Professional Documents
Culture Documents
Contents
General properties of silicone
Weatherability
6, 7
Electrical insulation
Thermal conductivity
Flame retardancy
Electrical conductivity
Compression set
10
10
11
Gas permeability
12
12
Radiation resistance
13
Vibration absorption
14
14
Physiologically inert
14
15
Si
Si
Si
Flame retardancy
Chemical stability
Good weatherability
Radiation resistance
Electrical properties
Si
O
Cold resistance
O
Si
Si
O
CH3
Si
Releasability
Si
Si
Water repellency
Si
Si
Si
O O
CH3
CH3
Si
O
O
Si
CH3
Silicone rubber
Ethylene propylene rubber
Heat resistance
Chloroprene rubber
Fluoro-rubber
Natural rubber
Good weatherability
Chemical stability
Chemical resistance
Flame retardancy
Electrical properties
Cold resistance
(Operating life defined as the time at which elongation at break is 1/2 that of the initial value)
105
Heat-resistant
silicone rubber
KE-552
Time (h)
103
General purpose
silicone rubber
KE-951
below.
Generally speaking, silicone rubber hardens when heated in air,
with decreasing elongation as it deteriorates; but in sealed
102
160
180
220
240
260
Temperature (C)
200
Chloroprene rubber
General purpose
silicone rubber
KE-951
100
Nitrile rubber
400
200
0
10
Chloroprene rubber
(250C)
2
Time (days)
Chloroprene rubber deteriorates rapidly and discolors at temperatures
between 150250C, but there is little change in silicone rubber even at 250C.
Silicone rubber
for low-temperature
applications
KE-136Y
-100
-80
-60
-40
-20
Temperature (C)
600
20
40
Weatherability
Silicone rubbers have exceptional weatherability. Ozone created by corona discharge rapidly deteriorates most organic rubbers, but has
almost no effect on silicone rubber. In addition, silicone rubber can be exposed to wind, rain and UV rays for long periods with virtually
no change in its physical properties.
Results of long-term outdoor exposure testing of various rubbers
Deterioration conditions
Location
Time of sunlight exposure until elongation is 1/2 that of the initial value (years)
Panama
Rock Island
Panama
Rock Island
Styrene butadiene
2 - 3.5
Over 10 years
10
Nitrile
0.5 - 1
10
8.5
Over 10 years
Over 10 years
Over 10 years
Over 10 years
Silicone (methylphenyl)
Over 10 years
Over 10 years
Fluorosilicone
0.5
Ethylene propylene
10
Fluorine
10
10
Rubber type
Chloroprene
Change in elongation
12
500
65
8
KE-7611
6
KE-551
4
2
400
KE-551
300
KE-7611
200
10
20
30
40
Time (days)
55
50
KE-951
45
40
KE-951
100
KE-551
35
KE-951
0
KE-7611
60
Hardness
10
Change in hardness
70
50
60
10
20
30
40
Time (days)
50
60
30
10
20
30
40
50
60
Time (days)
Reference oil C
Fluoro-rubber
Urethane rubber
25
Nitrile rubber
Premium gasoline
Regular gasoline
Reference oil B
Epichlorohydrin
rubber
50
Acrylic rubber
Chloroprene
rubber
75
Silicone
rubber
Reference oil A
Automatic Machine oil
transmission fluid ASTM No.2
100
ASTM No.1
125
-50
0
50
100
Temperature (C)
Oil
Acid
ASTM No.1
ASTM No.3
GM Hydramatic Fluid
Ford Brake Fluid
Diesel Fuel
Gasoline
Skydrol 500A Fluid
Motor oil (SAE #30)
Conc. Nitric acid
7% Nitric acid
Conc. Sulfuric acid
10% Sulfuric acid
Acetic acid
5% Acetic acid
Conc. Hydrochloric acid
10% Hydrochloric acid
10% Sodium hydroxide solution
2% Sodium hydroxide solution
Conc. Ammonia water
10% Ammonia water
Alkali
Chemical
Other
Water
3% Hydrogen peroxide solution
Immersion conditions
C/h
150/168
150/168
94/70
150/72
50/168
23/168
70/168
175/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
25/168
100/70
70/168
25/168
200
250
Aniline point: the lowest temperature at which equal portions of an oil and aniline are completely miscible.
The lower the aniline point, the greater the swelling effect of the oil.
