Pep Set Al5995 Catalyst

Page: 1 of 11
Revision Date: 23.03.2011

Print Date: 02.04.2012
MSDS Number: R0550104
Version: 1.0
SAFETY DATA SHEET

PEP SET AL5995 CATALYST
Trademark, ASK Chemicals, registered in
various countries
362028
Conforms to EU Regulation 1907/2006/EC as amended. - GENVAR_GB
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
ASK Chemicals GmbH
Reisholzstrae 16-18
D-40721 Hilden
Germany
Emergency telephone number

+1-800-274-5263/+1-606-329-5701 , or contact your
local emergency telephone number at 112
Product Information
+49 (0)211 711-030, or contact your local CSR contact
person
EUSMT@ashland.com
Product name
Product code
Product Use Description

Trademark, ASK Chemicals, registered in various countries
362028
Foundry - Catalyst.
2. HAZARDS IDENTIFICATION
Hazard Summary
Toxic
Corrosive
Harmful
Dangerous for the environment
Risks
Flammable.
May impair fertility., May cause harm to the unborn child.
Toxic: danger of serious damage to health by prolonged exposure if
swallowed., Toxic by inhalation and in contact with skin.
Causes burns.
Harmful if swallowed.
Possible risk of irreversible effects.
Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No.
EINECS-No.
Concentration
Symbol(s)
R-phrase(s)
Cyclohexyldimethylamin
e
Dibutyltin dilaurate
98-94-2
202-715-5
>=80 - <90%
77-58-7
201-039-8
>=10 - <15%
T, Xn, Xi, N
R10, R22, R34, R52/53,

R23/24
R48/25, R60, R61, R68,
R22, R36/38, R50/53
For the full text of the R-phrases mentioned in this Section, see Section 16.
4. FIRST AID MEASURES

General Information
Move out of dangerous area. Get medical attention immediately. Do not leave the victim unattended.
Consult a physician. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may
only appear several hours later.
Eyes
Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Remove contact lenses.
Skin
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water
for at least 15 minutes. Wash contaminated clothing before re-use.
Ingestion
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical
attention.
Inhalation
Move to fresh air. Call a physician or poison control centre immediately. Keep patient warm and at
rest. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear. In case
of shortness of breath, give oxygen.If breathing is irregular or stopped, administer artificial respiration.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
ABC powder, Water mist, Carbon dioxide (CO2), Dry chemical
Unsuitable extinguishing media
DO NOT USE: Halons
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Hazardous combustion products

carbon dioxide and carbon monoxide, stannic oxide fumes, toxic fumes, Hydrocarbons
Thermal decomposition
no data available
Precautions for fire-fighting
Do not allow run-off from fire fighting to enter drains or water courses. Keep containers and
surroundings cool with water spray. Prevent fire extinguishing water from contaminating surface water or
the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in
closed containments.
Personal protective equipment
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Persons not wearing protective equipment should be excluded from area of spill until clean-up has
been completed. Ensure adequate ventilation. Pay attention to the spreading of gases especially at ground
level (heavier than air) and to the direction of the wind. Evacuate personnel to safe areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth,
diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations
(see section 13). Keep in suitable, closed containers for disposal.
Other information
Comply with all applicable federal, state, and local regulations.
7. HANDLING AND STORAGE

Handling
Do not breathe vapours or spray mist. Avoid exposure - obtain special instructions before use. Avoid
contact with skin and eyes. For personal protection see section 8. Provide sufficient air exchange and/or
exhaust in work rooms. Avoid exceeding of the given occupational exposure limits (see section 8). Smoking,
eating and drinking should be prohibited in the application area. Ensure all equipment is electrically
grounded before beginning transfer operations. Take measures to prevent the build up of electrostatic
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charge. Mixture may charge electrostatically: always use earthing leads when transferring from one
container to another. Keep product and empty container away from heat and sources of ignition. No sparking
tools should be used. Avoid formation of aerosol.
Storage
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Stable under
recommended storage conditions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Dibutyltin dilaurate (CAS 77-58-7 )

EH40 WEL
EH40 WEL
time weighted average

Short term exposure limit
0.1 mg/m3
0.2 mg/m3
General advice
These recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect exposure
potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the
responsibility of the employer to follow regulatory guidelines established by local authorities. Keep away
from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash
stations and safety showers are close to the workstation location. Wash hands and face before breaks and
immediately after handling the product.
Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
level of overexposure (from known, suspected or apparent adverse effects).
Eye protection
Tightly fitting safety goggles
Skin and body protection
Wear as appropriate:
Safety shoes
impervious clothing
Flame-resistant clothing
Discard contaminated shoes.
Wear resistant gloves such as:
butyl-rubber
Nitrile rubber
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Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified
respirators.
In the case of vapour formation use a respirator with an approved filter.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state
Form
Colour
Odour
Boiling point/boiling range
Melting point/range
Sublimation point
pH
Flash point
Ignition temperature
Evaporation rate
Lower explosion limit / Upper explosion
limit
Dust explosion class
Dust explosion constant
Burning number
Particle size
Vapour pressure
Vapour density
Density
Bulk density
Solubility(ies)
Partition coefficient: n-octanol/water
log Pow
Autoignition temperature
Viscosity, dynamic
Viscosity, kinematic
Hydrolysis
Physico-chemical removability
10. STABILITY AND REACTIVITY
liquid
no data available
yellow
amine-like
(>)158.00 C
no data available
no data available
no data available
51.00 C, Pensky Martens closed cup
no data available
(<)1 (n-Butyl Acetate)
no data available
no data available
no data available
no data available
no data available
4.00 hPa @ 37.78 C Calculated Vapor Pressure
no data available
(+/- 5.2)875.00 g/cm3 @ 68.00 F / 20.00 C
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
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Stability
Stable under recommended storage conditions.
Conditions to avoid
Exposure to light. Heat, flames and sparks.
Incompatible products
Reducing agents, strong bases, Strong oxidizing agents, UV light.
Hazardous decomposition products
carbon dioxide and carbon monoxide, stannic oxide fumes, Hydrocarbons
Hazardous reactions
Hazardous polymerisation does not occur. Vapours may form explosive mixture with air.
11. TOXICOLOGICAL INFORMATION

