C(t-rs{1y

PAPER2 MARKING SCHEME

Question
No.
Explanation Mark I Mark
I (a)
b(D
(iD
c(i)
(iD
d(D
(iD
(iii)
No ofelectrons: 18, No of neutrons
=
22
The total number ofprotons and neutrons in the nucleus
of an atom
40
2. 7
w.Y
Isotoires have the same number ofvalence
electl'ons./proton number
Carbin dating to estimate the age of fossils
/artefacts/wood
Total Marks
1+l
1
1
1
2
1
I
1
10
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Question
No.
Explaration Mark X Mark
2(a)
(b)
(D
(iD
(c)
(d) (D
(iiD
(e)
(0
Ts a represenktion of a chemical substance using lerters
for atoms and subscripts for each type of atoms present
in the substance.
I
Able to name suitable acid and metal and its equation
]
For example
Hydrochloric acid and zinc metal
Zn+2HCl ) ZnCl 2 +
LI 2
Hydrogen gas must be flowed/through/into the
combustion tube for a few minutes before heating/
The flow o1'hydrogen gas must be continuous throughout
the experimenV
I
Accept any one answer]
Number of mole of copper
=
i.62
64
' 0. 025mo1e
Number of mole of oxygen
=
0.40
t b
: 0. 025mo1e
Numper of mole of copper : Number of mole of oxygen
0.025 : 0.025
The simplest ratio 1 : 1
'I'he
empirical formula of copper(Il) oxide is CuO
Iron(II) oxide / Tin(II) oxide / Lead(II) oxide
Burning of metal in exccss o.xygen
Total marks
I
I
1
1
I
I
I
I
I
r 0
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Question
No.
Explanation MK I Mark
3 (aX0
(ii)
(bXD
(iD
c(i )
(i D
d(D
(iD
Group 1
G
and Period 4
DzL
Soluble in water// high melting / boiling poinV/ conducts
electricity in molten or aqueous solution
E
The nuclei attraction towards the valence electrons is
weaker in E.
'I'hus
it is easier for E to lose / release an electron to
form a positively charged ion.
L//M
Covalent bond
Total Marks
1+
1
1
I
1
1
I
1
i
10
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Question
No.
Explanation
Ivlark X Mark
4 (a)
(b)
(c)
(d)
(e)
(r)
(e) (i)
(iD
A weak acid is an acid that dissociates
partially in
water to produce hydrogen ions
I
Sour
I
t
I
Colourless to pink
I
t
Neutralisation is an exothermic reaction./ releases heat
I
1
Some ofthe energy produced during the reaction
I
between a weak acid and strong base is used to
I
ionise/dissociate completely the weak acid molecules.
I
t
H - + OH - t I - I 2 O
I
I
I
Number of moles of malic acid=
)=Q0
I
=
l'oo,r, -",
I
t
I
Number ofmoles ofsodium hydroxide used
I
: 2. 00
x 17. 30
|
l ooo
]
:
0.0746 mol i
I
I
1 mble of H* reacts with 1 mole of OH-
l
ThuS. number of mole of H+ ions
I
I
in the sample
=
0.0746
I
t
l l
] .
O.O:Z+ mote of malic acid produces 0.0746 mole of
I
L
nydrogen lon.
I
I
Hence, I mole of malic acid produces 0.0J46
i
I
o.orz:
l
l ^
: 2mol eof r f
I
'
l o '
|
ilo rf -of" of malic,acid : No^of mole of NaoH
]
l 1 : 2 I
I
Therefore, malic acid is diprotic
(proven)
i
]
total ma4r
]
10
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Question
No.
t r w nl onot i nn Mark X Mark
sa(i)
(iD
(i i D
(b)
(c)(i)
(iD
Haber Prooess
3H2+N2) 2NH:
Catalyst : Iron
Temperature : 450oC
Sulphur trioxide is dissolved in concentrated HzSQ+
to lorm oloum
Oleum is diluted with water to produce sulphuric acid
(NH+)zSO+
% of N: 4! D
x 100%
132
:
21.21vo
Total marks
I
1 l
I
I
l l
r l
1 l
I
1
1
1
l 0
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Question
No.
