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1. Time duration for this test is 180 minutes. This test consists of 90 questions. The
maximum marks are 360.
2. There are three parts in the question paper, namely, Part A: Physics, Part B: Chemistry
and Part C: Mathematics.
3. This test contains 90 Multiple Choice Questions with single correct answer. Each
Question has four choices (1), (2), (3) & (4), out of which Only One is Correct.
4.
5. One-fourth (1/4) marks will be deducted for indicating incorrect response of each
question. No deduction from the total score will be made if no response is indicated for
an item in the answer sheet. Filling up more than one response in any question will be
treated as wrong response and marks for wrong response will be deducted accordingly
as per the instruction 5 above.
Part A Physics
Question 1: Figure (a) given below shows a circular disc that is uniformly charged. The central z-axis is
perpendicular to the disc. Figure (b) is the graph of the magnitude of the electric field along that axis in
terms of the maximum magnitude Em at the disc surface ( zS 16.0 cm).
(a)
What is the radius of the disc?
(1) 10.4 cm
(3) 13.9 cm
(b)
(2) 11.3 cm
(4) 14.1 cm
Solution: For the uniformly charged disc, the electric field along the z- axis is
z
E
1 2
2 0
z R2
Putting z 0 , we get
Em
2 0
0.5Em
8.0
1
2 0
(8.0)2 R 2
0.5
(8.0)2 R 2 (16.0)2
Therefore,
2I
0c
28
8.85 1012 3 108
77.6 N C1
(1) 0.2 A
(3) 2 A
(2) 1.7 A
(4) 2.4 A
Solution: Diodes are connected in such a way that the diode D1 is reverse biased and diode D2 is forward
biased.
So, the resistance of the diode D 1 is infinity and it can be replaced by a broken wire.
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And the resistance of the diode D 2 is zero and it can be replaced by a resistance- less wire.
The equivalent circuit would be
4
12 V
I1 2
I 2 1
mk12 2
mk22 1
2
k1
4
2:5
k2
1
25
Correct Option: (1)
Question 6: A spherical object of radius 1cm and density 4 103 kg m3 is dropped gently into a large
container containing viscous liquid of density 2 103 kg m3 and viscosity 0.1 Ns m2 . The distance
moved by the object in 9 s after it attains terminal velocity is (Take g = 10 m s)
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4
m
9
20
m
(3)
9
(1)
(2)
40
m
9
(4) 40m
vt =
2 r2
9
g downward
9 0.1
40
vt = m/s, downwards
9
Once the body acquires terminal velocity, it will have uniform motion. So distance travelled by the object
9 s after attaining terminal velocity is
vt =
d=
40
9
9 = 40 m
3 0 a 2
5d
2 a 2
(3) 0
3d
(1)
3 0 a 2
2d
5 a 2
(4) 0
3d
(2)
Solution: Now we know that capacitance of a parallel plate capacitor is given by relation
0 A
d
where A is the area of cross-section of the plates and d is the separation between the plates.
The given figure can be redrawn as below:
From the figure above, capacitors C2 and C3 are in parallel so their equivalent capacitance between points
D and point C is
C ' C2 C3
0a2
d
0a2
2d
3 0 a
2d
Now the equivalent capacitance between points A and point C will be
1
1
1
Ceq C ' C1
Ceq
C ' C1
C ' C1
3 0 a 2 0 a 2
d
2d 2
3 0 a
0a2
2d
d
2
3 a
0
5d
2
Hence,
When the object hangs from the spring,
kx mg
mg
x
k
mg
(2 ) 2 m
g
(2 ) 2
9.81
(2 3.14 5.00) 2
0.01m
(1)
(2)
(3)
(4)
Solution: Given circuit can be understood as two NOT circuits being fed into a NOR circuit.
For the first pulse of A and B,
Input
1
1
A
B
First Gate
0
0
Second Gate
1
Options
(1), (2), (4)
A
B
Input
0
0
First Gate
1
1
Second Gate
0
Options
(1), (2), (4)
A
B
Input
0
1
First Gate
1
0
Second Gate
0
Options
Second Gate
0
Options
(1), (4)
First Gate
0
1
(1)
Question 10: A force of F 12.0 N is applied to a 8.00kg block at a downward angle of 30.0 , as shown
in the following figure.
The coefficient of static friction between the block and the floor is 0.700 and the coefficient of kinetic
friction is 0.400. What is the magnitude of the frictional force on the block?
(1) 19 N
(2) 59 N
(3) 12 3 N
(4) 6 3 N
Solution:
(3)
2
Since this force is greater than F cos(30 ) , there will be no motion, and a 0ms .
Substituting the values from Eq. (2) and Eq. (3) into Eq. (1) we get
6 3 fs m(0)
o
6 3 fs 0
fs 6 3 N
It can be filled with air, water ( n 1.3 ), or CS2 ( n 1.6 ). The lens will diverge a beam of parallel light if
it is filled with
(1) air and immersed in air.
(2) air and immersed in water.
(3) water and immersed in CS2.
(4) CS2 and immersed in water.
Solution: From Lens makers equation:
1 1
1 n2
1
f n1
R1 R2
1 1
Using the Cartesian sign convention, R1 is negative and R2 is positive. Thus, is negative.
R1 R2
Now, for the given lens to act as a diverging lens, the focal length f must be negative. This implies that
n2
1 must be positive. Note that n2 is the refractive index of the medium inside, and n1 is the
n1
n
refractive index outside the lens. 2 1 is positive only when n2 > n1 or lens is filled with CS2 and
n1
immersed in water.
