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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273
IIT-1EE-Chemistry-Screening-2002

SCREENING


1. How many moles oI electron weighs one kilogram?

(A) 6.023 x 10
23

(B) 1/9.108 x 10
31

(C) 6.023/9.108 x 10
54

(D) 1/(9.108 x6.023) x 10
8


2. Which oI the Iollowing volume (V) temperature (T) plots represents the behavior oI
one mole oI an ideal gas at the atmospheric pressure?





3. II the Nitrogen atom had electronic conIiguration 1s
7
, it would have energy lower
than that oI the normal ground state conIiguration 1s
2
2s
2
2p
3
, because the electrons
would be closer to the nucleus. Yet 1s
7
is not observed because it violates
(A) Heisenberg uncertainty principle
(B) Hund's rule
(C) Pauli exclusion principle
(D) Bohr postulate oI stationary orbits

4. RutherIord's experiment , which established the nuclear model oI the atom, used a
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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273
(A) -particles , which impinged on a metal Ioil and got absorbed
(B) -rays, which impinged on a metal Ioil and got scattered
(C) Helium atoms , which impinged on a metal Ioil and got scattered
(D) Helium nuclei , which impinged on a metal Ioil and got scattered

5. When the temperature is increased, surIace tension oI water
(A) Increases
(B) Decreases
(C) Remains constant
(D) Shows irregular behaviour

6. A substance A
X
B
Y
crystallizes in a Iace centered cubic (FCC) lattice in which
atoms 'A' occupy each corner oI the cube and atoms 'B' occupy the centers oI each Iace oI
the cube. IdentiIy the correct composition oI the substance A
X
B
Y

(A) AB
3

(B) A
4
B
3

(C) A
3
B
(D) Composition cannot be speciIied

7. Consider the chemical reaction N
2
(g) 3H
2
(g) --~ 2NH
3
(g). The rate oI this
reaction can be expressed in terms oI time derivative oI concentration oI N
2
(g), H
2
(g), or
NH
3
(g). IdentiIy the correct relationship amongst the rate expressions
(A) Rate -d|N
2
|/dt -1/3 d|H
2
| /dt 1/2 d|NH
3
| /dt
(B) Rate -d|N
2
|/dt -3 d|H
2
| /dt 2 d|NH
3
| /dt
(C) Rate d|N
2
|/dt 1/3 d|H
2
| /dt 1/2 d|NH
3
| /dt
(D) Rate -d|N
2
|/dt - d|H
2
| /dt d|NH
3
| /dt
8. Standard electrode potential data are useIul Ior understanding the suitability oI an
oxidant in a redox titration. Some halI cell reactions and their standard potentials are
given below
MnO
4
-
(aq.) 8H

(aq.) 5e --~ Mn
2
(aq.) 4H
2
O ( E
0
1.51 V
Cr
2
O
7
2-
(aq.) 14 H

(aq.) 6e --~ 2Cr
3
(aq.) 7H
2
O () E
0
1.38V
Fe
3
(aq.) e --~ Fe
2
(aq.) E
0
0.77V
Cl
2
(g) 2e --~ 2Cl
-
(aq.) E
0
1.40V
IdentiIy the only incorrect statement regarding the quantitative estimation oI aqueous
Fe(NO
3
)
2
.
(A) MnO
4
-
can be used in aqueous HCl
(B) Cr
2
O
7
2-
can be used in aqueous HCl
(C) MnO
4
-
can be used in aqueous H
2
SO
4

(D) Cr
2
O
7
2-
can be used in aqueous H
2
SO
4


9. SpeciIy the coordination geometry around and hybridization oI N and B atoms in
a 1:1 complex oI BF
3
and NH
3

(A) N: tetrahedral , sp
3
; B: tetrahedral, sp
3

(B) N: pyramidal, sp
3
; B: pyramidal, sp
3

(C) N: pyramidal, sp
3
; B: planar, sp
2

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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273

