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Range of anionic emulsifiers

Application
Trade name

Product
group

Type

Pure
acrylic

Styreneacrylic

Dispersogen LFA

Phosphate
Ester

Tristyrl phenol ether


phosphate

Emulsogen APS 100

Sulfate ester

Allyl polyalkylene glycol


ether sulfate, ammonium salt

Emulsogen EPA 073

Sulfate ester

Sodium alkyl ether sulfate

Vinyl
acetate

Properties
Styrenebutadiene

E-PVC

HLB
value

Appearance

Active
content

APEO
free

n.a.

Brownish,
viscous liquid

ca. 85%

n.a.

Clear to cloudy
yellowish liquid

ca. 100%

n.a.

Clear, colorless liquid

ca. 30%

n.a.

Clear, colorless to
yellowish liquid

ca. 30%

n.a.

Yellowish liquid

n.a.

Low VOC
(<1%)

Food contact regulation

Biodegradability

US FDA1
registration,
chapter 21 CFR

European
registration
Directive 10/2011

German
BfR2

NZIoC

PICCS

TSCA

(Taiwan)

(New
Zealand)

(Philippines)

(USA)

>80% (28d)
OECD 301A

175.105, 176.170,
176.180, 177.1210

Readily
biodegradable

ca. 30%

Readily
biodegradable

Clear yellowish liquid

ca. 30%

n.a.

Yellowish brown liquid

ca. 50%

<10% OECD
302B

n.a.

Colorless, clear to
cloudy liquid

ca. 50%

Readily
biodegradable

78% (28d)
OECD 301B

175.105, 175.300,
175.320, 176.170,
176.180, 176.210,
177.1200, 177.2800,
178.3400

BfR II, XIV,


XXXIV,
XXXVI

exempted

3 LVE

Label

Signal word

Hazard
statement6

Mixture

Warning

H320

Substance

label free

label free

label free

Irritant (Xi)

R36

Harmful (Xn),
Irritant (Xi)

R22, R38, R41

Irritant (Xi)

R36/38

Warning

R36/41

label free

label free

BfR XIV,
XXI, XXXIV

3 LVE

Mixture

>60% OECD
301B

BfR XXI,
XXXVI

Mixture

>93% (28d)
OECD 301B

BfR XIV,
XXI XXXIV

Mixture

Mixture

exempted

Mixture

Emulsogen LCA 213

Sulfate ester

Allyl polyalkylene glycol


ether sulfate, ammonium salt

Emulsogen PF 20 S

Sulfate ester

Polyalkylene glycol ether


sulfate, ammonium salt

Emulsogen SF 8

Sulfosuccinate Dioctyl sulfosuccinate

Genapol LRO liquid

Sulfonate

Sodium lauryl ether sulfate

n.a.

Clear liquid

ca. 27%

Readily
biodegradable

95% (28d)
OECD 301E

176.210, 177.2800

BfR XIV, XXI,


XXXIV

Genapol LRO paste

Sulfonate

Sodium lauryl ether sulfate

n.a.

Paste

ca. 68-70%

Readily
biodegradable

100% (28d)
OECD 301B

176.210, 177.2800

Hostapal BV conc.

Sulfate ester

Sodium alkyl aryl ether


sulfate

n.a.

Clear, colorless to
yellowish liquid

ca. 50%

<10% OECD
302B

Hostapal BVQ 9

Sulfate ester

Sodium nonyl phenol


polyglycol ether sulphate

n.a.

Yellow liquid

ca. 40%

9% (28d)
OECD301D

Hostapal BVQ 25

Sulfate ester

Sodium nonyl phenol


polyglycol ether sulphate

n.a.

Clear yellowish liquid

ca. 30%

23% (21d)
OECD301D

Hostaphat 1306

Phosphate
ester

Alkyl ether phosphate

n.a.