Correct Option: (4)
Question 13: An input signal of 22 kHz and peak voltage 25 V is modulated with a carrier wave of
frequency 23 MHz and peak voltage 24 V. What will be the bandwidth of the modulated wave in the case
of amplitude modulation?
(1) 44 kHz
(2) 44 kHz + 46 MHz
(3) 46 MHz
(4) 22 kHz + 23 MHz
Solution: Bandwidth in the case of amplitude modulation = Twice the frequency of the modulating signal
Bandwidth 2 m
2 22
44 kHz
Correct Option: (1)
Question 14: The term coherence relates to
(1) the diffraction of two waves.
(2) the polarization state of two waves.
(3) the phase relationship between two waves.
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gas, P is the pressure in the gas and is the density of the gas.
(1) Statement 1 is true, Statement 2 is true; Statement 2 is the correct explanation of Statement 1
(2) Statement 1 is true, Statement 2 is true; Statement 2 is not the correct explanation of Statement 1
(3) Statement 1 is true, Statement 2 is false
(4) Statement 1 is false, Statement 2 is true
Solution: Though the speed of sound formula seems to suggest that v P , note that the other variable
in the denominator is not an independent variable but depends on pressure P. In fact, density is directly
proportional to P, given other independent parameters dont change, making v independent of P. So a
better formula to rely on is
RT
v
M0
V
p B
V
1.0 1010
(2.6 1010 )
2 3
(1.0 10 )
2.6 106 Nm 2
Since the pressure increases by 1.0 104 Nm2 for every meter,
Depth below the surface =
Question 17: An inductance L and a resistance R are connected in series to an ideal battery. A switch in
the circuit is closed at time t = 0, when the current is zero. The rate of increase of the energy stored in the
inductor is the maximum
(1) just after the switch is closed.
(2) at time t L / R after the switch is closed.
(3) at time t 2L / R after the switch is closed.
(4) at time t ( L / R) ln 2 after the switch is closed.
Solution: The transient current in an LR circuit is given by
V
t
i 1 exp
R
L / R
di V
t
exp
dt L
L/R
or
Energy stored in the inductor is given by
1
E Li 2
2
Rate of change of energy,
dE
di V 2
t
t
Li
exp
1 exp
dt
dt R
L / R
L / R
d2 E
V2
t
t
exp
1 2exp
2
dt
L
L / R
L / R
Now, for
dE
to be maximum,
dt
or
d2 E
0
dt 2
V2
t
t
exp
1 2exp
0
L
L / R
L / R
t 1
exp
L/R 2
t
ln 2
L/R
L
t ln 2
R
Correct Option: (4)
Question 18: The water in a glass kept on a table has a mass of 0.25 kg. It has the same temperature as
the room, which is 27C. A Carnot refrigerator is operating in this room. The water is put in the
refrigerator, the inside of which is maintained at 3C. How much work is done by the refrigerator in
cooling the water from 27C to 3C? Take the specific heat capacity of water to be 4.18 103 J kg 1K 1 .
(1) 2.2 kJ
(2) 6.7 kJ
(3) 8.3 kJ
(4) 5.9 kJ
Solution: For a refrigerator,
QC W QH
W QH QC
QC is the heat extracted from the cold reservoir; the water, in this case. So,
QC = mcT = (0.25kg)(4.18103 J kg1K 1 )(27 3) = 25103 J
Since its a Carnot refrigerator,
QH TH
QC TC
QH
TH
QC
TC
300
(25 103 )
276
27.2 103 J
Thus, work done by the refrigerator in cooling the water from 27C to 3C will be
W QH QC
2.2 103 J
2.2 kJ
Correct Option: (1)
Question 19: An ultraviolet lamp emits light of wavelength 400 nm at the rate of 400 W. An infrared
lamp emits light of wavelength 700 nm, also at the rate of 400 W. Which lamp emits photons at the
greater rate and by how much?
(1) UV, 8 1020 s 1
(2) UV, 6 1020 s 1
(4) IR, 6 1020 s 1
Solution: Since both lamps are emitting energy at the same rate (400 W), the energy emitted per second
by both is equal. The ultraviolet (UV) light has higher frequency, and hence its photons have higher
energy (since, E h ) than the photons of the infrared (IR) light. This means that the IR lamp emits
more number of photons per second.
Number of photons emitted per second by the UV lamp
N UV
400 4001
h 1
hc
400 400 2
h 2
hc
So, the IR lamp emits photons at a higher rate. The difference in number of photons emitted per second
by the IR lamp and UV lamp is
N IR
N N IR N UV
400 2
4001
hc
hc
400(700 400) 10 9
6.03 1020 s 1
Correct Option: (4)
Question 20: Seven 5 ohm resistors are connected in a circuit with a 10 volt battery and ammeter as
shown in the figure. The ammeter will read
(1) 5 A
(3) 3 A
(2) 0.5 A
(4) 0.3 A
Solution: Since five 5 ohm resistors between points A and B are connected in a Wheatstone bridge,
current through diagonal resistance of 5 ohm will be zero.
So, between points A and B, there are 3 sets of (5 + 5) ohm = 10 ohm resistors in parallel
combination.
So, equivalent resistance =10/3 ohm.