10. One mole oI a non-ideal gas undergoes a change oI state (2.0 atm. 3.0 L, 95 K ) a
(4.0 atm. 5.0 L, 245 K) with a change in internal energy , DU 30.0L atm. The change
in enthalpy (H) oI the process in L atm is
(A) 40.0
(B) 42.0
(C) 44.0
(D) Not deIined, because pressure is not constant

11. Consider the Iollowing equilibrium in a closed container

N
2
O
4
(g) --~ 2NO
2


At a Iixed temperature, the volume oI the reaction container is halved. For this change,
which oI the Iollowing holds true regarding the equilibrium constant (K
p
) and degree oI
dissociation ()?
(A) Neither K
P
nor u change
(B) Both K
P
and u change
(C) K
P
changes, but u does not change
(D) K
P
does not change, but u change

12. Which oI the Iollowing hydrocarbons has the lowest dipole moment ?



13. Compound A` (molecular Iormula C3H8O)is treated with acidiIied potassium
dichromate to Iorm a product B` (molecular Iormula C3H6O) B` Iorms a shining silver
mirror on warming with ammoniacal silver nitrate. B` when treated with an aqueous
solution oI H2NCONHNH2 and sodium acetate gives a product C`. IdentiIy the structure
oI C`


14. IdentiIy the correct order oI reactivity in electrophilic substitution reactions oI the
Iollowing compounds


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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273




(A) 1~2~3~4
(B) 4~3~2~1
(C) 2~1~3~4
(D) 2~3~1~4

15. IdentiIy the correct order oI boiling points oI the Iollowing compounds
CH
3
CH
2
CH
2
CH
2
OH CH
3
CH
2
CH
2
CHO CH
3
CH
2
CH
2
COOH
1 2 3

(A) 1~2~3
(B) 3~1~2
(C) 1~3~2
(D) 3~2~1

16. IdentiIy the set oI reagents / reaction conditions 'X' and 'Y' in the Iollowing set oI
transIormations
CH
3
- CH
2
- CH
2
Br --X-~ product --Y-~ CH
3
- CH - CH
3

,
Br
(A) X dilute aqueous NaOH, 20
0
C; Y HBr / acetic acid, 20
0
C
(B) X concentrated alcoholic NaOH, 80
0
C; Y HBr / acetic acid, 20
0
C
(C) X dilute aqueous NaOH, 20
0
C; Y Br
2
/ CHCl
3
, 0
0
C
(D) X concentrated aqueous NaOH, 80
0
C; Y Br
2
/ CHCl
3
, 0
0
C

17. IdentiIy a reagent Irom the Iollowing list which can easily distinguish between 1-
butyne and 2-butyne
(A) Bromine, CCl
4

(B) H
2,
Lindlar catalyst
(C) Dilute H
2
SO
4,
HgSO4
(D) Ammoniacal CuCl
2
solution

18. Consider the Iollowing reaction



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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273




19. Which oI the Iollowing acids has the smallest dissociation constant?
(A) CH
3
CHFCOOH
(B) FCH
2
CH
2
COOH
(C) BrCH
2
CH
2
COOH
(D) CH
3
CHBrCOOH
20. Which oI the Iollowing compounds exhibits steroisomerism?
(A) 2-methylbutene- 1
(B) 3-methylbutyne-1
(C) 3-methylbutanoic acid
(D) 2-mtethylbutanoic acid

21. The nodal plane in the H-bond oI ethane is located in
(A) The molecular plane
(B) A plane parallel to the molecular plane
(C) A plane perpendicular to the molecular plane which bisects the carbon - carbon o-
bond at right angle
(D) A plane perpendicular to the molecular plane which contains the carbon - carbon
o-bond

22. Polyphosphates are used as water soItening agents because they
(A) Form soluble complexes with anionic species
(B) Precipitate anionic species
(C) Form soluble complexes with cationic species
(D) Precipitate cationic species

23. IdentiIy the correct order oI acidic strengths oI CO
2
, CuO, CaO, H
2
O
(A) CaO CuO H
2
OCO
2

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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273
(C) CaOH
2
OCuOCO
2

