Vidyamandir Classes

Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[CHEMISTRY]
1.(A)

Covalent bonds are formed by orbital overlapping. It must take place is some direction.
Ionic bonds are electrostatic attraction in the lattice, which can be in any direction

2.(D)

[H ]

3.(A)

I3 linear

104
4 log 2 4.3

106 10 4 104
:
2
2

Hence pH = log

XeF2 linear
V2
25
2
V1 + V2 = 30
V2 = 10
V1 = 20
V1

4.(C)

V1 = Volume of NaOH in mixture.

V2 = volume of HCl in mixture.

Moles of NaOH in 25 ml = 20

1
2 m moles
10

Moles in 500 ml = 40 m moles

gms = 1.6 gm
5.(B)

LiCl, RbCl, BeCl2, MgCl2

Least ionic BeCl2
Most ionic RbCl

FAJANS RULE

6.(D)

C5 H12 O

7.(B)

4 O 1 4

3 O 2 2

COCl CN CHO OH NH 2

8.(D)

9.(A)
10.(B)

NH 4 OH HCl
1/3rd neutralization
Salt = 1/3
Base = 2/3

pOH pK b log

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1
= 4.7 log
2
p(OH) = 4.4
pH = 9.6

Test Series-2/ACEG/Paper-1

Vidyamandir Classes
11.(D)

II, III are chain isomers

I, II are chain isomers
I, III are position isomers
12.(C)

2BCl3 3H 2

2B

6HCl

For 21.6 g B 2 moles

3 moles H2 will be consumed 67.2L
13.(D)

n He

n SO2

MSO2
M HE

16 4

mSO2
m He
4
4
64
3 64

mSO2 12g
4
4
14.(D)

C rms ) He
T M
T 16
1 . 2 1
1
Crms )CH4
T2 M1
4 600

600
150 K
4
5
15.(A) (i)
C2 H 2 O2
2
1
(ii)
C(g) O(g)
2
1
(iii)
H 2(g) O 2(g)
2
We have to calculate

T1

123C
H 1300

2CO
2 H 2 O( l )

H 394

CO2 (g)

H 286

H 2 O( l )

2C(s) H 2(g)

C2 H 2(g)

2(ii) (iii) (i) gives us the desired reaction

2(394) 286 (1300) 226 .
1
O 2(g)
H 2 O(g)
2
1
H (H H) (O O) (2 O H)
2
1

x = 464 KJ/mole.
249 433 492 2 x
2
17.(D) pH is maximum when (H+) is least.
CH3COONa is basic salt
Hence pH is max.
[salt]
18.(C) pH pKa log
[acid]
16.(A)

H 2(g)

On dilution [salt] and [acid] remains the same.

Hence pH remains the same (neglecting minor changes)
H
Z
n
z
H

19.(C) 2.18 106

Z
1
2
2
n
Li

1
1 n
3

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Li

n3

Test Series-2/ACEG/Paper-1

Vidyamandir Classes
20.(A) Equivalent weight =

M
98

98
n factor 1

21.(C) 3 lone pairs around I

22.(C) After balancing

2 moles of K 3 [Fe(CN) 6 ] 1 mole of H 2 O2
Hence 4.5 moles of H2O2 will consume 9 moles of K3[Fe(CN)6]
23.(B) MgSO4
Assume density of water = 1 Kg/lt.
So 106 ml = 103 kg
Hence 6 gm of MgSO4 in 103kg of water

24.(D)

6
10 gm of CaCO2 in 103 kg of water
120
O
O
O
||
||
||
Br 6, 4
O Br Br Br O
||
||
||
O
O
O
Br3O8

5 gm in 103 kg of water

25.(C)
26.(B)

PV Pb RT
PV = Pb + RT
R
(Compare with y = mx + c)
V Tb
P
R
0.0821

2
slope
P 0.04105

27.(B)
sp2 sp2 sp2 sp2 sp
28.(C) For 100 KW reactor
105 J/s
In one second
105J will be used.
100 1.6 10 19 J produces one molecule.
Molecules of H2 produced =
Moles =

1022
1.6 6.023 1023

1 105
100 1.6 10

19

1022
1.6

: 102 moles

Hence volume of H 2 102 22.4 lt

: 224 ml
29.(A)

30.(A) Statement 1 is correct

Statement 2 is also correct and reason also.