Current in the circuit
I
V
10
3 A
R (10 / 3)
(3)
13
17
(4)
17
13
Now we take dot product of initial and final velocities with unit vector to find the components of
velocites along unit vector. The coefficient of restitution will be
v2, n v1, n
u2, n u1, n
or
3i 2 j i 3 j
4i j i 3 j
36
43
3
7
10 0
10 0
l
g
Given that time period of an oscillation is T = 78 / 40 1.95s.
Rearranging and substituting in the equation:
4 2 l
T 2
T2
4 (3.14)2 0.95
1.95 1.95
9.85 m s 2 9.8 m s 2
g l 2T
g
l
T
1 2 1
g 9.8
95 78
9.8(0.01 0.03)
9.8(0.04)
0.4 m s 2
g (9.8 0.4) ms 2
Therefore,
Correct Option: (1)
Question 23: A solid spherical region of radius R having a spherical cavity with diameter R, as shown in
the figure given below, has a total charge Q. The potential at a point P is
(1)
(3)
Q 7 x 4R
(2)
14 0 x 2 x R
4Q 7 x 4 R
(4)
21 0 x 2 x R
Q 7 x 4R
21 0 x 2 x R
2Q 7 x 4 R
7 0 x 2 x R
Q
6Q
3
7
R3
4
R
3
R
3
2
4 3 4 R
R
3
3
2
R
1
1
V
R 3 0 x
R
4 0 x
4 0 x
8 x
2
2
R3 4 2 x R x
R3 1
1
3 0 x 4 2 x R 3 0 4 x 2 x R
R3 7 x 4 R
R3 1
1
3 0 x 4 2 x R 3 0 4 x 2 x R
(1)
R3 7 x 4R
V
12 0 x 2 x R
or
(2)
3
Q 7 x 4R
6Q R 7 x 4 R
3
7 R 12 0 x 2 x R 14 0 x 2 x R
T = constant
or
1T1 2T2
Therefore,
T2 T1 1
2
T1 2
1
450
T1
700
0.64 T1
Thus, T2 is 36% lower than T1 .
Correct Option: (2)
Question 25: A hollow cylindrical conductor (inner radius = a, outer radius = b) carries a current i
uniformly spread over its cross-section. Then which of the graphs given below correctly represents B as a
function of the distance r from the center of the cylinder?
(1)
(2)
(3)
(4)
For r b , we have
0 J ( r 2 a 2 )
2r
B(2 r ) 0 J ( b 2 a 2 )
B
0 J (b 2 a 2 )
2r
It is given that the current density J is constant. Thus, the correct graphical representation is given in
option (3).
Points N, O and P correspond to the position of the projectile at one second intervals. If g 10ms2 , the
lengths X, Y, Z are
(1) 5 m, 10 m, 15 m
(2) 5 m, 20 m, 45 m
(3) 10 m, 40 m, 90 m
(4) 10 m, 20 m, 30 m
Solution: It is implicitly stated in the question that the reason why the projectile follows a parabolic path
and not the path along the dashed line is because of the presence of gravity. So, at any instant, the
difference between a point on the dashed line and the corresponding point on the parabolic trajectory is
the height fallen by the projectile due to gravity, which is given by
1
h gt 2 .
2
Thus, the three lengths are
1
X g (1)2 5m
2
1
Y g (2)2 20m
2
and
1
Z g (3)2 45m
2
Correct Option: (2)
Question 27: The binding energies per nucleon for a deuteron and an -particle are x1 and x2,
respectively. What will be the energy Q released in the following reaction?
2
2
42 He Q
1 H 1 H
(1) 4(x1 + x2)
(2) 4(x2 x1)
(3) 2(x1 + x2)
(4) 2(x2 xl)
Solution: Binding energy of reacting nuclei is
2 2 x1 4 x1
Binding energy of product nucleus is 4x2 .
We have to find the energy released (Q) which can be calculated as
Q = Binding energy of product nucleus Binding energy of reacting nuclei
That is,
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Q 4 x2 4 x1 4( x2 x1 )
GMm GMm
2R
R
GMm
2R
In an orbit of radius 2R , the potential energy of Earthsatellite system is
GMm
U2R
2R
Kinetic energy of the satellite is
GMm
K2 R
4R
Total energy is
TE2 R K 2 R U 2 R
GMm GMm
4R
2R
GMm
4R
So, when an artificial Earth satellite is moved from a circular orbit having radius R to another circular
orbit having radius 2R :
The total energy increases. This means that positive work has been done by an external agent,
which in turn means that negative work has been done by the gravitational force.
Correct Option: (1)
Question 29: At which point is the potential the highest in the circuit shown in the figure given below.
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(1) A
(3) C
(2) B
(4) D
Solution: Battery creates potential difference, therefore to write down potentials of different points, we
have to start by assuming potential at some point to be zero. Let us say that the potential at point C is
zero. So,
VC 0V
The potential at point B will be
VB VC 3E
VB 3E VC
3E 0
3E
The potential at point A will be
VA VB 2 E
VA 2 E VB
2 E 3E
5E
The potential at point D will be
VD VA E
VD E VA
E 5E
4E
Clearly, the potential is highest at point A.
Correct Option: (1)
Question 30: Three light waves travel through a certain point P along the x-axis. They are polarized
parallel to the y-axis, with the following variations in their amplitudes.
E1 (10.0 Vm1 ) sin[(2.0 1014 rads1 ) t ]
Since the light wave is polarized, we can add the three light waves using phasors.
The resultant will be directed along the x-axis. Its phase angle, 0.
The resultant amplitude
E 10.0 5.00cos45 5.00cos45 17.1 Vm1
Correct Option: (2)
Part B Chemistry
Question 1: Which of following compounds is a reducing sugar?
