Fulctbnal Polymers Division Showa Denko K

13'9, Shiba Daimon l'Chone,

Minato-Ku,

---fhone:
Facsimile:

Ib$o

105-8518, JaPan

+81-3-5403-5600
+81-3-5403-5720

MATERIAL SATEIY DATA SIIEET

Preparedon: February

25, 2010

r. CHEMICAL PRODUCNAND COMPANY IDENTINCEflON

Pmduct na:ne:

Ripo:ry R'8O2EX

Company name:

Functional Pollmers Division Showa Denko

Ad&ss:
Tblephone:

l'13-9, Shiba Daimon, Minato'ku, lbkyo

Qualif Assurance Group, Tatsuno Plant
079167-2091

FAX:

o79t67-tn2

Emergency contact:

Tatsuno Plant

Section:

KK

Phone; 0791-67-1111 (At night or on holiday)

Restriction on use:
Reference number:
2. IIAZARDS

Industrial uee
CN6194P

IDENTtr'ICATION

GIIS Classification
Physical hazards:

Explosives:
ffumrnshle gsses:
Flammable aerosols:
Oxidizinggases:
Gases under pressule:
Flammable liquiils:
Flammable solids:

Not aPPlicable
Not applicable
Not applicable
Not aPPlicable
Not applicable
Category 3

Not applicable
Selfreactive substances and mixtures Classification: Not applicable
Not aPPlicable
fomphoric
Not aPPlicable
fon:phoric
Not applicable
Selfheating substances and
Substances and nixtures whicl! in oontact with wate4 emit flammahle gases:
Not applicable
Not applicable
O:ridizing liquids:
Not applicable
Oxiilizing soliils:
Not applicable
Organic pemxides:
Not applicable
C,orrosive to metals:

liquids:
solids:

mixtures:

Ripo:ry R'8028K (r/9)

Health Hazards:
Acute toxicity (oraD:
Acute toxicity (dennal):
Acute toxicity (inhalation; gases):

Category 5
Category 5

Not applicable

Acute toxicity (inlalation; vapor):

Acute toxiciW Gnhalation dust/misd:
Skin cor:rcioniirritation:

Category 4

Classfication not possible

Category 2
Category 2A

Serious eye d^mpge/eye i:ritation:

Respiratory sensitization:
Skin sensitization:
Germ cell mutagenicity:

Classification not possible

Not classified

Carrcinogenicity:

Category 2
Category 18

Category 2

Repmductive toxicity:
Specific target organ toxicity Gingle exposurc):
Specific target organ toxicity Gpeated exposure):
Aspiration hazard:

Envimnmental hazards:
Acute aquatic toxiciw:
Chrcnic aquatic toxicity:

Category

Category I
Classification not possible

Category 2

Not classfied

Label elements:

Pictogram or

spbol:

90@
Signal word:

llazard statements:

Danger
Flammable liquid and vapor
May be harmfrrl if swallowed
May cause irritation or allergic dermatitis on skin
Ilarmflrl if inhaled
May be ha:rnfirl in contact with skin
Causes serious eye

irritation

Suspected of cawing genetic defects

Suspected of causing cancer
May da mage fertility or tlre unborn child
Cause darnage to organ (central nerve system)

May cause irritation on respiratory orga4 respiratory irritation

Pmlonged or rnepeated exposure may cause da"tage to organs
(Respiratory organ, nerve system, blood, liver)
May be frtal if swallowed and enters aimays
Tbxic to aquatic life

Ripoxy B'802EX (2/9)

Prcautionary statements:
lsafe hantllingl
Keep away fiom fir,e. Use under local ventilation.
While handling, have good air ventilation. Do not inhale the

vapor. If

necessary, wear mask for organic

airsupplying.
Wear protective glasses and gloves to avoid contact with eye or skin
Do not transGr to another ulspecified mntainer.
If spilled, wipe off using sand or doth and recover in non-combustible container or container containing
water.
[Emergency measurel
If in eyes, wash with large quantity ofwater 6r at least 15 minutes, and consult with a medical doctor.
If inhaled and feel unwell renove victin to fresh air and keep at rest. If necessary, consult with a
gas or

medical doctor.