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Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[PHYSICS]
31.(D)
33.(C)

32.(B) Total distance = (5 1) + (10 1) + (15 1) = 30 m.

y x tan

gn 2
2

2u cos

10 3
1
1
3
2

2
2u 3 / 4
3

1
u2

1
40

40 m / s

34.(C) Components of the velocities of the block along the strings are equal

V1 cos 1 V2 cos 2
35.(B) Let T1 and T2 are tensions in AB and BC
At B:

T1

At C:

T2

36.(C)

T2

T2

mg

Mg
T1 cos Mg T2 cos

2T2 cos mg

and

T1 sin T2 sin

13

2T2

T2

13 mg
10

4
mg
3 13mg 12
T1 Mg
and T1

5
2
5
10
13

8mg
mg
Mg
5
2

37.(C)

3T1 6mg

5
5
38.(A)

T1 2m

11m
8 1
M m
10
5 2

39.(B) To lift the block 2 kg, tension in the string is 2 g = 20 N

Let x: elongation in the spring for which the tension is 20 N.

kx = T

40x = 20

x = 0.5 m

For 5 kg: loss in GPE = gain in KE + gain in EPE

1
1
5 V 2 40 0.5 2
2
2

5 10 0.5

v 2 2 m/ s
40.(B) Minimum horizontal force required to apply on 4 kg block to slide it on 5 kg block
4
= 4 5 10 0.25 18 N .
5
6
2 / 3 m / s2
45

For F = 6 kg both are blocks are moving together with same acceleration a

Force of static friction f = 5a = 10/3 N.

Displacement of the slab in the given interval
1
= 5 2 / 3 32 2 2 5 / 3m
work done = f s = 10/3 5/3 = 50/9 = 5.55 J
2

41.(A) Let B falls by x then elongation in the spring is 2x, loss in GPE of B = gain in EPE of spring
1
mg
2

mg x k 2 x

x
2
2k

42.(D) Velocity is maximum when net force (on both the blocks) is zero.
Let T: tension in the string connecting A & x, elongation in spring at this instant

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mg

2k
loss in GPE of A = gain in KE of A & B + gain in EPE

mg

m2 g 2 5 2 m2 g 2
mv
4k
8
8k

mg = 2T and T = kx1

1 2 1 v
mg
2 mv 2 m 2
4k

1 mg
k

2 2k

block B falls by x1/2

V: velocity of A

velocity of B = V/2

mg 2
5k

vg

m
5k

43.(A) Let : angular velocity of rod just before impact & V: velocity of ball just after impact
V e l .

About axis L 0

l
e l
3

e = 1/3

44.(C)

m l 2
mvl
3

T f mg sin
N mg cos

mg sin

mg cos

45.(D)

mg sin

2
g sin
3

2
4
10 16 / 3 m / s 2
3
5

3 l

Ans. (C)

3 / 2 ml 2 .

Acceleration of point 1 = acceleration of point 2

2 4 2

4m/s2
1

48.(D) Frictional torque on the ring is

md
g R mg R
2

mg R

g / R .
mR 2
0
g
0
t
2
R

49.(C) About the triangular edge 16l 1 ml 2

P0 V0

3 rad / s

2m/s2

Angular retardation =

Ans. (D)

50.(B)

2/3

1
mR 2
2
a R

ml 2
ml 2 ml 2

3
3
12

PV nRT

tan
2

TR

mg cos

f i t

mg sin T ma

TR = fR

47.(C)

mg sin
mg cos
2

And to avoid sliding f N

46.(D)

About centre of mass:

mg sin
f
2

1 V0

V0

3
3P V
Tr . KE n R T 0 0
2
4

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RT

l 1 4l 2

and

0 R
2g

RT

m = 8 kg

P0V0
2

Test Series-2/ACEG/Paper-1

Vidyamandir Classes
51.(D)

Q1 2 W1 2 60 J ; U1 2 0
Q2 3 U 2 3 40 J
U1 2 U 2 3 U 3 1 0

52.(A)
53.(C)
54.(C)

7
22
8
P 3 103

8.31 300

32 28 44
T = constant.
T
AT 4
for edge length l
t
T
l 3S
6 l 2T 4
t
1
1
1
T
1

in first case
in second case

100
t 2
t
l
PV n R T

55.(B)
56.(C)

0 40 U 3 1 0

H yz H zx
80

KA 40 2

58.(A)

L dt

59.(A)

t 200 sec

120
49.7oC
2 1

P T isochoric with increasing pressure.

2l

57.(B)

P = 8.31 105 N/m2

KA 40

2 40

mg u x t dt

U 3 1 40 J

mg u cos t 2
; parabola passing through origin opening upwards.
2

ycm

yd m
d m

R cos

m d
2

R sin

m
Work done = inc. in GPE
R sin
= mg ycm 2 R g
= 2 R 2 g sin

60.(C) Net acceleration is vector addition of tangential & radian acceleration.

