IIT Section

Subject Topic Grand Test Paper II Date

C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

1

Key Answers:
1. d 2. a 3. c 4. b 5. d 6. a 7. 5 8. 4 9. 2 10. 6
11. 3 12. b 13. b 14. b 15. c 16. a 17. b 18. 19. 20. b
21. c 22. c 23. d 24. d 25. c 26. 3 27. 4 28. 7 29. 9 30. 1
31. d 32. b 33. a 34. c 35. a 36. c 37. 38. 39. b 40. a
41. a 42. a 43. d 44. c 45. 7 46. 2 47. 2 48. 4 49. 2 50. c
51. a 52. d 53. c 54. d 55. c 56. 57.

18. A r, B p, C s, D q; 19. A q, B r, C p, D s;
37. A p,q, B r, C r,s, D p,q; 38. A q, B r, C s, D-r;
56. A p,r, B p,q, C s, D p; 57. A p,q,s, B p,q,r, C p,q,s, D p,q,r;

Solutions:
Chemistry
1. No of lone pair of 0 Xe = and number of bond pair 5 =
Hybridisation of
3
Xe sp d =
Hence shape
3 2
XeO F should be trigonal bipyramidal and not octahedral
2. For the desired reaction
( )
1 ,
1
G
AgCl e Ag Cl E
F

A
+ + =
the needed , G A can be obtained by adding the values of , G A for the recton
'
1 ; Ag e Ag G nFE

+ A =
; ln ,
sp
AgCl Ag Cl G RT K
+
+ A = giving
, G A = ( )
( ) ( )
4 1 10
1 9.648 10 (298 ) ln 1.56 10 mol J mol K


77.10 55.95 21.15 kJ kJ kJ + =
The potential is
( )
( )( )
21.15
0.2192
1 96.485
E V

= = +

3.


4. Alkenes with even number of cumulative double bonds are optically active if both sides are
dissymmetric
5. None of the acids evolve
2
H gas with alkali metals
CH
3

C
2
H
5

O
OH
OH

O
CH
3

C
2
H
5

O
-H
2
O
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

2

6. Given 0.1 , 18.0
HCl HCl
M M V mL = =
3 3
0.125 , ?
NaHCO NaHCO
M M V = =
on applying ,
3 3
HCl HCl NaHCO NaHCO
M V M V =
3
0.1 18 0.125
NaHCO
V =
3
14.4
NaHCO
M mL =
Thus, 14.4mL of
3
1.25M NaHCO solution is needed to neutralise 18.0 mL of the 0.100
M HCl solution
7. The destruction reaction for
3
O is given as
3 2
2 3 O O
The net rate of production of
3
O =
15 1 1
7.2 10 rate of thisreaction mol h

= =
Now
| |
( )
2 3
2
;
d O
k a x
dt

=

but initially

0 x =
So
| |
( )
2
3 2 15 8
2 2
7.2 10 2 10
d O
k a k
dt

= =

15
1 1
2
16
7.2 10
4 10
k mol h

1 1 1 1
2
18
18
60 60
k mol h mol s

= =

3 1 1
5 10 . mol s

= So value of 5 x =

8. We know that ,
d d
p RT or M RT
M P
= =
given,
3
775
2.64 / ;
760
d g dm P atm = =
3 1 1
0.0821 , 310 273 583 R dm atmK mol T K

= = + =
2.64 0.0821 583 760
123.9 /
775
M g mol

= =
Atomic mass of 31 / P g mol =
Number of P atoms in a molecule
123.9
4
31
M = =

9. There are 2t bonds in ( ) C which is and ( ) B is
2 3
Na SO

10. Total number of unpaired electrons 6 =
11. ( ) C is an amide which on heating with
2 5
P O gives propane nitrole and so ( ) C is propanamide
2 5
3 2 2 3 2
PO
CH CH CONH CH CH CN
NaO S
S
O
ONa
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

3

( ) C is formed by the action of
3
NH on acid ( ) B , so acid ( ) B is propanoic acid
3 2 3 3 2 4 3 2 2
CH CH COOH NH CH CH COONH CH CH CONH
A A
+
( ) B ( ) C
(iii) Acid ( ) B is formed from hydrolysis of A as well as ( ) A fumes in moist air, so ( ) A is
acid halide. Thus ( ) A is
3 2 3 2
CH CH COCl HOH CH CH COOH HCl + + |
Also, (A)
3 2
(propanoyl chloride) CH CH COCl
(B)
3 2
(Propanoicacid) CH CH COOH
(C)
3 2 2
(propanamide) CH CH CONH
(i)
3 2
CH CH COCl (ii)
3 2
CH COCH Cl (iii)
2 2
ClCH CH CHO

