol
9.
The number of possible alcoholic isomers for C4H10O are :

(1) 4
(2) 2
(3) 3
(4) 5
10.
How many structural isomeric cycloalkene can give methylcyclobutane on hydrogenation :

(1) 2
(2) 3
(3) 4
(4) 1
11.
How many cyclic alcohols are possible with molecular formula C4H8O.
(1) 1
12.
(2) 2
(3) 3
(4) 4
Which can give only 3 monochloro structure isomers on reaction with chlorine in presence of light ?
(1) 2-Methyl propane
(2) 2-Methyl butane
(3) 3-Methyl pentane
(4) 3-Ethyl pentane
18
Page # 18
13.
The total number of monochloro products (structural) formed.

Cl2 / h
(1) 2
14.
(2) 3
(4) 1
A dichloroderivative of propane X (C3H6Cl2) gives three types of

chlorination. The correct structure of X is .
(1)
15.
(3) 4
(2)
(3)
(4)
The alkene which on ozonolysis yields acetone is

(1) CH2 =CH2
(2) CH3CH=CH2
(3) (CH3)2C=C(CH3)2
16.
trichloroderivative on further
(4) CH3CH=CHCH3
product
Product of the above reaction gives black precipitate with :
(1) Cu2Cl2 + NH4OH
(2) Dil cold KMnO4
(3) AgNO3 + NH4OH
(4) 2, 4-DNP
17.
Ozonolysis of which unsaturated hydrocarbon of the following will give aldehyde and ketone both ?
(1) 2, 3-Dimethyl but-2-ene
(2) 1, 2, 3, 4-Tetramethylcyclopenta-1,3-diene
(3) But-2-yne
(4) 2-Methylbut-2-ene
18.
3
CH2=CHCH=CHCH3
Products.
Zn,H O
Which product is not obtained in the above reaction ?

(1) CH2=O
19.
20.
(2) CH3CH=O
(4) CH3COOH
An organic compound C8H12 adds two moles of H2 per mole of hydrocarbon. It undergoes reductive
ozonolysis to give Butane-1,4-dial only. What is the structure of hydrocarbon ?
(1)
(2)
(3)
(4)
A hydrocarbon C9H16 consumes only mole of H2 in the presence of nickel as catalyst. On ozonolysis,
the hydrocarbon produces cyclohexanone and acetone. The hydrocarbon is
C
(1)
CH2
CH3
CH2
CH3
21.
(3) OHCCHO
(2)
CH3
CH3
(3)
CH3
CH3
(4)
CH2CH3
Zingiberene is the oil of ginger having structure as below :
Which is not true about this compound

(1) Its DU = 4
(2) After hydrogenation its chlorination gives 12 monochloro products.
(3) For hydrogenation it requires 3 mol of H2
(4) On ozonolysis it gives ketone only
22.
Benzoic acid can be distinguished from ethyl benzoate by

(1) NaHCO3
(2) Fehling solution
(3) Carbylamine test
(4) Action with dil. HCl
19
Page # 19
23.
Benzaldehyde and acetone can be distinguished by

(1) Mulliken Baker test
(3) Iodoform test
(4) Ninhydrin test
24.
Phenol and Benzoic acid can be distinguished by

(1) FeCl3 test
(2) Mollisch test
(3) Hinsberg test
(4) Tollen's test
Acetaldehyde and benzaldehyde can be distinguished by

(1) Tollen's test
(3) FeCl3 test
(4) NaHCO3 test
25.
26.
Propanal and propanone can not be distinguished by

(1) Iodoform test
(3) Tollen's test
(4) 2,4- DNP test
27.
Formic acid and acetic acid can be distinguished by

