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Explain why boiling point of alkanes increase descending the homologous series 3. Write the equation of combustion of pentane 1. Write the general formula of alkenes. 2. Explain why boiling point of alkenes increase descending the homologous series 3. Write the equation of combustion of pentene
B. 2.0
1. Define the carbon compound. 2. What is an organic compound? 3. List 3 examples of organic compound and 3 examples of nonorganic compound.
Alkenes
2.3
1. Define isomerism 2. Draw structural formula of pentane isomers 3. Draw structural formula of pentene isomers
2.4
1. Define polymer. 2. Explain the coagulation process of latex when it is added with formic acid. 2. Explain why vulcanized rubber is stronger than natural rubber.
Isomerism
Natural2.9 rubber
2.8 2.7
CARBON COMPOUND
2.5 2.6
1. Define the homologous series of alcohol 2. Write the chemical equation of combustion of propanol. 3. Describe a laboratory experiment to produce alcohol
Fat Ester
1. Define saturated fat and unsaturated fat. 2. Stated the difference between saturated fat and unsaturated fat. 3. What is the type of reaction that changes unsaturated fat to saturated fat?
Alcohol
Carboxylic acid
1. Define an ester. 2. Write the general formula of ester. 3. Describe an experiment to produce etil methanoic.
1. Define carboxylic acid. 2. Write the equation involved in the production of carboxylic acid from propanol. 3. Explain why methanoic acid cannot conduct an electric
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B. 2.1
Type of compound
Saturated hydrocarbon s Unsaturated hydrocarbon s
Inorganic compound
Hydrocarbon
Compound consists of carbon and did not come from the organism (animal or plant)
Examples; .
Compounds contain carbon and come from organism (living thing). Animal or plants
Examples: Carbonate of metal, Bicarbonate of metal, carbon dioxide, carbon monoxide, etc
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B. 2.2 n 1 2 3 4 5 10 Molecular formula CH4 C2H6 .. C4H10 Name methane ethane propane butane pentane 1. Non soluble in water 2. Non conductor of electricity .. . Structural formula Members Methane Ethane Propane Butane Pentane Hexane Size of molecule Small Melting point Low Density Low State Gas Gas Gas Gas Liquid Liquid
Increase
Increase
Increase
Chemical properties
Sun light CH4 + Cl2 CH3Cl + Cl2 CH2Cl2 + .. Cl2 CH3Cl + HCl CH2Cl2 + HCl .. +
Combustion
+ .
+ .
.. + .
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n 1 2 3 4 5 10
Structural Formula
B. 2.3 Members Ethene Propene Butene Pentene Hexene Heptene Molecul ar size Melting point Low Density Low State Gas Gas Gas Gas Liquid Liquid
Increase
Increase
increase
General formula
CnH2n n = 2.3,4,
Test to differentiate alkenes using bromine water /Acidic potassium magnate (VII). Experiment.
Polymerization of alkene
Reaction 1. Addition reaction (a) Addition of hydrogen (hydrogenation) (b) Addition of bromine (c) Addition of steam (d) Oxidation 2. Combustion Combustion in the air (oxygen) C2H4 C3H6 C2H4 C2H4 + H2
Examples
C2H6
+ Br2 C3H6Br2 H3PO4, 300oC, 60 atm. + H2O C2H5OH acidic KMnO4 + H2O + [O] C2H6O2 2CO2 + 2H2O . +
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Compound with the same molecular formula but different structural formula
IUPAC naming
Instruction: 1. Specify the number of carbon atom in the longest continuous carbon chain. 2. Numbering carbon atoms with 1,2,3, starting near functional group /and branch.. 3. Branch names -CH3 , methyl -CH2CH3, ethyl
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B.2.5 Misuse of the alcohol and the effect Carbon compound contained hydroxyl functional group, OH
CH3OH C2H5OH C3H7OH C4H9OH methanol ethanol propanol butanol
Fuel, solvent, Medical aspect, Cosmetic aspect.. Definition of alcohol Usage of alcohol Chemical properties of alcohol
Chemical properties of the ethanol 1. Combustion C2H5OH + O2 CO2 + H2O 2. Oxidation 2[O] C2H5OH CH3COOH + H2O 3. Dehydration Alumina C2H5OH C2H4 + H2O
Formula Am:
CnH2n+ 1OH
n = 1,2,3,
Naming
Ethanol
Preparation of ethanol
Cotton + Ethanol
Alumina Ethene
Heat Water
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methanoic acid ethanoic acid propanoic acid butanoic acid pentanoic acid
Naming
CARBOXYLIC ACID
1.