12. Na metal is soluble in liquid ammonia. The reaction takes place in a homogeneous solution
phase
13. More highly substituted alkenes are adsorbed on metal catalyst effectively so are not readily
reduce
14. The least stable alkenes has highest heat of hydrogenation
15. Yellow curdy precipitate with Ag
+
confirms the presence of I ion

in the compound The

precipitate ( ) AgI is insoluble in
4
NH OH
16. Compound A gives brown precipitate with
4
CuSO which becomes white when
2 2 3
Na S O is
added. Thus, compound A should be KI
17.
4 2 2 4
2 CuSO KI CuI K SO + +
( ) A
2 2 2 2
2CuI Cu I I +
brown
2 2 3 2 2 4
2 2 Na S O I Na S O NaI + +
white
(sodium tetrahtionate)
18. Magnetic moment, ( ) 2 n n BM = +
(where n = number of unpaired electrons)
For ( )
2
, 0, 0 0 2 0.00 Fe n BM
+
= = + =
For ( )
3
, 1, 1 1 2 1.73 Ti n BM
+
= = + =
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

4

For ( )
2
, 2, 2 2 2 2.83 Ni n BM
+
= = + =
For ( )
3
, 5, 5 5 2 5.91 Fe n BM
+
= = + =
19. , order of reaction
n
dC
KC n
dt
= =
or, ( ) ( )
1
/ time /
n
mol lit k mol lit

=
or, ( ) ( )
1 1 1
time
n n
K mol lit

=


IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

5

Mathematics
20. Favourable number of ways
12 47 4
1 1 1
1 C C C = +
Required probability
51 51
52 51 221
= =

21. For the vector a and b to be inclined at an obtuse angle, we must have
( ) . 0 0, a b for all x < e
( )
2
2 2
log 12 6 log 0 c x c x + < for all ( ) 0, xe
2
6 12 0 cy cy + < for all y R e
Where
2
log y x =
2
0 and 36 48 0 c c c < + <
(using
2
0 if 0 and 0 ax bx c x R a D + + < e < <
( )
4
0 3 4 0 , 0
3
c and c c c
| |
< + < e
|
\ .

22. We have ( ) ( )( )
2 2
0 0 a b c a b c a b c = + =
Line 0 ax by c + + = passes through either of the points ( ) 1, 1 and ( 1,1)

23. Let 2 and 3 y t z u = = then the equation becomes , where 1, 2, 3........... 2, 4, 6 x y u n x t + + = = =
and 3, 6, 9 u =
Hence, the number of solution of this equation
=
( )
2 3
coefficient of ......
n
x in x x x + + +
( )( )
2 4 6 3 6 9
..... .... x x x x x x + + + + + +
=
( )( )( )
6 2 2 4 3 6
coefficient of 1 ... 1 .... 1 .......
n
x in x x x x x x x + + + + + + + + +
( )
( ) ( )
1 1
1 6 2 3
coefficient of in 1 1 1
n
x x x x


=
24. The given quadratic equation is satisfied by , and x a x b x c = = = Hence the quadratic
equation has three roots, which is only possible if it is an identify, hence it has infinite roots
25. Let z ie =
z ie =
2
Arg Argz + =
t
e
3
arg
4
z =
t


IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

6

26. ( )
3 2
. 5 7 A A A A A I = =
2
5 7 A A =
( ) 5 5 7 7 A I A =
18 35 A I
Now ( )
4 3
. 18 35 A A A A A I =
2
18 35 A A
( ) 18 5 7 35 A I A
55 126 A I
( )
5 4
. 55 126 A A A A A I = =
2
55 126 A A
( ) 55 5 7 126 A I A
149 385 a and b = =
2 3 2 149 3 385 a b =
298 1155 1453 = + =
27. The period of
| |
sin
12
x t | |
|
\ .
is
2
24
t
t
=
as
| | | | 24 24
sin sin
12 12
x x t t | | | | + +
=
| |
\ . \ .


| | | |12
sin 2 sin
12
x x t t
t
| | | |
= + =
| |
\ . \ .

similarly the period of
| |
tan
3
x t | |
|
\ .
is 3 and the period of cos
4
x t | |
|
\ .
is
2
8
4
t
t
=
Hence the period of the given function
24,8,3 24 LCM of = =
201 201 24 4824 = =
28.
( )
( )
( )
2 3 97
1
.... 1 1 1 ....1
lim
1 x
x x x x
x
+ + + + + +

1 2 3 .... 97 = + + + +
( )
97
1 97 97 49 4753
2
+ = =


IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

7

29. If r be the radius and ' ' h be the height of the cylinder
Volume
2 3 3 2 3
2 2 4
3 3 3
V r h r r r h r t t t t t = + + = +

( )
( )
2 2
4
2 .3
3
V r h h r v tr r t t t A = A + A + A

2 2
2 4 r h rh r r r t t t = A + A + A

( )
2
2 4
4
3
r r h h r r r
V
V
r rh r
t
t
A + A + A
A
= =
| |
+
|
\ .


