THE GREAT VISION SECONDARY SCHOOL DAR-ES-SALAAM MBAGALA PRE- NATIONAL EXAMINATION CHEMISTRY- FORM FOUR 24TH SEPT

2011
TIME 3 HOURS INSTRUCTIONS

1. 2. 3. 4. 5.

This paper consist of sections A,B and C. Answer all questions in section A&B and only (2) questions from section C. Read the instruction carefully under each section before attempt any question Cellular phones and electronic calculator are not allowed in examination room. The following constants may be used where necessary. C=12, Fe=56, H=1, O=16, Na=23, 1GMV=22.4dm3 at stp SECTION A (20 MARKS) (Answer all questions)

1. For each of the items [i-x] choose the correct answer from among the given alternatives and its letter besides the items number. i] Zinc oxide, aluminum oxide and lead [ii] oxide forms a class of oxides known as a] neutral oxides b] amphitricha oxide] basic oxide d] acidic oxide

ii] The maximum number of structural isomers which can be written from the molecular formula c5h8 is a] 2 b] 4 c] 3 d] 6

iii] If 6.16g of a divalent metal is reacts completely with 100cm3 of 2.2m hcl solution the relative atomic mass of metal b is a] 54 b] 26 c] 64 d] 56

iv] The method of separating a mixture of two liquids and the dissolved sample in it by titration is known as a] decantation b] evaporation c] solvent extraction d] filtration v] Which soil sample is likely to contain the greatest amount of nitrogen? a] clay b] sand c] gravel d] loam

vi] The morality of 5.3g Na2C03 in 100ml of solution is a] 0.2m b] 0.5m c] 0.05m d] 0.05m

vii] The oxidation state of chlorine in sodium chlorate NaClO3 is a] -1 b] +2 c] +5 d] +3

viii] Mixture of a liquid and insoluble powder which has not settled down is called a] solute b] suspension c] solvent d] residue. Ix] Which of the following metal is most dilute? a] Aluminum b] Silver c] copper d] Tin

x] The compound CH3CH2CLis named as a] Carbon dichloride d] Ethyl chloride b] Methlylchloride c] Methyhloride

2. The items in list A with the responses in list B by writing the letter of the correct response beside the item number. LIST A i. Nitrogen dioxide ii. Urea iii. Polymerization iv. Hypothesis v. Class C fire vi. Detergents Vii. Ionic bond viii. Desiccators ix. Air x. Flocculation LIST B A] Keeps substance constantly dry B] Sodium salt of fatty acids C] Is formed between two oppositely charged ions D] Artificial fertilizers E] Binding together of soil particles F] Brown-ring test G] A gases mixture H] Burning materials is in liquefied state I] Combination of monomers J] A tentative statement to the observed problem

SECTION B (60 MARKS) (Answer all questions) 3 (a). Define the following terms i. Standard solution ii.Equivalent point of titration iii. Bassist of an acid

(b). Industrial sulphuric acid is usually labeled as containing 98% of acid and having density of 1.84g/Cm3 i. Calculate the morality of the acid ii. Calculate the volume of the acid required to prepare 2dm3 of 0.5m sulphuric acid. (C) .Explain with the aid of equation when sulphuric acid reacts with i. 0.5m sodium hydroxide ii. Sugar cane

4 (a). Explain with the aid of chemical equation and draw its energy profile i. Endothermic reaction.
and their applications. 5. (a) If 0.5g of hydrogen gas are exploited in air, what is the mass of water formed? (b) i. 2FeCl2 (aq) + H2S (aq) calculate the mass of iron 2FeCl2 + S(s) from above equations

ii. Exothermic reaction.

(b) From the energy profile diagram drawn above explain all labeled symbols

ii. Chloride formed by excess of the hydrogen sulphide gas on a solution containing 54.0g of iron (III) Chloride.

(C) Explain what will happen when; i. Nitric acid is left in sun light for long time. ii. Nitric acid reacts with aluminum foil

6. Identify the substance by using the following information write equation where necessary i. A small piece of sodium metal was placed over the surface of water containing some phenolphthalein indicator ii. A tightly closed bottle containing a color less sample of concentrated nitric acid was left in the sun for a long time. iii what will happen when aluminum chloride is dissolved in water. iv. A metal which burns in steam but does not react with cold water v. Sodium nitrate [NaNO3] is strongly heated. 7 (a). Explain the triangular cycle of fire (b) Explain why water is not used as an extinguisher in flammable flames eg petroleum products (C) How marble chips [calcium carbonates] it is used in fighter fighting. 8. Complete and balance the following equations i. N02 + SO2 +H2O ii. NH3 +H2SO4 iii. COOH + KMnO4 iv. Li2CO3 v. MnO2 + HCl

SECTION C (20 MARKS) [Answer only two (2) questions] 9 (a). Explains the following properties of periodic table i. Electro negativity. ii. Electropositive iii.Ionization.

(b). Periodic table it is divided into four parts explain each part with the aid of example whenever necessary 10(a). Define the following terms i. Homologous series ii. Functional group iii. Organic reaction.

(b) Two beakers A&B one contains alkenes and the other alkenes they have lost their lablle give the chemical test to distinguish between alkenes and alkanes. (C). Complete the balance the following reaction word equation i. ii. iii. Ethyne react with silver amonical hydroxide Carbon dioxide react with water Ethanol react with sodium metal

11(a) .What is pollution? (b) i. Explain the effect of over concentrated level of carbon dioxide in the atmosphere [at least 2effects] ii. With equation explain the effects of the following gases to ozone a}.Sulphur dioxide gas gas b}.Nitrogen monoxide c}.Chlorofluorocarbon

iii. Explain three effects of destroying the ozone layer.