Explanation
Mark I Mark
6(aXD
(iD
Ethanol
One mole of ethanol when completely bumt in oxygen
(undcr standard conditions) will release i260 kJ ofheat
energy
No of moles of alcohol
:
0.23 I 46
:
0.005 mol
I nrol ot alcohol burnt released lf60 kJ
Thus, 0.005 mol ofalcohol burnt released 6.3 kJ
mca: 6,3 kJ
Mcs: 6. 3 x 1000
6: 6300/ 20Ox 4. 2
=
7. s" C
(bXD
(i l )
(cJ Heat is lost to the sunounding // Heat is absorbed by
the apparatus or containers // Incomplete combustion
(d)
C z H s OH + 3 0 2
A F i : - 1260
KJMOI
I Reaction path
I
Lub"l "n".gy -d diagram has 2 different energy levels
I
Balanced chemical equation
(e)
I
-
2656 kJmorr // 2500-2700 kJmofl
Total marks
I
I
I
I
I
I
1
I
1
I
10
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Question
No.
Explanation
Mark X Mark
7(a)
(bXD
(iD
(c)
but-1-ene
but-2-ene /
2-methylpropene
1. Correct skuctural formula
2. Correct name
[Any
two structural formulae and related names]
X: propanol / propan-l
-ol
/ propan-2-ol
Y: propan-1,2-diol Z : propane
React i on I : C: Ho+ Hzo)C: HzOH
Reaction II : C:He + H20 +
[O]
) C3Hr6(Oll)2
Reaotion III : C: Ik + FIz I C:Hr
1. Hexene is a unsaturated hydrocarbon while hexane
is a saturated hydrocarbon
2. Hexene has a double bond between carbon and
carbon atoms
3. Undergoes addition reaction when it reacts with
bromine water
4. Hexane has single bond between carbon and carbon
atoms
5. Cannot react with bromine water
6.
' /o
of C in CaHr+
=
6(12) x 100%
86
7.
: 83. 72%
8. % of C i n CeHru: 6(12) x 100%
84
9.
=
85.71%
10. The percentage of carbon atoms in CeHr: is higher
than CoHr+
Total marks
H _
Fr
I
F I
, C :
} I H I I H
r t t t
f l - c = c
- c -
c - l t
l { H
F I H F I H
l l l l
FI
-
C
-
C
-
C
-
C
- H
l l
H H
FI
I
c . - l {
l H
t l
C _ C : _ H
I
I{
l +
4
l + 1
l + l + l
1
I
I
I
1
I
I
1
1
I
3
^
3
l 0
20
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Question
No.
Explanation
Mark I Mark
8 (aXD
(b) (D
(ii)
Correct apparatus set up
Correct labelling
Volume of gas I cmr
Time/min
Curve
labelf ing a.xes with units
CaCOr
+ 2IlCl * CaClz
No. of mol es aci d
-
(0. 1)(50)
=
1000
1
I
I
+ CO:
+ HzO
5 x 10-3
2 mol of I'ICI reaated evolve I mol of COz
0.005 mol of HCI reacted evolve 0.005 mol of COz
2
=
0.0025 mol COz
Volume of CC,
:(0.0025X24)
=
0.05 dm'
=
60 cm"
Overall average rate ofreaction
=Total
volume of COz
Total time
=
60 cm3
300 s
= 0 . 2 c m3 s l
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Rate of reaction in Expt II is higher than Expt I
Experiment Il is at a higher temperature,
the kinetic energy ofthe reaoting oarticles increases
and the particles move I'aster
Frequency ofcollision between marble and hydrogen
ions increases
Frequency o f efFectivc collision increases
Rate of reaction in Expt III is higher than Expt I
Powdered marble in Expt III has greater total surface
areal bigger surfbce area per unit volume
Powdered marble is more exposed to collision
Frequency of collision between marble and hydrogen
ions increascs
Frequencv of elfcctive collision increase
[
-l
if students use HCI or particles in the explaination]
I
I
1
1
1
1
i
I
1
1
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Question
No.