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Solutions to Test Series - 2/Paper - 1/IITJEE - 2014

[MATHEMATICS]
61.(D)
62.(C) Equality holds if f x g x 0
x , 1 2,

63.(A)

u 2 2u 2 0 u 1 i

x n x n

64.(C)

65.(A)

cot 1 1 i

cot 1 x

cos i sin n cos i sin n

sin n 2i
2i sin n
sin n 2i
sin n
sin n

1 i 5 1

3i

2i 3 i

5
4

n 2 n 1

19


2 6
12

principal argument is

i

2 2

n2 n 2

2i . 2

argument =

Tn

n
cot 1 1 i

2i

5
12
, n = 3, 4, 5, . . .

1 1
1

3 n 1 n 2

Tn 3

n 3

1 1 1
1 1 1
1 1 1 1 1 1

2 5
3 5 8
3 3 6 3 4 7

: :

. .......

1 1 1 1
S
3 2 3 4
1 6 4 3
13

3
12
36
66.(A)

2 3

3 1
3
3 5 6 3 10 2 2 3 3 1 3 1
3 1
3 1 3 1 2 3

1
So sum
1
1 3 1 2 3

2 2 3 42 3

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Vidyamandir Classes
67.(D) We have, a b cos 2 x c sin 2 x 0 for all x
a b c 2b sin 2 x 0 for all x

a b 0 and c 2b 0

a b and c 2b

Thus, the triplets are b, b, 2b , where b R .

Hence, there are infinitely many triplets.
68.(B) Line y x 1 0 is equally inclined to axes as slope is 1. As y x 1 0 is equidistant from the points

1, 2

and (3, 4),

4 2

69.(B) The lines PQ and PR will be inclined at an angle of 45 with the line 2 x y 3 .

m2
1
m ,3
1 2m
3

1
x 2 and y 1 3 x 2
3
Find the equation of pair of lines by multiplying these two equations.
Therefore, the lines are y 1

70.(A)

r 4 C1C3
r 10 C2 C3
2r 14 C1C2 10 4 14

r 14

Now,

PC3 x 14 8 6

l 2 r 2 x 2 142 62 160

l 4 10

2l 8 10

x 10

71.(B)

lim

1
3 x
x 2

x 5 tan

72.(A)

lim

7 x 8

x 5 tan
3x 2 7
2
x
x3 7 x 8

x 2 tan

2
lim

3 7
x2
1
3 7

tan
3
2
x 2

x
1
x x3

x x
lim

7
8
7
8
x

1 2 3
1 2 3
x
x
x
x

lim

sin x

x0

1 sin x ln 1 sin 2 x
.
sin x
x tan1 x

ln 2 lim

x0

sin x
tan

. lim

ln 1 sin 2 x
x

x0

ln 2 lim

x0

ln 1 sin 2 x 2 sin 2 x
sin x
x
.
. lim
.

1
x
sin 2 x
2x
tan x x 0

2 ln 2 ln 4

73.(B)

x
1 tan x

f x
0

1 tan x
So,
i.e.,

, if x 0
, if x 0
, if x 0

lim f x f 0 lim f x

x 0

x 0

f (x) is continuous at x = 0.

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Vidyamandir Classes

1 tan x x sec 2 x

1 tan x 2
1 tan x 1 x sec 2 x

f x

Now,

1 tan x 2

, if x 0

, if x 0

1 1 0 1 and f 0 11 0 1

f 0

So,

f x is not differentiable at x = 0.

74.(A) Let f x x 2a x a 4
x 2 3a 4 x 2a a 4

f x 0 for all 1 x 1 if f x 0 has two distinct real roots and f 1 and f 1 are negative.
D 3a 4 4 1 2a a 4 0
2

f 1 1 3a 4 1 2a a 4 0
2

f 1 1 3a 4 1 2a a 4 0
2

and

These conditions give

1
75.(C)

1
2

1
a3
2

.....

1
2
3
1

1
1
1
b
2 2 .....
12
3
5

1
2

.....

5
1
1
2 2
1
3
1

1
1
1

2 2 2 .....
2

4
6
1

2 .....

1
1

2 2 .....

2
1 1
1
a

2
3
1

= 1 2
1
1

4
b
2 1
2 2 2 .....