(D) H
2
OCO
2
CaOCuO

24. IdentiIy the least stable ion amongst the Iollowing
(A) Li
-

(B) Be
-

(C) B
-

(D) C
-


25. Which oI the Iollowing molecular species has unpaired electrons (s)?
(A) N
2

(B) F
2

(C) O
2
-

(D) O
2
2-


26. A gas 'X' is passed through water to Iorm a saturated solution. The aqueous
solution oI treatment with silver nitrate gives a white precipitate. The saturated aqueous
solution also dissolves magnesium ribbon with evolution oI a colourless gas 'Y'. IdentiIy
'X' and 'Y'.
(A) X CO
2
, Y Cl
2

(B) X Cl
2
, Y CO
2

(C) X Cl
2
, Y H
2

(D) X H
2
, Y Cl
2

27. An aqueous solution oI a substance gives a white precipitate on treatment with
dilute hydrochloric acid, which dissolves on heating. When hydrogen sulIide is passed
through the hot acidic solution, a black precipitate is obtained. The substance is a
(A) Hg
2
2
salt
(B) Cu
2
salt
(C) Ag

salt
(D) Pb
2
salt

28. Which oI the Iollowing process is used in extractive metallurgy oI magnesium?
(A) Fused salt electrolysis
(B) SelI reduction
(C) Aqueous solution electrolysis
(D) Thermite reduction

29. IdentiIy the correct order oI solubility oI Na
2
S, CuS and ZnS in aqueous medium
(A) CuS ~ ZnS ~ Na
2
S
(B) ZnS ~ Na
2
S ~ CuS
(C) Na
2
S ~ CuS ~ ZnS
(D) Na
2
S ~ ZnS ~ CuS

30. Anhydrous Ierric chloride is prepared by
(A) Heating hydrated Ierric chloride at a high temperature in a stream oI air
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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273
(C) Reaction oI Ierric oxide with hydrochloric acid
(D) Reaction oI metallic iron with hydrochloric acid
MAIN
Time : Two hours Max. Marks : 60

Instructions
1. The Question Paper has 4 printed pages and has 12 questions. Please ensure that the
copy oI the Question Paper you have received contains all the questions.
2. Attempts ALL questions. Each question carries 5 marks.
3. Answer each question starting on a new page. The corresponding Question number
must be written in the leIt margin.
4. Do not write more than one answers Ior the same question. In case you attempt a
question more than once, please cancel the answer(s) you consider to be wrong.
Otherwise, only the answer appearing last will be evaluated.
5. Use only Arabic numerals (0, 1, 2 .............9) in answering the questions irrespective
oI the language in which your answer.
6. Use oI logarithmic tables is NOT PERMITTED.
7. Use oI calculators is NOT PERMITTED.
8. Both magnitude and direction oI vector quantities, iI any, in your answer should be
indicated clearly.
9. Irrational numbers, iI any, in your answer need not be expressed in decimal Iorm.
10. II the Iinal answer appears in the Iorm oI a ratio or a product oI two numbers, that
need not to be Iurther simpliIied.
_______________________________________________________________

1. Five isomeric para-disubstituted aromatic compounds A to E with molecular
Iormula C
8
H
8
O
2
were given Ior identiIication. Based on the Iollowing observation, give
structures oI the compounds.
(i) Both A and B Irom a silver mirror with Tollen's reagent; also, B gives a positive
test with FeCI
3
solution.
(ii) C gives positive idoIorm test.
(iii) D is readily extracted in aqueous NaHCO
3
solution.
(iv) E on acid hydrolysis gives 1, 4-dihydroxybenzene.