(1)
(2)
(3)
(4)
Solution: Monosaccharides with hemiacetal (or hemiketal) linkages are in equilibrium with the openchain structures in aqueous solution and are therefore, reducing sugars. Monosaccharides with acetal (or
ketal) linkages are not in equilibrium with the open-chain aldehyde (or ketone) in neutral or basic aqueous
solutions, and hence are non-reducing.
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Compound in option (3) contains OHCOR structure (hemiketal linkage), so, it is a reducing sugar.
Si
Cl
Cl
Cl
..
Sn
H
Cl
(net moment = 0)
Cl
H
H
In SiCl4, the bond moments are cancelled out completely so the net dipole moment is zero and the
molecule is non-polar.
Correct Option: (2)
o
32 mm Hg and
Question 3: Benzene and toluene form nearly ideal solutions. At 300 K, ptoluene
o
pbenzene
103 mm Hg. A liquid mixture is composed of 3 mol of toluene and 2 mol of benzene. On
reducing pressure isothermally over the mixture at 300 K, the mixture vaporizes in a certain range of
pressure. The mole fraction of benzene in the last drop of liquid left is
(1) 0.17
(2) 0.4
(3) 0.6
(4) 0.68
Solution: On decreasing pressure over the liquid mixture, the first vapor occurs at 60.4 mm Hg. Further
decrease in pressure increases the vapor content of the mixture. Finally, when the last drop of liquid is
left, its vapor phase contains almost the same composition as it was for liquid phase in the beginning.
2
The initial mole fractions for benzene 0.4; and for toluene 0.6.
5
For the vapor phase in equilibrium with the last liquid drop, mole fractions: yB 0.4; yT 0.6
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From Raoults law and Daltons law for liquid-vapour equilibria, the mole fraction of benzene in liquid
and vapor phases are related by
po po 1
1
1
32 32 1
1 To To
1
xB 0.17
yB
pB pB xB
0.4 103 103 xB
Correct Option: (1)
Question 4: Which of the following cations will have the same color in aqueous solution with the color
of aqueous solution of Pm3+ (atomic number = 61)?
(1) Eu3+ (63)
(2) Tb3+ (65)
(3) Yb3+ (70)
(4) Ho3+ (67)
Solution:
The ions having nf n and nf14n configuration will have similar color (expected) because they have the
same number of unpaired electrons.
Pm3+: [Xe] 4f 4, that is,
four unpaired electrons.
The electronic configurations of other ions are as follows:
Ho3+: [Xe] 4f 10, that is, four unpaired electrons.
Eu3+: [Xe] 4f 6, that is,
Question 5: Which of the following compounds contains the maximum number of lone pairs at the
central atom in its best Lewis structure?
(1) XeO3
(2) ClO2
(3) SOCl2
(4) IO 4
Solution: After sharing three electrons with three oxygen atoms, two electrons are left as non-bonding
electrons on Xe in XeO3, so only one lone pair exists on the central atom.
..
Xe
:O
..
:O
..
:O
..
In ClO 2 , chlorine shares three electrons with two oxygen atoms, four electrons are left as non-bonding
electrons on Cl, so two lone pairs exist on the central atom.
..
: Cl
:O
.. :
O..:
In SOCl2 sulphur shares two electrons with oxygen and one with each chlorine atom, two electrons are
left as non-bonding, so only one lone pair exists on the central atom.
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..
S
:O
..
: Cl
.. :
:Cl
.. :
In IO 4 , iodine shares two electrons each with three oxygen atoms and one electron with one oxygen
atom, so no electron is left as non-bonding and zero lone pairs exist on the central atom.
..
O:
I
:O
.. :
:O:
O:
..
5
2
299.2
100 29.92% 30%
1000
17.6 0.2
5
1000
(1)
(2)
(3)
(4)
Solution: The reactant involved in the reaction contains highly deactivating nitro groups, so electrophilic
substitution is not possible at benzene ring in this case. Since it contains a good leaving group (Cl)
nucleophilic substitution reaction will take place.
The nucleophile in this reaction is hydroxide ion, so HO will substitute the chlorine atom from the
benzene ring.
Solution: Since the graph is not linear, so, average rate and instantaneous rates are different.
Here we need to calculate instantaneous rate after 15 min.
For the given reaction,
d[A]
Rate
dt
which is indicated by the slope of the graph at point P. The slope can be calculated by drawing tangent
line at point P. We need two points on this tangent line to find the slope.
The two points are (0, 0.03) and (15, 0.01). Therefore,
0.01 0.03
Rate
1.33 103 M min 1
15 0
Correct Option: (4)
Question 12: Choose the correct options from the following orders:
(1) Basicity order: NH3 > NH2NH2 > NH2OH > NF3
(2) Melting point order: NH3 < SbH3 < AsH3 < PH3
(3) Boiling point order: NH3 > SbH3 > AsH3 > PH3
(4)Thermal stability: NH3 < PH3 < AsH3 < SbH3
Solution: Option (1) is correct as all the three bond pairs are attracted towards N-atom and increase the
electron density on N-atom in the case of NH3. While in the case of NH2NH2, bond pair is not attracted
towards any N-atom; for NH2OH oxygen withdraws the bond pair towards itself; and finally in NF3, three
F-atom having I effect decrease the electron density on N-atom.
Option (2) is incorrect as due to H-bonding in NH3, the effective molecular mass increases, and
overcomes all other molecular masses. Thus, the melting point is highest in NH 3.
