CBSE UNIT TEST PAPER-02 CLASS - XII (CHEMISTRY) Time : 1.5 Hours M.M.

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In corundum Oxide ions are arranged in hexagonal close packing and Aluminium ions occupy two-third of the Octahedral voids. What is the formula of corundum? Differentiate between Molarity and Molality. (1) Silver forms fcc unit cell and X-ray studies of its crystals show that the nearest neighbour distance is 288.96pm Calculate the density of silver (Atomic mass = 107.9u) Zinc Oxide is white but it turns yellow on heating, Explain. (2) When a non volatile solute is added to a solvent, the B. pt of solution gets elevated. Explain with the help of diagram. (2) the depression in Freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly. (2) Silver is electrolysed/electrodeposited on a metallic vessel of total surface area 900cm2 by using a current of 0.5 amp for two hours. Calculate the thickness of silver deposited. Density of silver=10.5g/cm3 (Atomic mass of silver =108 amu, F = 96500Cmol-1) The following reaction was studied in a closed vessel. 2N2O5 4NO2(g)+O2(g) It was found that the concentration of NO2 increases by 2.0x10-2molL-1 in five seconds. Calculate. (3) i. the rate of reaction ii. the rate of change of concentration of N2O5. The emf of the following cell is found to be 0.20V at 298K Cd/Cd2+ (g) ll Ni2+ (2.0M)/Ni What is the molar concentration of Cd2+ ions in the solution of (Eo Cd2+/Cd=-0.40V,EoNi2+/Ni=-0.25Y (3)

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10. A colloidal solution of Agl is prepared by two different methods given below i. What is the charge on Agl colloidal particles in the two tubes (A) and (B)? ii. Give reason for the origin of charge. (3)

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11. The time required for 10% completion of a first order reaction at 298K is equal to that required for its 25% completion at 308K. If the pre-exponential factor for the reaction is 3.56x109s-1 calculate its rate constant at 318K and also the energy of activation. (3) 12 a. Differenciate b/w order and molecularity of a reaction. b. The half life period of a first order reaction is 60 minutes. What percentage will be left after 240 minutes? (5) 13 a. Write the cell reaction involved in i. fuel Cell ii. Mercury cell iii. Dry Cell b. In each of the following pairs which will allow greater conduction of electricity and why? i. Silver wire at 20oC, same silver wire at 50oC ii. NaCl solution at 20o, same NaCl solution at 50o C 14. a. 1M NaNO3(aq) solution having density 1.1g/cm3 calculate its freezing point and boiling point of solution. (Kb=0.52K/m,Kf = 1.86v/m). B.pt of water = 373.15K F.pt of water = 273.15k b. Derive the relationship between relative lowering of vapour pressure and mole fraction of the volatile liquid (5)

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