2. 500 mL oI 0.2 M aqueous solution oI acetic acid is mixed with 500 mL oI 0.2 M
HCI at 250
o
C.
(i) Calculate the degree oI dissociation oI acetic acid in the resulting solution and pH
oI the solution.
(ii) II 6 g oI NaOH is added to the above solution, determine the Iinal pH. |Assume
there is no change in volume on mixing; K
a
oI acetic acid is
1.75 10
-5
mol L
-1
|.
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GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273
3. Deduce the structures oI |NiCI
4
|
2-
and |Ni(CN)
4
|
2-
considering the hybridization
oI the metal ion. Calculate the magnetic moment (spin only) oI the species.
4. The density oI the vapour oI a substance at 1 atm pressure and 500 K is 0.36 kg
m
-3
. The vapour eIIuses through a small hole at a rate oI 1.33 times Iaster than oxygen
under the same condition.
(a) Determine (i) molecular weight, (ii) molar volume, (iii) compression Iactor (Z) oI
the vapour and (iv) which Iorces among the gas molecules are dominating, the attractive
or the repulsive?
(b) II the vapour behaves ideally at 1000 K, determine the average translational
kinetic energy oI a molecule.

5. Write balanced equations Ior the reactions oI the Iollowing compounds with
water:
(i) AI
4
C
3

(ii) CaNCN
(iii) BF
3

(iv) NCI
3

(v) XeF
4


6. IdentiIy X, Y and Z in the Iollowing synthetic scheme and write their structures.
|i| NaNH
2
H
2
/Pd BaSO
4
alkaline KMnO
2

CH
3
CH
2
C ? C - H -------------~ X -------------> Y ----------------~ Z
|ii| CH
3
CH
2
Br
Is the compound Z optically active? JustiIy your answer.

7. How is boron obtained Irom borax? Give chemical equations with reaction
conditions. Write the structure oI B
2
H
6
and its reaction with HCI.

8.
64
Cu (halI-liIe 12.8 h) decays by b
-
emission (38), b

emission (19) and

electron capture (43). Write the decay products and calculate partial halI-lives Ior each
oI the decay processes.

9. When a white crystalline compound X is heated with K
2
Cr
2
O
7
and concentrated
H
2
SO
4
a reddish brown gas A is evolved. On passing A into caustic soda solution, a
yellow coloured solution oI B is obtained. Neutralizing the solution oI B with acetic acid
and on subsequent addition oI lead acetate a yellow precipitate C is obtained. When X is
heated with NaOH solution, a colourless has is evolved and on passing this gas into
K
2
HgI
4
solution, a reddish brown precipitate D is Iormed. IdentiIy A, B, C, D and X.
Write the equations oI reactions involved.

10. Write the structures oI the products A, B, C, D and E in the Iollowing scheme.

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GRAVITY CLASSES
GRAVITY CLASSES, SCF-137, SEC-17, MKT, PH-0129-6464273


11. A biologically active compound, Bombykol (C
16
H
30
O) is obtained Irom a natural
source. The structure oI the compound is determine by the Iollowing reactions.
(a) On hydrogenation, Bombykol gives a compound A, C
16
H
34
O, which reacts with
acetic anhydride to give an ester,
(b) Bombykol also reacts with acetic hydride to give another ester, which on
oxidative ozonolysis (O
3
/H
2
O
2
) gives a mixture oI butanoic acid, oxalic acid and 10-
acetoxy decanoic acid.
Determine the number oI double bonds in Bombykol. Write the structures oI compound
A and Bombykol. How many geometrical isomers are possible Ior Bombykol?

12. Two moles oI a perIect gas undergo the Iollowing processes:
(a) a reversible isobaric expansion Irom (1.0 atm, 20.0 L) to (1.0 atm, 40.0 L);
(b) a reversible isochoric change state Irom (1.0 atm, 40.0 L) to (0.5 atm, 40.0 L);
(c) a reversible isothermal compression Irom (0.5 atm, 40.0 L) to (1.0 atm, 20.0 L);
(i) Sketch with labels each oI the processes on the same P-V diagram.
(ii) Calculate the total work (w) and the total heat change (q) involved in the above
processes.
(iii) What will be the values oI DU, DH and DS Ior the overall process?