Option (3) is incorrect as at the boiling point temperature, the extent of H-bonding is less and cannot
overcome the molecular weight of SbH3.
Option (4) is incorrect as the thermal stability depends upon bond energy of MH bond, which is the
highest (shortest bond length) for NH3 and thus it has the highest stability.
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2a 4 R a
4R
2
4 1.414
2
(1)
(2)
(3)
(4)
Solution: Brine is 10% aqueous solution of NaCl, so the reaction mixture contains Br2, Cl and H2O, out
of which Br2 can initiate the reaction since the first step of addition is electrophilic in nature. For the
second step, a nucleophile is required for which Br, Cl and H2O are available and lead to the following
products.
Formation of 1,2-dichlorocyclohexane is not possible in this reaction since the first step in the addition to
double bond involves an electrophilic attack and chlorine is not available as Cl+ (electrophile) in the
reaction mixture.
Correct Option: (4)
Question 15: Which one of the following represents the order of the decreasing sizes in the given four
isoelectronic species?
(1) F > N3 > O2 > C4
(2) C4 > N3 > O2 > F
(3) N3 > C4 > F > O2
(4) O2 > N3 > C 4 > F
Solution: We have
Element
C
N
O
F
Nuclear Charge
(Number of Protons)
6
7
8
9
Number of
Electrons
10
10
10
10
The order of ionic sizes is C4 > N3 > O2 > F . For the isoelectronic species, greater the nuclear charge
(number of protons), lesser is the ionic or atomic size.
Correct Option: (2)
Question 16: Phenol gives broad spectrum of reactions because OH group makes benzene ring very
reactive towards electrophilic substitution reaction. It reacts even with neutral electrophiles. Which of the
following reaction involves carbenes as electrophile?
(1) Gattermann reaction
(2) Reaction of phenol with HCHO in presence of acid
(3) Kolbe-Schmidt reaction
(4) Reimer-Tiemann reaction
Solution: Carbenes are electron-deficient neutral species due to which they act as electrophiles. Carbene
is formed during Reimer-Tiemann reaction. The electrophiles involved in Kolbe-Schmidt, Gattermann
and chloromethylation of phenols are CO 2 (neutral), HCNH+ and H2C=OH+, respectively. The detailed
mechanism is as follows:
(1)
(2)
(3)
(4)
Solution: The basicity of amines depends on the lone pair available on nitrogen atom. In benzyl amine,
lone pair is easily available since this lone pair is not delocalized over benzene ring. Also the nitrogen
atom is in sp3 hybridized state, so it is the most basic, even more basic than pyridine in which nitrogen
atom is sp2 hybridized. Increasing s-character in hybridization decreases basicity.
From the given options, however, p-nitroaniline is a weak base because nitrogens lone pair is delocalized
in the benzene ring. In pyrrole, nitrogens lone pair is involved in aromaticity and least available for
protonation. This effect makes it least basic among the given compounds.
Correct Option: (2)
Question 19: Select the correct product formed when cyclohexanone reacts with aqueous sodium
hydroxide at 100C?
(1)
(2)
(3)
(4)
RT 10b b 9b
pb
1 10
Z 1
1
or
RT
9 9
Correct Option: (1)
Question 21: Find the ligand having the highest denticity from the following options:
(1)
(2)
(3)
(4)
Solution
Denticity is the number of donor groups from a given ligand attached to the same central atom. The
denticity of compound (1) = 2; (2) = 3; (3) = 4; (4) = 2.
Correct Option: (3)
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Question 22: Which of the following pair of alcohols can be distinguished by Victor-Meyer test?
(1) Methanol and ethanol
(2) Ethanol and 1-propanol
(3) 2-Pentanol and 3-pentanol
(4) 1-Propanol and 2-propanol
Solution: Victor-Meyer test is used to distinguish between 1, 2 and 3 alcohols.
Methanol, ethanol and 1-propanol are 1 alcohols and 2-pentanol, 2-butanol and 3-pentanol are 2
alcohols. So, 1-propanol and 2-propanol can be distinguished by Victor-Meyer test since these alcohols
have different degrees.
Correct Option: (4)
hc
Number of photons
7.03 1011
Energy of one photon 6.636 1034 J s 3 108 m s 1
560 109 m
6
1.5 18 32.4 g
5
(1)
and
(2)
and
(3)
and
(4)
and
Solution: For two structures to be in resonance only movement of electrons takes place but there should
be no change in the skeleton of the molecule.
The structures given in option (3) are resonance hybrids of each other since they satisfy both the
conditions.
However, in structures given in options (1),(2) and (4), the position of hydrogen atom changes, so the
molecule undergoes a change in the skeleton of the structure. Hence, these pairs do not represent
resonance structures. In option (3), there is only delocalization of electrons in both structures, and no
change in the skeleton of structure is observed; so both represent the resonance structures.
Correct Option: (3)
Question 29: Calculate the maximum work that could be obtained at 25C and 1 atm by burning 1 mol of
C2H5OH.
[Given: Gfo (C2 H5OH(l)) 174.8 kJ mol1 ; Gfo (CO2 (g)) 137.3 kJ mol1 ;
(1)
(2)
(3)
(4)
Solution: Option (3): In cyclopentane, all hydrogen atoms are equivalent, so only one product is
produced on chlorination.
Option (1): Although bromination is more selective than chlorination for substitution of particular
hydrogen atom, but 1,4-dimethylcyclohexane contains 1, 2 and 3 hydrogen atoms out of which 2 and
3 hydrogen atom would participate in the reaction and mixture of isomers is produced.
