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c
ct
#v
G
) V
v
G
"!c
G
VP#V) (c
G
t
IG
)
#V) (c
G
t
R
)#j
G
c
G
g#f
G
, (i"L, G).
(4)
In Eq. (4), P is the pressure, v
G
is the velocity vector and
t
IG
the viscous stress tensor of phase i. f
G
represents the
interfacial forces of phase i (such as f
%
"!f
*
) and t
R
is
the Reynolds stress tensor. A simpli"ed relation can be
obtained by summing the general momentum balance
equation for each phase and by neglecting the viscous
and the inertial e!ects in the gas phase. If the #ow is fully
established, only the axial pressure evolution and the
radial evolution of the shear stress have to be taken into
account. The following expression is "nally obtained:
!
dP
dz
#
1
r
dt
dr
#j
*
(1!c
%
)g+0, (5)
where t is de"ned as
t"t
R
#c
*
t
I*
(with t
R
"j
*
v'
*
v'
*
). (6)
If the radial evolution of the gas hold-up can be modelled
using Eq. (1) that leads to
t"
j
*
gR
2
!dP
j
*
g dz
!1#c
%
,#
2c
%
,
m
(1!K)
. (7)
As the axial pressure drop can be simply related to the
wall shear stress t
U
using "1, t
U
is expressed as
t
U
"
j
*
gR
2
!1
j
*
g
dP
dz
!1#c
%
,
. (8)
Eqs. (6) and (7) lead to the following relation:
t"t
U
#
j
*
gR
2
2c
%
,
m
(1!K). (9)
The existence of a thin laminar layer (z))1) near the
wall is generally assumed. As a "rst approximation, the
C. Vial et al. / Chemical Engineering Science 56 (2001) 1085}1093 1089
Fig. 10. Theoretical velocity pro"le in a bubble column.
Table 1
Turbulence models compared in this work
Turbulence model (model number and equation) Eq. no.
1. v
R
"k' (12)
2. v
R
"k'c
%
(1!c
%
) (13)
3. v
R
"
k'R
A
6
t
N
j
*
(1!`)(1#2`) (14)
(Menzel, 1990)
4. v
R
"k'(g;
%
)`D"`
A
(1!`)"` (15)
(Burns & Rice, 1997)
5. l
K
"maxby
k'
cG
cG,
; R(0.14!0.08`!0.06")
(16)
(Geary & Rice, 1992)
#ow may be represented using the structure described in
Fig. 10 which assumes that the value of v
*
is minimal
when "z. Consequently, t"0 at this point and the
"nal expressions obtained are
t
U
"!
j
*
gR
2
2c
%
,
m
(1!zK), (10)
t"
j
*
gR
2
2c
%
,
m
(zK!K). (11)
The exponent m and the average void fraction c
%
, can
be estimated using the previous results. Eqs. (10) and (11)
may be used to predict the liquid velocity pro"le if an
adequate model is chosen to represent turbulence. Many
models have been proposed in the literature. Models
based on a turbulent viscosity v
R
can be distinguished
from those based on a mixing length l
K
. The turbulent
viscosity v
R
is sometimes assumed to be constant on the
whole section of the column (Ueyama & Miyauchi, 1979),
but it may be assumed to have a behaviour qualitatively
similar to that of a pure liquid (Menzel, In der Weide,
Staudacher, Wein & Onken, 1990, Eq. (14)). Another
possibility is to consider that v
R
is closely linked to the gas
hold-up. A last class of turbulence models is based on the
fact that v
R
is related to a characteristic length (most often
the bubble or the column diameter) and to the power
input brought by the gas: g;
%
(Burns and Rice, 1997,
Eq. (15)). Turbulence models based on a mixing length
are less frequent. Rice and Geary (1990) have proposed
a formulation which assumes that turbulence is mainly
induced by bubble wakes. Then, Geary and Rice (1992)
have improved this model and have considered that
classical turbulence competes with bubble-induced tur-
bulence (Eq. (16)).
Among these models, "ve belonging to the di!erent
classes have been selected and are reported in Table 1. In
this table, k' is a parameter which does not depend
directly on ;
%
, but may depend on the prevailing #ow
regime.
