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CHEMISTRY
Wednesday, August 16, 2000 12:30 to 3:30 p.m., only
The last page of the booklet is the answer sheet. Fold the last page along the perforations and, slowly
and carefully, tear off the answer sheet. Then fill in the heading of your answer sheet.
All of your answers are to be recorded on the separate answer sheet. For each question, decide which
of the choices given is the best answer. Then on the answer sheet, in the row of numbers for that question,
circle with pencil the number of the choice that you have selected. The sample below is an example of the
first step in recording your answers.
SAMPLE:
If you wish to change an answer, erase your first penciled circle and then circle with pencil the number of the answer you want. After you have completed the examination and you have decided that all of the
circled answers represent your best judgment, signal a proctor and turn in all examination material except
your answer sheet. Then and only then, place an X in ink in each penciled circle. Be sure to mark only one
answer with an X in ink for each question. No credit will be given for any question with two or more Xs
marked. The sample below indicates how your final choice should be marked with an X in ink.
SAMPLE:
The Reference Tables for Chemistry, which you may need to answer some questions in this examination, are supplied separately. Be certain you have a copy of these reference tables before you begin the
examination.
When you have completed the examination, you must sign the statement printed at the end of the
answer sheet, indicating that you had no unlawful knowledge of the questions or answers prior to the examination and that you have neither given nor received assistance in answering any of the questions during the
examination. Your answer sheet cannot be accepted if you fail to sign this declaration.
Part I
Answer all 56 questions in this part.
[65]
Directions (156): For each statement or question, select the word or expression that, of those given, best
completes the statement or answers the question. Record your answer on the separate answer sheet in accordance with the directions on the front page of this booklet.
1 If 60. liters of hydrogen gas at 546 K is cooled to
273 K at constant pressure, the new volume of
the gas will be
(1) 120 L
(3) 30. L
(2) 20. L
(4) 40. L
(2)
5 Water will boil at 22C if the pressure on the surface of the water is
(1) 760.0 mmHg
(3) 19.8 mmHg
(2) 92.5 mmHg
(4) 4.6 mmHg
(4)
14
6C
and 168 O
(3) 1s 2s 2p 3s
(4) 1s22s22p63s23p1
and 65
30 Zn
65
29 Cu
[2]
[OVER]
34 When an equilibrium exists between the dissolved and the undissolved solute in a solution,
the solution must be
(1) diluted
(3) supersaturated
(2) saturated
(4) unsaturated
36 The heat energy (H) absorbed or released during the formation of products is equal to
(1)
(2)
(3)
(4)
Chem.Aug. 00
(Hproducts) (Hreactants)
(Hreactants) (Hproducts)
(Hproducts) (Hreactants)
(Hproducts)
(Hreactants)
(1)
(2)
[4]
[H+] [H2PO4]
[H3PO4]
[H3PO4]
[H+] [H2PO4 ]
(3)
(4)
+
[H ] [H3PO4]
[H2PO4]
[H2PO4]
[H+] [H3PO4]
(3) HSO3
(1) HS
(2) OH
(4) NH4+
39 If a given solution at 298 K contains
[H+] = 1.0 109, what is the [OH]?
1
9
(3) 1.0 10
(1) 1.0 10
5
14
(2) 1.0 10
(4) 1.0 10
(2) Br (aq)
(4) F (aq)
+
NH3(aq) + H2O()
NH4 (aq) + OH (aq)
According to the Brnsted-Lowry theory, the
H2O() acts as
(1) a base, by receiving a proton
(2) a base, by donating a proton
(3) an acid, by receiving a proton
(4) an acid, by donating a proton
2+
(2) Fe(s) + 2e Fe (aq)
2+
Chem.Aug. 00
[5]
[OVER]
(3) H C
( 2 ) NH3
(4) H N
Chem.Aug. 00
[6]
Part II
This part consists of twelve groups, each containing five questions. Each group tests a major area of
the course. Choose seven of these twelve groups. Be sure that you answer all five questions in each group
chosen. Record the answers to these questions on the separate answer sheet in accordance with the directions on the front page of this booklet.
[35]
Group 1 Matter and Energy
If you choose this group, be sure to answer questions 57 61.
7
3
Substance B
8
4
1
2
5
6
Time
Chem.Aug. 00
[7]
[OVER]
Group 3 Bonding
electrons as Cl ?
2
2+
(3) Mg
(1) S
+
(2) Br
(4) Na
70 Two fluorine atoms are held together by a covalent bond. Which statement correctly describes
this bond?
(1) It is polar and forms a polar molecule.
(2) It is polar and forms a nonpolar molecule.
(3) It is nonpolar and forms a polar molecule.
(4) It is nonpolar and forms a nonpolar molecule.
66 What was the original mass of a radioactive sample that decayed to 25 grams in four half-life
periods?