Explanation
Mark I Mark
e (a)(i)
(b)
(c)
Precipitation // Exothermic
Ag ' + Cl - t Ag c l
Salt Y is added into a test tube and distilled water is
added to dissolve it.
The aqueous solution is separated into 3 portions.
Sodium hydtoxide solution is added into one portion
until in excess
White precipitate formed dissolves in excess sodium
hydroxide solution
showing zinc ion
,
lead ion & aluminium ion may be
present in salt Y.
Ammonia solution is added to another
portion
until in
excess .
White precipitate dissolves
confirming the presence of ion zinc in salt Y.
Dilute sulphuric acid is added to t}te last portion
,
followed by acidified iron (II) sulphate solution and
concentrated sulphuric acid.
Brown ring formed
sho*s the presence of NOr- ion in salt Y.
Preparation of zinc
sulphate salt
About 50 cm3 of 1 mol dm-3 sulphuric acid is poured
into a beaker.
The beaker containing the sulphuric acid is heated
gently .
Zinc oxide powder is added little by liule into the
warm sulphuric acid,
and stirred continuously till the zinc oxide powder no
longer dissolves in the acid.
The excess zinc oxide is removed by filtering.
The solution ofzinc sulphate /tle filtrate is poured into
an evaporating dish
and heated until it becomes saturated / concentrated.
The hot saturated zinc sulphate solution is allowed to
1
I
I
I
1
I
1
i
1
1
I
1
I
1
i
1
I
I
I
2
Max 8
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cool and crystals of zinc sulphate are formed.
The zinc sulphate crystals are filtered and then dried
between sheets of filter papers.
The equarion lor lhc rcaction is:
ZnO +
H2SOa---+ ZnSOa+ ll2O
(accept procedures in active voice)
I
I t 0
Total marks
20
Question
No.
Explanation
Mark I Mark
10 (a)
I
Chemical Equations : tt and III
I
I
Reasons : Involving oxidation and reduction occurring
]
simultaneously/at the same time
I
Reaction II
Oxidation: Cu loses electron to form Cu:*
I Reduction: Ag- gain electron to form Ag
// Electron transfbr from Cu to Ag*
or
I
O,.idution, Zn ioses electron to form Zn2'
I ^ ,
]
Reduct i on: 2H' gai n el ecnon ro f orm H;
l o r
I
Oxidation: Oxidation number of Zn increase from 0 to 2+
]
Reduction: Oxidation number of Ff decrsase from +l to 0
I
i/ Eleotron transfer lrom Znto H+
I
(bxi)
j
Bromine water
Oxidation number of Ag' decrease from +1
to 0
Terminal Half-
Observation
negative Fet * ) Fej * +e
Green to brown/yellow
positive Br 2 I
2s) 2Br - bro$.n to colourless
/decolourises
(iD
t +l
I
l + 1
Max 6
i
l
l +l
1
l +l
I +1
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Draw out I cm' of the solution from terminal nesative into a
test tube.
Add NaOH / NH3 solution /
Potassium l{exanocyanofenzte(Il) solution to the test tube
Observation: Brown ppt / brown ppt / dark blue ppt
respectively.
Shows that iron(il) ion is changed / oxidised to iron(Il) ion
[
-l
if students does not construct a table
]
Electrolytic Cells Chemicals Cells
Energy
change
Electrical energy
) Chemical
energy
Chemical Energy
) Electrical
Energy
Half-equation
at anooe
Cu I Cu'-
+ 2e Zn l Zn"'
+
2e
Electron flow Electrons flow
Iiom anode to
cathode.
Electrons flow from
zinc to copper./
l +l
1+1
1+l
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