UNIT VII Review Stoichiometry

Stoichiometry Calculations involving MASS, MOLES, VOLUME, and MOLECULES 1. Consider the reaction 4NH3 +5O2 6H2O + 4NO a. What mass of NO is produced when 5.00 mol of NH3 are reacted with excess O2? b. What volume of O2 at STP is required to produce 90.0L of NO? c. How many molecules of H2O are formed when 100.0g of NH3 react? 2. Consider the reaction SiCl4 + 2H2 Si + 4HCl a. How many moles of SiCl4 are required to produce 4.25 x 1012 molecules of HCl. b. If 25.0 mL of H2 (g) at STP react, calculate the mass of Si produced c. If 0.892 kg of SiCl4 react, calculate the number of molecules of HCl produced. 3. Silver reacts with nitric acid, HNO3 to form nitrogen monoxide, NO, silver nitrate, AgNO3 and water a. How many grams of nitric acid are required to react with 5.00g of silver? b. How many grams of silver nitrate will be formed? c. How many moles of nitrogen monoxide will be produced? Stoichiometry using MOLAR CONCENTRATION 4. Consider the following reaction CaCO3 + 2HCl CaCl2 + CO2 + H2O a. What volume of HCl having a concentration of 0.0010M is neutralized by a 0.850 g portion of CaCO3? b. What volume of CO2 at STP is produced if 1.25L of 0.0055 M HCl reacts with an excess of CaCO3? c. How many moles of 0.200 M HCl is reacted to produce 3.00g of CaCl2? 5. If 17.5 g of zinc are reacted with phosphoric acid, H3PO4, then zinc phosphate, Zn3(PO4)2, and hydrogen are produced. a. How many moles of phosphoric acid are required? b. If the phosphoric acid is a 3.00M solution, how many litres of the solution are needed? c. What mass of zinc phosphate will be produced?

Stoichiometry of Excess Quantities: 6. If 65.7 g of FeCl2, 13.0 g KNO3 and 54.0g HCl are mixed and allowed to react according to the equation: 3FeCl2 + KNO3 + 4HCl 3FeCl3 + NO + 2H2O + KCl a. Which chemical is the LIMITING REACTANT? b. How many grams of each excess reactant are actually present in excess? 7. If 40.0 g of H2 react with 80.0 g of O2 according to the reaction 2H2 + O2 2H2O, which reactant is in excess and by how many grams? 8. If 45.0mL of 0.250 M HCl is allowed to react with 30.0mL of 0.200 M NaOH according to the reaction HCl + NaOH NaCl + H2O, which reactant is in excess? and by how many grams? % Yield and % Purity: 9. What mass of NH3 is required to make 12.5 g Cu according to the reaction 2NH3 + 3CuO N2 + 3Cu + 3H2O if the reaction has a 58.0% yield? 10. The following reaction occurs: 4FeS2 + 11O2 2Fe2O3 + 8SO2 a. A 45.0 g sample of FeS2 is 43.0% pure. What mass of Fe2O3 can the
sample produce? b. A second sample of FeS2, with a mass of 65.5 g, is reacted so as to produce 27.0g of Fe2O3. What is the percentage purity of the Fe2O3?

THIS IS JUST A SELECTION OF THE TYPES OF QUESTIONS WE HAVE COVERED, THIS SHEET SHOULD NOT BE YOUR ONLY STUDY TOOL!!!