CHAPTER 12: THERMOCHEMISTRY

MULTIPLE CHOICE QUESTIONS

INSTRUCTION : Answer all questions.
1. Which of the following is an endothemic reaction?
A Precipitation of silver chloride
B Displacement of iron by magnesium
C Decomposition of magnesium sulphate hydrate
D Dilution of sulphuric acid with water
2. Which of the following is not true about eothermic reaction?
A !he bond is formed
B !he temperature of the miture increases
C !he heat is absorbed from the surrounding
D !he energy content of the reactants is higher than the energy content of the products
". Which of the following reactions occurs when ice change to water ?
A #ndothermic
B #othermic
C Decomposition
D $eutrali%ation
&. 'ne mole of hydrogen ion reacts with one mole of hydroide ion to form one mole of
water.
!he above statement refers to
A heat of displacement
B heat of neutrali%ation
C heat of combustion
D heat of precipitation
(. !he reaction between magnesium ribbon and iron)**+ sulphate solution can be used to
determine the heat of
A displacement
B neutrali%ation
C combustion
D precipitation

1
,. !he diagram shows the energy level diagram of a reaction

#nergy Products
-eat of reaction

.eactants
Which of the following reactions represents the above energy level diagram?
A eothermic reaction
B endothermic reaction
C neutrali%ation reaction
D combustion reaction
/. Which of the following informations is not needed to deteermine the heat of precipitation?
A !he 0uantity of reactants
B !he number of moles of reactants
C !he changes of temperature of the mied reaction
D !he time ta1en for the precipitate to occur
8. Why is a copper can used2 in the eperiment to determine the heat of combustion ?
A As heat insulator
B Conduct heat easily
C .educe the heat loss
D -ave higher melting point
3. Which of the following is an eothermic reaction ?
A Dissolving ammonium chloride in water
B -eating copper)**+ sulphate hidrate
C $eutrali%ing hydrochloric acid with sodium hydroide solution
D 4iing hydrochloric acid with potassium hydrogen carbonate
56. What happen when the eothermic reaction occurs?
* -eat is released
** !he surrounding temperature increases
*** !he energy released is more than the energy absorbed
*7 8tronger bond is formed and wea1er bond is bro1en
A * and ** only
B *** and *7 only
C *2 ** and *** only
D *2 **2 *** and *7
2
55. Why is the bea1er feels cold when ammonium chloride is added into a bea1er that
contains water ?
A -eat is absorbed from the water
B A strong bond is formed
C 8pecific heat of water is decreased
D 9oss of heat to the surrounding
52. A polystyrene cup is used in the eperiment to determine the heat of reaction because
* it is very light
** it does not absorb heat from the solution
*** it does not conduct heat to the surrounding
*7 it ensures that the reaction reacts completely
A * and ** only
B ** and *** only
C *2 ** and *** only
D *2 **2 *** and *7
5". What is the information needed to determine the heat of neutrali%ation between acid and
al1ali ?

* *ncreased in the temperature of reaction miture
** 7olume of acid and al1ali used
*** Concentration of both solutions used
*7 8pecific heat of solution for miture reaction
A * and ** only
B *** and *7 only
C *2 ** and *7 only
D *2 **2 *** and *7
5&. Which of the following is not an endothermic reaction?
A 4elting of naphthalene
B Photosynthesis
C #vaporation of water
D .usting of iron
3
5(. !he diagram shows the set up of the apparatus of an eperiment to determine the heat of
neutrali%ation between an acid and an al1ali
thermometer
polystyrene cup
miture of acid and al1ali
Why is polystyrene cup used?
A 9ight and cheap
B Act as heat insulator
C 4ore safely than glass container
D $ot easily corrode by acid and al1ali
5,. What is the meaning of heat of combustion ?
A Combustion for 5 mole of fuel
B Combustion of 5 mole of fuel with oygen
C Complete combustion of 5 mole of fuel with 5 mole of oygen
D Complete combustion of 5 mole of fuel with ecess oygen
5/. Which of the following statements is true about eothermic reaction?
* Brea1ing of bond occurs
** Dissolving ammonium chloride in water
*** Chemical reaction that released energy to the surrounding
*7 $eutrali%ation between hydrochloric acid with potassium hydroide solution
A * and ** only
B *** and *7 only
C **2 *** and *7 only
D *2 **2 *** and *7
4
5:. Which of the following energy level diagram is ehotermic reaction?
A energy B energy
reactants reactants
H neg!ti"e H#ositi"e

