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1. The ion that would be iso-electronic with the noble gas Xenon is:
a. I-2
b. S-2
c. Mg+2
d.K+1
2. No two elements in the same atom can have the same set of quantum is a
statement of
a. Hunds Rule of Multiplicity
b. Daltons Atomic Theory
c. Heisenbergs Uncertainty Principle
d. Paulis Exclusion Principle
3. Defines as acid as a compound that dissolves in water to produce the H+ ions
is
a. Arthenius
c. Lewis
b. Bronsted-Lowry
d. Lowry
4. The electrons of metals are free to move in a solid. This explains why
a. metals are unstable
b. metals can easily be melted
c. metals have high reflectivity
d. metals have high conductivity
5. Buffer solution resists changes in acidity. If an acid is added to a buffer
solution, the ______________ remains the same
a. pH
b. concentration
c. ionization constant
d. hydrolysis constant
6. In silver plating, the anode is
a. copper
d. graphite
b. the object to be plated
e. silver
c. platinum
7. Brass is an alloy of
a. aluminum and nickel
c. copper and zinc
b. lead and tin
d. copper and tin
8. The first step in precipitation is the formulation of
a. Nuclei
c. Seeds
b. Supersaturated solution
d. Crystals
9. Which will dissolve faster in coffee?
a. lump sugar in hot coffee
b. granular sugar in hot coffee
c. granular sugar in cold coffee
d. lump sugar in cold coffee
10. The most important component of pitch blend
a. Lead
c. Uranium
b. Mercury
d. Gold
11. A catalyst is a substance that
a. increases the rate of reaction
b. is independent on the concentration of the reactants
c. has no effect on the activation energy
d. is recovered chemically unchanged at the end of the reaction
12. Which of the following are most alike?
a. compound and suspension
b. mixture and compound
c. foam and solution
d. solution and compound
e. emulsion and colloid
13. An element having three valence of electrons and four main energy levels
may belong to
a. Family III-A
c. Family VII-A
b. Period 3
d. Family IV-A
14. The mass contribution of an electron in an atom is
a. 1/1,837 that of the proton
b. equal to that of a proton
c. equal to that of a neutron
d. not known
15. The percentage abundance of Xe in the atmosphere (% Volume) is
a. 1.4 x 10-4
c. 1.32 %
b. 8.0 x 10-6
d. 93%
50. Teflon is chemically inert, tough and tolerant of high temperature. These
properties of Teflon are due to
a. the strength of the carbon-carbon bond
b. the strength of the carbon-hydrogen bond
c. the strong carbon-fluorine bond
d. high cost
A 0.1 M Ca(OH)2 solution can also be labeled as:
a. 0.1 molal
c. 0.1N
b. 0.2 N
d. 0.1 N
51. When 27 grams of Al are added to one liter of 3N CuSO4 the number of grams
of Cu that will be displaced is (atomic weights : Cu = 64; Al=27).
a. 32
d. 128
b. 64
e. 96
c. 192
52. The determination of lead ions by reduction to metallic lead and weighing
as such is
a. an electrometric method
b. an electrodeposition method
c. a precipitation method
d. a potentimetric method
53. What is the color of nickel chloride?
a. white
c. yellow
b. red
d. green
54. Ksp values are valid
a. for all salts
b. only for slightly soluble compounds
c. when determined under supersaturated conditions
d. only when measured at 250C
55. The ph value at the equivalence point when titrating a weak acid against a
strong base is:
a. at exactly 7
b. greater than 7
c. less than 7
d. neutral
56. As2O3 is oxidized by KmnO4. The millequivalent weight of As2O3 (MW=197.84) as
a reducing agent is:
a. 0.0989
c. 0.01978
b. 0.03957
d. 0.04946
57. In a general analysis NH4 is tested advance because
a. NH4 cannot be present in acid medium
b. Several ammonium containing reagents are added during analysis
c. It is the standard procedure
d. It will make the solution basis
58. Ferric ferrocyanide is
a. Indigo blue
b. Prussian blue
c. Turnbulls blue
d. Cobalt blue
59. Which reagent will dissolve Zn(OH)2 but not Ni(OH)2?
a. HCl
c. H2SO4
b. NH3
d. NaOH
60. A solution of cation gives a crimson red flame. This flame test is a
confirmatory test for:
a. Sr+2
c. Mn+2
+1
b. K
d. Ca+2
61. Which of the following should be considered in the choice of an indicator:
a. ph range
b. ph at equivalence pt.
c. Direction of titration
d. Color of indicator
62. Mixing 10ml of a 2M HCl solution with 20 ml of a M HCl solution will result
in a solution whose molarity is:
a. 1.33
b. 1.5
c. 1.65
d. 1.75
91.
