CONCEPTUAL QUESTIONS

10. The elevation in boiling point , when 13.44 g of

COLLIGATIVE PROPERTIES
freshly prepared cucl2 are added to one
kilogram of water, is.[some useful data,
kb=0.52 kg k mol-1, molecular weight of
cucl2=134-4 g] (JEE-2004)
(a) 0.05
(b) 0.1
(c) 0.16
(d) 0.21
11.When 20g of naphthoic acid (C11H8O2) is
dissolved in 50 g of benzene (kf=1.72 k kg
mol-1), a freezing point depression of 2 k is
observed. The vant Hoff factor (i) is
(JEE2007)
(a) 0.5
(b) 1
(c) 2
(d) 3
12. The Henrys law constant for the solubility of
N2 gas in water at 298 k is 1.0 x105 atm. The
mole fraction of N2 in air is 0.8. the number of
moles of water of 298 k and 5 atm pressure is
(JEE-2008)
(a) 4.0 x 10-4
(b) 4.0 x 10-5
(c) 5.0x10-4
(d) 4.0x 10-6
13. The freezing point (in0C) of solution containing
0.1 g of k3[Fe(CN)6]( mol.wt.329) in 100g of
water (kf= 1-86k kg mol-1) is (JEE-2011)

1. An azeotropic solution of two liquiads has

boiling point lower than either of them when it
(JEE-1981)
(a) Shows negative deviation from Raoults
law
(b) Shows no deviation from Raoults law
(c) Shows positive deviation from Raoults
law
(d) Is saturated
2. For a dilute solution, Raoults law states that
(JEE-1985)
(a) The lowering of vapour pressure is equal
to the mole fraction of solute
(b) The relative lowering of vapour pressure
is equal to the mole fraction of solute
(c) The relative lowering of vapour pressure
is proportional to the amount of solute
in solution
(d) The vapour pressure of the solution is
equal to the mole fraction of solvent
3. A molal solution is one that contains one mole
of a solute in (JEE-1986)
(a) 1000 g of the solvent
(b) 1 L of the solvent
(c) 1 L of the solution
(d) 22.4 L of the solution
4. When mercuric iodide is added to the aqueous
solution of potassium iodide (JEE-1987)
(a) Freezing point is raised
(b) Freezing point is lowered
(c) Freezing point does not change
(d) Boiling point does not change
5. Which of the following 0.1 M aqueous solution
will have the lowest freezing point (JEE-1989)
(a) Potassium sulphate

6.

7.

8.

9.

(b) Sodium chloride

(c) Urea
(d) Glucose
The freezing point of equimolal aqueous
solution will be highest for (JEE-1996)
(a) C6H5NH3Cl (aniline hydrochloride)
(b) Ca(NO3)2
(c) La(NO3)2
(d) C6H12O6 (glucose)
The molecular weight acid of benzoic in
benzene as determined by depression in
freezing point method corresponds to
(JEE-1996)
(a) ionization of benzoic acid
(b) dimerization of benzoic acid
(c) trimerization of benzoic acid
(d) salvation of benzoic acid
during depression of freezing point in a
solution the following are in equilibrium (JEE2003)
(a) liquid solvent ,solid solvent
(b) liquid solvent,solid solute
(c) liquid solute, solid solute
(d) liquid solute,solid solvent
0.004 M Na2SO4 is isotonic with 0.01M glucose.
Degree of dissociation of Na2SO4 is (JEE-2004)
(a) 75%
(b) 50%
(c) 25%
(d) 85%

(a) -2.3x10-2
(b) -5.7x10-2
(c) -5.7x10-3
(d)
-1.2x10-2

1.

2.

3.

4.
5.

SOLID STATE
A binary solid (A+ B-)
has zinc blende structure with B - ions
constituting the lattice and A+ ions occupying
25% tetrahedral holes. The formula of solid is
(a) AB
(b) A2B
(c) AB2
(d) AB4
In a metal oxide, the oxide ions are arranged
in hexagonal close packing and metal ions
occupy two third of the octahedral voids. The
formula of the oxide is
(a) Mo
(b) M2O3
(c) Mo2
(d) M2O
The empty space in hexagonal close packing
pattern is
(a) 48%
(b) 52.4
%(c) 26%
(d) 70%
Which of the following crystallizes in bcc
structure?
(a) ZnS
(b) Na2S (b) NaCl
(d) CsCl
Doping of silicon with P or Al increasing the
conductivity. The difference in the two cases is
(a) P is non metal whereas Al is a metal
(b) P is a poor conductor while Al is conductor
(c) P gives rise to extra electrons while Al
gives rise to holes
(d) P gives rise to holes while Al gives rise to
extra electrons