In case offire, use carbon dioxide gas, foam, or powder type fire extinguisher.
[Storage]
Store in

ml

and dark place within adequate frcilities.

Keep away from children.

Keep container tightly closed.

,-

lDisposail
Dispose the unused content accordir:g to the applicable regulations.
Dispose after using up all the mntent.
3. COMPOSTNONAND

Chemical

INFORMAIION ON INGREDIENTS

substance/mixturc:

Chemical name or general

and contents:

name:

Component

(*)

Mixture
Vinyl eeter resin

Cbmical
frnnula

CAS number

Official Gazefte

Notificatbn numbed*)

Content

5l'

Bisphenol eystem vinyl ester

62N5-94-2

Existing substance

Styrene

t0&42-5

(B)-4

46%

Metbacrylic acid

79-41-4

(9-rozb

l.4o/o

Iaw coneming

4. FIRSTAID

the evaluatlm ofclemical subetances and rrgulatbn

oftleb manufictu,

etc,

55o/o

Indushial Saet5r and Health Iaw.

MEASUMS:

When inhaled:
Move victim imme<tiately to fresh air and keep at rcst, warming by using blanlet. If serious, consult with a

medial doctor.
In case ofskin contact:
Remove the mntaminated clothes and shoes, wipe ofrthe mntaminated portion with clotb, and then wash
with soap and rinse well with cold or wam water. If infammations appear, consult with a medial doctor.
Ifspilled in eye:
Wash the eye well with running water frr at least 15 minutes, and consult with a rnedial dostor,
If swallowed:
Do not induce vomiting. Wash mouth well with water and consult with a medial doctor immediaiely. If
natural vomiting occurs, keep the body inclined to avoid inhalation to tmchea

Ripoxy R'802EX (3/9)

Expected acute and delayed symptoms and the most important symptoms:
Cause rube frction in eye and on skin, dizziness, figadacftg, narsea, sluggishness, impaired consciousness,

asthma and lung edema. Asthna and lung edema may appear later and it gets worse if not keep at restPmtection of the person who giles the first aid:
Pay attention to fire
Wear pmtective glasses and oil-resistant gloves to prevent the exposure to eye and skinWear respiration pmtect equipment to avoid inhalation ofthe vapor.
Special instructions to the medical doctor:
Keep at rest, and medical monitoring is necessar5r.
5.

FIRT.FIGFIIING MEASURSS
Suitable extinguishers:
Powder extinguishet carbon dioxide, fram extincuieher, dry sand
Extinguisher which must not be used:

Pouring water
Specific hazads arising ftom the fue:
The mntainer might explode by heat.
Irritatiq toxic gas might be gpnerated by fire.
Specific fire fulrting metlod:
For erly stage offire, uee pon'der extinguiehea carbon dioxide or dry eand.
For large scale fi:re, 6am extinguisher is efuive to shut don'n the air.
For fire nearby, pour water to cool down the neighboring facilities. Movable containers ale to be moved
away to a saft place immediately.
Protection br fi re'fu hter:
Wear pereonel protective equipment euch ae selfontained respirator and work fom the windward to
prevent the inhqlarion oftoxic gases dwing the fre fighting.
6.

ACCIDENITAL RELEASE MEAfIURES

Personal precautions:
Wear pmtecbive equipment and work fi'om the windward.
Protection equipment and emergency prc@dwes:

Dudng the operatio4 wear protective equipment (oil'resistant gloves, protective glasses, and respiration
pmtective equipmend to aroid skin contact ofeplaeh and i"h"tqt'on oftoxic gasee and vapor.
Work from tlre windwar4 and evacuate people in leeward.
Prepare fire fighting equipment just in case it gpts fir.
Envimnmental precautions:
Tly not to allow the spills to flow into river, sewerage or dnin system.
Methods and materiale 6r containmeaf snd cleaning up:
In caee of emall volume, wipe ofr with dry ean4 sawdust, or waste cloth, and rccover in a eeaiable
container.

quantity prcvent eleansion by surmulding by sand, reover in a sealable container.