#ro$u%ts #ro$u%ts

C energy & energy
#ro$u%ts #ro$u%ts


H neg!ti"e H #ositi"e

reactants reactants
1'. !he temperature of a miture decreases when
A a piece of potassium is added into water
B ammonium nitrate is dissolved in water
C %inc powder is added into copper )**+ sulphate solution
D dilute sulphuric acid is added into sodium hydroide solution
26. !he following e0uations show neutrali%ation reactions
-Cl )a0+ ; $a'- )a0+ $aCl )a0+ ; -2' )l+< = - > (/." 1?
C-"C''- )a0+ ; $a'- )a0+ C-"C''$a )a0+ ; -2' )l+< = -> @((. 1?
!he heat of reaction2 =-2 for the above reactions are different because ethanoic acid
A can easily conduct heat
B will loose heat energy to the surrounding
C absorb parts of the heat energy for ioni%ation
D has one hydrogen ion that is replace with sodium ion
25. -eat of combustion for different type of alcohols are shown below A
Alcohol 4ethanol #thanol Propanol Butanol
=-B 1? mol
5
C 5"/6 262( 2,:6
Which of the following is the suitable value of C ?
A 565( 1? mol
5
B /5( 1? mol
5
C 35( 1? mol
5
D ,5( 1? mol
5
(
22. !he following e0uation shows the reaction of the formation of ammonia.
$2 ; "-2 2$-"
#othermic reaction occurs because
A the heat released is more than the heat absorbed
B the value of heat change is positive
C total energy of the product is more than total energy of the reactant
D higher temperature will increase the 0uantity of the product
2". Which e0uation below is endhotermic reaction?
A -2')g+ -2')l+
B C'2 )g+ C'2)s+
C CuC'")s+ Cu')s+ ; C'2)g+
D $a'-)a0+ ; -Cl)a0+ $aCl)a0+ ; -2')l+
2&. Why is the reaction between wea1 acid and strong al1ali released less than (/ 1? mol
5
of
heat energy?
A strong al1ali ioni%e completely
B wea1 acid always absorb heat
C strong al1ali has strong bond
D heat is used to ioni%e wea1 acid
2(. !he e0uation below shows the reaction between hydrochloric acid and sodium hydroide
solution.
-Cl )a0+ ; $a'-)a0+ $aCl)a0+ ; -2')l+ = - > (/ 1? mol
5
Which of the following e0uation have the same heat of reaction with the above e0uation?
A -$'")a0+ ; $-&'- )a0+ $-&$'")a0+ ; -2')l+
B -$'")a0+ ; D'-)a0+ D$'")a0+ ; -2')l+
C C-"C''-)a0+ ; $-&'- )a0+ C-"C''$-&)a0+ ; -2'
D C-"C''-)a0+ ; D'-)a0+ C-"C''D)a0+ ; -2')l+
2,. Why is the heat of combustion for propanol is higher than the heat of combustion of
methanol ?
A !he molecular mass of propanol is higher than molecular mass of methanol
B Propanol is more reactive than methanol
C Propanol is easily burn than methanol
D Propanol has 5 carbon atom and 2 hydrogen atom more than methanol
2/. -eat of combustion for different type of al1ane is shown below A
)
4aterial
-eat of combustion
= - B 1? mol
5
4ethane C-& ::2.6
#thane C2-, 5(&2.&
Butane C&-56 2://."
What is the value of heat of combustion for propane2 C"-:
A :6( 1?mol
5
B 3&2 1?mol
5
C 2262 1?mol
5
D 23&& 1?mol
5
2:. !he following is an e0uation for a reaction
Cu8'& ; 2$a'- E Cu)'-+2 ; $a28'& =- > p 1? mol
5
Which of the following represents =- in the above e0uation?
A heat of displacement
B heat of neutrali%ation
C heat of combustion
D heat of precipitation
23. !he reaction between %inc and copper )**+ sulphate solution is an eothermic reaction.
Which of the following energy level diagrams represent the reaction?
A energy C energy
Cu
2;
; Fn Cu ; Fn
2;
Cu ; Fn
2;
Cu
2;
; Fn

