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454U1

Chemistry
Paper

November
2012

hour

FINAL SEMESTER 2 EXAMINATION 2012


MAKTAB RENDAH SAINS MARA
FORM 4

CIIEMISTRY
PAPER I

I hour 15 minutes

DO NOT OPEN THIS BOOKLET UNTIL BEING TOLD TO DO SO

This question paper consists of 50 questions.

2. Answer all questions3. Answer each question by blackening the correct space on the answer shest'
4. Blacken only one sPace'
5. If you wish to change your answer, erase the blackened mark that you have made'
Then blacken the space for the new answer'

6.
7.

The diagram in the questions provided is not drawn to scale unless stated'

You may use a non-progwrmmable scientific calculator'

This question paper consists


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Question

Lo

Question 50

choose the best option


answer sheet.

for

four options +.B,C orD'


each qlestion and blackened the corresponding sPace on the obiective

are

followed

by

which of the following scientists is involved in the development of the Periodic Table?

l.

A
B
C
D
2.

John Dalton
James Chadwick

Henry J.G. MoseleY

Group l8 elements are known as

A
B
C
D
3.

Neils Bohr

halogens
noble gases

alkali metals
transition metals

Which ofthe following elements are in Group l? in the Periodic Table of Elements?

A
B
C
D

454lll

Fluorine and bromine


Chlorine and xenon
Bromine and neon
Fluorine and helium

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4.

is true?
Metal of Group I elements react with water' Which statement

A
B
C
D

the metals react vigorously

The reaction Produoes white flame

Solution produced turns red litmus paper to blue


The gas released ignites a burning wooden splinter

across Period 3?
Which statements are true about the properties of elements

5.

I
Il
III
IV
A
B
C
.D

Metallic ProPerties decreases


EleotropositivitY increases
Proton number increases

Atomic size decreases

I and Il

II

and

III

I, III, and IV

II, III, and IV

During the formation of ionic bonds, the atoms ofelements

6.

A
B
C
D
7.

All

transfer electrons
donate electrons
accept electrons
share electrons

Which substance.is a covalent compoun$l

A
B
C
D

454lll

HYdrogen chloride
Magnesium oxide
Sodium chloride

Lithium oxide

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8.

Which statement describes a covalent bond?

A
B
C
D
9.

Van der Waals forces between non metal atoms


Transfer ofelectron between metal and non metal atom

Metal atom donate electron to achieve a stable electron arrangement


Non metal atoms share electron to achieve a stable electron arrangement

Diagram 1 shows the formation ofa compound.


Calcium chloride
Diagram I
Which of the following compound has the same type of bond as the compound formed in
Diagram l?

A
B
C
D

Sulphur dioxide
Carbon disulphide

Hydrogen chtoride
Potassium sulphide

10. Which statement explains why a covalent compound

A
B
C
D
I

Insoluble in water
Ions present are not free
Consist of neutral molecules

Insoluble in organic solvents

l. Which of rhe following

A
B
C
D

454ill

@ 2012

d&s not conduct electricity?

substance is an electrolyte?

Chlorine gas, Cl2

Hydrochloric acid, HCI


Carbon tetrachloride, CClr
Phosphorus pentachloride, PCls

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12. Which

ofthe following ions are present in copper(Il) sulphate solution?

A
B
C
D

Cul* and H* ions


Cu2* and So+2- ions
Cu2*, so+z- and H" ions

cu?*, soq2-, H* and

olf

ions

13. Diagram 2 shows the apparatus set-up for the electrolysis

of t '0 mot

dm-3

silver nitrate solution.

.0 mol dm-3 silver nitrate solution

Diagram 2
'i

Which of the following are the ions that attracted to anode?

A
B
C
D

Ag* ions
NOs- ions

Ag* and Ff ions


NO3- and OH- ions

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14. Diagram 3 shows the apparatus set-up

ofa voltaic cell that is made up of iron and zinc

as

the electrodes.

Zinc
0.1 mol dm-r

0.1 mol dm-3

iron(ll) nitrate solution

zinc nitrate solution

Salt bridge

Diagram 3

What is the direction of the electron flow in the cell?

