COMPLETE CHEMISTRY (MEDICAL) TEST-2

READ THE INSTRUCTIONS CAREFULLY

1.
2.
3.
4.
1.

The test is of 45 minutes duration.

The maximum marks are 135.
This test consists of 45 questions.
Each correct answer of carries 3 Marks & for each wrong answer, 1 mark will be deducted.
Both glucose and fructose give the same
X
Polymerisation
5.
osazone because stereochemistry at ------- and ---- is destroyed:
Y

a.
c.
2.

b.
c.
d.

C2 and C4
C1 and C4

C5 and
molecule
C2 and
molecule
C1 and
molecule
C5 and
molecule

C2 respectively of the sugar

C5 respectively of the sugar
C5 respectively of the sugar

a.
b.
c.
d.

C1 respectively of the sugar

a protein
a monosaccharide
a lipid
An hamoamino acid

b.
[ CH 2 CH(C6H5 )]n

b.

[ NH CHR CO ]n

c.

[ OCH 2CH 2OCH 2CH 2OCH 2CH 2

]n

d.

O
O

||
||

NH

(
CH
)

NH

(
CH
)

2 6
2 4

Dr. Sangeeta Khanna Ph.D

CH2 CH3

CH2

CH2

CH3

CH2

CH2 CH3

CH2

CH2

CH3

CH2

CH2

CH2
H

H
CH2

c.

d.
n

Natural rubber, Gutta percha

Gutta percha, Natural rubber
Neoprene, Natural rubber
Gutta percha, Neoprene

In the reaction:
CH3
|

CH 3 C H CH 2 O CH 2 CH 3 HI
Which of the following compounds will be
formed?

a.

Which of the following is not a Homopolymer?

a.

CH2 CH3

H3C

X and Y respectively are:

A certain compound gives negative test with 6.

ninhydrin and positive test with Benedicts:
a.
b.
c.
d.

4.

b.
d.

In both DNA and RNA, heterocyclic base and

phosphate ester linkages are at:
a.

3.

C1 and C3
C1 and C2

CH3
|
CH 3 C H CH 2 CH 2 I CH 3 CH 2OH
CH 3 C H CH 2 CH 3 CH 3 CH 2OH
|
CH 3

CH 3 C H CH 2OH CH 3 CH 3
|
CH 3

CH 3 C H CH 2OH CH 3 CH 2I
|
CH 3

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Dr. Sangeeta Khanna Ph.D

CH3

COOH
NO2

NHCOCH3

O2N

NO2

a.

O2N

NO2

b.

7.
(ii)

(i)

(iii)

(iv)

What is order of reactivity in electrophilic

substitution.

O2N

COOH

NO2

c.

H2N

NH2

d.

a. (iv) > (iii) > (ii) > (i)

b. (i) > (ii) > (iii) > (iv)
c. (iii) > (ii) > (i) > (iv)
d. (iii) > (iv) > (i) > (ii)
8.

NO2

NO2

NO2

NH2

11. The correct decreasing order of boiling points

among amines and their corresponding acids
Nitration of aniline in strongly acidic medium,
and alcohols is:
results in the formation of m nitroaniline also.
This is because:
a. R CH2NH2 > RCOOH > RCH2OH
b. RCH2NH2 > RCH2OH > RCOOH
a. amino group is meta orienting during
c. R CH2OH > R CH2NH2 > RCOOH
electrophilic substitution reaction
d. R COOH > R CH2OH > R CH2NH2
b. nitro group goes always to the meta
position irrespective of the substituents
CH
c. nitration of aniline is a nucleophilic 12. A + H2 PdBaSO4
substitution reaction in strongly acidic
O
medium
CN
CCl
d. In strongly acidic conditions, aniline is
a.
b.
present as anilinium ion
O

9.

Identify the end product in the reaction:

COOH

CNH2

HNO3/H2SO4

Sn/HCl

(i) NaNO2 + HCl, 0.5 C

(ii) HBF4,

COOH

c.

CNH3

d.

13. Why does ClCH2CH2CH2COOH have a greater

pKa than ClCH2COOH?

COOH

a.

a.

b.

b.

F
N2Cl

c.

c.

F
F

d.
d.

10. The product of the reaction:

14. Benzoic acid gives benzene on being heated with

X and phenol gives benzene on being heated with
Y. Therefore X and Y are respectively:

COOH
O2N

NO2

: is:

a.
b.
c.
d.

