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Austenite
The first phase formed as liquid steel freezes. Austenite is a metallic non-magnetic allotrope
of iron or a solid solution of iron, with an alloying element. In carbon steel, austenite exists
above the critical eutectoid temperature of 727 C; other steel alloys have different eutectoid
temperatures.
Martensite
A supersaturated solid solution of carbon in iron. Carbon atoms trapped in an iron crystal. If
steel is cooled rapidly from austenite, the F.C.C structure rapidly changes to B.C.C leaving
insufficient time for the carbon to form pearlite. This results in a distorted structure that has
the appearance of fine needles. There is no partial transformation associated with
martensite, it either forms or it doesnt. Only the parts of a section that cool fast enough will
form martensite; in a thick section it will only form to a certain depth, and if the shape is
complex it may only form in small pockets. The hardness of martensite is solely dependant
on carbon content, it is normally very high, unless the carbon content is exceptionally low. It
is the hardest and strongest of the microstructures
Bainite
Same as martensite but considerably less carbon is trapped. Forms from austenite if rate of
cooling is in sufficient. Strength and hardness is between martensite and pearlite.
Cold Forming
Forming a metal at or near room temperatures using high pressures.
Ductility
The ability of a material to be plastically deformed without fracturing.
Fracture Toughness
The ability of a material at a given temperature to resist further crack propagation, once a
crack has started.
Hardness
The ability of a material to resist plastic deformation. The common measurement systems
are Rockwell, Brinell, Vickers and Knoop.
HSLA Steel
High Strength Low Alloy Steel
Impact Toughness
The ability of a material to resist fracture under an impact.
I.T. Diagram
Isothermal Transformation
Inclusions
Impurities in a metal. Ie MnS (Manganese-sulfide)
Mechanical Properties
Tensile strength, yield strength, and hardness
Metallograph
An inverted microscope using indirect lighting.
Microhardness
Hardness determined by using a microscope to measure the impression of a Knoop or
Vickers indenter.
Microstructure
The phases or condition of a metal as viewed with a metallograph
Modulus of Elasticity
Measure of stiffness. Ratio of stress to strain as measured below the yield point.
Oxidation
The chemical reaction between oxygen and another atom
Physical Properties
Electrical conductivity, thermal conductivity, thermal expansion and vibration dampening
capacity
Plastic Deformation
Deformation that remains permanent after the removal of the load that caused it.
Steel
A solid solution of iron and carbon
Tensile Strength
The ratio of maximum load to the original cross-sectional area.
Yield Strength
The point at which a material exhibits a strain increase without increase in stress. This is the
load at which a material has exceeded its elastic limit and becomes permanently deformed.
Cooling time t8/5
time taken, during cooling, for a weld run and its heat affected zone to pass through the
temperature range from 800 C to 500 C.
The Heat input
In arc welding, energy is transferred from the welding electrode to the base metal by an
electric arc. When the welder starts the arc, the base and the filler metal are melted and
create the weld. This melting is possible because a sufficient amount of heat (energy
transferred per time unit) supplied. Heat input is the relative measure of the energy
transferred per unit length of weld.
It is one of the most important characteristic related to welding because it influences the
cooling rate, which may affect the mechanical properties and metallurgical structure of the
weld and the HAZ. For many steels, abrupt cooling from the heat of welding needs to be
avoided, because of the risk of hardening or cold cracking. Depending on the type of
material, thickness of material and heat input, preheating and the maintenance of an upper
or lower interpass temperature are normally required.
The heat input during welding can be viewed as a main influencing factor on the properties of
ferritic and ferritic-austenitic stainless steel welds in particular.
where
Q is the heat input in kJ/mm;
k is the thermal efficiency;
U is the arc voltage, measured as near as possible to the arc, in V;
I is the welding current, in A
v is the travel speed in mm/s.
Thermal efficiency factor k for welding processes
Welding
Process
Process No
121
Submerged arc welding with wire electrode
111
Metal-arc welding with covered electrode
131
Metal-arc inert gas welding
135
Metal-arc active gas welding
114
Flux-cored wire metal-arc welding without gas shield
136
Flux-cored wire metal-arc welding with active gas shield
137
Flux-cored wire metal-arc welding with inert gas shield
138
Metal-cored wire metal-arc welding with active gas shield
139
Metal-cored wire metal-arc welding with inert gas shield
141
Tungsten inert gas arc welding
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Plasma arc welding
(table from EN 1011-1)
Factor k
1,0
0,8
0,8
0,8
0,8
0,8
0,8
0,8
0,8
0,6
0,6
Heat input can not be measured directly. It has to be calculated from the measured values of
arc voltage, current and travel speed.