salt + water CH3COONa + H2O salt + water + carbon dioxide 2CH3COOK + H2O + CO2 salt + hydrogen (CH3COO)2Mg + H2 esther + water ethyl ethanoat + water CH3COOC2H5 + H2O
2. Ethanoic acid + carbonate 2CH3COOH + K2CO3 3. Ethanoic acid + metal 2CH3COOH + Mg 4. Ethanoic acid + alcohol Ethanoic + ethanol CH3COOH + C2H5OH
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m 2 1 3
Molecular formula
Name of ester
0 1 2
General formula of ester Molecular formula and the name of ester Homologous series of ester
A group of homologous series with functional group of carboxyl, -COO-
Diagram?
Preparation
Definition
ESTER
Ethyl ethanoate etanoat Physical properties
The ester daily life usage Natural source of the ester To predict the formation of the ester
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B. 5.3
The fat molecule that built of only singular covalent bond between carbon atom in the molecules.
The fat molecules that built of multiple bond between carbon atom in molecules.
Definition
Saturated fat
Contoh:
Comparison
Type of fat
Fat Higher melting point (more than 20oC) Solid at room temperature Found in animals & human Oil Lower melting point (less than 20oC) Liquid at room temperature Found in plants & fish
Production of margerine: Hydrogenation process of unsaturated fat (palm oil) Ni - C = C - + H2 -C C H H single bond
Double bond
Taken too much saturated fat may cause: 1. Obesity 2. Hardness of an artery 3. High blood pressure 4. Heart disease 5. Stroke
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B. 5.4 R O R O R O R O + nH2O n
N - CH C - N - CH C H H protein (polymer)
Protein
Giant molecule with long chain (macromolecule) consist of repeated sequence small molecules (micro molecule) called monomer found in an animal & plant
Carbohydrate
NATURAL RUBBER
Natural rubber
Experiment
Vulcanization of rubber.
Experiment: 1. Vulcanization of natural rubber. 2. Comparison of properties between natural and vulcanized rubber
Diagram
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Latex is a colloid. It is a mixture of rubber particles and water. A rubber particle is made up of negatively charged protein membrane surrounds many rubber molecules. The negative charges are preventing the collision between molecules. When an acid is added to the latex, H+ from an acid is neutralized the negative charge at protein membrane to allow the collision between the rubber particles. The protein membrane breaks, and then the rubber molecules are free to clump together. Latex has coagulated
A. Analysing Alkanes 1. 2.. The general formula of alkanes are : ______________________________ Complete the table by writing the name , molecular formula and structural formula of alkanes. Number of Carbon atom per molecule 1 2 3 Molecular formula Name Structural formula
3. 4.
All alkanes _______________________ in water because they are _____________________ compounds. As the number of carbon atoms increases, a) b) the size of the molecule _____________________________ the boiling and melting point ___________________ because _____________________ ________________________________________________________________________ c) the amount of soot produced ______________________ because ___________________ ________________________________________________________________________
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5.
Complete combustion of alkanes produces carbon dioxide and water only. a) b) C2H6 + O2 O2
C5H12 +
6.
Alkanes undergo substitution reaction with halogrns in the presence of ultra violet light. CH4 + Cl2
B. Analysing Alkenes 1. 2 The general formula for alkenes is __________________________________________ Complete the table below by writing the names, molecular formula and structural formula . Number of Carbon atom per molecule 2 3
Molecular formula
Name
Structural formula
3.
Alkenes undergo addition reaction due to the presence of the double bonds. a) Hydrogenation : C3H6 + H2
Br-Br
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d)
Hydration :
4 . Polimerization : The process whereby small molecules are joined together to form large molecules. 5. Compare and contrast between alkanes and alkenes. Alkanes General Formula Bonding Combustion Physical properties Alkenes
Chemical properties
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II C2H5Cl
Ethanea C2H6
Ethene C2H4 X
VII
VIII
IX
III V 1,2 dibromoethane C2H4Br2 Write the balanced equation for the processes labeled above. I II III IV V VI VII VIII IX X
Ethanol C2H5OH
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II C4H9Cl
Butane C4H10
Butene C4H8 X
VII
III V 1,2 dibromobutane C4H8Br2 Write the balanced equation for the processes labeled above.
