Hojalata: Evaluacin de su Comportamiento frente a la

Corrosin en Medios Acuosos. (Spanish).

Tinplate: Evaluation of its Corrosion Behavior in Aqueous Media. (English)
Spanish
Culcasi, Jos D.1 jculcasi@ing.unlp.edu.ar
Elsner, Cecilia I.2
Di Sarli, Alejandro R.2
Informacin Tecnolgica. 2010, Vol. 21 Issue 3, p149-162. 14p.
Article
*CORROSION & anti-corrosives
*ELECTROCHEMISTRY
*SURFACES (Technology) -- Analysis
*SOLUTION (Chemistry)
*METALS -- Surfaces
*ANALYTICAL chemistry
corrosion
electrochemical impedance spectroscopy
polarization
scanning electronic microscopy
X rays difraction
corrosin
difraccin de rayos X
espectroscopia de impedancia electroqumica
microscopia electrnica de barrido
polarizacin
Language of Keywords: English; Spanish
The frst deterioration steps sufered by commercially available tinplate sheets exposed to
diferent saline solutions were studied using electrochemical and surface analysis techniques,
as well as optical and electronic scanning microscopy. Their results were analyzed and
interpreted utilizing models able to adequately describe the degradation of those as complex
as reactive metallic interfaces. It was concluded that: 1) independently of the medium, the
main degradation of the metallic surface takes place within the frst 24h immersion, but then
its behavior is relatively stable and reproducible; 2) except in the bufer solutions based on
borax or carbonate where the scarce corrosion products provided a protective efect, in the
other electrolyte medium such products were, in general, a variety of non-protective iron
oxyhydroxides; and 3) these results are in agreement with the electrochemically
determined corrosion rates and, therefore, with the coating useful life. [ABSTRACT FROM
AUTHOR]
Las primeras etapas del deterioro de chapas comerciales de hojalata expuestas a distintas
soluciones salinas fueron estudiadas mediante tcnicas electroqumicas y de anlisis de
superfcie complementadas por microscopia ptica y electrnica de barrido. Sus resultados
fueron analizados e interpretados utilizando modelos capaces de describir adecuadamente la
degradacin metlica de interfaces tan complejas como reactivas. Se concluy que: 1) el
deterioro de la superfcie metlica ocurre mayormente durante las primeras 24 horas de
inmersin, alcanzndose luego un comportamiento relativamente estable y reproducible con
independencia del medio utilizado; 2) excepto en las soluciones "bufer" basadas en brax o
carbonato donde los escasos productos de corrosin aportaron un efecto protector, en los
restantes medios tales productos fueron, en general variantes no protectoras de un
oxihidrxido de hierro; y 3) estos resultados coinciden con las velocidades de corrosin
determinadas electroqumicamente y, por ende, con el lapso de vida til del recubrimiento.
[ABSTRACT FROM AUTHOR]
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(CIT) and its content may not be copied or emailed to multiple sites or posted to a listserv
without the copyright holder's express written permission. However, users may print,
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the material for the full abstract. (Copyright applies to all Abstracts.)
1Universidad Nacional de La Plata, Facultad de Ingeniera, Laboratorio de Investigaciones de
Metalurgia Fsica (LIMF) "Ing. Gregorio Cusminski" , Calle 48 y 116, B1900TAG La Plata-
Argentina
2Centro de Investigacin y Desarrollo en Tecnologa de Pinturas-CIDEPINT (CIC-CONICET),
Av. 52 s/n, entre 121 y 122, B1900AYB La Plata-Argentina
0716-8756
10.1612/inf.tecnol.4242it.09
53292810
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Modelo Cintico tili!ado en el Estudio Electro"u#mico del
$roceso de Corrosin en Medio Acuoso.(Spanish).
Imgenes

Spanish
Mora, M.1
Alvarez, M.1
Fernandez, O.1
Aperador, W.1,2
Ortiz, C.1
Vera, E.1
Revista Colombiana de Fsica. 2009, Vol. 41 Issue 1, p88-91. 4p. 1 Diagram, 1 Graph.
Article
*ELECTROCHEMICAL analysis
*METALS
*DIRECT currents
*ELECTROSTATIC analyzers
*THERMODYNAMICS
activation energy
load transfer
metal-disolution interphase
reaction rate
sobrepotential
Ecuacin Butler-Volmer
energa de activacin
interfase metal-disolucin
sobre-potencial
transferencia de carga
velocidad de reaccin
Language of Keywords: English; Spanish
332811 Metal Heat Treating

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NAICS/Cdigos del
sector:
332810 Coating, engraving, cold and heat treating and allied activities
332812 Metal Coating, Engraving (except Jewelry and Silverware), and Allied Services to
Manufacturers
The purpose of this article is show from physical point of view, the theoretical review of the
electrochemical processes that happen in an interphase metal-dissolution, starting of of
termodinamicos and electrostatic concepts that entail to the deduction of the kinetic model
that describes or governs the anodic and cathodic processes implicitly revelated in the
present loading density in the system. this model it is known him like Butler-Volmer's kinetics
equation of, which by means of frst approach reveals the linear behavior between the load
and the energy of the carrier as it happens in the Ohm's law, being the fundamental base for
the development of conventional electrochemical techniques such as linear polarization
resistance (LPR), Tafel polarization curves, galvanostatic pulse (GALVAPULSE) and
Electrochemical Frequency Modulation (EFM) among others, used for measurements of
parameters that allow to determine of corrosion rate in conductive materials. [ABSTRACT
FROM AUTHOR]
Se presenta desde el punto de vista fsico, la revisin terica de los procesos electroqumicos
que ocurren en una interfase metal-disolucin, partiendo de conceptos termodinmicos y
electrostticos que conllevan a la deduccin del modelo cintico que describe o gobierna los
procesos andicos y catdicos manifestos implcitamente en la densidad de carga
presente enel sistema. A tal modelo se le conoce como ecuacin cintica de Butler-Volmer, el
cual mediante primera aproximacin revela el comportamiento lineal entre la carga y la
energa del portador tal como ocurre en la ley de Ohm, siendo la base primordial para el
desarrollo de tcnicas electroqumicas convencionales tales como resistencia a la
polarizacin lineal (LPR), curvas de polarizacin Tafel, pulso galvanosttico (GALVAPULSE)
y modulacin de frecuencia electroqumica (EFM) entre otras, utilizadas para mediciones de
parmetros que permitan determinar velocidades de corrosin en materiales conductores.
[ABSTRACT FROM AUTHOR]
Copyright of Revista Colombiana de Fsica is the property of Sociedad Colombiana de Fisica
and its content may not be copied or emailed to multiple sites or posted to a listserv without
the copyright holder's express written permission. However, users may print, download, or
email articles for individual use. This abstract may be abridged. No warranty is given about
the accuracy of the copy. Users should refer to the original published version of the material
for the full abstract. (Copyright applies to all Abstracts.)
1Universidad Pedaggica y Tecnolgica de Colombia Grupo de Superfcies Electroquimica y
Corrosin
2Universidad del Valle, Grupo de Materiales Compuestos
0120-2650
53888637
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Fig.1 Fig.3

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