B energy & energy
*n + Cu
2+
*n + Cu
2+

*n + Cu
2+
*n
2+
+ Cu
"6. When ecess magnesium is added to &66 cm
"
of ( mol dm
"
of copper )**+ sulphate2
the temperature increase from "6
6
C to "2
6
C. What is the heat of displacement of copper ?
,
2,/(
265/

5"/,
/5(
He!t o- %o./ustion0
12 .o3
1
Nu./er o- %!r/on !to.s #er !3%o4o3
.o3e%u3e
1 2 3 4 (
G spesific heat capacity > &.2 ?g
5 6
C
5
H
A 5,:6 ? mol
@5
C ,/26 ? mol
5
B "",6 ? mol
5
D 5,:66 ? mol
5
"5. An eperiment is carried out by miing ecess magnesium with (6 cm
"
of 6.2( mol dm
"
of iron )**+ chloride. !he energy level diagram for the reaction is shown below.
4g)s+ ; IeCl2)a0+
#nergy
5- > 265., 1? mol
5
4gCl2)a0+ ; Ie)s+
What is the temperature change in the eperiment?
G 8pecific heat capacity > &.2 ? g
5 6
C
5
H
A 5.6
6
C C 3.,
6
C
B 5.2
6
C D 52.6
6
C
"2. !he graph shows the heat of combustion of alcohol against the number of carbon
atom per alcohol molecule.
Calculate the
heat released when , g of
propanol is burnt ?
G.elative atomic mass A
C252< -25< '25,H
A 5/3.( 1?
C 26:./ 1?
B 265./ 1? D 25,.3 1?
"". When 5.: g of glucose is burnt in a bom calorimeter2 the heat released increase the
temperature of (66

cm
"
of water by 5"
6
C. Calculate the heat of combustion of glucose.
G .elative molecular mass of glucose>5:6< specific heat capacity of
water> &.2 ? g
5 6
C
5
H
A 2/"6 1? mol
5
B 2/"66 1? mol
5