(1) Iodoform test
(2) NaOH solution
(3) Tollen's test
(4) NaHCO3 test
NaHCO
28.
X gas
NaHCO
3
Ph-CH2-SO3H
Y gas
X and Y are respectively
14
(1)
29.
CO 2
14
, SO2
CO 2
(3) CO2, SO2
(4) CO2, SO3
PhCONH2 and PhCOOH can be distinguished by :
(1) NaOI,
30.
(2) CO2,
(2) NaHCO3
(3) 2, 4-DNP
Which compound can not give Prussian blue colour in lassaigne test ?
(1) CH3NHCH3
(2) Pyridine
(3) NH2NH2
(4) AgNO3
(4) Aniline
20
Page # 20
ELECTRONIC EFFECT & APPLICATION (GOC)
Instruction :
1.
2.
3.
4.

question.
________________________________________________________________________________

________________________________________________________________________________
1.
2.
Which of the following groups has the highest + effect.

(1) COO
(2) CH3 CH2
(3) (CH3 )2 CH
(4) (CH3 )3 C
In which of the following correct stability order is shown :

(1)
<
(3)
(2)
>
<
(4)
<
3.
Which of the following has the maximum number of resonating structures ?

(1) Benzene
(2) Naphthalene
(3) Anthracene
(4) Phenanthrene
4.
The bonding in ozone is best described in terms of :

(1)
(3) O
5.
(2)
O
(4) O
+
CH2 CH OCH 3
(2)
(3)
(4)
(Y)
(2) Z > Y > X
(Z)
(3) Y > Z > X
(4) Z > X > Y
Find out number of benzylic hydrogen in following compound :
(1) 4
9.
Which of the following orders is correct for heat of hydrogenation of these compounds ?
(X)
(1) X > Y > Z
8.
Which of the following resonating structure is more stable ?
(1)
7.
O+
Which of the resonating structures are not acceptable in the given groups
+
(1) CH2 =CHOCH3
(2)
(3) CH CH OCH
(4)
2
6.
O+
(2) 5
(3) 6
(4) 7
S 1 : Protonated pyrrole has resonance stabilised positive charge.

S 2 : CH2=C=O exhibits resonance.
S 3 : 1,3-Butadiene shows resonance and hyperconjugation effect.
S 4 : Carbon-oxygen bonds are of equal length in acetic acid.
(1) T F F F
(2) F T F F
(3) F F F T
(4) F F F F
21
Page # 21
10.
Arrange the following in increasing order of stability

,
(1) III < II < I
11.
(2) I < II < III
(3) III < I < II
(4) II < I < III
(3)
(4)
Which is the most stable resonating structure.

(1)
12.
(2)
Which of the following group has (+m) effect :

O
CH
NHCH 3
(1)
(2)
(3)
CH3
(4)
13.
For Cyclooctatetraene following is incorrect.

(1) There are two types of CC bond.
(2) Structure is non planar and resonance is not observed in molecule.
(3) Extensive resonance is found with in the molecule and all bonds are of same type.
(4) Its heat of hydrogenation is equal to that of 4 bonds hydrogenated.
14.
Pair of aromatic compound is/are(1)
(2)
(3)
(4)
&
S
15.
N
N
Choose the non aromatic compound among the following :

H
B
(1)
16.
(2)
(3)
W hich of the following pairs of ions is more stable ?

(i)
and
(ii)
and
(iii)
and
(1) (i) II , (ii) II , (iii) II

(3) (i) II , (ii) I , (iii) I
17.
(2)
(3)
(4)
The decreasing order of stability of following anion is :
(P)
(1) P > Q > R > S
19.
(2) (i) II , (ii) I , (iii) II

(4) (i) I , (ii) II , (iii) II
Which of the following carbanions is most stable ?

(1)
18.
(4)
(Q)
(2) Q > R > P > S
(R)
(3) P > R > Q > S
(S)
(4) S > R > Q > P
Which of the following carbocation would have greatest stability ?

(1)
(2)
(3)
(4)
22
Page # 22
20.
Which of the following cations is most stable ?
(1)
21.
(2)
(3)
(4)
In which of the following carbocation rearrangement takes place most rapidly ?