( )
2
1.5 0.05 2 4 0.01 4 1.5 0.01
4
1.5 4 1.5
3
+ +
=
+


0.215
9
=

0.215 21.5
100 100 2.389%
9 9
V
V
A
= = = =
2389 abcd =
30. Let
1 2 3 4, 5
, , , E E E E E and
6
E be the events of occurrence of 1, 2, 3, 4, 5 and 6 on the dice
respectively, and let E be the even of getting a sum of numbers equal to 9
( ) ( ) ( )
1 2 3
1 1 2 1
, ; ;
6 6 6
k k k
P E P E P E
+
= = =
( ) ( ) ( )
4 5 6
1 1 2 1
; ;
6 6 6
k k k
P E P E P E
+ +
= = =

and
1 2
( )
9 9
P E < s
Then, E= ( )( )( )( ) { }
3, 6 6, 3 4, 5 5, 4
Hence, ( ) ( ) ( ) ( )
3 6 6 3 4 5 5 4
( ) P E P E E P E E P E E P E E = + + +
( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )
6 6 3 4 5 5 4
3 P E P E P E P E P E P E P E P E = + + +
= ( ) ( ) ( ) ( )
6
2 3 2 4 5 P E P E P E P E +
{ }
1, 2 3 4
Since , , are independent E E E E
1 1 1 1 2
2 2
6 6 66
k k k k + + | || | | || |
= +
| | | |
\ .\ . \ .\ .

2
1
2 2
18
k k
(
=


since,
( )
1 2
9 9
P E s s
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

8

2
1 1 2
2 2 ...............(1)
9 18 9
k k
(
s s


2
2 2 2 4 k k s s
2
2 2 2 k k s
2
2 2 2 k k + + s
2
2 0 k k + s
( ) 2 1 0 k k + s
1
0
2
K s s
Hence, integral value of k is zero and for 0 k = from equation (1)
Set of integral value of { } 0 k =
Number of integral solutions of k is 1
31. Here 1 0 a = > therefore we make the substitution
2
2 2 x x t x + + = Squaring both sides of this
equality and reducing the similar terms, we get
( )
( )
2 2
2
2
2 2 2
2 2 2 ;
2 1
2 1
t t t
x tx t x dx dt
t
t
+ +
+ = = =
+
+

( ) ( )
2 2
2
2 4 4
1 2 2 1
2 1 2 1
t t t
x x t
t t
+ +
+ + + = + =
+ +

substituting into the integral, we get
( )
( )
( )
( )
( )
( )( )
2
2 2
2 2
2 1 2 2 2 2
4 4 2 1 1 2
t t t t t dt
I dt
t t t t t
+ + + + +
= =
+ + + + +
} }

Now let us expand the obtained proper rational fraction into per tail fractions

( )( ) ( )
2
3 2
2 2
1 2
1 2 2
t t A B D
t t
t t t
+ +
= + +
+ +
+ + +

32.
2
1
dx
I
x x x
=
+ +
}

Since here 1 0, c = > we can apply the second Euler substitution
2
1 1 x x tx + = ( )
( )
2 2
2
2 1
2 1 1 ;
1
t
t x t x x
t

= =

substituting into I, we can get an integral of a rational fraction
( )( )
2
2
2
2 2 2
,
1 1
1
dx t t
dt
t t t
x x x
+
=
+
+ +
} }

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

9

Now,
( )
( )
2
2
2 2 2
1 9 1 1 1
1
t t A B D E
t t t t t t
t
+
= + + +
+ +
+

33. In this case 0 0 a and c < < therefore, nether the first, nor the second Euler substitution is
applicable, But the quadratic
2
7 10 x x has the real roots 2, 5 = = o | . Therefore we
use the third Euler substitution
( )( ) ( )
2
7 10 2 5 2 x x x x x t = =
( )
2
5 2 ; x x t =
2
2
5 2
1
t
x
t
+
=
+

