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The table below gives some information about the elements in Group I of the Periodic Table.
element
boiling point / oC
density / g cm3
radius of atom in
the metal / nm
lithium
1342
0.53
0.157
sodium
883
0.97
0.191
rapid
potassium
760
0.86
0.235
very rapid
1.53
0.250
extremely rapid
rubidium
caesium
669
1.88
reactivity with
water
explosive
(a) How does the density of the Group I elements change down the Group?
(2)
(b) Suggest a value for the boiling point of rubidium.
(1)
(c) Suggest a value for the radius of a caesium atom.
(1)
(d) Use the information in the table to suggest how fast lithium reacts with water compared
with the other Group I metals.
(1)
(e) State three properties shown by all metals.
1.
2.
3.
(3)
2H20(I)
2Na0H(aq)
H2(g)
(i) State the name of the other product formed in this reaction.
(1)
Total / 9
(3)
(1)
(1)
(2)
(ii) Explain why lithium fluoride conducts electricity when molten but not as a solid.
......................................................................................................................................
......................................................................................................................................
(iii) State one other physical property of lithium fluoride.
...................................................................................................................................... (1)
(2)
Total / 10
3 (a) Brine is an impure solution of sodium chloride. The main impurity in brine is calcium chloride.
It is removed by reacting the brine with sodium carbonate.
CaCl2(aq) + Na2CO3(aq) CaCO3(s) + 2NaCl(aq)
(i) State the name for this type of reaction.
...................................................................................................................................
(ii) Construct an ionic equation for the reaction between calcium ions and carbonate ions to produce
calcium carbonate.
...................................................................................................................................
(iii) Suggest how the calcium carbonate is removed from the mixture.
...................................................................................................................................
(3)
(b) Chlorine is manufactured by the electrolysis of concentrated sodium chloride.
(i) Write equations for both of the electrode reactions.
...................................................................................................................................
...................................................................................................................................
(ii) Calculate the maximum volume of chlorine, at r.t.p., which can be obtained from 175.5 kg sodium
chloride.
(5)
(c) Chlorine reacts with methane to produce chloromethane, CH3Cl.
Draw a dot and cross diagram to show the bonding in chloromethane.
You only need to show outer (valence) electrons.
(2)
[10 marks]
(a) Copper has the structure of a typical metal. It has a lattice of positive ions and a sea
of mobile electrons. The lattice can accommodate ions of a different metal.
io
ns
pr
es
en
t
in
th
e
sol
uti
on
ar
e
as
fo
llo
w
s.
SO42 (aq),
H +(aq),
OH (aq)
(i) Write an ionic equation for the reaction at the negative electrode (cathode).
(1)
(ii) A colourless gas was given off at the positive electrode (anode) and the solution
changes from blue to colourless.
Explain these observations.
(2)
(c)
(1)
(1)
(ii) Explain why the colour of the solution does not change.
(iii) What is the large scale use of this electrolysis?
(1)
5 Sodium chloride is used in making many important chemicals including chlorine and hydrogen.
(a) Write the electrode reactions for the electrolysis of molten sodium chloride.
Which electrode reaction is an oxidation? Explain your answer.
.......................................................................................................................................................
...
...
...
...
...
...
...
...
...
............................................................................................................................
.......................................................................................................................................................
.......................................................................................................................................................
(3)
(b) Explain why the electrolysis of aqueous sodium chloride using inert electrodes gives
hydrogen.
.......................................................................................................................................................
(1)
(c) Explain why graphite is used as electrode in the electrolysis but diamond is not.
.......................................................................................................................................................
.......................................................................................................................................................
.......................................................................................................................................................
(3)
(d) Hydrogen is used to manufacture ammonia, NH3. Calculate the volume of hydrogen needed to
react completely with 240 dm3 of nitrogen, all gas volumes measured at room temperature
and pressure.
( 3)
Total / 10
No reaction.
No reaction.
Steady fizzing.
metal
least reactive
(2)
(c) The equation for the reaction of X with cold water is given below.
2X(s) + 2H2O(l)
2XOH(aq) + H2(g)
(i
)
D
e
s
cribe the test you would use to show that the gas evolved is hydrogen.
(1)
(ii) How could you show that the water contained a compound of the type XOH?
(2)
(iii) In which group of the Periodic Table does metal X belong?
(1)
5 Sodium chloride is used in making many important chemicals including chlorine and hydrogen.
(a) Write the electrode reactions for the electrolysis of molten sodium chloride.
Which electrode reaction is an oxidation? Explain your answer.
.......................................................................................................................................................
3
Total /
10
.......................................................................................................................................................
.......................................................................................................................................................
.......................................................................................................................................................
(3)
(b) Explain why the electrolysis of aqueous sodium chloride using inert electrodes gives
hydrogen.
