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Abstract
Reduced graphene oxide (RGO) was prepared via low-temperature heat treatment, which was used to study on the effect of
aqueous electrolyte on electrochemical properties of RGO. The RGO were characterized by X-ray diffraction (XRD), field
emission scanning electron microscope (FESEM) and transmission electron microscope (TEM), the electrochemical properties of
RGO were investigated by cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy
techniques. The results indicate that the retained functional groups were benefit for the improvement of specific capacitance and
the specific capacitance of RGO in 1 mol/LH2SO4 was better than that in 1 mol/L Na2SO4.
Keywords: Aqueous Electrolyte; Low-temperature; Reduced Graphene Oxide; Electrochemical Properties
014010
RGO
X XRDFTIRFESEMTEM
RGO
RGO
1 mol/LH2SO4 1 mol/LNa2SO4
[1-3]
[4]
[5-7]
[8-12]12
3
*
511640262010Y2004
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Hummers[13]
[14, 15][16][17]
>700400~700<400
[18]
[19]
[1,6]
1.1
G399 AR
AR
ARAR30%AR
1.2
Hummers [13](GO) 80
35 4h 50 30wt%
340 2hAr
1.3
1 mol/L H2SO4 1 mol/L Na2SO4
75:20:5 11cm
10Mpa 12h
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2.1
2.1.1
GO TG
100
2
90
80
Weighe/%
60
Heat Flow/mW
DTA
70
TG
50
-2
40
30
0
100
200
300
400
500
600
700
Temperature/
1 GO TG
1 GO ~700 TG-DTA TG GO
~125 12.55% GO
125~180 26.15% GO
180~340 26.4% GO
340 Ar [20]
340 2h
2.1.2
XRD
intensity/a.u
GO
RGO
10
20
30
40
50
60
2 /(deg.)
2 GO RGO XRD
2.1.3
FTIR
GO
Transmittance/(a.u.)
C=O
4000
C-OH
C-OH
-OH
C-O
RGO
3600
3200
2800
2400
2000
1600
Wavenumber/cm
1200
800
400
-1
3 GO RGO FTIR
3 GO RGO GO 1730 cm-1 C=O 13651425 1615 cm-1 COH O-H 1080 cm-1 C-O RGO FTIR ,
GO
2.1.4
FSEM TEM
aRGO TEM
bRGO FSEM
cRGO
2.2
2.2.1
H2SO4
Na2SO4
-1
-2
-3
0.0
0.2
0.4
0.6
0.8
1.0
Potential vs SCE / V
4 RGO 20 mV/s
4 20mV/s RGO
, 00.6 V ,
, RGO
4 H2SO4 Na2SO4 Cm
1[22];
V2
Cm
V idV
m v V2 V1
1
(1)
1, m (g); v v/sV V
H2SO4 Na2SO4 143F/g 81F/g
H+ Na+ H+
H2SO4
Na2SO4
2.2.2
Nyquist X [23] 5
H2SO4 0.19 0.79 H2SO4
Na2SO4 1/4
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22
20
18
Z''/
16
14
H2SO4
12
Na2SO4
10
8
6
4
2
0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Z'/
3.5
4.0
4.5
5.0
5.5
6.0
5 RGO
2.2.3
0.8
Potential/V
Na2SO4
0.6
H2SO4
0.4
0.2
0.0
-20
20
40
60
80
100
120
140
160
Time/s
6 RGO (1 A/g)
6 1A/g RGO
,
Cm 2[22]
Cm
I t
m V
1 GO RGO XRD GO
FESEM RGO GO
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1985-
1982-
Email: hyuanhy@gmail.com
Email: xingrg06@163.com
1973-
1982-
Email: bangwenz@126.com
Email: quan820720@126.com
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