Clear, yellowih liquid

ca. 100%

44% (28d)
OECD 301B

Hostapur OS liquid

Sulfonate

Sodium olefin sulfonate

Hostapur SAS 30

Sulfonate

Sodium alkyl sulfonate

Hostapur SAS 60

Sulfonate

Sodium alkyl sulfonate

Hostapur SAS 93

Sulfonate

Sodium alkyl sulfonate

Composition5

NECI

(Korea)

Readily
biodegradable

KECI

(China)

Ammonium alkyl ether


sulfate

IECSC

(Japan)

Sulfate ester

ENCS

(Europe)

Emulsogen LA 083

EINECS

(Canada)

46% (28d)
OECD301B

Sodium lauryl sulfate

DSL

(Australia)

Emulsogen EPA 1954 Sulfate ester

AICS

3
-

Hazardous labeling according to GHS3


or Dangerous Susbstance Directive4

Inventory registration status

3 LVE

Mixture

Irritant (Xi)

R36/38

Mixture

Irritant (Xi)

R38, R41

BfR XIV, XXI,


XXXIV

Substance

Danger

H315, H318, H412

BfR XIV

Mixture

Irritant (Xi),
Dangerous for the
environment (N)

R41, R52/53

Mixture

label free

label free

Mixture

Warning

H315, H411

178.3400

Substance

Danger

H315, H318, H411

Mixture

Irritant (Xi)

R38, R41

Irritant (Xi)

R38, R41

Irritant (Xi)

R38, R41

Danger

H302, H315,
H318, H412

n.a.

Yellowish clear liquid

ca. 40%

Readily
biodegradable

>80% (28d)
OECD 301B

175.105, 178.3400

n.a.

Clear, slightly
yellowish liquid

ca. 30%

Readily
biodegradable

>89% (28d)
OECD 301E

176.170, 176.180,
178.3400

BfR XIV,
XXXVI

Mixture

n.a.

Yellowish soft paste

ca. 60%

Readily
biodegradable

>89% (28d)
OECD 301E

176.170, 176.180,
178.3130, 178.3400

BfR II, V,
VI, XIV, XV,
XXI, XXXIV,
XXXVI

Mixture

n.a.

Yellowish tablets

ca. 93%

Readily
biodegradable

>89% (28d)
OECD 301E

176.170, 176.180,
178.3400

BfR XIV,
XXXVI

Substance

label free

1 Product listed in chapter 21 CFR of the US Food and Drug Administration


2 The product meets the requirements of the Bundesamt fr Riskikobewertung (German authority of risk assessment)
3 Hazardous labeling according to the Globally Harmonized System
4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC)
5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals
as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the
Regulation on classification, labeling and packaging of substances and mixtures on 16.12.08 (EU regulation 1272/2008).
According the EU regulation, the classification and labteling has to be done until:
- 01.12.2010 for substances

- 01.06.2015 for mixtures (i.e. chemical preparations)

Risk phrases:
R22:
Harmful if swallowed
R36:
Irritating to eyes
R38:
Irritating to skin:
R36/38: Irritating to eyes and skin
R41:
Risk of serious damage to eyes
R52:
Harmful to aquatic organisms
R53:
May cause long-term adverse effects in the aquatic environment
R52/53: Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
n.a.
Not applicable

Hazard Statements:
H302: Harmful if swallowed
H315: Causes skin irritation
H318: Causes serious eye damage
H411: Toxic to aquatic life with long lasting effects
H412: Harmful to aquatic life with long lasting effects

7 LVE = Low volume exempt

label free

Emulsion Polymerization

Range of anionic and


nonionic surfactants

Range of nonionic emulsifiers


Application
Trade name

Product
group

Type

Emulsogen 4084

EO/PO block
copolymers

60% EO, 40% PO

Emulsogen EPN 118

Pure
acrylic

Styreneacrylic

Vinyl
acetate

Properties
Styrenebutadiene

E-PVC

Active
content

APEO
free

Low VOC
(<1%)

Food contact regulation

Biodegradability

US FDA1
registration,
chapter 21 CFR

European
registration
Directive 10/2011

Hazardous labeling according to GHS3


or Dangerous Susbstance Directive4

Inventory registration status


German
BfR2

HLB
value

Appearance

AICS

DSL

EINECS

ENCS

IECSC

KECI

NECI

NZIoC

PICCS

TSCA

(Australia)

(Canada)

(Europe)

(Japan)

(China)

(Korea)