8
C 2/"6 1? mol
5
D 2/:66 ? mol
5
"&. !he combustion of 6."2 g of methane increase the temperature of 2(6 cm
"
water from
2:
6
C to &,
6
C. Calculate the heat of combustion of methane.
G C252< -25< specific heat capacity> &.2 ?g
6
C
5
H
A @ &26 1? mol
5
B @ ,/& 1? mol
5
C @ 3&( 1? mol
5
D @ 56(, 1? mol
5
"(. When 6./2g of pentene is completely burnt2 the heat released caused 266 cm
"
of water
change from 2(
6
C to ,6
6
C. Calculate the heat of combustion of pentane ?
A 23&6 1? mol
5
B ""(6 1? mol
5
C "/:6 1? mol
5
D &2:6 1? mol
5
",. When 2( cm
"
of 2.6 mol dm
"
sodium hydroide solution is mied with 2( cm
"
of
2.6 mol dm
"
nitric acid2 the temperature rise by 5&
6
C. Calculate the heat change.
G 8pecific heat capacity> &.2 ?g
6
C
5
H
A 5&/6 ?
B 2"(2 ?
C 23&6 ?
D "2:6 ?
"/. !he combustion of 5.:g of glucose2 released heat that increase the temperature of (6
cm
"
of water by ,.(
6
C. Calculate the heat of combustion of glucose.
G .elative atomic massA C252< -25< specific heat capacity> &.2 ?g
6
C
5
H
A /(.: 1? mol
5
B 3".& 1? mol
5
C 5",.( 1? mol
5
D 25,." 1? mol
5
":. !he following e0uation shows a reaction.
-Cl)a1+ ; $a'-)a1+ $aCl)a1+ ; -2')ce+ - > (& 1? mol
@5
'
Calculate the increase in temperature of a solution when ,6 cm
"
of 6.( mol dm
"
of
hydrochloric acid reacts with (6 cm
"
of 6.( mol dm
"
of sodium hydroide solution.
G8pecific heat capacity> &.2 ?g
6
C
5
H
A 2.32
6
C
B &.52
6
C
C 3.5:
6
C
D 5&.,5
6
C
"3. !he following e0uation shows a reaction.
C)p+ ; '2)g+ C'2)g+ = - > &6.6 1? mol
5
Calculate the mass of carbon needed to release :.6 1? of heat for the reaction.
G .elative atomic massA C252< '25,< -25 H
A 6.2 g
B 2.& g
C ".2 g
D (., g
&6. !he combustion of 5.,g of methanol increase the temperature of 2(6 cm
"
of water by
"&
6
C. Calculate the increase in temperature of (66cm
"
of water from the combustion
of ".2g of methanol.
A 5./
6
C
B ".&
6
C
C 5/.6
6
C
D "&.6
6
C
&5. !he following e0uation shows a reaction.
C-&)g+ ; 2'2)g+ C'2)g+ ; 2-2')l+ =- > 366 1? mol
@5
Calculate the heat released when &g of methane2 C-& is completely burnt in oygen.
G .elative atomic mass A -25< C252 H
A 22.( 1?
B 22( 1?
C ",6 1?
D ",66 1?
&2. !he following shows an ionic e0uation for a reaction.
Pb
2;
)a0+ ; 8'&
2
)a0+ Pb8'&)s+ =-> (6.& 1? mol
@5
16
Calculate the change in temperature when lead)**+ sulphate2 Pb8'&2 is precipitate from
the reaction of (6 cm
"
of 5 mol dm
"
lead)**+ nitrate solution2 Pb)$'"+22 and (6 cm
"
of 5
mol cm
"
sodium sulphate solution2 $a28'&2
G 8pecific heat capacity of water> &.2 ?g
5 6
C
5
H
A 6.,
6
C
B ,.6
6
C
C 5.2
6
C
D 52.6
6
C
&". !he following e0uation shows a reaction.
Fn)s+ ; Cu8'&)a0+ Fn8'&)a0+ ; Cu)s+ = ->25/ 1? mol
@5
#cess %inc powder is added into 52( cm
"
of 6.5 mol dm
"
copper)**+ sulphate
solution2Cu8'&2 Calculate the rise in the temperature of the miture.
G 8pecific heat capacity of solution > &.2 ?g
5 6
C
5
H
A 6.(
6
C
B 5.:
6
C
C &.5
6
C
D (.2
6
C
&&. !he following e0uation shows a reaction.
C)s+ ; 62)g+E C'2)g+ < = - > @"3& 1? mol
@5
Based on the above e0uation2what is the heat released when (g of carbon is
completely burnt in oygen?
G .elative atomic massA C252 < '25, H
A 5,&.2 1?
B /::.6 1?
C 3&(., 1?
D 5 3/6.6 1?
&(. !he following e0uation shows a reaction.
8)s+ ; '2)g+ E 8'2)g+ < = - > @"66 1? mol
@5
Based on the above e0uation2 which of the following pairs of sulphur and oygen2 does
not released "66 1? of heat?
G.elative atomic massA '2 5, < 82 "2H
A "2g sulphur and 5,g oygen
B "2g sulphur and "2g oygen
C ,&g suphur and "2g oygen
D "2g sulphur and ,&g oygen
&,. !he following ionic e0uation shows a reaction.
11
Pb
2;
)a0+ ; 8'&
2@
)a0+ E Pb8'&)s+ < = - > @(6.& 1? mol
@5
Based on the above e0uation2 determine the highest temperature obtained when
(6 cm
"
of 6.( mol dm
@"
lead)**+ nitrate solution is mied with (6 cm
"
of 5.6 mol dm
@"

potassium sulphate solution if the initial temperature is "6
6
C.
G8pecific heat capacity of water > &.2 ? g
@5

6
CH

A 2&
6
C
B 2/
6
C
C ""
6
C
D ",
6
C
&/. Iour mitures W2 J2 C2 and F are obtained by miing 5.6 mol dm
@"
of sodium hydroide
solution with 5.6 mol dm
@"
of sulphuric acid. Which of the following mitures2 provide the
highest rise in temperature?