The theoretical velocity pro"les can then be calculated
using Eqs. (10) and (11), a model of Table 1 and the
following set of equations for models 1}4:
t"!
c
*
j
*
#j
R
R
dv
*
d
(0))z), (17)
t"!
c
*
j
*
R
dv
*
d
(z))1), (18)
or the following relations for model 5
t"!
c
*
j
*
R
dv
*
d
#j
*
l`
K
R`
dv
*
d
`
(0))z), (19)
t"!
c
*
j
*
R
dv
*
d
(z))1). (20)
Two additional conditions are necessary:
v
*
("z)"v
*
("z>), (21)
v
*
("1)"0. (22)
In the previous equations, the two unknown parameters
to be estimated are t
U
(or z) and k'. They can be obtained
using the experimental results obtained in Section 3.
The experimental velocity pro"les have to be "tted with
the theoretical pro"les, optimising the values of z and k'.
The "ve models of turbulence proposed in Table 1 have
been applied successively to the results obtained with the
three spargers. The evolution of k' is used to test the
consistency of the models, as k' should depend essentially
on the hydrodynamic regime. Once a consistent model is
determined, t
U
and the radial evolution of t can be
obtained.
4.2. Results
Model 1 is shown to be inadequate because the turbu-
lent viscosity presents a radial evolution. Indeed, nega-
tive velocity values near the wall are underestimated by
the calculations (Fig. 11). Models 2 and 3 provide a better
"tting of experiments, but the evolution of k' is not
1090 C. Vial et al. / Chemical Engineering Science 56 (2001) 1085}1093
Fig. 11. Comparison of experiments and theoretical velocity pro"les.
Fig. 12. Evolution of the optimized averaged mixing length l
K
, with
;
%
and the three spargers.
Fig. 13. Evolution of t
U
with ;
%
for the three spargers.
correct. Model 4 is consistent with the results obtained
with the single-ori"ce nozzle if k'"0.16$0.01, but not
with the other distributors. Finally, only model 5 is
consistent for the three spargers. The following values of
k' are obtained: k'"0.0059$0.0005 in the transition
region (multiple-ori"ce sparger) and k'"0.012$0.001
in the heterogeneous regime (single-ori"ce nozzle).
The results are in agreement with the theoretical analy-
sis of Geary and Rice (1992) which is based on the
assumption that k' is proportional to the size of the
bubble wake which depends on the bubble size and
morphology. Consequently, the rise in k' value is due to
an increase in bubble wake volume which comes from the
presence of larger bubbles. With our experimental set-up
of 10 cm in diameter, only bubble-induced turbulence
prevails and Eq. (16) can be simpli"ed as
l
K
"k'
c
%
c
%
,
. (23)
As a consequence, the parameter k' is equal to l
K
,,
the averaged mixing length on the cross-sectional area.
The evolution of l
K
, with ;
%
is reported in Fig. 12
for the three spargers. This behaviour is in accordance
with the experimental results (Figs. 7 and 8) as the values
of l
K
, for the porous plate are close to those of the
multiple-ori"ce sparger when ;
%
is low and near to those
of the single-ori"ce nozzle when ;
%
is high. l
K
, values
in the heterogeneous regime are at least twice as high as
in the transition region. A slight increase in l
K
, with
;
%
is also observed with the multiple-ori"ce sparger.
This is not contradictory as the bubble size may increase
with ;
%
even if no bubbles larger than 1 cm are reported,
contrary to what is observed with the single-ori"ce
nozzle.
Optimised values of z con"rm that the boundary layer
is thin and z is always higher than 0.99. The evolution of
the wall shear stress t
U
with ;
%
is deduced from that of
z using Eq. (10) and is reported in Fig. 13. Fig. 13
shows that the predicted time-averaged wall shear
stress is higher in the transition region than in the hetero-
geneous regime. This surprising result is simply due to
the lower liquid velocity values near the wall when het-
erogeneous regime prevails (Fig. 7). Consequently, the
in#uence of #ow transition with the three spargers agrees
with the previous results on liquid velocity and mixing
length.
The radial evolution of the shear stress t is reported in
Fig. 14 for the column equipped with the porous plate.
