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solution; Beaker 1 is the opposite. The remaining beakers are in a series relative
to these two.
Observations:
2-
2-
3. I2 (aq) + HSO3 (aq) + H2O (l) --> 2 I (aq) + SO4 (aq) + 3 H (aq)
37G
TITRATIONS
WITH IODINE 34. I2 (aq) + I (aq) + starch (aq) --> starch-I (aq)
The oxidizing properties of iodine, the composition and stability of triiodide solu-
tions, and the applications of this reagent in volumetric analysis are discussed
http://chemed.chem.purdue.edu/demos/moviesheets/22.4.html
steps 1Starch
and
much
3, noprimeras;
I2for
accumulates
as long
ases
HSO3 remains in s
La
tercera
reaccin
es
2mucho
ms
slower
rpida
than
que
las
indicator
dos
de
manera
que
inBecause
Section 20C-3.
isare
ordinarily
employed
as step
an
iodometric
consumed,
I2 accumulates
andsodio
the blue-black
starch-triiodide
complex
is formed
in step 4.
titrations.
slo
cuando
el
bisulfito
de
se
termina
que
se
acumula
el
yodo
y
puede
formarse
el
complejo
triyoduro
cuyo
complejo
con
almidn
torna
azul
la
mezcla.
Diferentes
cantidades
relativas
de
cada
una
de
las
siguientes
disoluciones
37G-1 Preparation of Reagents
modificarn
entonces
el
tiempo
en
el
cual
aparece
la
coloracin
azul:
PROCEDURE
Disolucin
A:
10
mM
de
bisulfito
y
40
mM
de
cido
sulfrico.
(a) Iodine approximately 0.05 M. Weigh about 40 g of KI into a 100-mL beaker.
Disolucin
B:
g5
of
mM
de
y10
odato.
Add 12.7
I2 and
mL of water. Stir for several minutes (Note 1). Intro
duce an additional 20 mL of water, and stir again for several minutes. CareDisolucin
C:
Disolucin
indicadora
de
almidn;
la
cual
se
prepara
como
se
indica
a
fully decant the bulk of the liquid into a storage bottle containing 1 L of
distilled water. It is essential that any undissolved iodine remain in the beaker
continuacin:
(Note 2).
(b) Starch indicator (sufficient for about 100 titrations). Rub 1 g of soluble starch
and 15 mL of water into a paste. Dilute to about 500 mL with boiling water,
and heat until the mixture is clear. Cool; store in a tightly stoppered bottle. For
most titrations, 3 to 5 mL of the indicator are used.
The indicator is readily attacked by airborne organisms and should be freshly
Disolucin
D:
D
isolucin
prepared every
few
days. 40
mM
de
cido
sulfrico.
Notes Estas
disoluciones
se
mezclarn
en
un
vaso
de
precipitados
4
mL
de
la
1. Iodine dissolves
in thevKI
solution.
Thorough
stirring is needed
disolucin
C
con
cslowly
antidades
ariables
de
las
disoluciones
A,
B
y
to
D
hasten
de
manera
que
se
the
process.
mantenga
constante
el
volumen
final
de
la
mezcla.
2. Any solid I2 inadvertently transferred to the storage bottle will cause the con
centration of the solution to increase gradually. Filtration through a sintered
glass crucible eliminates this potential source of difficulty.
37G-2 Standardization of Iodine Solutions
Discussion
Arsenic(III) oxide, long a favored primary standard for iodine solutions, is now seldom used because of the elaborate federal regulations governing the use of even
small amounts of arsenic-containing compounds. Barium thiosulfate monohydrate
and anhydrous sodium thiosulfate have been proposed as alternative standards.9