Professional Documents
Culture Documents
Spreadability
Clarification Wetting
Solvency
UCON Fluids
Unique formulation
additives that deliver
emolliency, solvency,
and smooth application
UCON™ Fluids are a series of copolymers
of ethylene oxide and propylene oxide, or
of polyethylene glycol and polypropylene
glycol. These moderate-viscosity fluids
provide emolliency, solvency, and slip in
skin lotions, eye makeup removers,
antiperspirants, and deodorants. At the
same time, they can offer a number of
other benefits, such as the ability to
efficiently wet pigments, to generate
heat upon application, or to control
viscosity in shampoo systems.
2
UCON Fluids Offer a Range of
Chemistries and Solubility Performance
UCON Fluids are copolymers of ethylene oxide and propylene oxide, or of
polyethylene glycol and polypropylene glycol. They are classified into three
major groups that are variations on the idealized structure shown in Figure 1.
• m = % propylene oxide
• n = % ethylene oxide
UCON Fluid H
• R = ethylene or propylene glycol
• m = 25%, n = 75%
3
A Key to Product Nomenclature
XX Letter 1 Letter 2 Number
50 H B 660
Number: Viscosity
Saybolt Universal Seconds at 100°F
SUS at 100°F
Data listed above represent typical properties only, and should not be confused with, or construed
as, product specifications.
4
Table 2: Solubility Information for HB-Series UCON Fluids and
UCON Fluid 75-H-450 at 1%, 5% and 10%
1
Dimethicone Copolyol from GE
2
Cognis
3
Lubrizol Corporation
4
B.F. Goodrich
5
Hydrogenated Polyisobutene from Amoco Chemical
5
Table 3: Solubility Information for LB-Series UCON Fluids
and UCON Fluid AP at 1%, 5% and 10%
6
UCON Fluid AP Gives Antiperspirants
Outstanding Emolliency and
Smooth Application
For roll-on, stick, soft solid, and aerosol antiperspirant systems, UCON Fluid
AP gives a remarkably soft, smooth emollient feel. It suspends antiperspirant
actives and assists their spreadability.
7
Emolliency in Skin Care Formulations
The natural emolliency of UCON Fluids can add a luxurious feel and
demonstrably superior application properties to skin cream systems. Our
lab tests included both physical and subjective measures to compare the
performance of UCON Fluids to mineral oil.
w/w%
Deionized Water 78.1
Carbomer 934 (3% aq.) 10.0
DMDM Hydantoin 0.4
†
Test materials:
Mineral Oil T73-53-1
UCON Fluid AP T73-181-1
UCON Fluid LB-1715 T73-181-2
8
Table 5: Emollient Comparison Results
T73-53-1 (Mineral Oil)
Viscosity: 40,000 cPs
Appearance: White glossy cream
Feel Properties: Light emollience
More “watery” rub-in
Soft afterfeel
9
Salicylic Acid Study Demonstrates
Outstanding Solubility Properties
of UCON Fluids
This study was designed to model the solubility of salicylic acid in various
materials used in skin care formulations. The results show that UCON Fluids,
typically specified for emolliency and humectancy, also offer unusually good
solvency properties.
Salicylic acid is a common active used in skin care formulations like anti-acne
treatment products. Since it is recognized as a difficult material to solubilize
properly, salicylic acid provides a good reference point for comparing the
abilities of various materials to dissolve different formulation ingredients and
hold them in solution.
As seen in the photomicrographs in Figures 2 and 3, UCON Fluids are
excellent solvents for this difficult-to-dissolve material.
Materials:
2 grams crystalline salicylic acid
5 grams “Test Material”
Procedure:
Add salicylic acid to “Test Material” at room temperature. Stir until uniform.
Perform microscopic analysis at 430 x magnification.
10
Figure 2: Salicylic Acid in Solvents
PPG-14 Butyl Ether (UCON Fluid AP) PPG-40 Butyl Ether (UCON Fluid LB-1715) PPG-9-Buteth-12 (UCON Fluid 50-HB-660)
11
Pigmented Systems Get More
Efficient Wetting and Spreading
UCON Fluids can help you meet the challenge of wetting pigments, whether
hydrophobic or hydrophilic, over a wide range of pigment particle sizes.