NO2

Dr. Sangeeta Khanna Ph.D

4chlorobutanoic acid has higher molecular

weight than 2 chloroethanoic acid
4 chlorobutanoic acid has a lower molecular
weight than 2 chloroethanoic acid
4 chlorobutanoic acid has an electron
withdrawing group on the gamma carbon
while 2-chloroethanoic acid has an electron
withdrawing group on the - carbon
4 chlorobutanoic acid has a longer chain
than 2 chloroethanoic acid

Sodalime and copper

Zinc duet and sodium hydroxide
Zinc dust and sodalime
Sodalime and zinc dust
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Dr. Sangeeta Khanna Ph.D

15. The most reactive compound
cyanohydrin formation is:

towards 19. An alcohol gives turbidity on reaction with conc.

HCl/ZnCl2 (anhyd.) only on heating. It is:

a. Ph CHO
b. CH OH

a. CH2OH
b. O2N

CHO

c.
c. HO

C OH

d.

CHO

CH3

CH2

d. Ph

COH

20. Benzyl amine reacts with nitrous acid to give:

CHO

a. azobenzene
c. benzyl alcohol

b. benzene
d. phenol

16. In the Gattermann Koch reaction:

+ CO + DCl

AlCl3

21. The atomic numbers of two elements A and B

are 30 and 15 respectively. The possible
formula of the compound is:

The product is:

a. AB
a. C6H5CHO

b. C6H5CDO

CHO

CHO

c.

b. AB2

c. A2B3

d. A3B2

22. Conductivity (Unit : siemens S) is directly

proportional to the area of the vessel and the
concentration of the solution in it and is
inversely proportional to the length of vessel,
then the unit of constant of proportionality is:

d.
D

17. The cleavage of an aryl-alkyl ether with cold HI

gives:
a.
b.
c.
d.

alkyl iodide and water

aryl iodide and water
alkyl iodide, aryl iodide and water
phenol and alkyl iodide

a. S m mol1
c. S2 m2 mol

b. S m2 mol 1
d. S2 m2 mol 2

23. If a homogeneous catalytic reaction can take

place through three alternative paths as
depicted below, the catalytic efficiency of P,Q,R,
representing the relative case would be:
Potential Energy

18. The final product (B) of the following reaction:

SO3H
Fuming
H2SO4

(A)

(i) NaOH, fuse

(ii) H

(B) is:

OH

Q
R

Reaction coordinate

OH

OH

a.

a. P > Q > R
c. P > R > Q

b.

24. Consider the following reaction sequence:

OH

Cl2/FeCl3

OH

c.

HNO3/H2SO4

d. None of these
OH

Dr. Sangeeta Khanna Ph.D

b. Q > P > R
d. R > Q > P

HNO3/H2SO4

Cl2/FeCl3

Below 330 K

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Dr. Sangeeta Khanna Ph.D

In this B and D respectively are:
Cl

27. In the reaction,

2Al(s) + 6HCl(aq)2Al3+(aq) + 6Cl(aq) + 3H2(g)

Cl

a.
a.

and
NO2

b.

NO2

c.

Cl

Cl

d.

and

b.
NO2

28. In a hexagonal close packed (hcp) structure of

spheres, the fraction of the volume occupied by
the sphere is A. In a cubic close packed
structure, the fraction is B. The relation for A
and B is:

NO2
NO2

Cl
SO3H

and

a.
b.
c.
d.

c.
Cl
NO2
NO2

d.

Cl

NO2

CHO
25. Ozonolysis products of an olefin are |
and
CHO
CH 2CHO
|
. Olefin is:
CH 2CHO
30.

c.

A=B
A<B
A>B
A is equal to the fraction in a simple cubic
lattice

29. The line spectrum of two elements is not

identical because:

and
Cl

a.

33.6 L H2(g) is produced regardless of

temperature and pressure for every mole Al
that reacts
67.2 L H2(g) at STP is produced for every
mole of Al that reacts
11.2 L H2(g) at STP is produed for every
mole HCl (aq) consumed
6 L HCl (aq) is consumed for every 3 L
H2(g) is produced

b.

a.
b.
c.
d.

When the following solutions are separated by a

membrane made of gelatinous ppt. of cupric
ferrocyanide, in which case there is a flow of
solvent?
a.
b.
c.
d.

d.

they donot have same number of neutrons

they have dissimilar mass number
they have different energy level schemes
they have different number of valence
electrons

1 M sucrose and 1 M glucose

1 M NaCl and 2 M urea
0.05 M K4[Fe(CN)6] and 0.1 M MgCl2
0.001 M CaCl2 and 0.0015 M NaCl

26. The reduction of an alkyne to alkene using 31. Identify the correct statement regarding entropy:
lithium metal in liquid ammonia as solvent
results into:
a. At absolute zero of temperature, the
entropy of perfectly crystalline substance is
a. cis addition of hydrogen atoms
+ve
b. trans addition of hydrogen atoms
b. At absolute zero of temp. entropy of
c. both cis and trans additions of hydrogen
perfectly crystalline substance is taken to
be zero
atoms. The relative amounts of the two
c. At 00C the entropy of a perfectly crystalline
depends on temperature
substance is taken to be zero
d. both cis and trans additions of hydrogen
d.
At absolute zero of temperature, the
atoms. The relative amounts depend on
entropy of all crystalline substances is taken
the nature of alkyne
to be zero

