Information of Sodium carboxymethyl cellulose,and Method of use Monochloroacetic acid and the etherification reaction between alkali cellulose

is a complex chemical reactions, including monochloroacetic acid and alkali neutralization reaction, sodium monochloro acetic acid and alkali cellulose nucleophilic substitution reaction, the former is exothermic reaction, which requires energy to make sodium monochloro acetic acid dissociation of high-energy ions react with alkali cellulose ether. So, the general requirement is high etherification. Temperature control must be from chemical equilibrium, chemical kinetics and consideration of special structure of cellulose fiber, can be divided into etherification early, middle and late into consideration. Early etherification, mainly etherifying agent (monochloroacetic acid) and free alkali neutralization reaction and dispersion in sodium carboxymethyl cellulose, seepage, temperature, reaction system in this stage the temperature is low, the time should be longer for the penetration and dispersed evenly, for alkali cellulose affinity is greater than the affinity of a chloride (sodium) on cellulose acetate, etherifying agent for the spread of the base fine, if the high reaction temperature, etherification reaction speed too fast, on the one hand, cause local reactions, on the one hand, on the fiber surface generated by the CMC colloidal particles will hinder etherifying agent of chemical fiber further effective diffusion, osmosis and response, Sodium Carboxymethyl Cellulose the product will not be able to even replace. Temperature is too low, hydroxypropyl methyl cellulose in the early of a sodium chloroacetate acid crystals, outside in the alkali cellulose, etherification reaction begins to dissolve, then have difficulty with good penetration into the base fiber for reaction, ether effect and response uniformity are affected. This phase of the temperature can be controlled between the 40-55 degrees Celsius. Etherification, is the main stage of etherification reaction, general heating heating up to more than 60 degrees Celsius. Etherification late, because the main side effects in the middle of the etherification reaction quickly, has greatly declined, etherifying agent concentration at this time of sodium carboxymethyl cellulose polymerization degree and its distribution influence generated by the CMC spread out, viscosity increases too, the temperature can reach 75 degrees Celsius in order to make full use of etherifying agent, improve the effect of ether and replace the uniformity. The etherification reaction time can be adjusted within 1-2 hours. Alkalization and etherification reaction process complex factors, the formation of alkali cellulose specific ratio, reaction temperature and time must be combined with raw materials, equipment and reaction to carefully control, operating environment optimization to improve the quality of the product. Cellulose relation of quaternization and concentration of lye, temperature is most closely, and it is an exothermic reaction, in order to make cellulose can be fully swelling, have a combination of high alkaline to form alkali cellulose, and prevent the alkaline process strong oxidation degradation of cellulose and alkali cellulose, low temperature alkaline must be taken. Carboxymethyl cellulose sodium alkaline reaction speed is soon, but as a result of cellulose fiber morphological structure and super molecular structure of the complexity of the cellulose material evenly, fully alkali absorption and swelling and permeability and need to have enough time. So, about the classification of the cellulose ether reaction temperature and time should be depending

on the nature Food Additives Were Demonized in China and the reaction of cellulose raw material performance, alkali concentration, the amount and type of organic diluent, etc. Usually use alkaline for 25 to 40 degrees Celsius temperature, reaction time 15 to 45 minutes.