ENDEAVOUR CLASSES_CHEMISTRY

CONCEPTUAL QUESTIONS
6. In the laboratory, sodium chloride is made by
(c) Frenkel defect
burning sodium in the atmosphere of chlorine.
(d) None of these
The salt obtained is yellow in colour. The 16.
To get n type doped
cause of yellow colour is due to
Semi conductor, impurity to be added to
(a) Presence of Na+ ions in the crystal
silicon should have the following number of
lattice
valence electrons
(a) 2
(b) 5
(b) Presence of Cl- ions in the crystal
(c) 3
(d)
lattice
1
17.
Super conductors are derived from
(c) Presence of electrons in the crystal
compounds of
lattice
(a) p block
(b) Lanthanides
(c) Actinides
(d) Transition elements
(d) Presence of faced centred cubic crystal
18.
At
zero
Kelvin,
most
of the ionic crystals
lattice
possess
(a) Frenkel defect
(b) Schottky defect
7. The C C and Si C interatomic distances
(c)
Metal
excess
defect
are 154 pm and 188 pm. The atomic radius
(d) No defect
of Si is
(a) 77 pm (b) 94 pm (c) 114 pm (d) 111 19. Non stoichiometric metal deficiency is
shown in the salts of
pm
(a) All metals
(b) Alkali metals
8. ZnO is white when cold and yellow when
(c)
Alkaline
earth
metals
heated, it is due to the development of
(d) Transition metal
(a) Frenkel defect
(b) Schottky defect
20. Silicon doped with arsenic is
(c) Metal
excess
defect
(a) p type Semiconductor
(b) n type
(d) Metal
deficiency
Semiconductor
(c)
Like
a
metallic
conductor
defect
(d)
an
insulator
9. A mineral having the formula AB2 crystallizes
in the cubic close packed lattice, with the A 21. In a normal spinel type structure ,the oxide
ions are arranged in ccp whereas 1/8
atom occupying the lattice points. The Co
tetrahedral holes are occupied by Zn2+ and
ordination number of B atoms and the
50% of octahedral holes are occupied by Fe 3+
fraction of the tetrahedral sites occupied by
ions . The formula of the compound is
B atoms are
(a) Zn2Fe2O4
(b) ZnFe2O3
(a) 4,100%
(b) 6,75%
(c) ZnFe2O4
(d) Zn2Fe2O2
(c) 1, 25%
(d) 6,50%
10. How many unit cells are present in a cube 22. In a face centred cubic arrangement of A and
B atoms in which A atoms are at the corners
shaped ideal crystal of NaCl of mass 1.00 g?
21
21
of the unit cell and B atoms at the face
(a) 5.1410
(b) 1.2810
21
21
centres, one of the A atoms is missing from
(c) 1.7110
(d) 2.5710
one corner in unit cell. The simplest formula
11 If the coordination no. of an element in its
of compound is
crystal lattice is 8, then packing is
(a) A7B3
(b) AB3
(a) fcc
(b) hcp
(c)
A
B
(d) A7/8B3
7 24
(c) bcc
(d) none of the above
12.
In a hexagonal closest 23. A compound formed by elements A and B
crystallises in cubic structure, in which atoms
packing in two layers one above the other,
of A are at the corners while that of B are at
the coordination number of each sphere will
the face centre. The formula of the
be
compound is(a) 4
(b) 6
(a) AB3
(b) AB
(c) 8
(d) 9
13 . The number of molecules in a unit cell of
(c) A3B
(d) None of these
fluorite is
(a) 2
(b) 4
24. Na atom crystallises in bcc lattice with cell
(c) 6
(d) 8
edge (a) = 4.29A The radius of Na atom is
14. 4:4 Co ordination is found in
(a) 18.6A
(b) 1.86A
(a) ZnS
(b) CuCl
(c) 1.86 pm
(d) 1.860 pm
(c) AgI
(d) Au
25. CaO and NaCl have the same crystal
15 When NaCl is doped with MgCl 2, the nature
structure and nearly the same ionic radii. If x
of defect produced is
is the lattice energy of NaCl, the lattice
(a) Interstitial defect
energy of CaO is very nearly :
(b) Schottky defect
(a) 2 x
(b) x
(c) 4x
(d) x / 2
ENDEAVOUR CLASSES_CHEMISTRY

CONCEPTUAL QUESTIONS
26. Iron crystalizes in a bcc system with a lattice
30.
In closest packing of
parameter of 2.861 A. Calculate the density
atoms
of Iron in it (at wt. of iron = 56, NA = 6.02 x
(a) The size of tetrahedral void is greater
1023 per mole)
than that of the octahedral void.
(a) 7.92 g/ml
(b) 8.96 gm/ml
(b) The size of the tetrahedral void is smaller
(c) 2.78 gm/ml (d) 6.72 gm/ml.
than that of the octahedral void.
27. A metal crystalizes in 2 cubic phases i.e., fcc
(c) The size of tetrahedral void is equal to
and bcc whose unit cell lengths are 3.5A
that of the octahedral void.
and 3.0A respectively. The ratio of their
(d) The size of tetrahedral void may be larger
densities is
or smaller or equal to that of the octahedral
(a) 3.12
(b) 2.04
void depending upon the size of atoms.
(c) 1.46
(d) 0.72
28. The vacant space in bcc lattice unit cell is
about
(a) 32%
(b) 10%
(c) 23%
(d) 46%
29. A binary solid has a rock salt structure. If the
edge length is 400 pm, and radius of cation
is 75 pm the radius of anion is
(a) 100 mm
(b) 125 pm
(c) 250 pm
(d) 325 pm

SOLID
1 C

ENDEAVOUR CLASSES_CHEMISTRY