A
B
C
D

From zinc to iron electrode through salt bridge

From iron to zinc electrode through salt bridge


From zinc to iron electrode through extemal circuit
From iron to zinc electrods tfuough external circuit

15. Diagram 4 shows the apparatus set-up

ofa voltaic celt that

is made up ofmagnesium and

metal X as the electrodes.

Magnesium

MCTAI

Dilute hydrochloric acid


Diagram 4

Which of the following metal gives the highest voltage reading?

4541 /

Iron

Silver

Copper

Aluminium

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7
properties?
16. Which particle enables acids to show its

A
B
C
D

Hydroxide ion
HYdrogen ion
HYdrogen atom
HYdrogen molecule

17. Which of t}le

A
B
C
D

red to blue?
following gases will change damp litmus paper from

OxYgen

Ammonia
Carbon dioxide
HYdrogen chloride

following are strong acids?

18. Which of the

-l

19.

I
II
III
IV

HYdrochloric acid

A
B
C
D

I and

SulPhuric acid
Ethanoic acid

Nitric acid

lI

Il

and

III

I, II and IV

II, III and IV

A student is stung by an insect with an alkaline sting'


Whi.h substancels iuitable to treat tlie student?

A
B
C
D

4541/l

Vinegar
Detergent
ToothPaste

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Baking soda

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20. Table

shows the pH values

offour solutions with the same concentration'


pH value

Solution
P

1.0

2.0

4.5
6.5

Table I
Which solution has the lowest concentration ofhydrogen ions?

AP
BQ
CR
DS
21. Which substance is used by farmers to remove excess acidity in the soil?

A
B
C
D

Calcium nitrate
Calcium chloride

Calcium sulphate
Calcium hydroxide

22. Which substance is a soluble salt?

A
B
C
D

Silver chloride

Zinc carbonate
Sodium nikate

Barium sulphate

23. Which salt is prepared through precipitation?

A
B
C
D

'

4541/l

Lead(II) iodide
Barium chloride
Potassium iodide

Ammonium chloride

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acid?
24. Which salt can be prepared by reacting a metal with a dilute

A
B
C
D

Silver nitrate

Lead(ll) nitrate
CoPPer(II) sulPhate
Magnesium sulPhate

reactions?
25. Which ofthe foltowing reactions represent double decomposition

PbSOq

BaSOa

Pb(NOr, + NazSO+

IV

Ba(NO:): + Na2SO4

A
B
C
D

I and III

26. Th"

+ 2NaNO:
BaClz + 2KNO3

)
Ba(NOr2 + 2KCl )

I
II

II

and

+ 2NaNG

III

l, III and IV

ll, III

and

IV

follo*ing chemical equation

where a
shows a reaction between sodium and oxygen

and c are integers.

,rNa+G,
What are the values

ofa,

) d--l

c and the formula

ofthe product obtained?

Formula of Pr9d-uct

Na2O

NazO

.,

NaOz

NaOz

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Which of the
the Poriodic Table of Elernents'
27. Diagrarn Sshows six transition elements in
follJwing is true about the elemene?

Diagram 5

Low densitY

Loli mehing Point

High solubilitY in water

High tensile strngth

ofan element'
28. The following statements describe the characteristics
brown in oolour
Aqueous solution ofan ion are green or

'
.
.

Act as a catalyst in the production of ammonta


Has Nvo oxidation numbers' +2 and+3'

Which of the follorving is the element?

Platinum

Nickel

Iron

29, Diagram 6 shows the electron anangellent of element X and Y. Which of the bonding
type and formula is true for compound for.med bctween the two elements?

Diagram 5

Formula

Bonding'tYPe

XY

ionic bond

XYz

.ionic bond

XY

XYz

covalent bond
covalent bond

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l2

'

30. Table 2 shows the proton number

offour elements'

Element

Proton number
3

Lithium

t2

Magnesium

t9

.Potassium

20

Calcium

Table 2

Atom Y has 3 shells occupied with electrons. Element Y reacts with chlorine to form
compound T which has strong electrostatic forces.
Which of the following shows element Y and the chemical formula of T?

CompoundT

Element Y

A
B
'C
D

Lithium

YCI

Calcium

YCIu

Magaesium

YC12

Potassium

YCI

3l . The following statements are some information about the compound formed between
element P and Q.

o
.
.