4iture
7olume of 5 mol dm
@"
of
sodium hydroide
solution )cm
"
+
7olume of 5 mol dm
@"
of
sulphuric acid
)cm
"
+
A W 26 26
B J &6 26
C C 26 &6
D F &6 &6

&:. Which of the following pairs of solutions2 produce the highest rise in temperature when
they are mied?
A 2( cm
"
of 6.5 mol dm
@"
sodium chloride and 2(cm
"
of 6.5 mol dm
@"
silver nitrate
solution
B (6 cm
"
of 6.5 mol dm
@"
sodium chloride and (6 cm
"
of 6.5 mol dm
@"
silver nitrate
solution
C 2( cm
"
of 6.2 mol dm
@"
sodium chloride and 2(cm
"
of 6.2 mol dm
@"
silver nitrate
solution
D 2( cm
"
of 6.5 mol dm
@"
barium chloride solution and 2( cm
"
of 6.2 mol dm
@"
silver
nitrate solution
&3. !he heat of combustion of glucose is @2 /"6 1? mol
@5
. Calculate the mass of glucose
needed to burn in a calorimeter bom if the heat released increase the temperature of
(66 cm
"
of water by 5"
6
C?
G .elative molecular mass A glucose25:6< 8pecific heat capacity of water> &.2 ? g
@5

6
C
@5
H
A 5.: g
B 56.6 g
C 366.6 g
D 5 :66.6g
(6. !he heat of combustion of ethanol is @5 "(6 1? mol
@5
. Calculate the mass of ethanol
burnt if 5(6 cm
"
of water is boiled. !he initial temperature of water is 2(
6
C .
G.elative molecular mass A ethanol2 &, < 8pecific heat capacity of water > &.2 ? g
@5

6
C
@5
H
A 6.6"(g
B 6.(&6g
C 6./,6g
D 5.,56g
Paper 2
12
Section A
G,6 marksH
Answer all questions in this section.
The time suggested to complete this section is 90 minutes
5. Diagram 5 shows the set up of the apparatus to determine the heat of combustion
of ethanol.
!hermometer

Wind shield copper can
water
!ripod stand
8pirit lamp
#thanol
Diagram 5
!he following data is obtainedA
4ass of lamp ; ethanol before burning > 2".&6 g
4ass of lamp ; ethanol after burning > 25.56 g
7olume of water > &66 cm
"
*nitial temperature of water > 2:.6
6
C
-ighest temperature of water > ,,.6
6
C
G 8pecific heat capacity of water > &.2 ?g
6
C< water density > 5 g cm
"
H
Based on Diagram 52 answer the following 0uestions.
a+ Why is copper can used in the eperiment?
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G5 markH
(Knowledge)
b+ Write the e0uation for the combustion of ethanol with ecess oygen.
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G5 markH
(Understanding)
c+ Based on the results obtained2 calculate
13
i+ the heat releasedin the eperiment
G5 markH
(Aplication)
ii+ the number of moles of ethanol burnt
G5 markH
(Aplication)
iii+ the heat of combustion of ethanol
G2 marksH
(Aplication)
d+ Draw the energy level diaram for the combustion of ethanol
G2 marksH
(Synthesis)
e+ *s the value of the heat of combustion of ethanol2 C2-('- obtained in the
eperiment the same as the theoretical value ? #plain
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KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK..
KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK.....
KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK.
KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK.
G" marksH
(Aplication)
f+ *s the heat of combustion of propanol is higher than ethanol? #plain.
14
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G2 marksH
(Understanding)
2. An eperiment is carried out to determine the heat of displacement for the reaction
between copper )**+ sulphate solution and ecess %inc powder. (6.6 cm
"
of 6.( mol dm
"
copper )**+ sulphate solution is poured into a plastic cup. !he initial temperature of the
solution is recorded. #cess %inc powder is added into a plastic cup. !he miture is
stirred and the highest temperature is recorded.
!he following data is obtainedA
*nitial temperature of copper )**+ sulphate solution > 2:.(
6
C
-ighest temperature of the miture > "".(
6
C
G .elative atomic mass A Cu2,&< 82"2< '25,< Fn2 ,(< 8pecific heat capacity
of water A &.2 ?g
5

6
C
5
H
a+ What is meant by the heat of displacement based on the eperiment?
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G5 markH
(Knowledge)
b+ Write an ionic e0uation for the reaction of the eperiment.
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G5 markH
(Understanding)
c+ 8tate two observations in the eperiment.
i+ KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK
ii+ KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK
G5 mar1H
(Analyse)
d+ Calculate2
i+ the heat released
G5 markH
(Aplication)
ii+ the number of moles of copper )**+ sulphate reacted
1(
G5 markH
(Aplication)
iii+ the heat of displacement
G5 markH
(Aplication)
e+ Why is %inc used in this eperiment is in powder form?
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G5 markH
(Understanding)
f+ Draw the energy level diagram for the reaction in this eperiment.
G2 markH
(Syntesis)
1)
". Diagram 2 shows the energy level diagram for the reaction between strong acid and
strong al1ali. !he heat of of neutrali%ation for the reaction in #periment * is
(/ 1? mol
5
.
#nergy
-
;
)a0+ ; '-