The normal boiling point of chloroform, CHCl3, is 334K, its vapor
pressure is 0.824 atm. What is the enthalpy of chloroform fro this
temperature range?
a. 29.4 KJ/mol
c. 19.65 KJ/mol
b. 27.5 KJ/mol
d. 30.61 KJ/mol
92.
When the potential of 110 volts dc is applied to the terminals of an
electric lamp, a current of 2 amperes is found to flow. What is the
resistance of the lamp?
a. 62 ohms
c. 32 ohms
b. 55 ohms
d. 58 ohms
93.
How long would it take a current 1 ampere to reduce completely 80 cc
of 0.1 molal Fe2(SO4)3 to FeSO4?
a. 25.73 min
c. 31.26 min
b. 22.65 min
d. 19.69 min
94. A constant direct current flows through an iodine coulometer for a period
of 2 hours. At the end of this time, it is found that the coulometer contains
0.0020 equivalent of liberated I2. What was the current passing thorough the
coulometer?
a. 0.048 ampere
c. 0.027 ampere
b. 0.058 ampere
d. 0.034
ampere
95.
As a solid changes to a liquid, all of the following occur except
a. molecules become more disordered
b. kinetic energy of molecules decreases
c. intermolecular forces become separated
d. molecules become further separated
96. Absolute zero maybe regarded as that T at which a gas cease
a. all gases become liquids
b. all substances are solids
c. molecular motion increases
d. water freezes
97. Ethyl alcohol is to be used in an automobile carburetor that is adjusted to
give a 9 to 10 air-fuel ratio ( mass ratio ). If the temperature in the
manifold is 60dF and the pressure is atmospheric, what percentage of the
alcohol will be evaporated assuming the equilibrium between vapor and liquid
is reached?
a. 55%
d. 90%
b. 75%
c. 65%
98.
At what temperature will the velocity of CO2 molecules equal the
velocity of oxygen molecules at 0C
a. 102C
c. 132C
b. 632C
d. 125C
99. Suppose you are given a gaseous compound for which the formula is CxH2x-2 at
the same temperature and pressure at which oxygen weighs 4.8 grams per liter,
the unknown gas weighs 8.10 g/L. What is the formula of the compound?