Option (4): n-pentane also contains two types of 2 hydrogen atoms, so, a mixture of at least two isomeric
forms is produced. Option (2): In the case of bromination of 2-methylhexane, mixture of structural as well
as optical isomers is produced since it contains 2 and 3 hydrogen atoms for bromination.
Correct Option: (3)
Part C Mathematics
Question 1: The condition ( p q) p is
(1) a contradiction
(2) a tautology
(4) equivalent to (~ p ~ q)
q
T
F
T
F
pq
T
F
F
F
( p q) p
T
T
T
T
Hence, ( p q) p is a tautology.
Correct Option: (2)
Question 2: Consider a set of 25 observations: x1, x2, , x25 whose mean and standard deviation are 20
and 5, respectively. Later on, it is noticed that x25 is taken as 25 instead of 50, the actual standard
deviation is
(1) 6
(2) 59
(3) 26
(4) 69
1
1
1
xi 20,
xi2 xi 25
25
25
25
2
xi 500,
xi 25(25 400) 10625
1
1
500 441
59
8
(3) 15
(4)
1
15
Solution: The power of x is even, which implies that the power of (1x) is also even. Therefore,
2
2
y f ( x) touches x axis at x =0 or x =1 . Therefore, the graph of y x (1 x) is as shown in the following
figure:
So the area enclosed by the curve and the x-axis is given as,
1
x
0
(1 x) dx x 2 (1 x 2 2 x)dx
2
( x 2 x 4 2 x3 )dx
0
x3 x5 x 4
5
2 0
3
1 1 1
3 5 2
10 6 15 1
30
30
(if z 1 ).
1 z
1 ei
n
1 ei i
e ei 1
1 ei
Therefore,
1 z
1 z
11 2
1 z
1 z
n
67
C2 favourable cases to E.
P( E )
67
C2
100
C2
67 33
99 50
67
150
Hence,
P( E ) 1 P( E )
83
0.55
150
R is
(1) reflexive on
(2) symmetric
(3) transitive
and m 0
the value of
c2
x2
a
y2
b
(1) 1
(3) 3
Solution: It is given that
(2) 2
(4) 4
x2
a2
y2
b2
2x
a
2 y dy
0
b 2 dx
dy
x b2
2
dx
a y
dy
dx
b2 x
2 1
a y1
where we assume that the two curves intersect at point A(x1, y1).
Again, consider the curve x2 y2 = c. Differentiating with respect to x, we get
dy
0
dx
dy x1
(at point A( x1 , y1 )
dx y1
Since the two curves intersect orthogonally, the product of the slopes of the tangents drawn at the point
A(x1, y1) to both the curves must be 1.
So we get,
b x x
b2 x 2
(1)
2 1 1 2 12 1
a y1
a y1 y1
Since point of intersection of the two given curves is (x1, y1), we have
x12 y12
x1 / y1 2
a
x
1
y1
( x1 / y1 )2
c a
2 2
a c
2
c
2
1
1
2 2
c
b
b2 c2
2 2
b c
x
(b2 c 2 )a 2 a 2 (b2 c 2 )
1 2 2
b (c a 2 ) b 2 ( a 2 c 2 )
y1
2
2
2
1
b 2 b 2 (a 2 c 2 ) a 2
b a c
b2 c2 a 2 c2
b 2 a 2 2c 2
a 2 b 2 2c 2
(2)
4
5 5
2
(1)
2
We also know that (cos sin ) 1 sin 2 . Therefore,
4
3 5
2
(2)
4sin 27 5 5 3 5
Correct Option: (3)
Question 9: If a, b and c are chosen from the domain of f ( x) =
x 2 4x 2
distinct, then the probability that 0 (where is complex cube root of unity) is
1
2
(1)
(2)
6
9
1
2
(3)
(4)
3
9
a
Solution: We have
x 2 4x 2
C 2 x2 2 x 1
0 2x2 + 2x 1 x2 + 4x + 2
x 2x 3 0
(x 3) (x + 1) 0
1 x 3
2
x + 4x + 2 0 x ( , 2 2 ] [ 2 2, )
2
2x2 + 2x 1 0 x ( ,
3 1
, 3
x
2
x {1, 2, 3}
a, b, c {1, 2, 3}
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3 1
1 3
] [
, )
2
2
( 1 2 0 )
a1 a2
a2 a3
an 1 an
(1)
n 1
a1 an
(2)
n 1
a1 an
(3)
n
a1 an
(4)
n
an a1
Solution:
a2 a1
a2 a1
a3 a2
a3 a2
a4 a3
a4 a3
an a n 1
an a n 1
a a1
an a1
n
(n 1)
an a1
n 1
an a1
a11
A a21
a
31
a13
a23 , A 4
a33
a12
a22
a32
a11
a11 31 a12 32 a13
B 3a21
a22
31 a23 3a21
32 a31 3a32
a
33
9a31
1
1
a12
a13
a11
12
144
1
C 12a21
a22
a23
12
a33
144a31 12a32
1
a12
3
a22
3a32
1
a13
9
1
a23
3
a33
Note that
|B| = |C| = |A|
Therefore,
|B| + |C| = 4 + 4 = 8
