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Candidate Name
CHEMISTRY 5070/4
PAPER 4 Alternative to Practical
MAY/JUNE SESSION 2001 1 hour
TIME 1 hour
INSTRUCTIONS TO CANDIDATES
Write your name, Centre number and candidate number in the spaces at the top of this page.
Answer all questions.
Write your answers in the spaces provided on the question paper.
A B C
50
40 10 20 30 40 50
30
25
20 cm3
10
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(a) (i) What colour was the litmus paper in the solution?
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[2]
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The ammonia was neutralised by the addition of dilute nitric acid and a salt was formed.
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(iii) The student produced some crystals of the salt from the solution.
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[4]
(c) The salt is used industrially as a fertiliser. Which element in the fertiliser is necessary for
the growth of plants?
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+ –
A B
carbon electrodes
After a few minutes, a pink solid is deposited on one electrode and a gas is evolved at the
other electrode.
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test ............................................................................................................................
result .........................................................................................................................
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[4]
How does the colour of the electrolyte change during the electrolysis?
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[3]
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Eventually, no more of the pink solid is formed. Instead, a gas is given off from the electrode.
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test ............................................................................................................................
result .........................................................................................................................
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4 A student converted starch into ethanol by a process involving two stages. An acid was used
in stage A and yeast in stage B.
A B
STARCH → SUGAR → ETHANOL
A B
(a) H H H
H C C C H
H H H
(b) H H
H C C O H
H H
(c) H H H
H C C C
H H
(d) H
O
H C C
O H
H
[1]
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7 A student added 10.0 cm3 of 0.100 mol / dm3 hydrochloric acid to an excess of zinc pieces.
The volume of hydrogen produced was recorded at time intervals until no more gas was
produced. This was experiment P.
The experiment was repeated using 10.0 cm3 of 0.100 mol / dm3 sulphuric acid and an
excess of zinc powder. This was experiment Q.
(a) (b)
volume Q volume
Q
of H2 of H2
–––––– ––––––
cm3 cm3
P
P
0 0
0 time/s 0 time/s
(c) (d)
Q Q
volume volume
of H2 of H2
–––––– ––––––
cm3 P cm3 P
0 0
0 time/s 0 time/s
[1]
A sample of M CO3 was added to a previously weighed container which was then
re-weighed.
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The sample was placed in a volumetric flask to which 50.0 cm3 of 1.00 mol / dm3 hydrochloric
acid (an excess) were added. A gas was evolved.
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[2]
When no more gas was evolved, the solution was made up to 250 cm3 with distilled
water. This was solution R.
A 25.0 cm3 sample of R was transferred to a titration flask and a few drops of methyl
orange indicator were added.
Then, 0.100 mol / dm3 sodium hydroxide was run into R from a burette until an end point
was reached.
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(d) Three such titrations were done. Parts of the burette with liquid levels before and after
each titration are shown below.
0 24 2 28 21 46
1 25 3 29 22 47
2 26 4 30 23 48
3 27 5 31 24 49
Summary
Tick the best titration results. Using these results, the average volume of 0.100 mol / dm3
(e) Calculate how many moles of sodium hydroxide are in the average volume of
0.100 mol / dm3 sodium hydroxide in (d).
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(g) Calculate how many moles of hydrochloric acid are in 250 cm3 solution of R.
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(h) Calculate how many moles of hydrochloric acid were originally taken in 50.0 cm3 of
1.00 mol / dm3 hydrochloric acid.
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(j) By subtracting your answer (g) from (h), calculate how many moles of hydrochloric acid
reacted with the M CO3.
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(k) One mole of M CO3 reacts with two moles of hydrochloric acid.
Calculate how many moles of M CO3 were present in the original sample.
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(l) (Ar: C,12; O,16)
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Complete the table by describing these observations and suggest the test and observations
which led to the conclusion from test 4.
4
V contains Cl – ions.
Conclusions
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10 When sulphuric acid was added to aqueous sodium hydroxide, a rise in temperature was
observed.
A student added dilute sulphuric acid from a burette to 1.00 mol / dm3 sodium hydroxide,
using the apparatus shown below.
The temperature both of the sodium hydroxide and of the sulphuric acid was 25 °C.
burette
thermometer
dilute
sulphuric
acid
stirrer
insulated beaker
1.00 mol/dm3
sodium hydroxide
20.0 cm3 sample of 1.00 mol / dm3 sodium hydroxide was placed in the beaker. To the
20.0 cm3 of sodium hydroxide, 5.0 cm3 of sulphuric acid were added from the burette and the
temperature was recorded. Further 5.0 cm3 portions of acid were added and each time the
temperature was recorded.
30 35 35 35
25 30 30 30
20 25 25 25
0 25
5.0
15.0
25.0
35.0
45.0 28
[2]
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(b) Plot these results on the grid below. Join up the points with two straight lines which
intersect and use the resulting graph to answer the questions below.
35
30
temperature
/°C
25
20
0 5 10 15 20 25 30 35 40 45
(c) (i) Use your graph to deduce the highest temperature reached.
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The experiment was repeated using 20.0 cm3 of 0.50 mol / dm3 sodium hydroxide and
sulphuric acid of concentration of 0.50 mol / dm3. The initial temperature of each solution was
25 °C, the same as in the first experiment.
(e) (i) Suggest the volume of sulphuric acid required to produce the highest temperature.
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(ii) Suggest whether the temperature would be higher, lower or the same as in the first
experiment. Explain your answer.
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[3]
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