34. Ans (c)
35. Ans (a)
36. Let the equation of the circle be
2 2
2 2 0 x y gx fy c + + + + = ..(1)
The line 1 lx my + + = will touch the circle (1) if the length of perpendicular from the centre
( ) , g f of the circle on the line is equal to its radius,
i.e.,
( )
( )
2 2
2 2
1 gl mf
g f c
l m
+
= +
+

( )
( )( )
2 2 2 2
1 gl mf l m g f c + = + +
( ) ( )
2 2 2 2
2 2 2 1 0 ( ) c f l c g m gl fm gflm ii + + + =
But the given condition of tangency is
2 2
4 5 6 1 0 l m l + + = .(iii)
Comparing equations (ii) and (iii), we get
2 2
4 5, 2 6, 2 , 2 0 c f mc g g f c gf = = = = = =
solving we get 0, 3, 4 f g c = = =
substituting these values in equation (i), the equation of the circle is
2 2
6 4 0 x y x + + = .
any point on the line 1 0 x y + = is ( ) ,1 , t t t R e
Chord of the contact generated by this point for the circle is ( ) ( ) 1 3 4 0 tx y t t x + + + = or
( ) ( ) 3 3 4 0 t x y x y + + + = which are concurrent at point of intersection of the 3 0 x y = and
3 4 0 x y + + = for all values of t. Hence, lines are concurrent at
1 5
,
2 2
| |

|
\ .

Also point ( ) 2, 3 lies outside the circle from which two tangents can be drawn
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

10

37. (A) 2 7 z i z i k + = is ellipse if 7 2 5 k i i or k > >
(B) We have, for z eC
( ) 2 2 2 i z i z z i z = + s +
2 2 z z i s +
Thus, minimum value of 2 z z i + is 2 and it is attained for any z lying on the segment joining
2 . z i =
(C) 3 4 z z i k = is hyperbola, if 3 4 0 5 k i k < < <
(D)
( ) 3 4
50
k
z i az az b + = + +
( ) 3 4
5 2 3 4
az az b
k
z i
i
+ +
+ =
+

This is hyperbola if 1 5
5
k
k > >
38. ( ) ( ) ( )
1
.
12
P A B P A P B = =
( )
1 1 1 4 3 1 6 1
3 4 12 12 12 12
P A B
+
= + = = =
( ) ( ) ( )
1
2
3
/ /
1
3
2
P A A B P A P A B = = =
( )
( )
( )
/ ' ' 0
' '
P
P B A B
P A B
|
= =

( )
( )
( )
( ) ( )
( )
'
'/
P A s P B P A B
P A B
P B P B

= =

1
1 2
12
1 1
1
3 3
4
= = =

IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

11

Physics
39. The centre of mass will follow the same path.





2
R
mx m mR = +
or
3 3 100
150
2 2
R
x

= = = m

40.
4 4 4
1 2 3
1 2 3
Pr Pr Pr
, ,
8 8 8
V V V
l l l
t t t
q q q
= = = and
4
Pr
8
V
l
t
q
=
Now
1 2 3
V V V V = + +
Substituting the values, we get
1 2 3
1 2 1 2 2 3
l l l
l
l l l l l l
=
+ +
1 2 3 6
1 2 1 3 2 3 11

= =
+ +
m

41.
1 2
( )
1
nR T T
e

2/3 2/3
1 2
(5.6) (0.7) T T =
2 1
4 T T =
1
1
3 9
2
2
3
nR T
nRT e = =
But
1
4
n =

1
9
8
RT e =

42.
2
2 2
1
1 1
13.6(1)
2 3
hC

| |
=
|
\ .

2
2 2
2
1 1
13.6(2)
2 4
hC

| |
=
|
\ .

Dividing
( )
( )
2
1
1 5 / 36
4 3/ 16

2 1
5
1215
27
o
A = =



x
R/2
R
m
m m
COM
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

12

43.
2
1
2
2
i
u v =

2 2
(2 )
2 10 5
t
V V
u

= =

Loss of energy
2 2
2
4
5 5
V V
V = =
% loss
2
2
4 / 5
100
V
V
= = 80%
44. Ratio of magnetic moment and angular momentum is given by
2
M q
L m
=
Which is a function of q and m only. This can be derived as follows :

2
( )( ) M iA qf r t = =

2
2
( ) ( )
2 2
q r
q r
e e
t
t
| |
= =
|
\ .

