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System
Part 2
Cell Nomenclature
A shorthand way of expressing what takes place
electrochemical cell.
in an
s
t
P
g
2
H
( )
Cathode, reduction
()
q
a
4
O
S
n
Z
s
n
Z
Anode, oxidation
( )
()
g
2
H
q
a
( )
2
n
Z
q
a
4
O
S
n
Z
s
n
Z
( )+
( )+ ( )
Example
A mixture consisting of pieces of solid zinc and solid chromium
in contact with a solution containing 1 M Zn2+ and 1 M Cr3+.
Write the cell equation for this reaction and calculate the value
of the Ecell.
Cr3+(aq) + 3e Cr(s)
E = 0.74 V
Zn2+(aq) + 2e Zn(s)
E = 0.76 V
Example
Calculate the following standard cell potential, label the
anode and the cathode and write the net (redox)
reaction for the following cell.
Zn(s)|Zn2+(aq)||Ni2+(aq)|Ni(s)
Calculate the standard cell potential for this
electrochemical cell
Example
The spontaneous reaction under standard conditions:
Cu2+(aq) + Sn(s) Cu(s) + Sn2+(aq)
Cu2+(aq) + 2e Cu(s)
+0.34 V
Sn2+(aq) + 2e Sn(s)
0.14 V
Example
Assuming that the electrolyte solutions are dilute,
calculate the EMF of the cell
Co | Co2+ || Ni2+ | Ni
if the concentrations are
a. [Ni2+] = 1.0 m and [Co2+] = 0.10 m
b. [Ni2+] = 0.010 m and [Co2+] = 1.0 m
( )
( )+
g
2
O
C
0
1
l
O
2
H
8
( )+
q
a
2
n
M
2
( )+
q
a
H
O
O
H
C
C
O
O
H
5
q
a
H
6
q
a
n4
M
2
Consider
( )+
( )
=+
V
9
4
.
0
V
1
5
.
1
( )+ + ( )+
()
( ) + ( )+
( )+
E E
l e
O 2
2
H
4 g2
O
q C
a 2
( )+
n q
M a
H
2
e
5
q
q a
a H
H O
8 O
H
q C
a C
O
n4 O
M H
V
9
4
.
0
V
1
5
.
1
8
.
7
7
K
5
1
1 .
8
l 9
o
m 2
J 1
k
2
0
1
3
9
.
1
l
o
m
1
K
J
4
1
3
.
8
3
0
1
5
.
6
K
o
T
G R
K
n
l
o
l
o
m
J
k
2
0
1
3
9
.
1
l
o
m
C
5
8
4
6
9
0
1
E
F
n
Determination of E &
Measurement of the cell potential at low concentration
(dilute solution).
Consider an electrochemical cell consisting of the Ag+/Ag &
S.H.E half-cells at 298 K.
q
a
H
( )
s
g
A
( )+
g
2
H
2
1
q
a
g
A
+
( )+ + ( )
d
e
R
d
e
R
x
O
d
e
R
x
O
x
O
a a
n
l
T F
R n
m
m
1
1
0
3
0
.
0
)+
g
A
)=
g
A
m
m
g1
o
l
6
1
9
5
0
.
0
E
n
l
T
R F
g
A
g
A
m
m
n
l
T
R F
Example
The cell potential E for the cell
Pt(s)|H2(g, aH2=1)|H+(aq, aH+=1)
||NaCl(aq,m=0.300)|AgCl(s)|Ag(s)
is +0.260 V. Determine Cl assuming that = Na+= Cl
Example
The data in the following table have been obtained for the potential of the cell
Pt(s) | H2(g, f = 1 atm) | HCl(aq, m) | AgCl(s) | Ag(s)
as function of m at 25C
m (mol kg1)
E (V)
m (mol kg1)
E (V)
m (mol kg1)
E (V)
0.00100
0.59715
0.0200
0.43024
0.500
0.27231
0.00200
0.54425
0.0500
0.38588
1.000
0.23328
0.00500
0.49846
0.100
0.35241
1.500
0.20719
0.0100
0.46417
0.200
0.31874
2.000
0.18631