Dissolve in water
High melting point
Solid at room temperature

Which is true about element P and Q?

A
B
C
D

P is a metal element and Q is a non melal element


P and Q have equal number of electrons

Both P and Q are non - metal elements


Both P and Q share electrons

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IJ

electrolysis of aluminium oxide' AlzOr'


32. Diagrarn 7 shows apparatus set-up of

Molten lead(Il) oxide

Diagram 7
and cathode of this process?
Which ofthe fotlowing is the halfequation at anode

pb2* + 2e --+ Pb
pbz* + 2e --r Pb
Pbz" + 2e

'-,

Pb

33. Diagram 8 shows apparatus set-up for electrolysis

of0'l

mol din-3 sodium nitrate solution

using Platinum electrodes'

0.1 mol dm-3 sodium nitrate solution

Diagram 8
selected discharged at anode and
Which of the following pairs of ions that will be
cathode?

Anode

Cathode

No:-

Na'

oH-

oH-

NOr-

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=--

Na'

H'

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t4
copper(Il) sulphate solution using copper
34. Diagram 9 shows electrolysis of 0'1 mol dm-3
electrodes-

Copper ele.trode

0.1 mol dm-3


copper(Il) sulPhate solution

Diagram 9
after 30 minutes?
Which of the following will be observed at anode

Brown solid dePosited


B

Electrode becomes thinner

Electrode becomes thicker

Colourless gas bubbles released

for electroplating an iron key with silver'


35. Diagram I 0 shows the apparatus set-up

Iron key

Diagram l0
What is X?

A
B
C
D

Silver nitrate

Iron(II) nitrate
silver chloride

Iron(III) chloride

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36. Diagram I

shows the apparatus set-uP

ofa voltaic cell with magnesium

and copper as

the electrodes.

CopPer

Magnesium

Copper(Il) sulphate solution

Magnesium nitrate solution


Salt bridge

Diagram 1 I

Whichofthefollowingis.thehalfequationforthereactionatnegativeterminal?
A

M{'+2e"-Mg

Mg--- Mg2* + 2e

Cu2* + 2e

Cu --- Cul*+ 2e

--

Cu

produce gas bubbles?


37, Which ofthe following substances reacts with calcium carbonate to

Salt solution

Ethanol

Vinegar

Sugar solution

38. Table 3 shows the concentration and pH values

oftwo types ofacid'

Type of acid

Conc.ntration / mol dm-'

pH value

0.1

0.1

Table 3

Which statement is true about the acids?

A
B
C
D
4541/l

Mis

a weak acid,

Nis

a strong acid

Concentration ofhydrogen ion in Mis higher than tr/


The degree of dissociation ofacid 7f is higher than acid M

M ionises partially in water, N ionises completely in water

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for neutralisation reaction?


39. Which ofthese are suitable reactants

I
tl
III
IV

Sulphuric acid + sodium hydroxide


Hydrochloric acid + copper(Il) oxide

I and II

I and lV

II

III

Sulphuric acid + calcium carbonate

HYdrochloric acid + magnesium

and

lll

and

lV

a chemical reaction40. The word equation below represents

Dilute hydrochloric acid

Substance

'

Salt + water

carbon dioxide

What could substance W be?

A
B
C
D

Zinc sulphate
Zinc carbonate
CoPPe(Il) oxide
CoPPer(II) hYdroxide

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t7
41. Rubidium is below lithium in Group I elements'
What will happen when rubidium reacts with water?

A
B
C
D

Reaction produces less gas bubble


'

Reaction occurs more slowlY


Produces Yellow flame
Produces an exPlosion

nerjo{i1 fatt3 of
and element Y are located in Group I and Group 17 in tleis the chemrcal rormula or
Element respectively' X reacts with Y to form a compound' What

42. Element

the compound?

AXY
B x2Y
C XY2
D X2Y3
43. Table 4 shows the electron arrangeinents of four atoms'

Table 4
Arrange the elements in increasing order of electronegativity'

A
B
C
D

F, AI, CI,

F, CI, AI,

K, AI, CI, F
K, CI, AI, F

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l8
P' Q and R'
44. Table 5 shows the properties ofcompound

Compound

ProPerties

Soluble in water, does not conduct electricity

Soluble in water, conduct electricity in both


molten and aqueous state.