)a0+
-> (/ 1? mol
5
-2')l+
Diagram 2
a+ $ame one eample of strong asid and strong al1ali.
i+ 8trong acidKKKKKKKKKKKKKKKKKKKKKKKKKKKK
ii+ 8trong al1aliKKKKKKKKKKKKKKKKKKKKKKKKKKK..
G2 markH
(Knowledge)
b+ What is meant of heat of neutrali%ation?
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KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK
G5 markH
(Knowledge)
%7 An eperiment )eperiment **+ is carried out under the same condition2 that is (6
cm
"
of 5 mol dm
"
of ethanoic acid is mied with (6 cm
"
of 5 mol dm
"
strong
al1ali. !he temperature of the miture is increased by ,.(
6
C.
i+ Calculate the number of moles for strong al1ali used.
G5 markH
(Understanding)
ii+ Calculate the heat of neutrali%ation between ethanoic acid with strong al1ali.
Gspecific heat capacity of solution > &.2 ?g
5 6
C
5
<
density of solution > 5 g cm
"
H
G5 markH
(Understanding)
1,
d+ i+ Compare the heat of neutrali%ation for #periment * and #periment **
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KKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKKK
.
G5 markH
(Analysis)
ii+ #plain your answer.
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G2 marksH
(Analysis)
e+ *f #periment ** is repeated by miing 566 cm
"
of 5 mol dm
"
ethanoic acid with 5
moldm
"
of strong al1ali with the same concentration2 the temperature increased is
still ,.(
6
C. #plain.
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G" marksH
(Synthesis)

&. 2( cm
"
of 6.( mol dm
"
barium chloride solution is measured by using a mesuring
cylinder and poured into a polystyrene cup. !he initial temperature is recorded. !hen2
2( cm
"
of 6.( mol dm
"
sodium sulphate solution is measured and the initial
temperature is recorded. 8odium sulphate solution is poured into barium chloride
solution. !he miture is stirred and the highest temperature is recorded.
!he following data is obtainedA
*nitial temperature of barium chloride solution > 2:.6
6
C
*nitial temperature of sodium sulphate solution > 2:.6
6
C
-ighest temperature of the miture > "5.6
6
C
G8pecific heat capacity > &.2 ?g
5 6
C
5
H
a+ What is the colour of barium sulphate precipitate?
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G5 marksH
(Knowledge)
b+ Calculate
i+ the number of moles of barium ion
18
ii+ the number of moles of sulphate ion
iii+ the heat released
G" marksH
(Aplication)
c+ Write an ionic e0uation for the formation of barium sulphate precipitate.
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G5 marksH
(Understanding)
d+ Calculate the heat of precipitation of barium sulphate
G2 marksH
(Aplication)
e+ Draw the energy level diagram for the reaction.
G2 marks
(Synthesis)
1'
Section B
G26 marksH
Answer any one question.
The time suggested to answer this section is 30 minutes.
5. Diagram " shows the energy level diagram for a reaction between nitrogen and oygen
gas.
#nergy
2$'2 )g+
=- > ;,, 1? mol
5
$2)g+ ; '2)g+
Diagram "
)a+ #plain how the energy changes during the brea1ing and formation of bond in the
reaction based on the value of = - itu.
G, marksH
Understanding
#periment Procedure
!emperature changes of
the miture
*
**
4iing 2(cm
"
of 5.6 moldm
"
sodium
hydroide solution with 2(cm
"
of 5.6
moldm
"
nitric acid in a plastic bea1er.
4iing 2(cm
"
of 5.6 moldm
"
sodium
hydroide solution with 2(cm
"
of 5.6
moldm
"
methanoic acid in a plastic
bea1er.
!emperature is increased
by ,./(
o
C
!emperature is increased
by ,."6
o
C
!able 5
2. )b+ i+ Based on the result of the eperiment shown in table 52 calculate the heat of
neutrali%ation for #periment * and #periment **.
G8pecific heat capacity of the solution > &.2 ? g
5o
C
5
H
G56 marksH
Aplication
ii+ Compare the values of the heat of neutrali%ation in b)i+. #plain.
26
G& marksH
Analysis
Section C
G26 marksH
Answer any one question.
The time suggested to answer this section is 30 minutes.
5. )a+ !he following e0uations represent neutrali%ation reactions.
.eaction * A
-Cl)a0+ ; $a'-)a0+ $aCl)a0+ ; -2')l+ = - > J 1? mol
5
.eaction ** A
C-"C''-)a0+ ; $a'-)a0+ C-"C''-$a)a0+ ;-2')l+ = - > C 1? mol
5
!he heat of neutrali%ation for both reactions are different. 8tate the differences and
eplain.
G& marksH
)b+ Diagram & shows the energy level diagram of a reaction.
#nergy
Ag
;
; Cl