Correct Option: (1)
Question13: The equation of a plane which lies mid-way
( x 1) 2( y 2) 3( z 3) 0 and 2(x 2) 4( y 4) 6( z 6) 0 is
(1) 3x 6 y 9 z 70 0
(2) 3x 6 y 9 z 35 0
(3) x 2 y 3z 21 0
between
(4) x 2 y 3z 21 0
x 2 y 3z 14 0
and 2 x 4 y 6 z 56 0 or
x 2 y 3z 28 0
(1)
(2)
14 28
x 2 y 3z
0
2
x 2 y 3z 21 0
(3)
Note
Any point on plane given in Eq. (3) is (0, 0, 7). Its distance from plane given in Eq. (1) is
0 0 21 14
1 2 3
2
7
14
14
0 0 21 28
1 2 3
2
the
planes
Solution:
(a 2 b 2 ) x 2 2b(a c) x b 2 c 2 0
a 2 x 2 2abx b 2 b 2 x 2 2bcx c 2 0
(ax b) 2 (bx c) 2 0
b2 ac
Hence, both roots are equal to
b
c
b
or . Moreover, also satisfies option (2), that is,
a
b
a
a2 x2 a(c b) x bc 0
Correct Option: (2)
x
(1) 0
(3) 1
(2) 1
(4) Does not exist
x
Solution: Let f lim x . Therefore,
x 0
ln f lim ln x x
x 0
ln f lim x ln x
x 0
(0 form)
ln x
form
x 0 1 / x
1/ x
lim
lim ( x) 0
x 0 (1 / x 2 )
x 0
lim
f e0 1
lim x y ,
x 0
1
(0 )
Correct Option: (1)
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y 1 as x 0
15
f ( x) dx
table:
x
f(x)
0
50
3
48
6
44
9
36
(1) 543
(3) 143
12
24
15
8
(2) 343
(4) 43
15
approximate area under the curve y = f(x) and x-axis. Using the data provided in the table, we can write as
f (0) f (3)
f (3) f (6)
f (6) f (9)
f (9) f (12)
f (12) f (15)
3
3
3
3
3
2
2
2
2
2
50 48 48 44 44 36 36 24 24 8
3
2
2
2
2
2
3 (49 46 40 30 16)
3 181 543
Correct Option: (1)
a 2 b2 c2
Question 17: In ABC, if R 2 R 2 cos A cos B cos C
, find the value of n.
(1) 1
(2) 2
(3) 4
(4) 8
Solution: We have
R2
(2cos A cos B)[cos ( ( A B))]
2
R2
R2
[cos( A B ) cos( A B )] [( cos( A B )]
2
R2
R2
[cos 2 ( A B) cos( A B) cos( A B )]
2
R2
R2
[cos 2 ( c) cos 2 A sin 2 B]
2
R2
R2
(cos 2 c cos 2 A sin 2 B)
2
R2
R2
[(1 sin 2 c) (1 sin 2 A) sin 2 B]
2
R2
R2 R2
(sin 2 A sin 2 B sin 2 C )
2
2
2
R
a
b2
c2
2 4R
4 R 2 4 R 2
1
(a 2 b 2 c 2 )
8
Now,
d (1 r 2 )
9
1 r
2r 9d 31 and d (1 r ) 9
99
2r
31
(1 r )
2r 2r 2 81 31(1 r )
2r 2 29r 50 0
Therefore,
(1)
(2)
29 841 400
4
29 21
12.5 or 2
4
Question 19: Let a, b and c be non-coplanar vectors. Suppose A, B, C and D are four points with
position
vectors
a 4b 3c, 3a 2b 5c, 3a 8b 5c
and
3a 2b c respectively.
If
(2) x 1, y 1
(4) x 1, y 1
Solution: We have
AB x AC y AD
4a 2b 2c x(2a 4b 2c) y (2a 2b 4c)
Equating the corresponding coefficients of both sides, we get
2 x 2 y 4
(1)
4 x 2 y 2
(2)
2 x 4 y 2
(3)
Solving Eqs. (1) and (2), we get that x 1 and y 1 which also satisfy Eq. (3).
Correct Option: (4)
Question 20: Let f be differentiable on R and f ' ( x) 3 x . If x, y ; which of the following is
always correct?
(1) f ( x) f ( y) 9 x y
(2) f ( x) f ( y) 6 x y
(3) f ( x) f ( y) 3 x y
(4) 3 x y f ( x) f ( y) 9 x y
Solution: According to mean value theorem on f, we can say that there is at least one number c in (x, y)
such that
f ( x) f ( y )
f ' (c )
x y
Given that f '(c) 3 . This implies that
f ( x) f ( y )
3
x y
f ( x) f ( y ) 3 x y
Correct Option: (3)
Question 21: Find the transformed form of the equation x 10 xy 3 y 0 if the origin is shifted to the point
(3, 5).
2
2
(1) X 3Y 10 XY 50 X 60Y 234 0
(2) X 2 3Y 2 10 XY 56 X 30Y 234 0
2
2
2
(3) X 3Y 10 XY 56 X 60Y 225 0
2
2
(4) X 3Y 10 XY 56 X 60Y 234 0
Solution: Substituting x 3 X and y 5 Y where ( x, y) represents the old coordinate system and
( X , Y ) represents the new coordinate system (see the following figures).