(Taiwan)

(New
Zealand)

(Philippines)

(USA)

18

Pale yellow wax

ca. 100%

<10% (28d)
OECD302B

175.105, 176.180,
176.200, 176.210,
177.1200, 177.1680

BfR XIV,
XLVIII, LIII

Composition5

Label

Signal word

Hazard
statement6

Substance

label free

label free

label free

Harmful (Xn),
Irritant (Xi)

R22, R41

Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 11 moles EO

15

Clear colorless liquid

ca. 80%

Inherently
biodegradable

> 80 % OECD
302 B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Mixture

Emulsogen EPN 217

Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 21 moles EO

17

Clear colorless liquid

ca. 70%

Inherently
biodegradable

> 80 % OECD
302 B

176.170, 176.180,
181.30

BfR XIV, XXI,


XXXIV

Mixture

label free

label free

label free

Emulsogen EPN 287

Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 28 moles EO

17,5

Clear colorless liquid

ca. 70%

Inherently
biodegradable

> 80 % OECD
302 B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Mixture

label free

label free

label free

Emulsogen EPN 407

Fatty alcohol
C11 oxo alcohol, ethoxylated
polyglycol ether with 40 moles EO

18

Clear colorless liquid

ca. 70%

Inherently
biodegradable

> 80 % OECD
302 B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV

Mixture

label free

label free

label free

13

Clear to cloudy liquid

ca. 100%

Readily
biodegradable

>80% (28d)
OECD301E

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Substance

Danger

H302, H318

13,5

Clear liquid

ca. 80%

Readily
biodegradable

>61% (28d)
OECD301B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Mixture

Harmful (Xn),
Irritant (Xi)

R22, R41

Emulsogen LCN 070 Fatty alcohol


ethoxylate

C11 oxo alcohol, ethoxylated


with 7 moles EO

Emulsogen LCN 088 Fatty alcohol


ethoxylate

C11 oxo alcohol, ethoxylated


with 8 moles EO

Emulsogen LCN 118

Fatty alcohol
ethoxylate

C11 oxo alcohol, ethoxylated


with 11 moles EO

14

Clear liquid

ca. 80%

Readily
biodegradable

>61% (28d)
OECD301B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Mixture

Harmful (Xn),
Irritant (Xi)

R22, R41

Emulsogen LCN 158

Fatty alcohol
ethoxylate

C11 oxo alcohol, ethoxylated


with 15 moles EO

16

Clear liquid

ca. 80%

Readily
biodegradable

>75% (28d)
OECD301B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV

Mixture

Harmful (Xn),
Irritant (Xi)