Arc Voltage
In determining the arc voltage (U), the voltage should be measured as close to the arc as
possible, as opposed to the value displayed on the welding machine voltmeter. Measuring
the voltage across the arc provides the actual voltage drop across the welding arc. The
welding equipment voltmeter reading is always higher than the arc voltage due to the
resistance of the welding cables. The equipment voltage, therefore, can be used only for
approximate calculations and, in the case of significant voltage drops, may lead to heat input
calculation errors.
Current
The welding current (I) is measured with either an inductance meter (tong meter) or a shunt
with appropriate metering equipment. The current is never fixed with respect to time,
especially on a microsecond level. The current is also a function of the arc length, which is
dependent on the welder's skill. The current used in heat input calculations is, normally, an
average value.
Travel Speed
The travel speed (v) is the travel speed of the arc measured in millimeters per second. Only
the forward progress contributes to the travel speed. If a weaving technique is used, only the
forward speed counts, not the oscillation rate. For vertical welding, the upward or downward
speed of the arc is used. The travel speed must be measured in terms of minutes and not
seconds in order to have a balanced value in the heat input equation. When the travel speed
is measured, the arc should be established for an amount of time that will produce an
accurate average speed. A continuous welding time of 30 seconds is suggested. The travel
speed accuracy for manual or semi-automatic welding is dependent on the welder.
Figure 2. The Fe-C phase diagram shows the phases which are expected at metastable
equilibrium, for different combinations of carbon and temperature values.
At the low-carbon part of the metastable Fe-C phase diagram, we distinguish ferrite (alphairon), which can at most dissolve 0.02 % C at 738 C, and austenite (gamma-iron), which can
dissolve 2.08 % C at 1154 C. The much larger phase field of gamma-iron (austenite)
compared with that of ferrite indicates clearly the considerably grater solubility of carbon in
austenite, the maximum value being 2.08 % at 1154 C. The hardening of carbon steels, as
well as many alloy steels, is based on this difference in the solubility of carbon in ferrite and
austenite. At the carbon-rich side of the metastable Fe-C phase diagram we find cementite
(Fe3C).
Figure 7 - TTT Diagram and microstructures obtained by different types of cooling rates
Time-Temperature-Transformation (TTT) diagram for two steels: one with 0.4% wt. C (red
line) and one with 0.4% wt. C and 2% wt. Mn (green line). P = pearlite, B = bainite and M =
martensite.
Figure 9 - TTT diagram for a 0.12% C-0.85% Mn-0.3% Si-1.4% Ni-0.7% Cr Steel
An important factor related to the steels weldability is the carbon equivalent value. The
equivalent carbon content of a steel alloy refers to method of measuring the maximum
hardness and the weldability of the alloy based on the chemical composition of the alloy.
Higher concentrations of carbon and other alloying elements tend to increase the hardness
and decrease the weldability of the material. Each of these materials tends to influence the
hardness and weldability of the steel to different magnitudes, however, making a method of
comparison necessary to judge the difference in hardness between two alloys made of
different alloying elements.
The equivalent carbon content is the most common such standard, but others exist, such as
the equivalent nickel content and the equivalent chromium content (usually used together
and in conjunction with the Schaeffler-Delong diagram and considered more accurate for
measuring weldability).
For carbon steel specifications, it is specified as the maximum carbon content shall be 0.25%
and the maximum carbon equivalent (CE) shall be 0.43%, where:
CE=C%+Mn%/6+(Cr% + Mo% +V%) / 5 + (Ni% + Cu%) / 15.
For this equation, weldability is defined as:
Weldability
Carbon equivalent (CE)
Up to 0.35
Excellent
0.360.40
Very good
0.410.45
Good
0.460.50
Fair
Over 0.50
Poor
The carbon equivalent is a measure of the tendency of the weld to form martensite on
cooling and to suffer hydrogen cracking.
Generally: The higher the CE value, the greater the risk of hydrogen cracking.
When the carbon equivalent is between 0.40 and 0.60 weld preheat may be necessary.
When the carbon equivalent is above 0.60, preheat is necessary, postheat may be
necessary, and techniques to control the hydrogen content of the weld are required.
For stainless steels and welds between carbon steels and stainless steels, the equivalent
nickel content and the equivalent chromium content (usually used together and in
conjunction with the Schaeffler-Delong diagram) are considered more accurate for
measuring weldability.