.......................................................................................................................................................
(1)
(c) Explain the three stages in the purification of water supplies.
.......................................................................................................................................................
.......................................................................................................................................................
.......................................................................................................................................................
(3)
(d) Hydrogen is used to manufacture ammonia, NH3. Calculate the volume of hydrogen needed to
react completely with 240 dm3 of nitrogen, all gas volumes measured at room temperature
and pressure.
The
frac
tion
al
dist
illat
ion
of
cru
de
oil
usu
ally
pro
du
ces
larg
e
qua
ntit
ies
of
the
hea
vie
r
fra
ctio
ns.
The
mar
ket
demand is for the lighter fractions and for the more reactive alkenes. The heavier fractions
are cracked to form smaller alkanes and alkenes as in the following example.
C8H18
octane
C4H10
butane
C4H8
butenes
(a)
(i)
Wri
te a
diff
ere
nt
equ
ati
on
for
the
cra
cki
ng
of
oct
ane
.
C8H18
+
(1)
(ii) The
cracking
of
octane
can
produce
isomers
with the
molecul
ar
formula
C4H8.
Dra
the
stru
ura
form
lae
of
two
of
the
iso
ers.
(2)
(b) (i) Give the essential condition for the reaction between chlorine and butane.
(1)
(ii) What type of reaction is this?
(1)
(iii) This reaction produces a mixture of products. Give the names of two products
that contain four carbon atoms per molecule.
and
(2)
(c) Alkenes are more reactive than alkanes and are used to make a range of organic
chemicals. Propene, CH3CH=CH2, is made by cracking. Give the structural formula
of the addition product when propene reacts with the following.
(i) water
(1)
(ii) bromine
C
(d) Propene reacts with hydrogen iodide to form 2 - iodopropane.
CH3CH=CH2
HI
CH3CHICH3
a
l
(1)
percentage yield
(4)
DATA SHEET
The Periodic Table of the Elements
Group
I
III
II
IV
VI
VII
He
Hydrogen
Helium
1
7
11
12
14
16
19
20
Li
Be
Ne
Lithium
Beryllium
Boron
23
24
Na
Mg
Sodium
Magnesium
11
Nitrogen
Oxygen
28
31
32
Al
Si
13
Silicon
14
Phosphorus
Neon
10
Sulphur
16
15
Fluorine
27
Aluminium
12
Carbon
35.5
40
Cl
Ar
Chlorine
17
Argon
18
39
40
45
48
51
52
55
56
59
59
64
65
70
73
75
79
80
84
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
Potassium
Calcium
19
20
85
Scandium
Titanium
21
88
22
89
Vanadium
23
91
Chromium
24
93
Manganese
25
Iron
26
96
Cobalt
27
101
Nickel
28
103
Copper
29
Zinc
30
106
108
Gallium
31
112
Germanium
32
Arsenic
33
115
119
Selenium
34
122
Bromine
35
Krypton
36
127
128
131
Rb
Sr
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
Cd
In
Sn
Sb
Te
Xe
Rubidium
Strontium
Yttrium
Zirconium
Niobium
Molybdenum
Technetium
Ruthenium
Rhodium
Palladium
Silver
Cadmium
Indium
Tin
Antimony
Tellurium
Iodine
Xenon
37
38
133
39
40
139
137
41
178
42
181
44
43
184
186
45
46
192
190
47
48
195
197
Cs
Ba
La
Hf
Ta
Re
Os
Ir
Pt
Au
Hg
Caesium
Barium
Lanthanum
Hafnium
Tantalum
Tungsten
Rhenium
Osmium
Iridium
Platinum
Gold
Mercury
55
56
Fr
57
226
227
Ra
Ac
Radium
Francium
88
87
72
73
X
b
76
77
78
79
80
52
54
53
207
Tl
Pb
Bi
Po
At
Rn
Lead
Bismuth
Polonium
Astatine
Radon
Thallium
81
82
209
83
84
85
86
Actinium
140
141
144
Ce
Pr
Nd
Cerium
Key
75
51
204
89
74
50
49
201
58
X = atomic symbol
b = proton (atomic) number 90
Praseodymium
59
Neodymium
60
232
Pm
Promethium
61
150
152
157
159
162
165
167
169
173
175
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Samarium
62
Europium
63
Gadolinium
64
Terbium
65
Dysprosium
66
Holmium
67
Erbium
68
Thulium
69
Ytterbium
70
Lutetium
71
238
Th
Pa
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Thorium
Protactinium
Uranium
Neptunium
Plutonium
Americium
Curium
Berkelium
Californium
Einsteinium
Fermium
91
92
93
94
95
96
97
98
99
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
100
Md
Mendelevium
101
No
Lr
Nobelium
Lawrencium
102
103
16