a. C2H2
c. C4H6
b. C3H8
d. C4H10
100. A gas tends to expand indefinitely into a vacuum or into another gas. This
ability is referred as
a. viscosity
c. compressibility
b. turbulence
d. diffusion
101. If a given gas has a compressibility factor, z>1, this means that
a. attractive forces
b. repulsive forces
c. no force of attraction
d. exist between the molecules of gases
102. The vapor pressure of a liquid
a. always increases with temperature
b. always decreases with temperature
c. is independent of temperature
d. increases only up to boiling point
103. As the atmospheric pressure decreases, the boiling point of a liquid
a. cannot be determined
b. is not affected
c. increases
d. decreases
104. The direction of electron flow is from
a. from anode to cathode
b. from cathode to anode
c. either way
105. PCl5 (g) dissociates to PCl3 (g) and Cl2 (g) when heated at 250C and 1 atm.
If the density of the gas mixture at equilibrium is 4.4 g/L, the fraction of
PCl5 (g) dissociated is
a. 0.103
b. 0.328
c. 0.725
d. 0.209
106. An ideal gas is made up of molecules that have these properties except
a. Are points in space in time
b. have mass and velocity
c. attract or repel each other on the wall of the container
d. collide with the walls of the container without loss of energy
107. Which of these 0.1M solution will give the highest boiling at 1 atm
a. table salt solution
c. barium chloride
b. sugar solution
d. potassium
chloride
108. What term is used to define the phenomena of emission of light in a
chemical reaction
a. photosensitisation
b. chemical luminescence
c. photosensitisation and chemical luminescence
d. none of these
109. The vapor pressure of all the liquids
a. is the same at 100C
b. is the same at their frezzing pint
c. increases with the volume of liquid separated
d. increases with temperature
110. If ethanol are mixed 50/50 by weight at 60C, and the solution assumed
ideal, the composition of the vapor above the solution is
a. 28% ethanol, 72% methanol
b. 72% ethanol, 28% methanol
c. 59% ethanol, 41% methanol
d. 41% ethanol, 59% methanol
111. All of the following conclusion of the kinetic theory of gases except
a. a derivation of the Van der Waals equation
b. derivation of Boyles and Charles Law
c. relation of average kinetic energy of gases to temperature
d. Grahams law of diffusion
112. The freezing point of a substance is always lower than its
a. melting point
c. specific heat
b. boiling point
d. heat of vaporization
113. One colligative property of solutions is its freezing point depression.
Which observation will show that the solute is an electrolyte? t/m
a. is not constant
c. is less than Kf
b. is not Kf
d. is
greater
than
Kf
114. Colligative properties depend upon
a. the chemical properties of the solute
b. the physical properties of the solute
c. the chemical properties of solvent
d. the number of solute particles present in the solution
115. All of the following factor increases the strength of Van der Waals forces
between molecules except by an
a. increase in the molecular weight of the molecules
b. increase in the number of atoms in the molecules
c. increase in the number of electrons in the molecules
d. increase in the ionic strength of the molecule
116. For a chemical reaction in a state of equilibrium, a decrease in
temperature will
a. favor reaction that is exothermic
b. favors reaction that is endothermic
c. have no effect on the system
d. increase the equilibrium constant of the system
c.
Nerrist Distribution Law
d.
Law
of
Hess
162.In alcohol fermentation by yeast, this microorganism furnishes an organic
catalyst or enzyme which affects this hydrolysis
a.
bacterease
c. lactase
b.
zymase
d. invertase
163.At standard temperature and pressure, a gas occupies 0.213 liters. How many
moles are there in this sample of gas?
a.
0.0089 mole
c.
none of these
b.
0.0890 mole
d.
0.0095 mole
164. If common salt NaCl is dissolved in water, which of the following
statements is true about the behavior of the solution relative to the
behavior of pure water?
a. boiling point is lowered
c. freezing point is decreased
b. melting point increases
d. none of these is true
165. The osterified product of n-propanone acid and methane is:
a. none of these
c. methyl propanoate
b. n-propanoxy methane
d. ethyl acetate
166.Complete the following equation CH3CH2Br + 2Li
a. CH3CH2Li + LiBr
c. CH3CH2Br2Li + Li
b. CH3CH2Li2 + Li
d. CH3CH2Li2 + Br
167.L is a non-volatile, non-electrolytic liquid. A solid S, is added to L to
form a solution that just boils at 1 atmospheric pressure. The vapor pressure
of pure L is 850 torr. What is the mole fraction of liquid L in the solution?
a. 85.7%
b. 95.3%
c. 89.4%
d. 79.4%
168.The behavior of the plastics that can be simulated using physical models
such as Maxwell and Kelvin Models
a. elasticity
c. deformation
b. wear resistance
d. viscoelastic
169.The following 5 expressions describe general energy equation for an open
system
a. Transfer of energy out of mass flow
b. Accumulation of energy
c. Transfer of energy is by mass flow
d. Net energy transfer by work (std Sign concentration)
e. Net energy transfer by heat (std Sign concentration)
170.Which combination would represent the general energy equation representing
the first law of thermodynamics?
a. b = d + e + c + a
c. b = c e c a
b. b = d e c + a
d. b = d + e + c + a
171. The study of the interrelation of the various forms of energy in a system
is called
a.physical chemistry
b. chemistry
c. physics
d.
thermodynamics
172. The standard for mass measurement is
a. wavelength of kr 86
b. invariant property of Cs 133
c. earths pull
d. a cylinder of platinum-iridium alloy
173. The heat content of the system is called
a. sensible heat
b. specific heat
c. heat capacity
d.
a
or
b
174.The quantity of heat required to raise the temperature of a unit weight of
a substance 1 degree temperature is called
a. specific heat
b. heat capacity
c. sensible heat
d. a or b
175. During the adiabatic expansion of an ideal gas, work is done by the system
and change in internal energy
a. decreases
b. increases
c. does not
change
176. Which law is the basis for the manufacture of thermometers?
a. Boyles law
c. Raoults Law
b. Zeroth
Law
of
d. Carnots
principle
Thermodynamics
193. A heat engine absorbs heat from the combustion of gasoline at 2200 C.
The gasoline has a specific gravity of 0.8 and a heat combustion of
11,200cal/gram. The engine rejects heat at 1200 C.
The maximum work in
calories that can be obtained from the combustion of 1 liter of gasoline is
a.
3.62 x 106 cal
b.
4.53 x 104
c. 3.78 x 105
d.
4.22
x
106
194. A 70% NaOH liquor at 160 F with a heat content of 325 Btu/lb is diluted
with 20% NaOH liquor at 80 F with a heat content of 40 BTU/lb to give a
final solution containing 40% NaOH (heat content is 94 Btu/lb). For every
100 lb of product, how much heat must be removed to maintain a final product
temperature of 100 F?
a. 6,000 Btu
b. 20,100 Btu
c. -11,700 Btu
d.