- > negative
AgCl
Diagram &
i+ $ame the reactants involved.
G2 marksH
ii+ Write the chemical e0uation for the reaction.
G5 markH
iii+ What is the assumption made in calculating the heat of precipitation in this
eperiment.
G2 marksH
)c+ Describe an eperiment to determine the heat of neutrali%ation of sulphuric acid2
-28'& with pottassium hydroide solution2 D'-. Cour eplaination should include
chemical e0uation for the reaction2 calculations involved and precautions in getting
a more accurate results.
G56 marksH
21
Paper 3
Answer all question in this section
5. Diagram 5 shows the set up of the apparatus to determine the heat of displacement of
iron by magnesium metal.
Displacement of iron by magnesium occurs as shown in the e0uation below A
4g ; Ie8'& 4g8'& ; Ie
a+ i+ Based on the information in diagram 52 complete the table A
*nitial temperature of iron )**+ sulphate solution)
o
C+
-ighest temperature of iron )**+ sulphate
solution)
o
C+
iii+ 8tate the type of reaction that occurs?

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b+ 8tate one observation in the eperiment.

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22
Initi!3 te.#er!ture
Hig4est te.#er!ture
T4er.o.eter
8e!suring /ott3e
9:%ess .!gnesiu.
#ow$er
166%.
3

iron ;II7
su3#4!te
so3ution
stir
&i!gr!. 1
<in$ s4ie3$
T4er.o.eter
Co##er %!n

Tri#o$ st!n$
S#irit 3!.#
A3%o4o3
<oo$en /3o%1
c+ i+ Predict the change of temperature if the eperiment is repeated by using a bigger
base polystyrene cup.

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ii+ #plain.

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c+ Why is magnesium used in this eperiment is in powder form ?
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2. Diagram 2 shows the set up of the apparatus used to determine the heat of combustion
for different type of alcohol
water
Diagram 2
23
T4er.o.eter
=o3ystyrene %u#
Bigger /!se
stir
!able 2 shows the results obtained from the eperiment.
Alcohol
$umber of carbon atoms per
alcohol molecule
-eat of combustion of
alcohol )1? mol
L5
+
4ethanol2 C-"'- 5 L/5&
#thanol2 C2-('- 2 L5"(&
Propan@5@ol2 C"-/'- "
Butan@5@ol2 C&-&'- & L2(,&
a+ i+ Draw a graph of the heat of combustion of alcohol against the number of carbon
atoms per alcohol molecule.
iii+ Based on the graph2 determine the heat of combustion of propanol.

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b+ 8tate the variables for the eperiment.
i+ .esponding variable
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ii+ 4anipulated variable
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iii+ Constant variable
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c+ 8tate the hypothesis for the eperiment.
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d+ What is the relationship between the number of carbon atoms with the value of
the heat of combustion of alcohols
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24
".
!he following information shows the heat of combustion of two types of alcohols.
Plan an eperiment to compare the heat of combustion of the alcohols. Cour planning should
include the following aspects.
)a+ Problem statement
)b+ All the variables
)c+ statement of the hypothesis
)d+ 9ist of substances and apparatus
)d+ Procedure of the eperiment
)e+ !abulation of data.
G5/ markH
Heat of combustion of ethanol = - 1376 kJ mol
-1
Heat of combustion of propan- 1- ol = - 2016 kJ mol
-1
2(