Type of oil/chemical
150
Change in properties
Hardness points
-10
-25
-35
-20
-30
-20
-5
-8
Weight %
+10
<1
Dissolves
<1
+3
+2
+3
+2
-2
<1
+2
+2
<1
<1
+1
<1
Volume %
+10
+40
+35
+15
+105
+165
+10
-8
+10
<1
Dissolves
<1
+4
+2
+4
+2
-1
<1
+1
+2
<1
<1
<1
<1
Tensile strength %
-10
-20
-40
-60
-10
-70
-80
-50
Dissolves
0
-20
-20
-40
-50
-10
0
-30
-20
0
-10
-10
0
Elongation %
-10
-20
-5
-40
+5
-65
30
-30
Dissolves
0
+10
+10
-20
-50
0
0
+10
0
0
-10
+10
+20
Correlation between solubility parameter value (SP value) of a solvent and rubber swelling
400
Natural rubber
Swelling (Vol %)
300
Neoprene rubber
Fluorosilicone rubber
Silicone rubber
200
100
Fluoro-rubber
Acetone/diester
Benzene
Toluene
CCI4
Cyclohexane
n-Octane
Gasoline
SP value
10
Temperature
C
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
100
50
Nitrile
28%
15
-1
10
20
-2
0.5
10
20
0.5
50
250
290
110
250
360
450
50
10
2
33%
10
-1.5
3
12
-2
1
10
20
0.5
30
250
230
75
200
380
470
40
11
3
38%
6
-2
0.5
5
-2
1.5
10
18
0.5
20
250
230
55
160
420
510
25
12
3
Chloroprene
Natural
rubber
Styrene
butadiene
Butyl
Silicone
Hypalon
55
5
65
70
27
30
25
7
2
95
150
380
330
300
125
85
40
12
5
250
60
200
250
100
110
6
3
0.5
170
85
420
420
350
15
35
55
10
2
140
12
130
150
50
50
7
-5
0.5
135
80
400
400
350
30
60
35
2.5
7
240
20
120
250
10
10
0.5
2
-0.2
90
15
300
275
150
10
3
7
5
0.5
260
4
40
150
4
4
1
15
1
270
150
300
300
240
7
10
25
2
0.5
85
4
65
120
40
45
1.2
5
0.5
85
150
600
350
430
70
80
20
4
0.5
Electrical insulation
Silicone rubber has high insulation resistance of 1Tm100Tm,
Arc resistance
Material
10
4.5
Chlorosulphonated polyethylene
5.2
Butyl rubber
72
1
Silicone rubber
Ethylene
propylene rubber
Chloroprene rubber
8.5
Epoxy resin
184
Polyester resin
10-1
10-2
165-185
Silicone rubber
over 180
Tracking resistance
DIN method
Material
10-4
Butadiene rubber
10-5
0
20
40
60
80
100
120 140
Temperature (C)
Rating
Erosion depth mm
[ ] drip count
Butyl rubber
KA-3C
0.342
KA-3C
0.240
Chlorosulphonated polyethylene
KA-3C
0.224
Chloroprene rubber
KA-2
[18]
Polyethylene
KA-2
[46]
Cross-linked polyethylene
KA-3C
0.302
Polystyrene
KA-2
[15]
Silicone rubber
KA-3C
0.0064
134
Polytetrafluoroethylene (PTFE)
10-3
100
80
Corona resistance
Material
DC voltage
60
40
AC voltage
20
10
0.1
0.2
0.4 0.6
1.0
Thickness (mm)
over 180
2.0
4.0
6.0
Polyethylene
24.0
Polytetrafluoroethylene (PTFE)
33.5
Cellulose triacetate
36.5
50.0
Polyester varnish
22.0
55.0
65.5
Asphalt varnish
81.0
Silicone rubber
over 35,600
Thermal conductivity
The thermal conductivity of silicone rubber is about 0.2
Mica
rollers.
Polyester
Polyethylene
Polystyrene
0.2
0.4
0.6
0.8
1.0
1.2
1.4
Flame retardancy
If silicone rubber is brought close to a flame, it will not ignite easily; but once
ignited it will continue burning. It is possible to impart flame retardancy and/or
self-extinguishing properties by adding a small amount of flame retardant.
Some silicone rubber products have received UL94 V-0 certification according
to the UL94 (USA) standards for flammability classification, shown at right.