Wipe offthe remeini"g liquid with dry san4 sawdust, or waste clot\ and rccover in a sealable container.

In

case of large

Prevention of eemndary disaster:

Remove all potential fire sources, and prepa:e fire fuhting equipment for fire. If the spill flowed into
sewerage, or drain Byetem, inform pollution conbol section ofthe local gorernment.

rier,

Ripo:ry B-8028X (4/9)

7.I{ANDUNGAND STORAGE
Ilantlling
Engineering measures:

Inetall frcilities as described

in 8.

Expmure contno}lersonal pmtectiori, and wear prctective

equipment.
Local exbausVtotal ventilation:
Install local exhaust as described

in'8. Expcure ontnollpersonal pmtection, and wear

pmtective

equipment
Special precautions:

Work in a plaoe with local exhauet.

Measuree 6r saft haadling:
Work only after reading and undentanding all the safrty precautione.
No fir,e.
Never use any materials, which could cause fire or spar\ in near'by.
Never turn wer the container, or give a shek, or bandle mughly such ae dragging.
Never contaqt, inbale, nor swallow.
Never put in eye.
Wash hande well after use.
Storage

Appmpriate etoring onditions:

Avoid sun light, and store at a cool dark place with good ventilation.
Follow Fire Sen'ice Law and Industrial Safety and Health Law.
Appnpriate container material:
Use containers as defined in Firc Service Law and IJN Ifuzadous Substance Transportation
Regulation.
8. EXPOSIJRE CONTROI.S/PERSONAL PRCYIECTION

"

Facility meaeures:
Install local exbaust equipmen! saGty shower, hand waeh and eye washing equipnent.
20 ppm Gtyrene)
Confrol conoenhration:
Aceptable concenbation limit:
Japan Socief 6r Oocupational Health (200D % ppm (Styrene)
TwA 20ppm Gtyrene)
ACGtrI@OO5)
STEL 40ppn(Styrene)
Protection equipment
Respiratory protection: C'as ma6k br organic gas, airsupplied mash selfcontaining respirator.
Iland protection:
Oil'resietant pmtective gloves.
Protective gJasses.
Eye protection: '
Skin and body protection: Protective clothee (anti'static charge), protective shoee (anti'statb cba:ge).

Ripoxy R'Eo2EX (6/9)

9.

PI{YSICALAND CIIEMICAL PROPERTIES

Appearance (physical state, shape and

Odor:
pH:

cobr):

Viscous purple.led

liquid

Ilpical

eharp omell 6tvrene)

Not aPPlicable

point:
ranep:

Meltir:g poinUficezing
hitial boiling point and boifing

Flashpoinfi

Unlmown

f4StGoiling point, Stvrene)

3ft

(Setatype aosed rvstem meaeuring equipmenD

point:

Unlnown
Combustion or explosion rangp 0ower limit and upper li:nit):
lon'er limifi 0.9%, upper limi$
OJlilaf?nT (StYrene)
Vaporpreseure:
Self ignition

Vapordensity:
Evaporation rate:

Specific emvity Glative

Solubility:

6tyrene)

3.59 (f: air)

density):

@ffcient:
Decomposition temperatuire:
Hygiene meaeuns:
Spontaneous igrrition temperatue:
OctanoVwater partition

10.

6.8%

Unknown
f.O'f.2giml (25t)
Insoluble in water, soluble in organic solvents such ae acetone.
Unknown
Unknown
Wash hand well after use.

