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"Boyle's Law":
Boyles Law describes the inverse proportional relationship between pressure
and volume at a constant temperature and a fixed amount of gas.
" (P1)(V2) = (P2)(V2) = (P3)(V3) = constant "
Problem #1: 5.00 L of a gas is at 1.08 atm. What pressure is obtained when
the volume is 10.0 L?
Problem #2: 2.00 L of a gas is at 740.0 mmHg pressure. What is its volume
at standard pressure?
Problem #3: 2.50 L of a gas was at an unknown pressure. However, at
standard pressure, its volume was measured to be 8.00 L. What was the
unknown pressure?
"Charles's Law":
Charles's Law describes the directly proportional relationship between the
volume and temperature (in Kelvin or Rankine) of a fixed amount of gas,
when the pressure is held constant.
Problem #1: 4.40 L of a gas is collected at 50.0 C. What will be its volume
upon cooling to 25.0 C?
Problem #2: 5.00 L of a gas is collected at 100 K and then allowed to
expand to 20.0 L. What must the new temperature be in order to maintain
the same pressure (as required by Charles' Law)?
Problem #3: A 2.5 liter sample of gas is at STP. When the temperature is
raised to 273 C and the pressure remains constant, what is the new
volume?
"Amontons's Law":
Given a constant number of mole of a gas and an unchanged volume,
pressure is directly proportional to temperature.
Problem #1: 10.0 L of a gas is found to exert 97.0 kPa at 25.0C. What
would be the required temperature (in Celsius) to change the pressure to
standard pressure?
Problem #2: 5.00 L of a gas is collected at 22.0C and 745.0 mmHg. When
the temperature is changed to standard, what is the new pressure?
"Avogadro's Law":
Volume of a gas is directly proportional to the amount of gas at a constant
temperature and pressure.
V1
m1
V2
m2
, (V1)(m2) = (V2)(m1)
Problem #1: 5.00 L of a gas is known to contain 0.965 mol. If the amount of
gas is increased to 1.80 mol, what new volume will result (at an unchanged
temperature and pressure)?
P2 V 2
T2
Problem #1: 2.00 L of a gas is collected at 25.0 C and 745.0 mmHg. What
is the volume at STP?
Problem #2: The pressure of 8.40 L of nitrogen gas in a flexible container is
decreased to one-half its original pressure, and its absolute temperature is
increased to double the original temperature. What is the new volume?
"Ideal Gas Law":
Combination of all Gas Laws.
PV = mRT
where:
P = Pressure
V = Volume
m = mass
T = Absolute Temperature
R = Specific Gas Constant or Simply Gas Constant ( values below)
For air:
53.342
ft .lb f
lb m . R
287.08
N .m
kg . K
English
Unit
Lb/ft2
Ft3
lb
ft . lb f
lb m . R
SI Unit
N/m2
m3
kg
N .m
kg . K
Problem #1: For a certain Ideal Gas of R=0.277 KJ/kg.k. What mass of this
gas would occupy a volume of 0.425 m3 at 577.11 KPa and 26.7C ?