R22, R41

Emulsogen LCN 217

Fatty alcohol
ethoxylate

C11 oxo alcohol, ethoxylated


with 21 moles EO

17

Clear liquid

ca. 70%

Readily
biodegradable

>75% (28d)
OECD301B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV,
XXXVI

Mixture

label free

label free

label free

Emulsogen LCN 287

Fatty alcohol
ethoxylate

C11 oxo alcohol, ethoxylated


with 28 moles EO

17,5

Clear liquid

ca. 70%

Readily
biodegradable

>75% (28d)
OECD301B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV

Mixture

label free

label free

label free

Emulsogen LCN 407 Fatty alcohol


ethoxylate

C11 oxo alcohol, ethoxylated


with 40 moles EO

18

Clear liquid

ca. 70%

Inherently
biodegradable

> 80 % OECD
302B

175.105, 176.170,
176.180, 181.30

BfR XIV, XXI,


XXXIV

Mixture

label free

label free

label free

Emulsogen TS 200

Tristyryl
ethoxylate

Tristyryl ethoxylated with


20 moles EO

14

Yellowish brown liquid

ca. 100%

10-35% OECD
302B

BfR XIV, XXI,


XXXIV

Substance

label free

label free

label free

Genapol PF 10

EO/PO block
copolymers

10% EO, 90% PO

13

Clear colorless liquid

ca. 100%

Readily
biodegradable

100% (28d)
OECD 301B

175.105, 176.180,
176.200, 176.210,

BfR V, VI,
XIV, XXXVI

Substance

label free

label free

label free

Genapol PF 20

EO/PO block
copolymers

20% EO, 80% PO

14

Slightly cloudy,
colorless liquid

ca. 100%

Readily
biodegradable

99% (28d)
OECD 301F

175.105, 176.180,
176.200, 176.210,

BfR V, VI,
XIV, XXXVI

Substance

label free

label free

label free

Genapol PF 40

EO/PO block
copolymers

40% EO, 60% PO

16

Slightly cloudy,
colorless liquid

ca. 100%

Readily
biodegradable

61% (28d)
OECD 301F

175.105, 176.180,
176.200, 176.210,

BfR V, VI,
XIV, XXXVI

Substance

label free

label free

label free

Genapol PF 80

EO/PO block
copolymers

80% EO, 20% PO

19

Wax

ca. 100%

<10% (28d)
OECD302B

175.105, 176.180,
176.200, 176.210,

BfR XIV,
XLVIII, LIII

Substance

label free

label free

label free

Genapol X 080

Fatty alcohol
ethoxylate

C13 oxo alcohol, ethoxylated


with 8 moles EO

Genapol X 307

Fatty alcohol
ethoxylate

C13 oxo alcohol, ethoxylated


with 30 moles EO

Genapol X 407

Fatty alcohol
ethoxylate

C13 oxo alcohol, ethoxylated


with 40 moles EO

Genapol X 1003

Fatty alcohol
ethoxylate

C13 oxo alcohol, ethoxylated


with 100 moles EO

Genapol X 1005

Fatty alcohol
ethoxylate

C13 oxo alcohol, ethoxylated


with 100 moles EO

12

Slightly cloudy,
colorless liquid

ca. 100%

Readily
biodegradable

60% (28d)
OECD 301F

175.105, 176.170,
176.180, 176.200,
176.210, 181.30

BfR V, VI,
XIV, XV, XXI,
XXXIV,
XXXVI, LI, LII

Substance

18

Clear colorless liquid

ca. 70%

Readily
biodegradable

100% (25d)
OECD 301B

176.170, 176.180,
176.200, 181.30

BfR V, VI,
XIV, XV, XXI,
XXXIV

Mixture

18

Clear colorless liquid

ca. 70%

Readily
biodegradable

100% (25d)
OECD 301B

176.170, 176.180,
176.200, 181.30

BfR V, VI,
XIV, XV, XXI,
XXXIV

19

Clear colorless liquid

ca. 35%

50-60% OECD
301B

176.170, 176.180,
176.200, 181.30

BfR V, VI,
XIV, XV, XXI,
XXXIV

19

Clear colorless liquid

ca. 50%

Readily
biodegradable

>95% (25d)
OECD 301B

176.170, 176.180,
176.200, 181.30

BfR V, VI,
XIV, XV, XXI,
XXXIV

Danger

H302, H318

label free

label free

label free

Mixture

label free

label free

label free

Mixture

label free

label free

label free

Mixture

label free

label free

label free

1 Product listed in chapter 21 CFR of the US Food and Drug Administration


2 The product meets the requirements of the Bundesamt fr Riskikobewertung (German authority of risk assessment)
3 Hazardous labeling according to the Globally Harmonized System
4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC)
5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals
as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the
Regulation on classification, labeling and packaging of substances and mixtures on 16.12.08 (EU regulation 1272/2008).
According the EU regulation, the classification and labteling has to be done until:
- 01.12.2010 for substances
- 01.06.2015 for mixtures (i.e. chemical preparations)

6 Risk phrases:
6 Hazard Statements:
R22:
Harmful if swallowed
H302: Harmful if swallowed
R36:
Irritating to eyes
H315: Causes skin irritation
R38:
Irritating to skin:
H318: Causes serious eye damage
R36/38: Irritating to eyes and skin
H411: Toxic to aquatic life with long lasting effects
R41:
Risk of serious damage to eyes
H412: Harmful to aquatic life with long lasting effects
R52:
Harmful to aquatic organisms
R53:
May cause long-term adverse effects in the aquatic environment
R52/53: Harmful to aquatic organisms, may cause long-term adverse

effects in the aquatic environment

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