1 lDENTlFlCATlON OF THE SUBSTANCE/PREPARATlON AND OF THE COMPANY/UNDERTAKlNG PRODUCT NAME BARlUM CHLORlDE 2H2O LRG CAS-No. 10326-27-9 EU lNDEX NO. 017-003-00-8 EC No. 233-788-1 Reagent Chemical Services SUPPLlER 18 Aston Fields Road Whitehouse lndustrial Estate Runcorn Cheshire WA7 3DL T: 01928 716903 F: 01928 716425 E: info@reagent.co.uk PRODUCT NO. 1509 APPLlCATlON General chemical reagent 2 HAZARDS lDENTlFlCATlON Harmful by inhalation. Toxic if swallowed. CLASSlFlCATlON (67/548) - 3 COMPOSlTlON/lNFORMATlON ON lNGREDlENTS EU lNDEX NO. 017-003-00-8 EC No. 233-788-1 CAS-No. 10326-27-9 4 FlRST-AlD MEASURES lNHALATlON Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. lNGESTlON Do not induce vomiting. lmmediately rinse mouth and drink plenty of water. Get medical attention immediately! SKlN CONTACT lmmediately remove contaminated clothing and wash before re-use. Wash the skin immediately with soap and water. ln serious cases or if discomfort continues obtain medical attention. EYE CONTACT Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids.lf possible remove any contact lenses and continue to wash. Get medical attention. 5 FlRE-FlGHTlNG MEASURES EXTlNGUlSHlNG MEDlA The product is non-combustible. Use fire-extinguishing media appropriate for surrounding materials. SPEClFlC HAZARDS ln case of fire, toxic and corrosive gases may be formed. PROTECTlVE MEASURES lN FlRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACClDENTAL RELEASE MEASURES PERSONAL PRECAUTlONS Wear protective clothing as described in Section 8 of this safety data sheet. 3 1 / REVlSlON DATE: October 2004 BARlUM CHLORlDE 2H2O LRG SPlLL CLEAN UP METHODS Dampen spillage with water. Transfer to a container for disposal. Wash contaminated area with water. 7 HANDLlNG AND STORAGE USAGE PRECAUTlONS Avoid spilling, skin and eye contact. STORAGE PRECAUTlONS Store in tightly closed original container in a dry and cool place. STORAGE CLASS Toxic storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTlON Std STEL - 15 min TWA - 8 hrs Name Notes 0.05 as Ba mg/m3 OES BARlUM CHLORlDE 2H2O LRG ENGlNEERlNG MEASURES Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit (WEL) is not exceeded. RESPlRATORY EQUlPMENT ln case of inadequate ventilation use suitable respirator. HAND PROTECTlON Wear protective gloves. Rubber or plastic EYE PROTECTlON Wear safety glasses. Use tight fitting goggles if dust is generated. HYGlENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. Promptly remove any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. 9 PHYSlCAL AND CHEMlCAL PROPERTlES APPEARANCE Solid COLOUR White ODOUR Odourless BOlLlNG POlNT (C) 1560 MELTlNG POlNT (C) 900 pH-VALUE, DlLUTED SOLUTlON 5 - 8 5 SOLUBlLlTY VALUE (g/100g H2O@20C) 35.7 10 STABlLlTY AND REACTlVlTY STABlLlTY Stable under normal temperature conditions. 11 TOXlCOLOGlCAL lNFORMATlON TOXlC DOSE 1 - LD 50 118 mg/kg (oral rat) lNHALATlON Harmful by inhalation. lNGESTlON Toxic if swallowed. 12 ECOLOGlCAL lNFORMATlON ECOTOXlClTY Barium ions are toxic to aquatic organisms. 13 DlSPOSAL CONSlDERATlONS DlSPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 3 2 / REVlSlON DATE: October 2004 BARlUM CHLORlDE 2H2O LRG 14 TRANSPORT lNFORMATlON UK ROAD CLASS 6.1 PROPER SHlPPlNG NAME BARlUM COMPOUND, N.O.S. PROPER SHlPPlNG NAME BARlUM COMPOUNDS, N.O.S 1564 UN NO. ROAD lll UK ROAD PACK GR. 6.1 ADR CLASS NO. Class 6.1:Toxic substances. ADR CLASS lll ADR PACK GROUP 6.1 ADR LABEL NO. 2Z HAZCHEM CODE 61GT5-lll CEFlC TEC(R) NO. 6.1 RlD CLASS NO. lll RlD PACK GROUP 1564 UN NO. SEA 6.1 lMDG CLASS 6.1 lMDG PAGE NO. lll lMDG PACK GR. F-A, S-A EMS See Guide MFAG No. MARlNE POLLUTANT 1564 UN NO. AlR 6.1 AlR CLASS lll AlR PACK GR. 15 REGULATORY lNFORMATlON LABELLlNG Toxic RlSK PHRASES R20 Harmful by inhalation. R25 Toxic if swallowed. SAFETY PHRASES S45 ln case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S1/2 Keep locked up and out of the reach of children. STATUTORY lNSTRUMENTS Chemicals (Hazard lnformation and Packaging) Regulations. Control of Substances Hazardous to Health. APPROVED CODE OF PRACTlCE Classification and Labelling of Substances and Preparations Dangerous for Supply. COSHH essentials: Easy steps to control chemicals. Control of Substances Hazardous to Health Regulations. GUlDANCE NOTES Workplace Exposure Limits EH40. lntroduction to Local Exhaust Ventilation HS(G)37. NATlONAL REGULATlONS Control of Substances Hazardous to Health Regulations 2002 (as amended) 16 OTHER lNFORMATlON GENERAL lNFORMATlON Under REACH Material Safety Datasheets (MSDS) are referred to as Safety Datasheets (SDS). REVlSlON COMMENTS Change to section 2. REVlSlON DATE October 2004 REV. NO./REPL. SDS GENERATED Supercedes issue April 2004 SDS NO. 20365 3 3 /