2
2
Now, x 10 xy 3 y 0 becomes
X 2 3Y 2 56 X 60Y 10 XY 234 0
X 2 3Y 2 10 XY 56 X 60Y 234 0
Correct Option: (4)
A 3
B
C 3
x (ln x)2 x3 (ln x)
x constant , then find A + B + C
3
9
27
(2) 1
(4) 5
Solution: We have
( x ln x)
t
dx
e3t t 2 dt
Note: (et)2 = e2t, e2tet = e2t + t = e3t
Integration by parts gives
e3t
e3t
2t
dt
3
3
t 2 e3t 2 e3t
e3t
dt
3
3 3
3
I t 2 e3t dt t 2
I
II
t 2 e3t 2 3t 2 1 3t
te e c
3
9
9 3
x3 (ln x)2 2 3
2
x (ln x) ( x3 ) c
3
9
27
Therefore,
A + B + C = 1 2 + 2 = 1.
Correct Option: (2)
1 3 1 2
x x x 1 ; x 0
Question 23: If f ( x) 6
2
ex
; x0
ex
; x0
lim f ( x) 1
x 0
lim f ( x) lim e x 1
x 0
x 0
e
; x0
f (0 h) f (0)
,h 0
h0
h
(h3 / 6) (h2 / 2) h 1 1
lim
h0
h
2
h
h
lim
1 1
h 0 6
2
Let us consider
f (0 ) lim
f (0 ) lim
h0
f (0 h) f (0)
,h 0
h
f (h) f (0)
h 0
h
3
(h / 6) (h2 / 2) h 1 1
lim
h 0
h
h2 h
lim 1 1
h 0 6
2
ex
; x0
Let us consider
x 1 ; x 0
g ( x) h( x) x
; x0
e
Therefore,
f (0) 1
g (0 h) g (0)
;h 0
h0
h
[(1 / 2)(h)2 ] h 1 1
lim
h0
h
h
lim
1 1
h 0 2
lim
0
h 0
h
2
Therefore, g (0) 1 , that is, g'(0) exists. Thus,
g (0 ) lim
x 1 ; x 0
g ( x) x
; x0
e
= h(x)
(say)
(1) T6
(2) T7
(3) T8
(4) T9
1
20
is
20
as follows:
(20 1) 1 / 3
1 1/ 3
p 1.
Therefore
p
(20 1)(1 / 3)
1 (1 / 3)
21
3 1
7.686
(a 3c)2 (2b)2 0
(a 3c 2b)(a 3c 2b) 0
a 2b 3c 0 or a 2b 3c 0
1
2
1
2
a bc0
a bc0
3
3
3
or 3
Point of concurrency is 1 , 2 or 1 , 2
3 3
3 3
4
.
3
(1) 4
(2) 5
(3) 6
(4) 7
Solution: We have
1 1
A
1 2
Therefore,
1 1 1 1 0 1 1 0 1 1
A2
I A
1 2 1 2 1 3 0 1 1 2
Thus,
A3 = A A2 = A ( I A) = 2A I
A4 = 2A2 A = 2 (I A) A = 2I 3A
A5 = 2A 3A2 = 2A 3(I A ) = 5A 3I
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A6 = 5A2 3A = 5(I A) 3A = 5I 8A
n6
6
(3) tan 1
5
2 3
(4) tan 1
5
3
2
(3 / 2)
touches the parabola y2 = 6x for all real values of m (m 0) . This tangent line
m
passes through the point (1, 3), which implies that
3
3m
2m
2m 2 6m 3 0
Let the roots of this equation be m1 and m2, then m1 + m2 = 3 and,
3
m1 m2 =
2
Let be the acute angle between the tangents, then
The line y mx
m m2
tan 1
1 m1m2
(m1 m2 )2 4m1m2
1 m1m2
96 2 3
3
5
1
2
2 3
tan 1
2
2
(2) x y 5x 10 y 25 0
2
2
(3) x y 5x 10 y 25 0
2
2
(4) x y 10 x 5 y 25 0
Solution: Theorem: The equation of circle having diameter extremities as (x1, y1) and (x2, y2) is
( x x1 )( x x2 ) ( y y1 )( y y2 ) 0
Since (0, 5) and (5, 5) are extremities of a diameter of the circle, the equation is expressed as
( x 0)( x 5) ( y 5)( y 5) 0
or
x2 y 2 5x 10 y 25 0
Note: If a circle touches y-axis at (0, 5), then the centre of the circle must lie on y = 5. Therefore, (0, 5)
and (5, 5) must be the extremities of its diameter.
Correct Option: (3)
Question 29: The equation of the line represented by x 3 y 5 and z 7 x 9 in symmetrical form is
(1) z 7(3 y 5) 9
(2) z 7(3 y 5) 9
(3) x 21y 35 z 9
(4) z 5 7 x 4 21y 31
Solution: If x 3 y 5 represents one plane and z 7 x 9 represents another plane. Let , and be the
points common to both of these planes. This implies that
3 5 and 7 9
9
3 5
7
z 9
x 3y 5
(The line of intersection of the two given plane)
7
7 x 21y 35 z 9
7 x 4 21y 31 z 5
x 1 yy'
(1) x 1 y
9
y'
x 1 yy '
(2) x 1 y
9
y'
1 x yy '
2
x 1 yy '
(3) x 1 y
9
9 (4) x 1 y
y'
y'
x xc 2 y yc 2 r 2
x 12 y yc 2 32
(1)
where yc is a parameter (or variable). Since the number of parameter is one, we need to differentiate only
once. That is,
2 x 1 2 y yc
dy
0
dx
x 1 yy ' yc y ' 0
yc y ' x 1 yy '
x 1 yy '
yc
y'
x 1 yy '
x 1 y
9
y'
which is the required differential equation; which we obtained by eliminating the parameter yc .
Correct Option: (3)
2
(2)