I tnsoluble in water, conduct electricity in


I
I molten state

Table

Which of the following represent P, Q and R?

I and II

I and III

II and IV
III and IV

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19

45- Diagram 12 shows f}le apparatus set-up

of eleotrolysis of concentrated

potassium chloride

solution.

Carbon elechodes

Concentrated
potassium chloride

solution

Diagram 12

What is the halfequation at cathode?

A K*+ e- ) K
B 2r{+2 > H2
C 2Cl' ) Clz+ 2eD 4OH- ) 2H2O + 02 +4e
46. What is the volume of distilled water required to be added to 25.0 cm3 of 0.5 mol dm-3
nitric acid in order to produce a solution of 0.1 mol dm-' ?

5.0 cm3

12.5 cm3

125-0 cm3

150.0 cm1

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z0
acid and potassium hydroxide solution
47.Diagraml3 shows the titration of hydrochloric

0.2 mol dm-3

hydrochloric acid

50 cm3 of

0.I mol

dm-3

of

potassium hYdroxide solution +


phenolphthalein

Diagram 13
needed to neutralize potassium hydroxide
What is the volume ofhydrochloric acid

A
B
C
D

25 cm3
50 cm3

75

cm3

100 cm3

48. Diagram 14 shows a chemical cell

Copper plate

Zinc plate
Zinc sulPhale solution

Coppe(II)
sulphate solution

Diagram 14

Whatisthechemicalreaotionthattakesplaceatthepositiveterminalofthechemical
cell?

A
B
C

D
454lll

ion
Coppr atom losss electron to form oopper(Il)
ion accpt electron to form copper atom

Copper(ll)

Zinc ion accept electron to form zinc atom


Zinc storn loses electron to form zinc ion
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2t

49. Table

6 shows information about three voltaic cells.

Pair of metals

Potential difference (Y)

Negative terminal

R and copper

0.44

S and copper

110

T and copper

0.53

Cu

Table 6
What is t}re potential differenbe for the pair of metal S and T?

A
B

0.97 V
2.14 V
2.23 Y
2.67 Y

50.

40 cm3 of 0.5 mol dm'3 nitric acid is added to 50 cm3 of 0.2 mol drr3 sodium hydroxide'
Calculate the mass ofthe salt formed in this reaction.
[Relative atomic mass: Na; 23, O; 16, N; 14, H;1]

A
B
C
D

0.85 g

l l2g
l.7O g
2.55 g

END OF QNESTION PAPER

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4541

Chemistry
Paper 213
November
2012
2 Yz hour

FINAL SEMESTER 2 EXAMINATION 2012


MAKfAB RENDAII SAINS MARA
FORM4

Section Question

CHEMISTRY
Paper 2

&

do Nor oppN TrrE eUESTIoN BooKLET


LINTIL BEING TOLD TO DO SO

L Write your name and oollege number in


. the space provided.

3.
4.
5.
6.

t2

12

12

12

20

20

Two hours and thifi minutes

2.

Full
mark

This question booklet consists of Section


A, B and C.
Answer atl question in Section A and C.
Answer any one question from Section B'
You may use a non-Programmable
sciEntific calculator.
The diagrams in the questions provided
are not dravr'n to scale unless stated.

l5
I

TOTAL

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t7
100

Marks

SULIT
Section
148

4541D

narksl

Answer all questions in this section.

Table I shows some elements in Period 3 in the Periodic Table of Elements.


Elernent

Sodium

Aluminium

11

l3

Proton number

Silicon Chlorine Argon

t4

l7

18

Table I
Based on Table 1, answer the following questions:

(a)

State one element which is

(D

metal

(iD

semi-metal

(iii)

non-metal

13

(b)

(c)

4541/2

marksl

Chlorine is in Group 17 in the Periodic Table. State the common name for
Group 17 elemerits.

11

nark)

ll

narkl

Write the electron arrangement of sodium atom.

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SULIT

4s41/2

-)

(d)

State the number of valence electron of argon atom'

(D

(iD

mark'l

ll

marhsl

12

marksl

In which group can you find argon in the Periodie Table?