(1) 50 g
(3) 200 g
(2) 100 g
(4) 400 g
Chem.Aug. 00
[8]
72 A characteristic of a nonmetal is
(1) low ionization energy
(2) high electronegativity
(3) high electrical conductivity
(4) the ability to form positive ions
(3)
Cl
(2)
Al
3+
NO3
[9]
2+
Cl
NO3
NO3
Chem.Aug. 00
Mg
Cl
(4)
C12H22O11
[OVER]
(2) HS
(4) HCl
(2) HCl
(4) Cl
Chem.Aug. 00
[10]
Power source
e-
e-
93 Based on Reference Table N, what is the standard electrode potential (E0) for the oxidation of
Cu(s) to Cu2+(aq)?
(1) +0.52 V
(3) 0.52 V
(2) +0.34 V
(4) 0.34 V
Ag+
+
94 When an equation is correctly balanced, it must
show conservation of
(1) charge but not of mass
(2) mass but not of charge
(3) both charge and mass
(4) neither charge nor mass
Ag+
Key
(1)
(2)
(3)
(4)
SO4
+ 8H+
Silver
Chem.Aug. 00
[11]
[OVER]
98 An example of a ketone is
(1) propanone
(3) propanal
(2) propane
(4) propanol
(3) N2 + 3H2
H H
(4) C14H30
600C
600C
2NH3
C7H16 + C7H14
(1) H C C C H (3) H C C C
H OH H
H H
H H
(2) H C C C
H H
H H
H H
Pb + PbO2 + 2H2SO4
(4) H C C C
OH
OH
H H OH H
(2) H C C C C H
H H H H
(4) H C O C H
H
2NH3(g) + energy
Chem.Aug. 00
2PbSO4 + 2H2O
OH OH
(3) H C C H
H H
H
charge
discharge
[12]
Fuel
rods
Steam
generator
Water
Pump
Chem.Aug. 00
[13]
[OVER]
Initial
level
14 mL
Heating Time
(min)
Mass of Salt
(g)
0.0
10.0
4.0
9.2
8.0
8.6
12.0
8.0
20.0
8.0
30.0
8.0
Final
level
16 mL
116 Which technique is safest for diluting a concentrated acid with water?
(1) add the acid to the water quickly
(2) add the water to the acid quickly
(3) add the acid to the water slowly while stirring
constantly
(4) add the water to the acid slowly while stirring
constantly
Chem.Aug. 00
[14]
Tear Here
Answer the questions in only seven of the twelve groups in this part. Be sure to mark the answers to
the groups of questions you choose in accordance with the instructions on the front cover of the test
booklet. Leave blank the five groups of questions you do not choose to answer.
Group 1
Matter and Energy
Group 3
Bonding
Group 4
Periodic Table
57
62
67
72
58
63
68
73
59
64
69
74
60
65
70
75
61
66
71
76
77
82
87
Group 8
Redox and
Electrochemistry
92
1 2 3 4
78
83
88
93
79
84
89
94
80
85
90
95
81
86
91
96
Group 5
Mathematics of Chemistry
Group 6
Kinetics and Equilibrium
Group 7
Acids and Bases
97
Group 10
Applications of
Chemical Principles
102
1 2 3 4
98
103
108
113
99
104
109
114
100
105
110
115
101
106
111
116
Group 9
Organic Chemistry
Tear Here
Group 2
Atomic Structure
Group 11
Nuclear Chemistry
Group 12
Laboratory Activities
107
112
I do hereby affirm, at the close of this examination, that I had no unlawful knowledge of the questions or answers prior to the examination
and that I have neither given nor received assistance in answering any of the questions during the examination.
Signature
Chem.Aug. 00
[15]
CHEMISTRY
Credits
Part I . . . . . . . . . . . . . . . . .
...........
Male
Female
Teacher ................................................................................................
Part II . . . . . . . . . . . . . . . .
Total
Raters Initials:
School ..................................................................................................
Record all of your answers on this answer sheet in accordance
with the instructions on the front cover of the test booklet.
Part I (65 credits)
..............
...........
...........
Tear Here
ANSWER SHEET
.........
Part I Credits
Directions to Teacher:
In the table below, draw a circle around the
number of right answers and the adjacent number
of credits. Then write the number of credits (not
the number right) in the space provided above.
21
41
No.
Right Credits
No.
Right Credits
22
42
23
43
24
44
25
45
26
46
27
47
28
48
29
49
10
30
50
11
31
51
12
32
52
13
33
53
56
55
54
53
52
51
50
49
48
47
46
45
44
43
42
41
40
39
38
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
19
18
17
16
15
14
13
12
11
10
9
8
7
6
5
4
3
2
1
0
14
34
54
15
35
55
16
36
56
17
37
18
38
19
39
20
40
65
64
63
62
62
61
60
59
58
57
56
56
55
54
53
52
51
51
50
49
48
47
46
45
45
44
43
42
41
40
39
39
38
37
36
35
34
33
33
32
31
30
29
27
25
23
21
19
17
14
12
10
8
6
4
2
0
Tear Here
Your answers for Part II should be placed in the proper spaces on the back of this sheet.