Name: ___________________________ Physical Science Multiple Choice Identify the choice that best completes the statement or answers

the question. ____

SG

Colligative Properties

1. Which compound dissociates to produce the ions SO42(aq) and NH4+(aq)? a. NH4SO4(s) c. NH4(SO4)2(s) b. (NH4)2SO4(s) d. (NH4) (SO4)2(s) 2. Which compound dissociates to produce the ions !a2+(aq) and NO (aq)? a. !aNO (s) c. !a(NO )2(s) b. !a2NO d. !a2(NO ) . "recipitation is an e#amp$e o% &hat t'pe o% reaction? a. composition c. sin($e)rep$acement b. decomposition d. doub$e)rep$acement General Solubility Guidelines 1. *ost sodium+ potassium+ and ammonium compounds are so$ub$e in &ater. 2. *ost nitrates+ acetates+ and ch$orates are so$ub$e. . *ost ch$orides are so$ub$e+ e#cept those o% si$,er+ mercur'(-)+ and $ead. .ead(--) ch$oride is so$ub$e in hot &ater. 4. *ost su$%ates are so$ub$e+ e#cept those o% barium+ strontium+ and $ead. /. *ost carbonates+ phosphates+ and si$icates are inso$ub$e+ e#cept those o% sodium+ potassium+ and ammonium. 0. *ost su$%ides are inso$ub$e+ e#cept those o% ca$cium+ strontium+ sodium+ potassium+ and ammonium.

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4. When so$utions o% 1a!O and 2e2(SO4) are combined+ &hat precipitate(s) %orms? a. 1aSO4 c. 1aSO4 and 2e2(!O ) b. 2e2(!O ) d. none o% the abo,e /. When so$utions o% NH4OH and 32SO4 are combined+ &hat precipitate(s) %orms? a. (NH4)2SO4 c. (NH4)2SO4 and 3OH b. 3OH d. none o% the abo,e

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Name: ___________________________ ____ Physical Science 0. What is the spectator ion in the e6uation !u2+(aq) + 7n2+(aq) + 2S2(aq) !uS(s) + 7nS(s)? a. !u2+(aq) c. S2(aq) b. 7n2+(aq) d. none o% the abo,e 8. 9he separation o% ions that occurs &hen an ionic compound disso$,es is ca$$ed a. ioni:ation. c. precipitaion. b. dissociation. d. o#idation. ;. -ons are %ormed %rom so$ute mo$ecu$es b' the action o% the so$,ent in a process ca$$ed a. ioni:ation. c. precipitation. b. dissociation. d. o#idation. <. =isso$,in( H!$ in &ater produces a. H O+ and !$. b. H+ and !$.

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c. H O!$(aq). d. H O and !$+.

____ 15. > compound o% $o& so$ubi$it' a. is a$&a's a stron( e$ectro$'te. b. is a$&a's a &ea? e$ectro$'te.

c. ma' be a stron( or a &ea? e$ectro$'te. d. is a$&a's a none$ectro$'te.

____ 11. Which o% the %o$$o&in( is a &ea? e$ectro$'te? a. h'dro(en ch$oride c. sodium ch$oride b. su(ar d. acetic acid ____ 12. !o$$i(ati,e properties depend on a. the identit' o% the so$ute partic$es. b. the concentration o% the so$ute partic$es. c. the ph'sica$ properties o% the so$ute partic$es. d. the boi$in( point and %ree:in( point o% the so$ution. ____ 1 . Wh' is boi$in()point e$e,ation a co$$i(ati,e propert'? a. -t is in,erse$' proportiona$ to the mo$a$ concentration o% a so$ution. b. -t is direct$' proportiona$ to the mo$a$ concentration o% a so$ution. c. -t does not depend on a mo$a$ boi$in()point constant %or each so$,ent. d. -t is independent o% chan(es in ,apor pressure. ____ 14. Wh' is osmotic pressure a co$$i(ati,e propert'? a. -t depends on the rate o% osmosis. b. -t depends on the t'pe o% so$ute partic$es in t&o so$utions o% une6ua$ concentrations. c. -t depends on the concentration o% so$ute partic$es in a so$ution. d. -t depends on the t'pe o% so$ute partic$es in a so$ution.

