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Culture Documents
Halogens
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Sodium Chloride
NaCl +H2SO4 --> HCl +NaHSO4 NaBr +H2SO4 --> HBr + NaHSO4 then 2NaBr +2H2SO4 --> 2H2O +Br2 +SO2 +Na2SO4 NaI +H2SO4 --> HI +NaHSO4 then 8NaI + 5H2SO4 --> 4I2 +H2S +4H2O +4Na2SO4
Sodium Bromide
Sodium Iodide
chlorine will displace bromine and iodine bromine will displace iodine but not chlorine Iodine will displace neither chlorine or bromine !idising "ower
F2>Cl2>Br2>I2 Halide ion 1) Br 2) IObservations 1) ello!"bro!n 2) bro!n #olo$r% bla#& ''t Con#l$sion 1) Br2 dis'la#ed 2) I2 dis'la#ed Halide ion 1) Cl 2) IObservations 1) no #han(e 2) bro!n #olo$r% bla#& ''t Con#l$sion 1) Cl2 not dis'la#ed 2) I2 dis'la#ed Halide ion 1) Cl-
Reactions with I2
2) BrObservations 1) no #han(e 2) no #han(e Con#l$sion 1) Cl2 not dis'la#ed 2) Br2 not dis'la#ed
Trend in electronegati#ity
Be#a$se )to*i# n$*ber in#reases attra#tion +or bondin( ele#tron 'air in #ovalent bond in#rease in#rease n$*ber o+ ele#tron shells shieldin( in#reases ele#trons less stron(l attra#ted ato*i# radi$s in#reases
all e!ist as diatomic molecules attraction $ wea% intermolecular &orces #an der 'aals &orces increase with si(e o& molecule Tests &or halide ions Reagents
Tests
Silver nitrate sol$tion Fl$oride ions Silver +l$oride is sol$ble no ''t +or*ed Chloride ions ,hite ''t +or*ed sol$ble in dil$te a**onia Bro*ide ions #rea* ''t +or*ed sol$ble in #on#entrated a**onia Iodide ions ello! ''t +or*ed insol$ble in a**onia sol$tion +ollo!ed b a**onia sol$tion
)nergetics
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Q$mcdelta*t+
enthalpy change when , mol o& a compound is &ormed &rom its elements under standard conditions all reactants and products in their standard states enthalpy when , mol o& a substance is completely burned in o!ygen under standard conditions and all reactants and products in their standard states enthalpy change that accompanies the neutralisation o& an acid by a base to &orm , mol o& H2 under standard conditions 2-. / ,00/"a ,moldm1*23+
Standard conditions
Redo!
o
!idation
loss o& electons addition o& o!ygen gain o& electrons loss o& o!ygen
reduction
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reactions which in#ol#e both o!idation and reduction o!idising agent is reduced reduing agent is o!ididesd Titanium
Ti 2 42C 42Cl2225 TiCl6 42C TiCl6 467a 225 67aCl 4Ti economic &actors
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#hlorine and sodi$* have to be 'rod$#ed hi(h te*'erat$res involved ar(on at*os'here has to be #ontained
Aluminium
Bau!ite
)l2O.
Iron
2C 4 2 225 2C 8e2 3 43C 225 28e 4 3C 2 28e2 3 43C 225 68e 4 3C 2 Impurities
SiO2 CaCO. + SiO2 --> CO2 + CaSiO. CaSiO. is sla( s$l'h$r i*'$rities 0( + S --> 0(S 1hos'hor$s 0an(anese O2 $nder 'ress$re blo!ed on *olten iron #arbon o-idised to #arbon *ono-ide
9a%ing steel
*an$+a#t$rin( #hlorine and sodi$* ele#trol sis o+ brine !ater #hea'er to re# #le al$*ini$* than *ine ba$-ite and ele#trol sis
Recycling aluminium
ele#trol sis needs hi(h te*'erat$re and lar(e ele#tri#it hi(h resistan#e to #orrosion 2arths resivoirs o+ ore are saved ener( o+ *inin( ore% trans'ortation% s*eltin( is (reater than re# #lin(