As a student in weld metallurgy we should now that Ferrite is important in avoiding hot
cracking during cooling from welding of austenitic stainless steels. 'Constitution diagrams' are
used to predict ferrite levels from the composition by comparing the effects of austenite and
ferrite stabilizing elements. The Schaeffler and Delong diagrams are the original method-s of
predicting the phase balances in austenitic stainless steel welds.
A 'nickel equivalent' is calculated for the austenite stabilizing elements and a 'chromium
equivalent' ferrite stabilizing elements. These are used as the axes for the diagrams, which
show the compositional equivalent areas where the phases austenite, ferrite, martensite (and
mixtures of these) should be present. Although intended to show the phase balance of weld
fillers, these diagrams can also be used to illustrate the phase balance of the 'parent'
material. There are different diagrams for different alloy systems.
The Schaeffler Diagram
The nickel and chromium equivalents use the formulae:
Ni (eq) = Ni + (30 x C) + (0.5 x Mn)
Cr (eq) = Cr + Mo + (1.5 x Si) + (0.5 x Nb)
This gives a diagram that is useful for the austenitic steels, except those with Nitrogen
additions. This the main disadvantage of this diagram since Nitrogen, which is a very strong
Austenite former. The Schaeffler diagram, identifying the phase boundaries is shown below.
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11
12
6. Overlap
7. Cracking
Excessive amperage
Improper electrode angle
Travel speed too slow
Bend too small or too concave
Failure to fill craters
Wet or dirty plate
Wet or dirty electrode
8. Excess spatter
Excessive amperage
sized spatter)
Excessive arc length (large
sized spatter)
9. Rough appearance Oscillations spaced too far
apart
Improper travel angle
10. Fingernailing (of Flux coating cracked or
flux)
chipped
Flux coating not concentric
with rod
Observation: Cracking in welded joints can be classified in cold and hot cracking.
The location of cracks in a welded joint may occur in the weld metal, base metal, or
in both.
Cold cracking appears due the existing hydrogen content in the welded joint.
In the next table we presented the relation between hardness, martensit content
and the cracking susceptibility of the welded joint: for the case of a unalloyed steel.
Maximum hardness in HAZ
>450 HV 10
>50 %
<70 %
< 50 %
>30 %
< 30 %
Remarks
very probable appearing of
cracks
possible appearing of cracks
without cracks
no need of postheating
Hot cracking is a function of the chemical composition. The appearing of this type of
cracking is due the constituents in the welded metal who have a relatively low melting
temperature and which accumulate at the grain boundaries during solidification.
If cracking is observed during welding the cracks should be removed prior to further
welding because the cracks can continue into the newly deposited weld metal.
Solutions to cracking problems are including also:
changing the base metal;
changing the filler metal;
changing the welding technique/procedure.
2.TUNGSTEN INERT GAS WELDING (GTAW)
Welding Problems and Remedies
Numerous welding problems may develop while setting up or operating a GTAW
operation. Their solution will require careful evaluation of the material, the fixturing, the
welding equipment, and the procedures.
Tungsten Inclusions
One discontinuity found only in gas tungsten arc welds is tungsten inclusions.
Particles of tungsten from the electrode can be embedded in weld when improper welding
procedure are used with GTAW process. Typical causes are the following:
Contact of electrode tip with molten weld pool
13
2. Tungsten
contamination of
workpiece
PROBABLE CAUSE
REMEDY
Entrapped gas impurities Blow out air from all lines before
(hydrogen, nitrogen, air, striking arc; remove condensed
water vapor
moisture from lines; use welding grade
(99.99%) inert gas
Defective gas hose or loose Check hose and connections for leaks
hose connections
Oil film on base metal
Clean with chemical cleaner not prone
to break up in arc; (! Do not weld while
base metal is wet)
Contact
starting
with Use high frequency starter; use copper
electrode
striker plate
Electrode
melting
and Use less current or larger electrode;
alloying with base metal
use thoriated or zirconium-tungsten
electrode
Touching
tungsten
to Keep tungsten out of molten pool
molten pool
14
care to provide a clean electrode. Contaminants may be introduced during handling in the
users facility. Users who are aware of such possibilities take steps to avoid serious
problems, particularly in welding hardenable steels. The same awareness is necessary in
welding aluminum, except that the potential problem is porosity caused by relatively low
solubility of hydrogen in solidified aluminum, rather than hydrogen embrittlement.