Similar trends are obtained with the other distributors:
t peaks when "
"
, which is between 0.65 and 0.8,
depending on ;
%
. It appears that
"
tends to decrease as
;
%
increases. Fig. 14 shows clearly that t
U
is of little
in#uence on t, except in the wall region. As a "rst approx-
imation, t
U
can be neglected in Eq. (9), which corre-
sponds to z+1 in Eq. (11).
The order of magnitude of the shear stress can be
compared to the axial normal stress. As this quantity
presents an important radial evolution (Fig. 14), we
C. Vial et al. / Chemical Engineering Science 56 (2001) 1085}1093 1091
Fig. 14. Radial evolution of the Reynolds shear stress with ;
%
for the
columns equipped with the porous plate.
Fig. 15. Evolution of t
U
with ;
%
for the three spargers.
suggest comparing the following criterion:
}
`
"Min[v'`
*
/v'
*
) v'
*
]. (24)
The evolution of
}
`
with ;
%
for the three spargers is
reported in Fig. 15. The shear stress values are shown to
be at least one order of magnitude lower than the axial
normal stress. This agrees with the experimental results
of Mudde, Lee, Reese and Fan (1997b) who have found
similar ratio using PIV, even if their work is limited to
low gas #ow rate in a 2-D bubble column.
Finally, these results show clearly the strong aniso-
tropy of the stress tensor in bubble columns. It explains
why turbulence models proposed for pure liquid or gas
#ows, such as the k}c model, do not represent adequately
the dispersion in bubble columns except at very low gas
input (Sokolichin & Eigenberger, 1999). As a conclusion,
a model has been proposed, which is consistent with the
experimental results obtained with the three spargers.
This model is based on the assumption of a bubble-
induced turbulence due to bubble wakes and uses a mix-
ing length proportional to the local gas hold-up. The
radial pro"les of t and the evolutions of t
U
and l
K
, have
been shown to con"rm the experimental results.
5. Summary and conclusions
In this work, the time-averaged liquid mean and rms
velocity pro"les have been measured using LDA in
a bubble column equipped with three di!erent spargers
up to gas hold-up values of 15}20%. Their evolution
with ;
%
has been related to gas distribution (uniform or
non-uniform distribution and start-up procedure for the
porous plate) and hydrodynamic regimes (homogeneous
regime, transition region and heterogeneous regime). The
well-known liquid circulation pattern has been reported
in the transition region, but this structure is destroyed
when large bubbles appear at the beginning of the estab-
lished heterogeneous regime. A simple model based on
momentum balance equations can be used to evaluate
the Reynolds shear stress if an adequate turbulence for-
mulation is chosen. Five models have been selected in the
literature and the model of Geary and Rice (1992) has
been shown to be consistent with the results obtained
with the three spargers. The evolution of t pro"les and of
t
U
with ;
%
has been analysed and the strong anisotropy
of turbulence has been outlined. Finally, a precise de-
scription of the local hydrodynamics of the liquid phase
has been obtained and its evolution with ;
%
has been
explained. We hope that this study will be useful for
further works in order to propose better models to rep-
resent turbulence in bubble columns, which can be imple-
mented in CFD codes.
Notation
g gravitational constant, m/s`
k' parameter used in Table 1
I
!
centreline turbulence intensity
l
K
mixing length, m
l
K
, cross-sectional averaged mixing length, m
m exponent de"ned in Eq. (1)
P static pressure, Pa
r radial coordinate
R column radius, m
}
`
ratio de"ned in Eq. (24)
;
%
super"cial gas velocity, m/s
v
!
centreline liquid velocity, m/s
v velocity, m/s
v velocity vector, m/s
v' #uctuating velocity component, m/s
z axial coordinate
1092 C. Vial et al. / Chemical Engineering Science 56 (2001) 1085}1093
Greek letters
c
%
local gas hold-up
c
%
, volume-averaged gas hold-up
z boundary layer thickness, m
j viscosity, Pa s
j
R
turbulent viscosity, Pa s
v molecular kinematic viscosity, m`/s
v
R
turbulent kinematic viscosity, m`/s
j density, kg/m`
o rms velocity, m/s
t shear stress, Pa
t
I
viscous stress tensor
t
R
turbulent stress tensor
t
U
wall shear stress, Pa
dimensionless radius
Subscripts and other symbols
ax axial
rad radial
G gas phase
liquid phase
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