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Study on corrosion behaviour of mild steel using different environments
By
Mir Ishfaq
NE14M005
MM14M006
In the world today, mild steel is used in different Engineering applications for
the production of some automobile components, structural shapes such as
angle iron, wire rods and rebars used in reinforcement concrete. Mild steel is
not expensive and is readily available. It has outstanding ductility and
toughness, high machinability and weld ability which make its applications
possible in the engineering fields. The application for which mild steel was
developed generally did not involve corrosion resistance as a primary
consideration; corrosion resistance of metals and alloys is a basic property
related to the ease with which these metals react with a given environment.
With the increased utilization of this metal in the manufacturing and
construction firms, one of the major problems encountered is the control of
corrosion rate when exposed to different corrosive environments. Corrosion is
a natural process that eats away the metal and may prove catastrophic during
failure in a structure or a design. Corrosion is a natural phenomenon, which is
inevitable; instead it can be controlled to an appreciable extent. For this
control to be implemented certain tests are carried out by placing the metal in
the environment and a careful study of the metals degradation is observed
and assessed for a specified time. Based on the observation and inference
drawn, the corrosion rate can be assessed and a proper measure can be made
to control the rate of corrosion. Since corrosion can never be eliminated,
instead by all human effort can only be controlled or managed. Study on
Corrosion behaviour of materials can lead to minimization of corrosion rate
and hence can prevent any hazard thereof.
Abstract:
This experiment specifically investigated the corrosion rates of mild steel in
concentrated H2SO4, HNO3 and HCL. Also analysis was done on samples kept in
1 Molar solution of each acid.1 Molar solution of NaCl was also prepared and
7th sample was dipped in it and all the samples were kept in these different
environments with a view to determine the most aggressive environment that
may cause heavy loss or degradation of sample. All the samples were kept for
352 hours.8th sample was subjected to hot oxidation and was kept in a furnace
for 3 hours.. The most common method for estimating corrosion rate from
mass loss is to weigh the corroding sample before and after exposure and
divide by the total exposed area and the total exposure time making sure that
appropriate conversion constants are used to get the rate in the required units.
The method in mm/yr can be represented by the following equation.
= ( ) ( )
= Penetration (corrosion) rate (/), = Weight loss in gram, A =
Exposed surface area of Coupon in cm2, = Density of mild steel (/3) =
7.86/3 , T = Time of exposure in hours, k = Constant for unit
conversion = 8.76 104.
Weight loss technique was used in which sample known weight before and
after treating to the respective environments was analysed and results were
collected. The samples were cuboidal in shape with small thickness. The
surface area was simply calculated by the following formula:
S.A=2(lb+bh+hl), where l=length, b=breadth and h=thickness of sample.
7. Now weigh all the samples one by one and note down the dimensions
also. Calculate surface area of each sample and make table as given
below.
Sample
No.
1.
Weight(g)
6.530
length(in
mm)
23.84
Breadth
(in mm)
18.94
Thickness(i Surface
n mm)
area(mm2)
1.87
1063.0564
Surface
area(cm2)
10.6305
2.
7.105
22.2
21.60
1.90
1125.48
11.2548
3.
4.9089
21.77
15.49
1.92
817.513
8.17513
4.
5.180
23.20
15.18
1.93
852.4988
8.5250
5.
6.138
21.40
19.32
1.96
986.5184
9.8652
6.
5.3286
23.58
15.87
1.92
829.830
8.2983
7.
4.920
22.57
15.34
1.90
836.50
8.3650
8.
6.972
22.35
21.68
1.91
1054.472
10.54472
TABLE 1.1
Experimental work
1. Label all the beakers with sample numbers. Pour concentrated
H2SO4, HNO3 and HCL acids in beaker number 1,2 and 3 respectively.
Now put 1 molar H2SO4 in beaker no.4,one molar HNO3 in beaker
number 5 and one molar HCL in beaker no.6.Also make 1 molar NaCl
solution in beaker no.7.
2. Put all the samples in their respective beakers i,e. all the sample
numbers from 1 to 7 in their respective beaker numbers. Drop them
slowly.
3. Keep the beakers in a separated area. Allow the fumes to escape
generated due to the reaction between metal and acid.
4. For sample no.8, switch on the muffle furnace and keep the
sample inside the furnace for 2 hours at 700C.Now after two hours
take the sample out of the furnace and measure its final weight W2.
5. For sample numbers from 1 to 7, wait for 15 days(352 hours) and
after that take samples out of the beakers and allow them to dry in
an oven.
6. Measure the final weight W2 of all the samples. Make a table of all
the results and analyse each one.
7. Calculate corrosion rate of each sample using the above formula
and note down the inferences.
8. Through this method we can analyse the severity of corrosion for
each sample in each environment and we can anticipate the
immunity (passivity) of sample which has least mass difference.
9. We hence are now making the table for results.
Sample
No.
Initial
Weight
(W1 g)
Final
Weight
(W2 g)
Weight
Area of
Time of
Corrosion
loss/mass specimen exposure( rate in
difference (in cm2)
in hours) mm/year
(W g)
1.
6.53
6.480
0.05
10.6305
352
0.14892
2.
7.105
6.836
0.269
11.2548
352
0.75675
3.
4.9089
4.9089
8.17513
352
Sample
dissolved
completely
4.
5.18
0.843
4.337
8.5250
352
16.1077
5.
6.138
4.341
1.979
9.8640
352
6.3515
6.
5.3286
5.136
0.1926
8.298
352
0.73485
7.
4.920
5.005
0.085
8.365
352
0.321
8.
6.972
6.626
0.346
10.54
182.85
Table 1.2
Fig.1.2
References
1. W. D. Callister, "Material Science and Engineering and
Introduction", John Willy and sons Inc. 4th Edition, pp. 550-554, 1997
2. Corrosion Wikipedia.
3. E. A. Noor, A. H. Al-Mubarak, Corrosion Behaviour of Mild Steel in
Hydrochloric Acid, International Journal on Electrochemistry and
science, Vol.3, pp.806-818, 2008
4. E. N. Wami, "Investigation of Underground Corrosion of Mild Steel
and Carbon Steels", Journal of school of Engineering RSUST, NJTE
Vol.15, No.1, pp.7-8, 1990.
5. S. Syed, Atmospheric Corrosion of Materials. Emirates Journal for
Engineering Research, 11 (1), 2006, 1-24.