Dr. Sangeeta Khanna Ph.D

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Dr. Sangeeta Khanna Ph.D

38. In BrF3 molecule, the lone pairs occupy
equatorial positions of minimize:

32. The value of log10K for a reaction A B is:

(Given : rH0298 K 54.07 kJ mol -1,
rS0298 K 10JK 1 mol1 & R =8.314 JK1 mol1;
2.303 x 8.314 x 298 = 5705)

a. 5

b. 10

c. 95

d. 100

33. 1.1 mole of A are mixed with 2.2 moles of B and

the mixture is kept in a 1 L vessel till the
equilibrium is established in the reaction. If the
molar conc. of C at the equilibrium point is 0.2
mole:
A + 2B 2C + D
The value of equilibrium constant for the
reaction is:
a. 0.001
c. 0.003

lone pair lone pair repulsion only

lone pair bond pair repulsion only
bond pair bond pair repulsion only
lone pair lone pair repulsion and lone
pair bond pair repulsion

39. Calgon is:

a. Na2 [Na4 (PO3)6]
b. Na2Al2Si2, O2xH2O
O
C2H5

c.
O

d.

b. 0.002
d. 0.004

CaCN2 + C

40. Which one out of the following statements is not

correct for ortho and para hydrogen?

34. The degree of hydrolysis in hydrolytic equilibrium:

A + H2O HA + OH
at salt concentration of 0.001 M is:
(Ka = 1 x 10 5)
a. 1 x 10 3
c. 5 x 10 4

a.
b.
c.
d.

a.
b.
c.
d.

b. 1 x 10 4
d. 1 x 10 6

they have different boiling points

ortho form is more stable than para form
they differ in the spin of their protons
the ratio of ortho to para hydrogen
increases with increase in temperature and
finally pure ortho form is obtained

35. Resistance of a conductivity cell filled with a 41. Water is oxidized to oxygen by:
solution of an electrolyte of concentration 0.1 M
a. F2
b. H2O2
c. KMnO4
d. O3
is 100 . The conductivity of this solution is 1.29
1
S m . Resistance of the same cell when filled 42. Water obtained after treatment with organic ion
with 0.02 M of the same solution of 520 . The
exchange resins is:
molar conductivity of 0.02 M solution of the
a. pure water
electrolyte will be:
b. free from only Ca2+ , Mg2+ ions
c. free from HCO3 , SO42 and Cl ions only
a. 1.24 x 10 4 S m 2 mol 1
d. demineralised water
b. 12.4 x 10 4 S m2 mol 1
4
2
1
c. 124 x 10 S m mol
43. Which of the following metal ions plays an
d. 1240 x 10 4 S m2 mol 1
important role in muscle contraction?
36. Which one of the following orders is not in
a. K+
b. Na+
c. Mg2+
d. Ca2+
accordance with the property stated against it?
44. Al2O3 can be converted to anhydrous AlCl3 by
a. F2 > Cl2 > Br2 > I2 : bond dissociation energy
heating:
b. F2 > Cl2 > Br2 > I2 : oxidizing power
a. Al2O3 with Cl2 gas
c. HI > HBr > HCl > HF : acidic property in water
b. Al2O3 with HCl gas
d. F2 > Cl2 > Br2 > I2 : electronegativity
c. Al2O3 with NaCl in solid state
d. a mixture of Al2O3 and carbon in dry Cl2 gas
37. The correct order of dipole moment is:
45. AgNO3 on heating above its melting temperature
a. NF3 < CH4 < NH3 < H2O
liberates a gas. The same gas is also liberated
b. CH4 < NF3 < NH3 < H2O
on heating ______:
c. NH3 < NF3 < CH4 < H2O
d. H2O < NH3 < NF3 < CH4
a. Cr2O3
b. KMnO4
c. CrO5
d. CaO

Dr. Sangeeta Khanna Ph.D

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Dr. Sangeeta Khanna Ph.D

Complete Chemistry Test 2 (Med.) Answers
1.

2.

3.

4.

5.

6.

7.

8.

9.

10. C

11. D

12. A

13. C

14. D

15. D

16. B

17. D

18. C

19. A

20. C

21. D

22. B

23. D

24. A

25. C

26. B

27. C

28. A

29. C

30. C

31. B

32. B

33. A

34. A

35. C

36. A

37. B

38. D

39. A

40. D

41. A

42. D

43. D

44. D

45. B

Dr. Sangeeta Khanna Ph.D

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