Argon is chemically unreactive. Explain.

(iiD

(e)

fl

Which element forms an amphoteric oxide?

(D

(ii)

Write the chemical formula of the oxide of element in l(eXi)'

Il
(i

454112 @

ii)

Copti*tt

markl

State one chemical property ofthe oxide in

narkl

l(e)(ii).

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SULIT
2.
.

4541D

Diagram 2 shows the electron arrangement of compound J. Compound J is formed


from the reaction between element X and element Y. The letters used do not
represent the actual symbols of the elements.

-\2a -.+- \.
a\iit i ,.-.,. I t /-.,..-\

i{oiiltioiit

,l I \C./ i | \\o/./
j \-_ '-r- )
L

Dirgram2
Based on Diagram 2:
State how Y ion and

(a)

X ion are formed from their atoms.

Y ion:...........
X ion:...........
12 marksj

(b)

Write the electron arrangement for atom X and Y

Y:,..--....
12 marks"l

I-r(-lo1

(c)

(i)

State the type ofcompound for J,

[E

ll
(ir)

Write the chernical equation for the reaction between element


and element Y to form compound J.

mark.l

12 marks'l

(iii)

State two physical properties ofcompound J.

12 marks'l

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4541D

SULIT
(d)

Y exists as diatomic molecules. Draw the electron arrangement for


the molecule,

12 marksl

Name the type of bond in 2(d)(i)'


..,..............-..:,..,-.-..

U narkl

4541/2

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CONTIDENTIAL

SULIT
J.

4s4ll2

Diagram 3 shows the apparatus set-up for the electrolysis of 0.001 mol dm-3
hydrochloric acid solution using carbon electrodes X and Y'

Carbon electrode

Carbon electrode

0.001 mol dm-3


hydrochloric acid

Diagram

Based on Diagram 3, answer tlre following questions.

(u)

(D

(ii)

(iiD

What is meant by cation?

ll

nmkl

11

narkl

State all the ions present in hydrochloric acid solution.

Which electrode is the anode and cathode.


Electrode

X:

'....'.'.'....'....

Electrode Y:
12 marlcsl

(b)

(D

Name the gas formed at electrode X.

11

(iD

narkl

Write the half equation for the reaction that takes place at electrode

x.

ll

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markl

4541D

SULIT
(c)

acid
The electrolvsis is repeated by replacing 0.001 mol dm-3 hydrochloric
solution witlr 1.0 moi dmr hydrochloric acid solution'
trtrr'hat

will

be observed at the electrodes?

Electrode

X:

Electrode

Y:
12

(d)

narksl

ofthe usage ofelectrolysis is electroplating' A student intends to


electroplate anlron spoon with silver to make it more attractive'

One

Suggest the suitable substances as the:

Electrolyte
Anode
Cathode
13

(e)

narksl

Write the halfequation for the reaction that takes placeht cathode'

ll

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4541D

SULIT

Table 4 shows the pH values of solutions V, W, X, Y and Z with a concentration


of 2.0 mol dm-3.
Solution

pH value

l0

13

Table 4
Based on Table 4, answer the following questions.

(a)

State one solution which has the following properties:

(i)

Neutal:................

(ii)

Alkaline:
12

marksl

Identifu the solution which contains the highest concentration of the

(b)

following

ions:

(i)

Hydrogen ion

(ii)

Hydroxide ion:

12

(.)

marksl

Name an example of solution V.

U nark'l

(d)

Distilled water is added to 20.0 cm3 of solution Z to make 100-0 cm3 of


solution.
Calculate the new concentration ofsolution Z-

p
4541i2

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4541/2

SULIT
(e)

Diagram 4 shows the preparation ofsalt Q.

Magnesium
carbonate

.F.,",,;;l-.*F;l.m.E
Diagram 4

Answer the following questions based on Diagram 4.

(i)

Name salt Q.

State the

ll

mark)

lt

markl

13

marks]

solubility of salt Q.

,
Describe briefly how to prepare a solution of mlt Q from
magnesium carbonate.

4541f2

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CONr,IDENTIAL

4541D

10

SULIT

Section B
[20 rnarks]

Answer any one question from this section.

5.

