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Alcan International Limited, Kingston Research and De6elopment Centre, PO box 8400, Kingston, Ont., Canada K7L 5L9
b
Banbury Laboratory, Southam Road, Banbury, Oxon OX16 7SP, UK
Received 20 June 2000; received in revised form 19 September 2000
Abstract
Aluminum alloys containing Mg and Si as the major solutes are strengthened by precipitation of the metastable precursors of
the equilibrium b (Mg2Si) phase in one or more sequences. There are several metastable particles that can form during ageing, but
the strengthening potential of these particles relative to one another is not extensively studied. In this paper, the precipitation and
hardening potential of different metastable precursors in an Al 0.4%Mg 1.3%Si 0.25%Fe (wt.%) alloy is studied with the help
of differential scanning calorimetry (DSC), transmission electron microscopy (TEM) and hardness measurements. It has been
found that the hardness increase in a freshly solutionized alloy during natural ageing occurs primarily due to precipitation of
clusters and zones, while peak hardness is achieved due to precipitation of b particles. The particles formed following b phase
are not effective hardeners. 2001 Elsevier Science B.V. All rights reserved.
Keywords: Precipitation hardening; Aluminum alloy; Mg2Si
1. Introduction
2. Experimental
0921-5093/01/$ - see front matter 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 9 2 1 - 5 0 9 3 ( 0 0 ) 0 1 8 1 4 - 1
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3. Results
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3.2. DSC
Fig. 3. Variation in room temperature hardness of a freshly solutionized Al 0.4%Mg 1.3%Si0.25%Fe alloy due to heating to different
temperature at a heating rates (a) 5C min 1; (b) 10C min 1;
(c) 15C min 1; (d) 20C min 1.
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Fig. 8. Bright field images of a freshly solutionized Al0.4%Mg 1.3%Si 0.25%Fe alloy after ageing at 180C for different times (a) 30 min; (b
and c) 8 h; (d) 24 h.
A.K. Gupta et al. / Materials Science and Engineering A301 (2001) 140146
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Fig. 9. Variations in microstructure and hardness of a freshly solutionized Al 0.4%Mg 1.3%Si 0.25%Fe alloy due to heating at 10C min 1 to
different temperature. The particles marked 18 were chemically analysed in a STEM. (a) Heated to 234C; (b) heated to 250C; (c) heated to
305C.
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5. Conclusions
The hardness increase during natural ageing of an
Al0.4%Mg1.3%Si 0.25%Fe aluminum alloy occurs
primarily due to precipitation of clusters and zones.
The choice of heating rate used to achieve the ageing
temperature has a significant effect on the hardness
reversion during ageing of the freshly solutionized
material.
The peak hardness in the as-quenched AA6016 variant is primarily caused by precipitation of b phase.