1
3
5

a
b

4
3

76.(D) Given that cos 1 x cos 1 y cos 1 z

cos 1 x cos 1 y cos 1 z

cos 1 xy 1 x 2 1 y 2 cos 1 z

xy z

1 x 1 y
2

Squaring both sides, we get : x 2 y 2 z 2 2 xyz 1

Trick : Put x y z
77.(A) Put

1
1
1
1
so that cos 1 cos 1 cos 1
2
2
2
2

x cos
1
2

1
2

cos 1

1 x 2
cos 1 cos cos 45 sin sin 45
2

cos 1 cos 45 45

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12

cos 1

So,

1 x 2

cos 1 x

2
4

1
4

tan

78.(B) Graph of | f | x| | x 1, 0 0, 1

79.(D)

graph of [ | g (x) |] is :

range of is {0, 1}
2r 1

Tr

r 1

Sn

1
r

r 1 2

where Vr

r 1

41

1 S40

lim

Let

g x ax b

For

x 0, f x e

r2

x 0

f 0 g 0 1

41 1681

lim sin x ln |x|

f 0 lim | x |sin x e x 0

S40 1

r 1 2 r 2
2
r 2 r 1

Tr Vr Vr 1 1 n 1 2 ,
r 1

80.(B)

Graph of g (x) = | f | x|| | f x | is :

Graph of | f x | x 1, 0 0, 1

and

ln |x|

x 0 cosec x

[Apply L.H. rule]

(As f (x) is continuous)

b 1 g x ax 1

sin x ln |x|

f 1 1 0 sin1 sin1

cos xln | x |

sin x

f 1 a 1 a 1 sin1

g x 1 sin1 x 1
81.(C)

1
1

...
3 32
9

y
z

1/ 3
11 / 3

1
1

...
3 32
4

wr

where w

r 1

1
1 i

w
z
as
1 w
x yz 3

1 / 3
11 / 3

1
|w|
1
2

1
1
1i
i
z=
1
i
1
1i

2i

2
1
Its argument is tan

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Vidyamandir Classes
82.(C)

2008

f 3 3

3 r 3 r
2008

r 1

2008

3 r 3 r

Q 3 r 3 r .

2008

r 1

3 0 3

f 1 x g x

83.(B) Q

84.(A)

f g x g x 1

g x

n
1
1 g x
f g x

2 sin 2 A 2 B cos 2 A
2 sin 2 A cos 2 A

f g x x

sin 2 A 2 B

sin 2 A

3
1

sin 2 A B B 3 sin 2 A B B

sin 2 A B cos B cos 2 A B sin B 3 sin 2 A B cos B 3 cos 2 A B sin B

4 cos 2 A B sin B 2 sin 2 A B cos B

85.(B) Let

tan 2 A B 2 tan B

f x ax 2 bx c
g x 2a 2ax b ax 2 bx c

Determinant

b 2a 4a b c 2a
2

b2 4a 2 4ab 4ab 4ac 8a 2

b2 4ac 4a 2
But for f x , f x 0 x R

b2 4ac 0, a 0

So determinant < 0, a > 0 for g (x)

Hence g x 0 x R

86.(A) Given O(0, 0) is the orthocenter. Let A(h, k) be the third vertex, B 2, 3 ,
and C 5, 1 the other two vertices. Then the slope of the line through
4
. By the
7
property of the orthocenter, these two lines must be perpendicular, so we
have
A and O is k/h, while the line through B and C has the slope

Also,

k 7
k
4
h 7 1 h 4

k 3
Slope of AB
h2
1
Slope of OC
5
1 k 3
AB OC

1
5 h2
5h k 13 0

. . . .(i)

. . . .(ii)

Solving it with (i) we get :

h 4 , k 7
87.(B)

cot cot 0 tan tan 0 i.e. m 1 + m 2 = 0

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Vidyamandir Classes
where m1 and m 2 are the slopes of the tangents from P(h, k).

If y mx a 1 m 2 is a tangent from P(h, k) then k mh a 2 1 m2

2

i.e.

a 2 m2 2hkm k 2 a 2 0

m1 and m2 are the roots of this equations such that m1 + m2 = 0

2hk
0
i.e.
locus of P(h, k) is xy = 0
2
h a2
88.(B)

0 x 2 x 1 1 and

x 1, 0

For

x 1

0 x2 x 1

L.H.S. 2 sin 1 1 cos 1 0

3
2

x 1 is a solution

For x = 0 L.H.S. 2 sin 1 1 cos 1 0

3
2

x = 0 is a solution
sum of the solutions = 1

b ic

1 a
1 iz

1 iz
b ic
1 i

1 a
1 a c ib

1 a c ib
1 i

89.(A)

90.(C)

1 a c ib 1 a c ib
1 a c 2 b2

Q a 2 b 2 c 2 1

1 2a a 2 b 2 c 2 2ib 2iab
1 a 2 c 2 b 2 2ac 2 a c

a a 2 ib iab
1 ac a c

a ib
c 1

2a 2a 2 2ib 2iab
2 2ac 2 a c

1
log3 k , k l
x
1
log3 k x 3 k
x
Possible values of k are 1, 0 , 1, 2 , 3, . . . .
1
1 1

2 3 . . . .
3
3 3

S 3 1
4

1 3
1 1 3

1 9

2 2

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