-7,500
Btu
195. A certain process requires cooling of a brine solution continuously from
70 F to 30 F. The atmospheric temperature is 80 F. There is an available
refrigerator with a power requirement of 40 kW. Can this refrigerator be used
if 100 gallons of brine is to be cooled per minute?
a. Yes
b. no
c. can not be
determined
196. Superheated steam flows at a steady state through an insulated nozzle with
an inlet diameter of 5 cm. At the nozzle entrance, steam P is 700 kPa and T is
300 C, and the velocity is 30 m/s. At the nozzle exit, the steam temperature
and pressure are 233 C and 350 kPa respectively, the exit diameter of the
nozzle is
b. 3.26 cm
b. 1.62 cm
c. 0.38 cm
d. 2.92 cm
197.It is proposed to warm a collector plate with solar energy. The collected
energy is then transferred as heat to a fluid in a heat engine which in turn
rejects heat to the atmosphere. If 200 BTU/hr-ft2 of energy can be collected
when the plate is operating at 190 F, estimate the minimum collector area
required for a plant producing 1 kW of useful shaft power. Assume atmospheric
temperature of 70 F.
a.86.2 ft2
b. 92.4 ft2
c. 97.5 ft2
d.
81.6
ft2
198. Eight grams of oxygen gas at 27 C and 10 atm expands adiabatically and
reversible to a final P of 1.0 atm. The work done in the process is
a. 842 J
b. 445 J
c. 798 J
d. 752 J
199. An inventor claimed that he has devised an engine that absorbs 1000 kW of
heat from the heat source and discards 700 kW of heat to the heat sink. If the
engine operates between 500 K and 200 K, is the inventors claim valid?
a. Yes
b. no
c. can not be
determined
200. The turbine in a hydroelectric plant is fed by water falling down from a
height of 30 m..
Assuming 95 % efficiency of converting potential energy to
electrical energy and 10 5 loss of resulting power in transmission, how many MT
of water per hour are needed to keep a 100W light bulb burning?
a.1.43
b. 1.29
c. 1.63
d. 1.75
201. Liquid water at 0 C and atmospheric pressure ahs a density of 1.0 g/cc.
At the same conditions, ice has a density of 0.917 g/cc. How much work is done
in kJ at these conditions by 1.0 kg of ice as it melts to liquid water?
a.0.00917
b. 0.0912
c. -0.00917
d. 0.0912
202. 3.0 g-mole of an idle gas at 1.0 atm and 20 C are heated at constant
pressure until the temperature is 80 C. (Cv = 7.50 + 3.2 x 10-2T, cal/mol-K).
The change in internal energy of the process is
a.5429.16 cal
b. 3425.27 cal
c . 3210.50 cal
d. 4590.42
cal
203.The difference between the heat of combustion of methane at constant
pressure and at constant volume at 27 C when liquid water is formed is
a.-1192.2 cal
b. -2314.5 cal
c. 1257.44 cal
d. -1257.44
cal
204.The minimum work required for the manufacture of 5 lbs of ice cubes from
water initially at 32 F is
a.87.6 Btu
b. 73.0 Btu
c. 90.2 Btu
d. 70.0
Btu
205.If the surrounding air is 80 F and the latent heat of fusion of water is
143.4 Btu/lb
Calculate the change in entropy when 100 grams of ice at 0 C is
converted to steam at 100 C and 1 atm.
a. 645.23 eu
b. 302.34 eu
c. 205.28 eu
d. 342.25
eu
206. The main concern in the study of thermodynamics is
a. change in enthalpy
b. the time element in transformation
c. the initial and final state of the system
d. the change in entropy
207. At 90 C, the vapor pressure of acetic acid 293 mmHg and its vapor
[pressure at a 100 C is 417 mmHg. Calculate the normal boiling point of acetic
acid.
a.271.4 K
b. 391.3 K
c. 298.2 K
d.
313.0 K
208.Calculate the change in molar Gibbs energy of liquid H2O treated as
incompressible fluid when pressure is increased from 1.0 bar to 2.0 bar at 298
K.
a.+ 1.82 J
b. 182 J
c. + 1.82 x 10-4 J
d.
-4
-1.82 x 10 J
209.One mol of N2O4(g) forms 2.0 mol of NO2 (g) under standard conditions. If S =
4.8 J/K, the reaction is
a. spontaneous
c. in equilibrium
b. non-spontaneous
d. can not be determined
210. The densities of liquid and solid mercury are 13.7 and 14.19 g/cc
respectively at a melting point of -38.87 C. The heat of fusion of Hg is 566
cal/g-atom. The change in melting point per atmospheric change in pressure is
a. 0.505 K
b. 0.0051 K
c. 0.013 K
d.
0.231 K