In formulating pigmented products, two key points of performance are
wet points and flow points. The wet point gives an indication of wetting
efficiency and the pigment dispersion uniformity. The lower the wet point,
the less oil is necessary to “wet” out the pigment. The flow point provides an
idea of the ease of spreading and uniformity of coverage. The lower the flow
point, the lower the level of oil needed for internal lubrication of pigments.
12
Figure 4: Wet Points of UCON Fluid AP, Mineral Oil, and Caprylic/Capric Triglyceride
With Commercial Titanium Dioxide Products
350
UCON Fluid AP
300
Mineral Oil
Caprylic/Capric Triglyceride
Wet Point, mL/100 Grams
250
200
150
100
50
0
TiO2 #328 TiO2 #MT-100T TiO2 #MT-500B TiO2 #P-25 TiO2 #3328
13
Even better flow properties
Using the same set of TiO2 materials, we conducted flow point tests with
UCON Fluid AP, mineral oil, caprylic/capric triglyceride, and polyisobutene.
Figure 5 shows the remarkable efficiency of UCON Fluid AP at achieving
good flow of pigment particles compared to the other test materials.
By these comparisons, UCON Fluid AP stands out in its superb lubricating
qualities. The quantities of UCON Fluid AP required to achieve good flow
are close to those required for good wetting (compare Figures 4 and 5).
For mineral oil and caprylic/capric triglyceride, significantly higher
concentrations are required for good flow.
Figure 5: Flow Points of UCON Fluid AP, Mineral Oil, Caprylic/Capric Triglyceride,
and Polyisobutene With Commercial Titanium Dioxide Products
1200
UCON Fluid AP
1000 Mineral Oil
Caprylic/Capric Triglyceride
Flow Point, mL/100 Grams
Polyisobutene
800
600
400
200
0
TiO2 #328 TiO2 #MT-100T TiO2 #MT-500B TiO2 #P-25 TiO2 #3328
14
Efficient Control of Viscosity in Table 9: Model Shampoo Systems
for Viscosity Studies
Surfactant-Thickened Shampoo Systems
T73-183-1 Salt w/w%
In surfactant-thickened shampoo systems, you can use UCON Fluids for fine Deionized Water 57.1
control of viscosity to meet performance and aesthetic objectives.
Sodium Lauryl Sulfate 34.0
The three shampoo formulations detailed in Table 9 were developed to Lauramide DEA 4.0
evaluate the viscosity-controlling performance of UCON Fluids in systems Coco-Betaine 4.0
relying on different viscosity-building techniques. These include a conventional
DMDM Hydantoin 0.4
salt/surfactant combination, one using a cellulosic thickener (CELLOSIZETM
QP-4400 H), and another relying on surfactants alone. Citric Acid q.s. pH 7.0–7.4
Sodium Chloride 0.5
As shown in Figure 6, UCON Fluid 50-HB-660 very efficiently reduces the
viscosity of the surfactant system formulation (T73-185-1) at low use levels.
It had no viscosity-lowering effect on the cellulosic-thickened system, and T73-184-1 Cellulosic Gum
created only a minor viscosity reduction in the salt/surfactant system. Deionized Water 46.1
Other products within the UCON Fluid family may also be good candidates TEA-Lauryl Sulfate 50.0
for shampoo viscosity control. Figure 7 compares viscosity-reduction profiles Lauramide DEA 2.0
for UCON Fluid 50-HB-660 and UCON Fluid 50-HB-3520 in the surfactant CELLOSIZE QP 4400H 1.5
system formulation. While UCON Fluid 50-HB-3520 is a more efficient DMDM Hydantoin 0.4
viscosity-lowering additive, both UCON Fluids generate dramatic viscosity Citric Acid q.s. pH 7.0–7.4
reduction at very low concentrations. And
both follow similar viscosity-
reducing profiles across the T73-185-1 Surfactants
range of use levels tested Deionized Water 59.6
for the formulation. Lauramide DEA 5.0
TEA-Lauryl Sulfate 15.0
Sodium Laureth Sulfate 10.0
Citric Acid q.s. pH 6.5
Cocamidopropyl Betaine 10.0
DMDM Hydantoin 0.4
15
Figure 6: Viscosity Effect of UCON Fluid 50-HB-660
in Shampoo Systems
20,000
Surfactants
Cellulose Gum
15,000
Salt
Viscosity (cPs)
10,000
5000
0
0 0.025 0.05 0.075 0.1 0.125
20,000
10,000
5000
0
0 0.025 0.05 0.075 0.1 0.125
16
A Good Candidate for Detackifying:
UCON Fluid 75-H-450
For formulations that need a little “lightening up,” UCON Fluids can
significantly reduce the sensation of tackiness during or after application.