When they do burn, almost no black smoke or noxious gas is produced during
Electrical conductivity
Conductive silicone rubbers contain electrically conductive
100,000
10
1
Ketjen black
0.1
0
10
20
30
40
50
60
Content (parts)
Compression set
When using rubber materials for gaskets that will be under
140
120
100
Natural rubber
Creep (%)
Butyl
rubber
80
Chloroprene
rubber
Styrene
butadiene rubber
60
40
Fluoro-rubber
20
Silicone rubber
10
100
Compression set (%)
Organic rubber
80
60
Silicone rubber for low-temperature applications
40
General purpose silicone rubber
20
-50
50
100
150
200
Temperature (C)
Brand name
KE-951
KE-9510
KE-9511
KE-5151
30-40
45-55
200-300
400-500
Keypad keystroke durability2 ( x 10,000 times) approx 250 approx 300 approx 1,100 approx 2,000
1 Tested using De Mattia flexing fatigue tester, 100% elongation, 5 cycles/sec.
2 Measured using a model keyboard. Expressed as the number of keystrokes
until the rubber's recovery force is 50% its initial value.
10
1,000
Time (hour)
100
products are ideal for molding large items, reverse tapered forms,
Tear strength
50
Tear strength Crescent pieces (kN/m)
28
40
30
20
Styrene butadiene rubber
24
Styrene butadiene rubber
20
16
12
8
10
4
50
100
200
250
50
100
150
200
250
Temperature (C)
Temperature (C)
The strength of silicone rubber at room temperature is inferior to that of organic rubber,
but silicone rubber maintains strength better at high temperatures, such that the two eventually trade places on the graph.
40
KE-555
30
20
10
KE-953
KE-951
Tear strength test (crescent piece)
High-strength silicone rubber
11
Gas permeability
Compared to organic rubber or plastic films, thin films of
silicone rubber have better gas and vapor permeability, and
they have selectivity. One application for silicone rubber being
investigated is as a gas and water separation membrane in
oxygen enrichment systems.
Comparison of gas permeability with natural rubber=100 for reference (25C)
Material
P x 108cccm
cm2secatm
Natural rubber
H2
O2
N2
CO2
Air
37.4
17.7
6.1
99.6
100
100
100
100
100
1070
2200
3300
1600
2700
15
56
48
Polybutadiene (emulsified)
86
82
80
105
81
Silicone rubber
Nitrile
Acrylonitrile content
20%
51
35
31
48
33
27%
32
17
13
24
15
32%
24
10
7.5
14
8.5
Teflon
46
44
43
19
Polyethylene d=0.926
15
11
Polypropylene
23
Polyvinyl chloride
Silicone rubber
15.5-51.8
PVA
0.04-40.0
Ethylcellulose
21.5
Polyethylene
0.05-4.85
Polytetrafluoroethylene (PTFE)
2.94
Polycarbonate
1.0
Nylon
Permeability
0.32-0.63
12
high-strength silicone rubbers that are used for tubing and molded
because the fine silica it contains does not spoil the natural
Radiation resistance
Common silicone rubber (dimethyl silicone rubber) really has no
Silicone rubber with added phenyl groups has the same fine heat
800
108
50
100
100
Hardness
Dose (Mrad)
107
106
70
Methyl vinyl
silicone rubber
40
105
50
100
Dose (Mrad)
Acceptable
temperature range (C)
80-90
80-110
Natural rubber
Urethane rubber
90-120
100-150
200-250
200-300
Chloroprene rubber
Butyl rubber
Fluoro-rubber
Silicone rubber
12
8
Methyl vinyl
silicone rubber
40
50
100
Dose (Mrad)
13
Vibration absorption
The loss modulus (tan ) of silicone rubber is generally low,
to +100C.
Vibration-absorbing
silicone rubber
KE-5560
Butyl rubber
Natural rubber
SEP rubber
0.1
General purpose
silicone rubber
KE-951
tan =
G2
G1
The larger the value of tan , the greater the ability of a particular
material to absorb energy (vibration, etc.).
0.01
-40
50
100
Temperature (C)
Physiologically inert
14
Consumer electronics
Defrosters
Industry
Application example
Required properties
Electrical wiring
EMI gaskets
Heat resistance,
non-adhesiveness,
low compression set
Machinery
Automobiles
Diaphragms, O-rings
Waterproof connectors
Hoses
Turbo chargers
Intercooler hoses
Solar hoses
Vibration absorption
Food
Gaskets for pressure cookers,
Steam resistance, chemical resistance,
Nipples
Leisure
Swimming goggles
Snorkels
Mouthpieces
Goggle bands
15
India Branch
Germany Branch
Rheingaustrasse 190-196, 65203 Wiesbaden, Germany
Phone : +49-(0)611-962-5366 Fax : +49-(0)611-962-9266
The
The
Naoetsu Plant
Takefu Plant
(JCQA-0018 JCQA-E-0064)
(JQA-0479
JQA-EM0298)
http://www.silicone.jp/
C Shin-Etsu 2005.3/2012.6 2 1.B.P. Printed in Japan.