Exposure routes
Skin contact, Eye Contact, Ingestion, Skin Absorption
Eye contact
May cause irreversible eye damage.
Skin contact
Causes skin burns.
Ingestion
Inhalation
Toxic by inhalation.
Aggravated Medical Condition
Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to
this material: Skin, lung (for example, asthma-like conditions), Liver
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of
the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation
(nose, throat, airways), Cough, Lung irritation, Headache, Shortness of breath
Target Organs
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Overexposure to this material (or its components) has been suggested as a cause of the following
effects in laboratory animals:
Acute oral toxicity
Cyclohexyldimethylamine (98-94-2 )
no data available
Dibutyltin dilaurate (77-58-7 )
LD 50 Rat: 175 mg/kg
no data available
LC 50 Mouse: 150 mg/m3, 2 h
no data available
LD 50 Rabbit: > 2 g/kg
Acute inhalation toxicity
Acute dermal toxicity
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)

Biodegradability
no data available
23 % Exposure time: 39 d Not readily biodegradable.
no data available
no data available
Bioaccumulation
The bioaccumulation potential cannot be determined.
no data available
48 h LC 50 Leuciscus idus (Golden orfe): 2.000 mg/l

Mortality
96 h LC 50 Danio rerio (zebra fish): 2.000 mg/l

Physico-chemical removability
Ecotoxicity effects
Toxicity to fish
Toxicity to daphnia and other aquatic invertebrates.
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no data available
24 h EC 50 Water flea (Daphnia magna): 0.660 mg/l ;

Intoxication
no data available
no data available
no data available
no data available
Toxicity to algae
Toxicity to bacteria
13. DISPOSAL CONSIDERATIONS

Waste disposal methods
Dispose of in accordance with the European Directives on waste and hazardous waste. Do not
contaminate ponds, waterways or ditches with chemical or used container. Container hazardous when
empty. Dispose of in accordance with local regulations.
Empty packaging
Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an
approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use
a cutting torch on, the empty drum.
European Waste Catalogue
The Waste code should be assigned in discussion between the user and the waste disposal
company.
14. TRANSPORT INFORMATION
REGULATION
ID
PROPER SHIPPING
NUMBER
NAME
ADR
*HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
MARINE
POLLUTANT /
LTD. QTY.
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UN
1992
ADNR
UN
1992
RID
UN
1992
FLAMMABLE LIQUID,
TOXIC, N.O.S.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
(6.1)
III
FLAMMABLE LIQUID,
TOXIC, N.O.S.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
(6.1)
III
FLAMMABLE LIQUID,
TOXIC, N.O.S.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
(6.1)
III
(6.1)
III
INTERNATIONAL MARITIME DANGEROUS GOODS

UN
1992 FLAMMABLE LIQUID,
3
TOXIC, N.O.S.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

UN
1992 Flammable liquid, toxic,
3
(6.1)
n.o.s.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
UN
1992 Flammable liquid, toxic,
3
(6.1)
n.o.s.
(DIMETHYLCYCLOHEXY
LAMINE, DIBUTYLTIN
DILAURATE)
MARINE
POLLUTANT:(DI
BUTYLTIN
DILAURATE)
III
III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
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15. REGULATORY INFORMATION
Hazard symbols
Toxic
R-phrase(s)
R60
R61
R22
R23/24
R48/25
R10
R34
R68
R51/53
S-phrase(s)
S53
S26
S36/37/39
S38
S45
S51
Dangerous for the environment
May impair fertility.

May cause harm to the unborn child.
Also harmful if swallowed.
Also toxic by inhalation and in contact with skin.
Also toxic: danger of serious damage to health by prolonged exposure if swallowed.
Flammable.
Causes burns.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Avoid exposure - obtain special instructions before use.

In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of insufficient ventilation, wear suitable respiratory equipment.
In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
Use only in well-ventilated areas.
Special labelling of certain mixtures

1999/45/EC
Restricted to professional users.
Contains
Cyclohexyldimethylamine
Dibutyltin dilaurate
98-94-2
77-58-7
Notification status
US. Toxic Substances Control Act
Australia. Industrial Chemical (Notification and Assessment) Act
Canada. Canadian Environmental Protection Act (CEPA).
Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
Japan. Kashin-Hou Law List
y (positive listing)
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Korea. Toxic Chemical Control Law (TCCL) List
Philippines. The Toxic Substances and Hazardous and Nuclear
Waste Control Act
China. Inventory of Existing Chemical Substances
New Zealand. Inventory of Chemicals (NZIoC), as published by
ERMA New Zealand

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16. OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3
R22
R34
Causes burns.
R48/25
Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R23/24
Toxic by inhalation and in contact with skin.
R60
May impair fertility.
R61
May cause harm to the unborn child.
R68
R51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R10
Flammable.
R52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R36/38
Irritating to eyes and skin.
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
The information accumulated herein is believed to be accurate but is not warranted to be whether originating
with the company or not. Recipients are advised to confirm in advance of need that the information is
current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's
Environmental Health and Safety Department (+31 10 497 5000).

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Page: 1 of 11

Revision Date: 23.03.2011

SAFETY DATA SHEET

Conforms to EU Regulation 1907/2006/EC as amended. - GENVAR_GB

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

Emergency telephone number