(1)
(2)
(3)
(4)
22.
How many number of sp2 hybridised nitrogen atoms in given structure.
(1) 3
(2) 5
(3) 2
23.
Write basicity order of following :

CH3CH2NH2
(P)
(1) P > S > R > Q
24.
(S)
(4) S > R > Q > P
(Q)
(2) R > S > Q > P
(R)
(3) Q > R > S > P
(S)
(4) S > R > Q > P
(Q)
(R)
(2) R > S > P > Q
(S)
(3) S > Q > P > R
(4) P > Q > R > S
Arrange the following in decreasing order of their acidic strength :
(P)
(1) P > Q > R > S
27.
(R)
(3) P > R > Q > S
Arrange the following in decreasing order of their acidic strength :
(P)
(1) S > P > Q > R
26.
(Q)
(2) R > S > Q > P
(CH3)2NH
The correct order of acidity in following compound is :
(P)
(1) P > S > R > Q
25.
(4) 4
(Q)
(R)
(2) Q > P > S > R
(S)
(3) S > R > Q > P
(4) R > S > P > Q
The correct order of acidic strength of the following :
(P)
(1) P > Q > R
(Q)
(2) R > P > Q
(R)
(3) Q > R > P
(4) P > R > Q
23
Page # 23
28.
Compare acidic strength of the following compound.
(P)
(1) P > Q > R
29.
(R)
(3) R > P > Q
(4) R > P > Q
Which of the following will not react with Na metal ?

(1)
30.
(Q)
(2) Q > P > R
(2)
(3)
(4)
Which of the following compound will not exhibit enolization ?

(1)
(2)
(3)
(4)
24
Page # 24
STEREOISOMERS
Instruction :
1.
2.
3.
4.

question.
________________________________________________________________________________

________________________________________________________________________________
1.
Types of geometrical isomerism shown at point X, Y and Z of the following compound respectively are :
X
(1) cis
(3) trans
2.
Y
trans
trans
Z
trans
cis
(2)
(3)
(4)
(2)
(3)
(4)
A natural occurring substance has the constitution shown below. How many isomers may have this
constitution ?
(1) 2
5.
X
(2) cis
(4) cis
Geometrical isomerism is possible in :

(1)
4.
Z
trans
cis
Which of the following compounds does not have any geometrical isomer ?
(1)
3.
Y
cis
cis
(2) 8
(3) 16
(4) 64
Which is correct option for given character ?
fn;sx;sy {k.k d sfy ;slgh fod Yi gS\

(1)
(2)
(water solubility)
(3) Maleic acid > Fumaric acid

(4)
6.
(Melting point)
(Dipole moment)
Which of following statement is incorrect for the pair of geometrical isomers :

(1) Known as diastereomers.
(2) Mirror image of each other.
(3) Trans isomer is generally more stable than cis isomers but not always.
(4) Geometrical isomers have same connectivity of atoms.
25
Page # 25
7.
Which of the following compounds having E-configuration

CH3O
(1)
OHC
CH 2Br
(2)
CH2 NO2
HSCH2
(3) CH CH C
CH
CH3
CH2CH2CH3
CH3
NO2
C
C=C=C=C
CH3
(4) H3 CH2C
CH2NH2
CH 2COOH
CH 2CONH 2
8.
Find out number of stereogenic centers present in following compound simvastatin.
(1) 5
9.
(2) 7
(3) 8
(4) 6
Number of functional groups present in the following compound is :
(1) 5
(2) 7
(3) 6
(4) 8
10.
The observed rotation of 2.0 g of a compound in 10 mL solution in a 25 cm long polarimeter tube is +