They leave formulations feeling smoother without adversely affecting other
essential rheology properties.
Lubrajel DV
(Glyceryl polymethacrylate) 25.0%
Water 74.0%
Detackifier—each of the
following added to individual
samples of test formulation: 1.0%
UCON Fluid 50-HB-660
UCON Fluid 75-H-450
Dimethicone copolyol
Glucam E-20
(Methyl Gluceth-20)
Glucam P-10
(PPG-10 Methyl Glucose Ether)
Lubrajel oil1
1
Glyceryl Polymethacrylate (and)
Propylene Glycol (and) PVM/MA
Copolymer from ISP
17
Table 11: Heat of Solution Data for
UCON Fluids in Water From Starting-
UCON Fluids Generate Useful Heat
Point Temperature of 22°C, 2.5:1 Ratio of Solution in Water
of Product to Water (10 g : 4 g)
UCON Fluids generate considerable heat of solution in water. They may be
considered for anhydrous products like self-heating facial masks, ointments,
Product Final Temperature, °C and hair conditioners. The UCON Fluids provide heat while acting as
UCON Fluid 75-H-450 emollient solvents.
(PEG/PPG-17/6 Copolymer) 32
UCON Fluid 50-HB-400
(PPG-9-Buteth-12) 30
Suggested Applications for UCON Fluids
UCON Fluid 50-HB-660
(PPG-12-Buteth-16) 30
UCON Fluid 50-HB-3520 Table 12: Suggested Applications for UCON Fluids
(PPG-28-Buteth-35) 31 by Finished Product Type
UCON Fluid 50-HB-5100
(PPG-33-Buteth-45) 31
18
Table 13: Recommended UCON Fluids by Physical Form
of Finished Product
Functional
Physical Form Suggested UCON Fluids Contributions
O/W Emulsions UCON Fluid 50-HB-660 Provides emollience
UCON Fluid 50-HB-3520 Reduces tackiness
UCON Fluid 50-HB-5100
UCON Fluid LB-1145 Oil phase alternative
UCON Fluid LB-1715 Easily emulsifiable
UCON Fluid AP Provides emollience
W/O Emulsions UCON Fluid LB-1145 Provides non-greasy
UCON Fluid LB-1715 emollience
UCON Fluid AP Improves spreading
Hydrogels UCON Fluid 75-H-450 Provides emollience
UCON Fluid 50-HB-660
UCON Fluid 50-HB-3520
UCON Fluid 50-HB-5100
Pigmented UCON Fluid LB-1145 Provides good
Systems UCON Fluid LB-1715 pigment wetting
UCON Fluid AP Gives emollience
Improves spreadability
Anhydrous UCON Fluid 75-H-450 Provides detackification
Systems UCON Fluid 50-HB-660 Improves afterfeel
UCON Fluid 50-HB-3520 Enhances clarity
UCON Fluid 50-HB-5100 Heat generation
Provides emolliency
Provides solvency
19
Emolliency
Spreadability
Clarification Wetting
Solvency
UCON Fluids
For more information, complete literature, and product samples, you can reach a Dow
representative at the following numbers:
From the United States and Canada call 1-800-FOR ELEGANCE (1-800-367-3534)
fax 1-989-832-1465
†
In Europe toll-free +800 3 694 6367
call +32 3 450 2240
fax +32 3 450 2815
Hungary (00), Ireland (00), Italy (800 783825), The Netherlands (00), Norway (00), Portugal (00), Spain (00),
Sweden (00), Switzerland (00), and the United Kingdom (00)
‡
Toll-free from all Pacific countries except Indonesia and Vietnam
Or you can contact us on the Internet at:
www.amerchol.com
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