Butanol C4H9OH
I II III IV V
VI VII VIII IX X
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II C3H7Cl
Propane C3H8
Propena C3H6 X
VII
Propanol C3H7OH
Write the balanced equation for the processes labeled above. I II III IV V VI VII VIII IX X
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Objective Questions 1. What is the functional group for alcohol? A. Carboxylate B. C. Hydroxide D. Diol Hydroxyl
2.
Which process is involved in changing propene into propanol ? A. Oxidation B. Hydration C. Fermentation D. Combustion The equation below representsthe reaction in the industrial preparation of ethanol. X + H2O CH3CH2OH What is X ? A. C. Ethene Glucose B. Ethane D. Maltose
3.
4.
What are the products of the reaction between propanoic acid and sodium hydroxide ? A. water and carbon dioxide B. Ethyl ethanoate and sodium ethanoate C. Water and ethyl ethanoate D. Sodium ethanoate and water. Which of the following is not true about the difference between saturated fats and unsaturated fats A B C D Characteristic Melting Point Source Cholesterol content Physical state at room temperature Saturated Fats Low Animals High Solid Unsaturated fats High Plants Low Liquid
5.
6.
Coagulation of latex takes place by adding . I formic acid II nitric acid III aqueous ammonia IV hydrochloric acid A. C. I and II only I , II and III only B. II and III only D. I , II , III and IV.
7.
Vulcanised rubber is harder because.. A. the polymers of rubber are arranged orderly B. the polymers of rubber combine to form longer chains C. the polymers are held by sulphur linkage D. the polymers became neutral. Structural Questions 1. The figure below shows the set up of apparatus for the preparation of ethyl ethanoate from the reaction of etanol with ethanoic acid.
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Liebig condenser
Water bath
Heat
a) Y
On the Liebig condenser above, mark X to indicate where water flows in and where water flows out. [ 1 mark]
b)
Why is the mixture heated using a water bath ? _________________________________________________________________ _________________________________________________________________ _________________________________________________________________
[2 marks] c) (i) Name the reaction for the preparation of ethyl ethanoate.
___________________________________________________________ [1 mark] (ii) Write the chemical equation for the reaction in c (i) __________________________________________________________ _ [1 mark]
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d)
The experiment is reapeated by replacing ethanol with propanol. (i) Name the ester formed . __________________________________________________________ ___ [1 mark] (ii) State one physical property of the ester. __________________________________________________________ ___ [1 mark]
.e) ethanoic
The flow chart below shows the conversin of etanol to ethene and etanol to acid.
Process I Process II
Based on the flow chart below shows the conversin of etanol of ethene and etanol to ethanoic acid. (i) Process I
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[ 1 mark ]
2. Propanol reacts with acidified potassium manganate(VII) solution to produce an organic
compound X.
Propanol Acidified potassium Manganate (VII) Solution Organic Compound X a) (i) the organic compound X. Name the reaction for changing propanol to Organic Compound X
_______________________________________________________________ [1 mark] (ii) Name the organic compound X. _______________________________________________________________ b) (i) [1 mark] Name a reagent which can be used to derive oranic compound Y when propanol and X react with one another. ______________________________________________________________ [1 mark] (ii) Name the homologous series to which compound Y belongs to. _______________________________________________________________ [1 mark] (iii) Draw the structural formula of compound Y.
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Figure 2.1 shows changes of a carbon compound involving a series of reactions. Propane +H2 Heat Alkene Heat Alumina Propanol
Potassium dichromate(IV) in acid Propanoic acid Figure 2.1 (a) (b) Draw the structural formulae of two propanol isomers. Name both isomers. The information below is regarding alkene Y: Carbon 85.7% Hydrogen 14.3% Relative molecular mass = 42 Relative atomic mass of H = 1 and C = 12
[ 4 marks ]
Based on the information of the alkene Y: (i) (ii) (iii) (iv) Determine the molecular formula Draw the structural formula Name the alkene Write the general formula for its homologous series [ 8 marks ]
(c )
(i)
Table 2.2 shows the results of a test to differentiate between alkene Y and propane. Procedure Observations
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Bromine water is added to alkene Y Bromine water is added to propane Table 2.2
Explain why there is difference in these observations. [ 4 marks ] (ii) Table 2.3 shows results of latex coagulation. Procedure Propanoic acid is added to latex Latex is left under natural conditions Table 2.3 Explain why there is a difference in these observations. [ 4 marks ] Observations Latex coagulates immediately Latex coagulates slowly
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