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3,229,777
Patented Jan. 18, 1966
3,229,777
long tube such as an oil well and most will not foam
tional foaming characteristics in aqueous solutions even
if said solutions contain foam-suppressing materials such 15 water from a saturated salt solution. We have tested
dozens of known foaming agents for this purpose and
as, for example, the water normally encountered in the
found less than 1% of these to possess this property and
gas drilling of subterranean formations. Our invention
none of them to be as effective for this purpose as our
is also directed to an improved method of transporting
novel composition.
such aqueous solutions containing much of any soluble
Adding our composition in amounts as small as 0.01%
or dispersable foam suppressing constituent present out 20
by weight of the Water present will very effectively trans
of columns such as the bore holes in drilling operations.
the bore hole and gums up the drill cuttings. The mass
then tends to coat the walls of the bore holes, the drill
bit, and the pipes causing at least a reduction in the rate
general type:
3,229,777
be purchased. One method of producing the condensa 20 supplying element, the fatty acids or their monohydroxy
tion product is to charge the desired alcohol containing
aliphatic alcohol esters may be employed. The preferred
an alkaline catalyst into a suitable reaction vessel. The
fatty acyl supplying element is coconut oil or coconut oil
alcohol-catalyst mixture is agitated and the vessel is heat
fatty acids as well as fatty mixtures containing a sub
as follows:
________________________________ __ 25:3
Composition:
50
Percent by weight
55
5-10
EXAMPLE II
fonic acid, tetradecylbenzene sulfonic acid, and dodecyl 60 diethanolamine. Approximately 25 parts by weight of the
The a'lkylolamine salts of
salt of the ether sulfate so formed was mixed with about
these alkyl aryl sulfonic acids, are readily prepared by
25 parts by weight of free diethanolamine, 25 parts by
reacting, for example, diethanolamine, either alone or in
naphthalene sulfonic acid.
product.
EXAMPLE III
200 grams of tridecyl alcohol were charged into a re
3,229,777
5
EXAMPLE VIII
EXAMPLE IV
A mixture of ingredients was prepared containing 4
(C) ________________ -_
(D) ________________ ._
(E) ________________ __
Composition
350 parts product of Ex. VII
100 parts product of Ex. V.
310 parts product of Ex. III.
100 parts product of Ex. VI.
375 parts product of Ex. VII
100 parts product of Ex. II.
400 parts product of Ex. VII
100 parts product of Ex. II.
400parts product of. Ex. VI-I
100 parts product of Ex. II.
(c).
(1?).
(g).
(b).
into this solution and the mixture poured into the column.
Agent Added
Adlctlegi, ly
.
grgdgctgf
Ex.fIII]_-_?.I.____
5
r0 not 0
x.
___
._
cc.
0.2
68.0
0.2
None
-i
_ }
0 2
Vol. H2O
Recovered,
'
0 2
30
190
159 0 35
'
60 O
'
EXAMPLE V
Soybean oil and an excess of diethanolamine was heated
at 310 F. for 4 hours at 26" vacuum. 51.85% of the
15
20
20
25
28
3,229,777
7
amine; and circulating gas in said well whereby substan
2,855,367
3,073,387
1/1963
3,076,508
2/1963
OTHER REFERENCES
15-26.
5. In the method of transporting water from a well
Drilling with Air, article in the Oil and Gas Journal, vol.
10/1958
55, June 10, 1957, pages 105, 107, 110 and 111.
ter in Air or Gas Drilling, article in The Oil and Gas Jour
nal, Nov. 3, 1958, pages 78 to 83.
Gray: Chemicals in Drilling Muds, article in The Oil
fonate, an alkylolamine salt of a sulfated polyethoxylated 15 and Gas Journal, vol. 56, December 15, 1958, pages 97.
175-7 1.
6/1954
8/1934
2,758,977
2,766,212
8/1956
10/1956
'