13.4. The specific rotation of compound is :
(1) + 30.2
(2) 26.8
(3) + 26.8
(4) + 40.2
11.
If a mixture of 2-bromobutane has enantiomeric excess of 50% of (+) -2-bromobutane, the stereo
isomeric composition of the mixture with respect to (+) and () enantiomer respectively is :
(1) 75% (+) and 25% ()
(2) 70% (+) and 30% ()
(3) 80% (+) and 20% ()
(4) 25% (+) and 75% ()
12.
Increasing order of stability among the three main conformations (i.e. eclipse, anti, gauche) of 3hydroxypropanoic acid is :
(1) eclipse, gauche, anti
(2) gauche, eclipse, anti
(3) eclipse, anti, gauche
(4) anti, gauche, esclipse
13.
Find the correct statements regarding following molecules.
II
(1) I, II and III are meso compounds

(3) I, III and IV are enantiomer
14.
IV
Which of the following compound is meso isomers ?

(1)
15.
III
(2) II and III are enantiomers
(4) III and IV are identical
(2)
(3)
(4)
The following compounds differ in respect of :
(1)Their chemical and physical properties

(2) The direction in which they rotate plane of polarized ligth
(3) Their interaction with molecule
(4) None of these
26
Page # 26
16.
Which of the following statements about the relationships of the structure (P), (Q) , (R) and (S) is
incorrect ?
(P)
(1) P and R are enantiomers
(3) Q and S are identical
17.
(Q)
(R)
(S)
(2) P and R are identical
(4) P and Q are enantiomers
Which of the following pairs of compounds are functional isomers ?

(1)
and
(3)
(2)
and
and
(4)
and
18.
Which of the following properties are different for (R)-2-bromo butane and (S)-2-bromobutane
(1) Boiling point
(2) Melting point
(3) Density
(4) Configuration
19.
Which of the following compounds do not have the plane of symmetry ?
(1)
20.
(2)
(3)
Which of the following statements are INCORRECT about these molecules ?
(1) I and II are a pair of enantiomers

(3) I and II are optically active compound
21.
23.
(2) 7
(3) 10
(4) 9
The number of alkynes possible with molecular formula C5H8 is :

(1) 2
(2) 3
(3) 4
(4) 5
Identify R isomer in the following compound :

COOH
(1) OH
(3)
CH 3
C2 H5
CH3
COOH
CH 3
OH
CH 3 (2)
H
24.
(2) III is metamer of I and II

(4) III is not stereoisomer of I and II
Calculate no. of stereogenic center in following molecule.
(1) 8
22.
(4)
H
H3 C
(4)
H H
H3C
HOOC
HO
CH3
Number of stereocenter and stereoisomer of the given compound :
(1) 1 and 2
(2) 2 and 4
(3) 3 and 8
(4) 3 and 6
27
Page # 27
25.
Metamer of compound B is :
B:
(1)
26.
(2)
(2) 2S , 3R
(2)
(3)
(4)
(b)
Select correct answer using the codes given :

(1) a and c
(2) a and b
(c)
(3) b and c
(4) a, b and c
Which of the following compound on reaction with NH2OH shows Geometrical isomerism.
O
(1)
30.
(4) 2S , 3S
Which of the following compounds is/are can be optically active ?

(a)
29.
(3) 2R , 3S
Which of the following compound is chiral ?
(1)
28.
(4)
In the structure the configurations at chiral centers are :
(1) 2R , 3R
27.
(3)
(2)
Me
Me
(3)
(4) All of these
Which of the following molecule can show geometrical isomerism ?