and
2
( ) L I mr e e = =


2
2
2
2
r
q
M q
L m
mr
e
e
= =

45. Distance between two cars leaving from station X is,

1
60 10
6
d
| |
= =
|
\ .
km
Man meets the first car after time,

1
60 1
60 60 2
t h = =
+

He will meet the next car after time,

2
10 1
60 60 12
t h = =
+

In the remaining half an hour, number of cars he will meet again is,
1/ 2
6
1/ 12
n = =
Total number of cars would be meet on route will be 7.
46. From work energy theorem

net
KE W A =
or
f i
K K pdt =
}

or
2
2 2
0
1 3
2 2
mv t dt
| |
=
|
\ .
}
( 2 m = kg)
or
2
3
2
0
2
t
v
(
= (
(

or 2 v = m/s
2
s
1
2 F
8 F
V
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

13

47.
2
4 cos
2
o
I I
| | |
=
|
\ .

2
4 cos
2
o o
I I
| | |
=
|
\ .


1
cos
2 2
| | |
=
|
\ .

or
2 3
| t
=
or
2 2
3
x
t t
|

| |
= = A
|
\ .

or
1 1
.
3
d
D

| |
=
|
\ .

yd
x
D
| |
A =
|
\ .


7
4
6 10
3 10
3
y
d
D

= =

3
2 10

= m = 2 mm
48. / ,
E
v m s t s
m v

= = = =
7 9
2
2 10 2 10
For 200 neutrons generation: T t = 200
s

=
7
4 10
49.
d
dq idt
R
|
= = = Area under i - t graph
d| = (Area under i - t graph) ( R )

1
(4)(0.1)(10) 2
2
Wb = =

50. For rod
2
( 3 )
1:
(2 )(16 ) / 3
N l
m l
o =






or
32
3 3
ml
N
o
=


N
A
3l
-
N
mg
30
o
B
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

14

51. (2 ) (2 )(2 ) 4
c
N F m a m l ml o o = = =







32 12 3
4
3 3
F N ml ml o o
| |

= =
|
|
\ .

52.
2
2
2
2
( cos30 ) (2 sin30 )
( )(2 ) / 3
m gl N l
m l
o

=

2
2
32
( 3 / 2)
3 3 8
3 3
8 3 (4 / 3)
ml
mgl
g
l
ml
o
o

| |
= = |
|
\ .

53. (4)(2)(1) 8 V Bvl V = = =
, R C and L all are in parallel. Therefore, ,
R C
V V and
L
V all are 8V .

L
di
V L
dt
=
or 8 (4)
di
dt
= 2
di
dt
= A/s
i.e.., rate of exchange of current through L is constant. After 2s current will be 4A.
54. ( ) ( )
applied m
F rightwards F leftwards =
IlB =
1 2 3
( ) I I I lB = + +
3
I we have already calculated at 2 which is 4 A.
( )
2
(8) 0
C
dq d d
I CV
dt dt dt
= = = =
and
1
8
4
2
R
V
I A
R
= = =

(4 4)(1)(4) 32
applied
F N = + =

55. . (32)(2) 64 / P F v J s = = =
2
1
1
( )
2
d di
p Li Li
dt dt
| | | |
= =
| |
\ . \ .

3
(4)(4)(2) 32 / ( ) J s i I = =
2 2
2 1
(4) (2) 32 / ( ) P i R J s i I = = =


N
a
2l
2
c
a lo =
C
F
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

15

56. (A) Since 0 E = and 0, B = so path will be straight line if velocity is parallel to B . Or path will be
circular if V B . Or path will be helical (with uniform pitch) if V is at some other angle to B .
Hence. (A) p, r

(B) Since 0 E = and 0, B = so path will be straight line if V B or parabola otherwise.
Hence (B) p, q

(C) 0 E = , 0, B = E B





Helical path with non-uniform pitch Hence, (C) s
(D) Straight line path if V B E =





Hence. (D) (p)


57.





F f ma + =
,
a
Fx fR Ia a
R
= =
Solve to get
2
( ) F MxR I
f
I MR

=
+

B
E
90
o
v
B
E
V

F

a
x
a
R
k
f
, M l
IIT Section

Subject Topic Grand Test Paper II Date
C + M + P Grand Test 07
IIT GT 07
10
th
May 2014
I20140510

16

0, f = if
1
x
MR
=
0, f > if
1
x
MR
>
So friction will act in forward direction.
0 F < if / x I MR < , so friction will act in backward direction.
Also solved to get
2
( ) FR x R
a
I MR
+
=
+

A is positive for all cases, hence body will accelerate in forward direction in all cases.
It means o will be in clockwise direction. Hence bodies will rotate in clockwise direction.