(a)

Diagram 5.1 shows the electron arrangement of a molecule XY+. The


letters used do not represent the actual symbols ofthe elements'

@ @:
Diagram 5.1
Based on Diagram 5.1, write the electron arrangement for atom
elements X and Y.

(b)

of
l2 marksl

Table 5 shows the proton numbers ofelements P, Q, R and S.

Element

Proton Number

-,

Table 5

(D

(ii)

4541f2

Arrange elements Q, R and S in ascending order of atomic size.


Explain your answer.
14

narksl

16

narksl

The reaction between elements Q and S form a chemical


comPound.
Describe the formation ofthis compound'

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(c)

Metal X is
Diagram 52 shows 0rc ractiol betni'een metal X and watcr'
a Group 1 elemenl

Water
Diagrarr

52 -

using three named aramples ofGroup I elcments' desoribean


the rcactivity ofGroup I elements with
to in
"stigarc
"ip".i--*t
water.
of the
inlour des"ription include a batanced chemical equation for one
thrce reactions involved.

Bi

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6.

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Diagram 5.1 shox,s two containers ofchloride sah- The sahs can be preparcd
in the school laboratory.

Lchloride

M chloride

Diagram 6.1

(a)

(D

L chloride is soluble in water while M chloride is insoluble in


waterSuggest a name for L ohloride and M chloride

Vntksl

(iD

State suitabte chemicals for the PreParation for M ohloride in

dGXr).

\lhfte

a balanced chemical equation to rpresent the reaotion'

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13

(b)

Diagram 6.2 shows the wastewater from a textild-iactory. The water is


found to be contaminated with hydrochloric aoid.

Diagrara 6.2
Describe an experiment to determine the concentration ofa
hydrochloric acid solution using titration method. A standard solution
of 0.1 mol dm-3 sodium hydroxide is provided.

In your description show t}e following aspeots:

.
o
.
o
o

A list of materials and apparatus


Procedure of the experiment

A labeled didgram showing the apparatus

set-up

Table of result

All

the calculation steps involved

[4

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454112

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Section C
[32 marks]

For

Answer all questions from this section'

7.

to determine the
Diagram 7.1 shows the set-up of apprltul-for. an ?xPrlneT
p"tiriiJ al*"**e of an electroche#cal cell using zinc and copper as electrodas'

Copper

l-?W:-'=-!W::

.:#.{:j-#=
_-_-lrit_-_---_-_g----.

---'-E*:---':-fi:--.

After 30 minutes

-::-&----:---#-:_-----------_--------j

:;w;=t%
'-:--:-:-:::-::--1r--@::
.:---------_----------:-.

sulphate

solution

Diagam 7'l
i

(a)

State the observations that can be made from

this oxperiment after 30

min8es:
Description

Observation

Zinc elootode

Copper electrode

The copper(Il) zulPhate solution

l3 narks)

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The experiment is repeated by replacing copper with metals P and Q

as

electrodes.

'Diagram 7.2 shows the voltneter readings of all the experiments'


MetalP I Zinc

Zinc I Coppr

Reading: ........

Zino / Metal Q

Reading:

Reading:
Diagram 7.2

(b)

Record the voltmeter readings in the spaces provided in Diagram 7'2'

Il
(c)

Construct a table to .""orA tt voltmeter reading for the different pairs


"
of metal.

13

(d)

marksl

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Based-on the experiment, state the

(0

Manipulated variable

(iD

Responding variable

(iiD

Constant variable

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For

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(e)

454112

difference in this
State the operational definition for the potential
experiment.

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17

Diagram
solvents.

8 shows two test tubes containing glaoial ethanoic acid in different

Clacial
ethanoic acid

Glacial
ethanoic acid
in water

in dry
propanone

Diagram 8
Based on Diagram 8, plan a laboratory experiment to investigate the solvent that
is needed for glacial ethanoic acid to show its acidic properties.

Your planning should include the following aspects:

(a)

Problem statement

(b)

AII the variables

(c)

Statement ofthe hypotlresis

(d)

List of substances and apparatus

(e)

Procedure for the

(0

Tabulation ofdata

experiment

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END OFQI]ESTIONPAPER

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IIELAIAN JAWAPANFSEI

NO.SOALIN:

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