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Name: ___________________________ Physical Science ____ 1/. 9he %ree:in( point o% an a6ueous so$ution that contains a none$ectro$'te is ;.5@!. What is the mo$a$ concentration o% the so$ution? a. 1.;0 m c. 4./ m b. 4. m d. 14.; m ____ 10. What is the boi$in()point e$e,ation o% a so$ution made %rom 15.5 ( o% a none$ectro$'te so$ute and 55.5 ( o% &ater? 9he mo$ar mass o% the so$ute is /5.5 ( and the mo$a$ boi$in() point constant %or &ater is 5./1@!. a. 5.51@! c. 5. 2@! b. 5.2@! d. 5. 4@! ____ 18. > &ater so$ution containin( an un?no&n 6uantit' o% a none$ectro$'te so$ute has a %ree:in( point o% 5.21@!. What is the mo$a$ concentration o% the so$ution i% Kf A 1.;0@!4m? a. 5.11 m c. 1.11 m b. 5.12 m d. 1.12 m ____ 1;. What is the boi$in()point e$e,ation o% a so$ution made %rom 25.5 ( o% a none$ectro$'te so$ute and 55.5 ( o% &ater? 9he mo$ar mass o% the so$ute is /5.5 ( and Kb A 5./1@!4m. a. 5.1 @! c. 5.42@! b. 5. ;@! d. 5.0;@! ____ 1<. What is the appro#imate %ree:in()point depression o% a 5.515 m a6ueous !a!$2 so$ution? a. 5.51<@! c. 5.5/0@! b. 5.5 8@! d. 5.584@! ____ 25. What is the appro#imate %ree:in()point depression o% a 5.5/5 m a6ueous Na2SO4 so$ution? a. 5.11@! c. 5.22@! b. 5.2;@! d. 5. <@! ____ 21. What is the actua$ %ree:in()point depression o% a 5.525 m a6ueous Na!$ so$ution? a. s$i(ht$' $ess than 5.5844@! c. s$i(ht$' more than 5.5844@! b. e#act$' 5.5844@! d. e#act$' 5@! ____ 22. 9he =eb'e)HBc?e$ theor' accounts %or a. attraction bet&een ions in so$utions. b. repu$sion bet&een ions in so$ution. c. attraction bet&een ions in cr'sta$s. d. the (reater %ree:in()point depressions in e$ectro$'te so$utions than in none$ectro$'te so$utions.

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Name: ___________________________ Physical Science ____ 2 . !ompared &ith the %ree:in()point depression %or a so$ution o% an e$ectro$'te that dissociates into a + and a ion+ the %ree:in()point depression %or an e6ua$$' concentrated so$ution o% an e$ectro$'te that dissociates into a 1+ and a 1 ion is $i?e$' to be a. the same. c. much $o&er. b. s$i(ht$' $o&er. d. (reater. ____ 24. !ompared &ith a 5.51 m su(ar so$ution+ a 5.51 m 3!$ so$ution has a. the same boi$in()point e$e,ation. c. the same boi$in()point depression. b. rou(h$' t&ice the boi$in()point d. about ha$% the boi$in()point depression. e$e,ation. ____ 2/. >s e$ectro$'te concentration decreases+ %ree:in()point depression a. approaches the ,a$ue ca$cu$ated b' assumin( comp$ete ioni:ation. b. (ets %arther %rom the ,a$ue ca$cu$ated b' assumin( comp$ete ioni:ation. c. remains e#act$' e6ua$ to the ,a$ue ca$cu$ated b' assumin( comp$ete ioni:ation. d. approaches 5@!. Questions and Problems: If the solute is not given please assume it is a molecular, non-electrolytic substance. Kf of water is -1.86oC/m and the Kb is .!1 oC/m 1. Write the equation for the dissociation of the following compounds: Na r !g"l# $N%&'()*&

#. Write the equations for the ioni+ation of the following: %( )*& % r %#"*(

(. ,ive two e-amples of colligative properties.

&. If the molal concentration of a solution is increased the will free+ing point ................., and the boiling point will ..................

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Name: ___________________________ Physical Science /. Write the general and ionic equations for a precipitation reaction between aqueous solutions of "u$N*('# and Na#01 $2emember that compounds that contain Nitrate are always soluble.'

3. 4escribe the differences and similarities of ioni"ation and dissociation of electrolytes1

5. What is the boiling point elevation of a solution that contains #.1/ moles of a molecular solute in 16g 6ilogram water1

7. What is the free+ing point of a solution that contains 7./-g of a molecular solute of a molar mass /7./ g8mole dissolved in 199-g of water1

:. What is the boiling point of a 9.:-m aqueous solution of ;"l1

19. What is the boiling point of a 9.&/-m aqueous solution of !g"l #1

11. <he boiling point of an aqueous solution of Na #"*( is 19#.5/". What is the molality of the solution1

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Name: ___________________________ Physical Science 1#. What is the molar mass of a non-electrolyte solute if dissolving 9.753 g of solute in 1/.9-g of water produces a solution that free+es at -1.&5 "1

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