CH3
H
(1)
Cl
Cl
H
CH3
(2)
(3)
(4)
HOOC
COOH
28
Page # 28
ANSWER KEY
PHYSICAL CHEMISTRY
MOLE CONCEPT
1.
6.
11.
(3)
(4)
(1)
16.
21.
(3)
(3)
2.
7.
12.
(1)
(3)
(3)
3.
8.
13.
(1)
(1)
(3)
4.
9.
14.
(3)
(2)
(3)
5.
10.
15.
(3)
(3)
(2)
(3)
(2)
20.
25.
(3)
(1)
29.
34.
(3)
(3)
30.
35.
(1)
(3)
39.
44.
(3)
(3)
40.
45.
(2)
(1)
49.
54.
59.
64.
(3)
(4)
(3)
(3)
50.
55.
60.
65.
(3)
(4)
(1)
(2)
69.
(4)
70.
(3)
QUANTUM NUMBERS & ELECTORNIC CONFIGURATION

17.
22.
(3)
(4)
18.
23.
(3)
(4)
19.
24.
GASEOUS STATE (REAL GAS)

26.
31.
(4)
(4)
27.
32.
(2)
(2)
28.
33.
(1)
(4)
PERIODIC TABLE
36.
41.
(4)
(1)
37.
42.
(4)
(1)
38.
43.
(2)
(3)
CHEMICAL EQUILIBRIUM
46.
51.
56.
61.
(1)
(1)
(3)
(2)
47.
52.
57.
62.
(1)
(2)
(2)
(1)
48.
53.
58.
63.
(2)
(3)
(3)
(2)
IONIC EQUILIBRIUM-3
66.
(1)
67.
(2)
68.
(2)
CHEMICAL BONDING
71.
(2)
72.
(4)
73.
(4)
74.
(2)
75.
(2)
76.
81.
(1)
(2)
77.
82.
(1)
(3)
78.
83.
(3)
(4)
79.
84.
(3)
(3)
80.
85.
(3)
(3)
(1)
(1)
(3)
90.
95.
100.
(3)
(3)
(3)
104.
109.
114.
(1)
(4)
(3)
105.
110.
115.
(3)
(2)
(3)
119.
(3)
120.
(4)
124.
129.
(2)
(1)
125.
130.
(2)
(2)
SOLUTION & COLLIGATIVE PROPERTIES

86.
91.
96.
(4)
(4)
(2)
87.
92.
97.
(3)
(3)
(2)
88.
93.
98.
(4)
(2)
(1)
89.
94.
99.
COORDINATION COMPOUNDS
101.
106.
111.
(1)
(1)
(2)
102.
107.
112.
(3)
(2)
(2)
103.
108.
113.
(1)
(4)
(4)
s-BLOCK ELEMENTS
116.
(4)
117.
(2)
118.
(2)
SURFACE CHEMISTRY
121.
126.
(4)
(2)
122.
127.
(1)
(2)
123.
128.
(4)
(1)
29
Page # 29
ORGANIC CHEMISTRY
IUPAC NOMENCLATURE
1.
(3)
2.
(3)
3.
(2)
4.
(3)
5.
(4)
6.
(3)
7.
(2)
8.
(4)
9.
(3)
10.
(2)
11.
(2)
12.
(3)
13.
(4)
14.
(4)
15.
(2)
16.
(1)
17.
(1)
18.
(4)
19.
(1)
20.
(1)
21.
(2)
22.
(2)
23.
(3)
24.
(2)
25.
(3)
26.
(2)
27.
(3)
28.
(2)
29.
(3)
30.
(3)
ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

1.
(3)
2.
(2)
3.
(4)
4.
(1)
5.
(3)
6.
(1)
7.
(2)
8.
(3)
9.
(1)
10.
(2)
11.
(4)
12.
(4)
13.
(2)
14.
(3)
15.
(3)
16.
(3)
17.
(4)
18.
(4)
19.
(3)
20.
(3)
21.
(4)
22.
(1)
23.
(3)
24.
(1)
25.
(2)
26.
(4)
27.
(3)
28.
(2)
29.
(2)
30.
(3)
ELECTORNIC EFFECTS (GOC)