Oxygen and Nitrogen Contamination
Oxygen and Nitrogen Contamination are potentially greater problems than hydrogen
in the GMAW process. If the shielding gas is not completely inert or adequately protective,
these elements may be readily absorbed from the atmosphere. Both oxides and nitrides can
reduce weld metal notch toughness. Weld metal deposited by GMAW is not tough as weld
metal deposited by gas tungsten arc welding. It should be noted here, however, that oxygen
in percentages of up to 5 percent and more can be added to the shielding gas without
adversely affecting weld quality.
Cleanliness
Base metal cleanliness when using GMAW is more critical than with SMAW or submerged
arc welding (SAW). The fluxing compounds present is SMAW and SAW scavenge and
cleanse the molten weld deposit of oxides and gas-forming compounds. Such fluxing slags
are not present in GMAW. This places a premium on doing a thorough job of preweld and
interpass cleaning. This is particularly true for aluminum, where elaborate procedures for
chemical cleaning or mechanical removal of metallic oxides, or both, are applied.
Weld Discontinuities
Some of the more common weld discontinuities that may occur with the GMAW
process are listed in the following paragraphs.
Undercutting
The following are possible causes of undercutting and their corrective actions
1.
2.
3.
4.
5.
POSSIBLE CAUSES
Travel speed to high
Welding voltage too high
Excessive
welding
current
Insufficient dwell
Torch angle
CORRECTIVE ACTIONS
Use slower travel speed
Reduce the voltage
Reduce wire feed speed
Increase dwell at edge of molten weld puddle
Change torch angle
Porosity
The following are the possible causes of porosity and their corrective actions:
POSSIBLE CAUSES
1.
2.
3.
4.
5.
CORRECTIVE ACTIONS
Optimize the gas flow. Increase gas flow to displace all
air from the weld zone. Decrease excessive gas flow to
avoid turbulence and the entrapment of air in the weld
Inadequate shielding gas zone. Eliminate any leaks in the gas line. Eliminate
coverage
drafts (from fans, open doors, etc.) blowing into the
welding arc. Eliminate frozen regulators in CO2 welding
by using heaters. Reduce travel speed. Reduce nozzleto-work distance. Hold gun at the end of weld until
molten metal solidifies.
Gas contamination
Use welding grade shielding gas.
Electrode contamination
Use only clean and dry electrode.
Worpiece contamination
Remove all grease, oil, moisture, rust, paint, and dirt
from work surface before welding. Use more highly
deoxidizing electrode.
Arc voltage too high
Reduce voltage
15
CORRECTIVE ACTIONS
Joint design must provide proper access to the
bottom of the groove while maintaining proper
electrode extension. Reduce excessively large
root gap in butt joints, and increase depth of
back gouge.
Maintain electrode angle normal to work surface
to achieve maximum penetration. Keep arc on
leading edge of the puddle.
Increase the wire feed speed (welding current).
CORRECTIVE ACTIONS
Reduce wire feed speed (welding current) and
the voltage. Increase the travel speed.
Reduce root opening. Increase root face
dimension.
CORRECTIVE ACTIONS
Maintain proper groove dimensions to allow
16
3. Too
small
a
weld
bead
(particularly fillet and root beads)
4. Heat input too high, causing
excessive
shrinkage
and
distortion
5. Hot-shortness
Use electrode with higher manganese content
(use shorter arc length to minimize loss of
manganese across the arc). Adjust the groove
angle to allow adequate percentage of filler metal
addition. Adjust pass sequence to reduce
restrain on weld during cooling. Change to
another
filler
metal
providing
desired
characteristics.
6. High restraint of the joint Use preheat to reduce magnitude of residual
members
stresses. Adjust welding sequence to reduce
restraint conditions.
7. Rapid cooling in the crater at the Eliminate craters by backstepping technique.
end of the joint
Heat Affected Zone Cracks
Cracking in HAZ is almost always associated with hardenable steels.
POSSIBLE CAUSES
CORRECTIVE ACTIONS
1. Hardening in the heat-affected Preheat to retard cooling rate.
zone
2. Residual stresses too high
Use stress relief heat treatment.
3. Hydrogen embrittlement
Use clean electrode and dry shielding gas.
Remove contaminants from the base metal. Hold
weld at elevated temperatures for several hours
before cooling (temperature and time required to
diffuse hydrogen are dependent on base metal
type).
PROBABLE CAUSE
Low gas flow
High gas flow
Excessive wind drafts
Contaminated gas
1. Porosity
17
REMEDY
Increase gas flowmetter setting clean
spatter clogged nozzle.