49Ot

STABIIJTYAND REACIIVTTY
Stability:
Stable when storcd in cool dark plaoe in tightly-sealed container.
Possibility of hazardous reactions:

Unknovt'n
C,onditions to avoid:

Polymerizes and generates heat when orpoeed to heat, light, or pemnide.

Electrostatic tlischarge
Incompatible materials:
Avoid ueing breathable materials, and material soluble in the sohnt ofthe component.
Ilazardoue decomposition pmducts:

Unknown
1T.

1\])ilCOLOGICAL INFORMATION
Acute toxisity:

Oral:
Dermal:
Inhalation:

Category 5 according to the GHS standard ofATE frr Mixture

Category 5 according to the GIIS standard ofATE frr Mixtue
Category 4 according to the GHS standard ofATE br Mixtu:re

Skin cormsion/irritation:
Ingledient stgne is reported to have moderate irritation as a result of dermal irritation test on rabbit.
And cormsion wae observed after 3 minutes open application of an ingretlient of methacrylic acid as a
rBult of skin irritation test on a rabbit.
Causes skin irritation (cateepry 2)

Ripo)ry R'802EX (6/9)

Serious eye .la mage/irritation:

Ing:edient styrene is reported to have moderate irritation 0asted 7 days) as a result ofeye iritation test on
rabbit and in the case of epidemiolory.
Corneal opacity, irritation on iris, conjunctival hypermia and conjunctival edema were observed on all
rabbits after 24 hours of application oftlre ingredient methacrfic acid at the eye irritaion study on rabbit.
And corneal opacity, irritation on iris and conjunctiva was not recovered on a-fter day 7 and chenical bum,
necmsis defluxion ofcorneal epithelial and pumlent accumulation have been observed.
Causes serious eye i.rritation. (Category 210
Respiratory sensitization:
No data alrailable
Skin sensitization:
Classified as out of category because an ingredient of methacrylic acid is concluded as not
sensitizinaccording to the case on human and stuilies on animal
Germ cell mutagenicity:
An ingredient st5rne was reported as positile at in vivo mutagenicity test on body cell. (chromosome
aberration test, micro neudeus test)
But no test is reported of in vrvo inter generation germ cell mutagenicity or in vivo germ cell genetic
toxiciff.
Suspected of cawing genetic defects (Category D
Carcinogenicif:
An ingrcdient of styrene is classified as 28 by IARC.
Suspected ofcausing cancer (Category D
Rproductive toxiciff:
Decrease ofviabfity index ofnewborn ofFl and F2 was observed in 3 generations reproductive study.
And abnormalities were reported at many investigation of behavior on pup qnirn"ls, such as decrease of
cerebrum serotonin, delay of righting reflex and auditory response at dose level which has no toxicitlr on
dam at development toxicity test and lactation period ad-ministration test.
Suspected ofcausing genetic defects (Category fB)
Specific target organ toxicity Gingle exposure):
An ingredient styrene is reported to cause irritation to eye and noee and has an efiect on cenbcal nerve
system.

An ingedient of methacrylic acid is reported to have "irritation to rcspiratory air wa/' at animal test.
Cause ilarnage to organ (entral nene systen) (Category D
May cause irritation on respir,"atory organ (Category 3)
Specific target organ toxicity Gpeated exposure):
An iry:edient stJnene caus irritation to eye, skin, nose and throat and it cause obstructive pulmonary
defect, cbmnic bronchitis as effect on respiratory system. And influence on cenbal nen'e such as
dizziness, headache, lassitude, muddle and ircomnia, efiect on psychoneumtic function such as descent of
response time and verbal memory effect on sight and auditory sense, eftct on blmd system such as
increment of lymphocytes and decrease of thmmbocltes and effect on liver such as increment of AST GGT
andAI.JTactivity.'Epithelialcellvacuo}atiorSsublationofcellandpyknosisofnasalcavityandbachea
mumsa", "decrease of caudal peripheral nerve conduction velocity SCV' and 'liver cell necrcsis ' is reported
at experiment on animaL An ingredient methacrylic acid is reported to cause rapid pulse, hypotensioa
excess reaction with nitmglyceriq low body temperature, wealr reaction by exposute to heat or ultra violet
pathological alternation of Ashner r,eflectioq acracyanmis and hemor of hand finger. "Alternation of
enzyme in live4 altemation of elecde, decrease ofweight of liver and adrenal gland ahophia of liver and
kidney/adrenal gland and altemation of nasal cavity olfactory epithelial" are reported at experiment on
qnimal Prolonged or repeated o<posurte rnay cause darnqge to orans Gspiratory organ, nerve system,
blood, liver, kidney and adrenals)
(Category l)
Bipoxy R.802EX (?/9)