1.
(1)
2.
(3)
3.
(4)
4.
(2)
5.
(4)
6.
(2)
7.
(1)
8.
(2)
9.
(2)
10.
(2)
11.
(2)
12.
(3)
13.
(3)
14.
(4)
15.
(3)
16.
(3)
17.
(3)
18.
(3)
19.
(2)
20.
(3)
21.
(1)
22.
(2)
23.
(3)
24.
(3)
25.
(3)
26.
(1)
27.
(2)
28.
(2)
29.
(3)
30.
(3)
STEREOISOMERS
1.
(1)
2.
(4)
3.
(4)
4.
(4)
5.
(2)
6.
(2)
7.
(4)
8.
(2)
9.
(3)
10.
(3)
11.
(1)
12.
(3)
13.
(1)
14.
(2)
15.
(2)
16.
(1)
17.
(2)
18.
(4)
19.
(3)
20.
(1)
21.
(4)
22.
(2)
23.
(1)
24.
(3)
25.
(4)
26.
(2)
27.
(2)
28.
(3)
29.
(4)
30.
(3)
30
Page # 30

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Dear Students,

The test is of 1 hour duration.

Straight Objective Type

What is correct about methyl butane and 2-methyl pentane.

Which of the following has CnH2n general formula ?

Degree of unsaturation of the following compound is :

Number of 3 and 2 carbon atoms in iso-octane is

(1) Unsaturated homocyclic

(2) Aromatic heterocyclic

What is correct IUPAC name of

The correct IUPAC name of the following compound is :

word root changes by replacing the value of R. What will be R.

Select the strucuture with correct numbering in the chain :

Correct IUPAC name of the following compound is :

What is the structure of 4-Methylhex-5-en-3-thiol.

Structural formula of 3Ethynyl1,4pentanediol is :

(4) None of these

The IUPAC name of CH3CH2COCH(CH3)2 is :

IUPAC name of CH3CH2CHO is

IUPAC name of CH3 CH COCl is :

(2) 2-Methylbutanoyl chloride

The IUPAC name of CH3 C CH2 CONH2 is :

Structure of the 2,2-Dimethylbutane dioic acid :

The IUPAC name of

(2) 4-Cyano-2-chlorocyclohex-5-ene carboxamide

What is the correct IUPAC name for CH3 CH CH CH CH2 C N

The IUPAC name of

(1) Ethyl 3-chlorocarbonyl-2, 3-dimethylpropanoate

(1) Ethyl 3-Oxobutanoate

What is the correct IUPAC name for

(2) Ethyl 3-Formylbutanoate

(2) Cyclopentane carboxylic anhydride

Which is the correct structure of compound Propyl cyclobutane carboxylate

The IUPAC name of

(1) 3-Hydroxy-2-oxobutanedioic anhydride

What is the IUPAC name of

Which is the correct IUPAC name of the following compound :

The correct IUPAC name of the compound :

Which has correct IUPAC numbering :

(4) None of these

OBJECTIVE RESPONSE SHEET (ORS)

ISOMERISM STRUCTURAL & PRACTICAL ORGANIC CHEMISTRY

The test is of 1 hour duration.

Straight Objective Type

(2) Length of parent or side chain changed

The structures (CH3)2CHCH2Br and CH3(CH2)3Br shows :

Which of the following are chain isomer :

(2) 1,1-Dichloroethane and 1,2-Dichloroethane

1,1-Dimethylcyclopropane and 1,2-Dimethylcyclopropane are :

Diethylether and Methylpropyl ether are

(2) Functional isomers

The isomerism exhibited by alkyl cyanide and alkyl isocyanide is :

Methyl propanoate and ethyl ethanoate are :

(3) Chain isomers

Which of the following pairs are not isomeric compounds :

The number of possible alcoholic isomers for C4H10O are :

How many structural isomeric cycloalkene can give methylcyclobutane on hydrogenation :

(2) 2-Methyl butane

(3) 3-Methyl pentane

(4) 3-Ethyl pentane

The total number of monochloro products (structural) formed.

A dichloroderivative of propane X (C3H6Cl2) gives three types of

The alkene which on ozonolysis yields acetone is