Decrease to eliminate turbulence
Shield weld zone from draft/wind
Check gas source
Check for leak in hoses/fittings
Clean weld joint faces
Remove drawing compound on wire
Clean oil from rollers
Avoid shop dirt
Re-dry filler wire
3. Cracking
Change wire
Reset voltage
Reset stickout & balance current
Reset stickout & balance current
Adjust speed
Direct electrode to the joint root
Increase current
Reduce travel speed
Decrease stickout
Reduce wire size
Increase travel speed (self-shielded
electrodes)
Improper joint design
Increase root opening
Increase root face
Excessive joint restrain
Reduce restraint
Preheat
Use more ductile weld metal
Employ peening
Improper electrode
Check formulation and content of the
flux
Insufficient deoxidizers or Check formulation and content of the
inconsistent flux fill in core
flux
18
sectioning and etching a sample weld. To correct the problem, the welding variables or the
joint geometry must be changed. To decrease the depth of penetration compared to the
width of the face of the joint, the welding travel speed as well as the welding current can be
reduced.
Cracking in the weld metal or the heat-affected zone may be caused by diffusible
hydrogen in the weld metal. The hydrogen may enter the molten weld pool from flux, grease
or dirt on the electrode or base metal. Cracking due to diffusible hydrogen in the weld metal
is usually associated with low alloy steels and with increasing tensile and yield strengths. It
sometimes can occur in carbon steels. There is always some hydrogen present in deposited
weld metal, but it must be limited to relatively small amounts. As tensile strength increases,
the amount of diffusible hydrogen that can be tolerated in the deposited weld decreases.
Cracking due to excessive hydrogen in the weld is called delayed cracking; it usually
occurs several hours, up to approximately 72 hours, after the weld has cooled to ambient
temperature. Hydrogen will diffuse out of the base metal at elevated temperatures (above
approximately 1000C) without resulting in cracking. It is at ambient temperatures that
hydrogen accumulated at small defects in the weld metal or base metal results in cracking.
To keep the hydrogen content of the weld metal low:
Remove moisture from the flux by baking in an oven (follow manufacturers
recommendations).
Remove oil, grease, or dirt from the electrode and base material.
Increase the work temperature to allow more hydrogen to escape during the
welding operation. This may be done by continuing the preheat until the seam
is completely welded, or by postheating the weld joint for several hours before
letting it cool to ambient temperature.
6.ELECTROSLAG WELDING
Some problems that may be encountered and possible remedies are listed in the
following table:
Location
Problem
Causes
Remedy
Weld
1. Porosity Insufficient slag depth
Increase flux additions
Moisture, oil, or rust
Dry or clean workpiece
Contaminated or wet flux
Dry or replace flux
2. Cracking Excessive welding speed
Slow electrode feed rate
Poor form factor
Reduce current; raise voltage;
decrease oscillation speed
Excessive center-to-center Decrease spacing between
distance between electrodes electrodes or guide tubes
or guide tubes
3. Nonmetallic
inclusions
Fusion line 4. Lack of
fusion
Increase voltage
Decrease electrode feed rate
Decrease flux addition; allow
slag to overflow
Misaligned electrodes or Realign electrodes or guide
guide tubes
tubes
Inadequate dwell time
Increase dwell time
Excessive oscillation speed
Slow oscillation speed
Excessive electrode to shoe Increase oscillation width or
distance
add another electrode
Excesive center to center Decrease spacing between
distance between electrodes electrodes
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5. Undercut
Heataffected
zone
6. Cracking
High restraint
Crack-sensitive material
Excessive inclusions in plate
7.OXYFUEL-GAS WELDING
Problems and corrections:
The appearance of a weld does not necessarily indicate its quality. If imperfections
exist in a weld, they can be grouped into two broad groups: those that are apparent to visual
inspection and those that are not. Visual examination of the underside of a weld will
determine whether there is complete penetration and whether there are excessive spatter of
metal. Inadequate joint penetration may be due to insufficient beveling of the edges, too thick
a root face, too high a welding speed, or poor torch and welding rod manipulation.
Oversized and undersized welds can be observed readily. Weld gauges are used to
determine whether a weld has excessive or insufficient reinforcement. Undercut or overlap at
the sides of the welds can usually be detected by visual examination.
Although other imperfections, such as incomplete fusion, porosity, and cracking,
may not be externally apparent, excessive grain growth and the presence of hard spots
cannot be determined visually. Incomplete fusion may be caused by insufficient heating of
the base metal, too rapid weld travel, gas or dirt inclusions. Porosity is a result of entrapped
gases, usually carbon monoxide, which may be avoided by careful flame manipulation and
adequate fluxing where needed. Hard spots and cracking result from the metallurgical
characteristics of the weldment.
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