Aspiration hazard:
No data available.
However, as main ingredient styrene is classified as category 1, label element correspond to stlrene is
displayed on label as the company policy.
12.

ECOIOGICAL INFORMAIION

lbxicity:

Fathead minnow I'CIO a'O2mg,M96H

Tbxic to aqueous lift (CategorY D
No data available'

desrailability:
Bioaccumulativepotential: NodataavailablePersistence and

Mobility in
13. DIfIPOSAL

soil:

No data avaitrable.

CONSIDERANON

Dispcal method:
Incjnerate in emsll portions in incinerator above 8OOt, or consign to waste dispoeer approved by the local
government,
Container:
When disposing a container, the content must be completely remwed ftom
14. TRANSFORT

it

INFONMATION

International rcgulations
Class 3 (fannabte liqui0
UN classification:
1866
UN nu.mber:
(UN
ether resin
Vinyl
name):
shipping
name
Article
lll
Packing grouP:
Not
classified.
pollutant:
Marine
Domestic regulations
Follow the regulations ofFire Senrice Law.
Inland transporfi
Follow the regulatione oflaw br Safrty ofVessels.
Marine transport:
Follow the regulations of Civil Aeronautics I.aw.
Air transport:
transport:
Special precautiom and couditions during
Avoid collapee ofcargp by Ioading the containers without damages such as fall-down and collision.
Confm spills ard lids 6r each container.
Emergency guidance number:
128

Ripox!' R'802EX (8/9)

15.

REGUI,AfORY INFORMANON
Fire Service Law:
(1,000I)
Ilazardous substanoe, Clas84 lype 2 petroleum oil 0nsoluble to water)
Industrial Safety and Health Law:
Dangerow eubetane (flammable)
The second kind organic solvent (ontain mor than 5% styrne)
Ilarmirl substance which na.me should be displayed (styl!e: odina-nce nunber

l7'D

nare ehould be notifretl (Styrene: Odinance nunber 323)

I{armfr

substance which

Ilarmf

eubstance which name should be notifred 0vtethacrylic acid: Otdinance mrmber 556)

PRTR Law:
ttesignated chemical subetance (Styrene: Onlirance number 240)
class 1 degignatd cbemical substance o4ethacrilb acid: orrrtinance number 415)

Class

Law for Safety ofvessels:

High flash point flarnrnable liquid(Reeulation of shipping and storing dangemus artide announcement
appendix 5)
Foul Smell C.onbol Law:
Oftnsive odor substanre 6tYrene)
Road Tlucking Vehicle law:
Safety etandard
Act on Port Law:
DangBrow substance flqmmatrle liquid class
Marine Pollution Prevention law:
Class Y substance GtYrene)
16. CYIHER INFORI\,IIf

IION

The inbrmation contained herein is accurate, based on the refrrence bfrrostion and data available now.
However it might be nevised by new infrrmation. All precautions desriM herein ale 6r normal hendling.
If used under spcial confitions, extra saftty measurea must be taken This pmvides inbrmation only, and
doee not provide any guarantees.

Ripo)ry R-802EX (9/9)