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Chemistry
Paper
November
2012
hour
CIIEMISTRY
PAPER I
I hour 15 minutes
2. Answer all questions3. Answer each question by blackening the correct space on the answer shest'
4. Blacken only one sPace'
5. If you wish to change your answer, erase the blackened mark that you have made'
Then blacken the space for the new answer'
6.
7.
The diagram in the questions provided is not drawn to scale unless stated'
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Question
Lo
Question 50
for
are
followed
by
which of the following scientists is involved in the development of the Periodic Table?
l.
A
B
C
D
2.
John Dalton
James Chadwick
A
B
C
D
3.
Neils Bohr
halogens
noble gases
alkali metals
transition metals
Which ofthe following elements are in Group l? in the Periodic Table of Elements?
A
B
C
D
454lll
CONFIDENTIAL
4.
is true?
Metal of Group I elements react with water' Which statement
A
B
C
D
across Period 3?
Which statements are true about the properties of elements
5.
I
Il
III
IV
A
B
C
.D
I and Il
II
and
III
I, III, and IV
6.
A
B
C
D
7.
All
transfer electrons
donate electrons
accept electrons
share electrons
A
B
C
D
454lll
HYdrogen chloride
Magnesium oxide
Sodium chloride
Lithium oxide
@ 2Ol2
Wglrt
Reserved MARA
CONFIDENTIAL
8.
A
B
C
D
9.
A
B
C
D
Sulphur dioxide
Carbon disulphide
Hydrogen chtoride
Potassium sulphide
A
B
C
D
I
Insoluble in water
Ions present are not free
Consist of neutral molecules
A
B
C
D
454ill
@ 2012
substance is an electrolyte?
CONFIDENTIAL
12. Which
A
B
C
D
olf
ions
of t '0 mot
dm-3
Diagram 2
'i
A
B
C
D
Ag* ions
NOs- ions
as
the electrodes.
Zinc
0.1 mol dm-r
Salt bridge
Diagram 3
A
B
C
D
Magnesium
MCTAI
4541 /
Iron
Silver
Copper
Aluminium
7
properties?
16. Which particle enables acids to show its
A
B
C
D
Hydroxide ion
HYdrogen ion
HYdrogen atom
HYdrogen molecule
A
B
C
D
red to blue?
following gases will change damp litmus paper from
OxYgen
Ammonia
Carbon dioxide
HYdrogen chloride
-l
19.
I
II
III
IV
HYdrochloric acid
A
B
C
D
I and
SulPhuric acid
Ethanoic acid
Nitric acid
lI
Il
and
III
I, II and IV
A
B
C
D
4541/l
Vinegar
Detergent
ToothPaste
@ 2012
Baking soda
CONFIDENTIAL
20. Table
Solution
P
1.0
2.0
4.5
6.5
Table I
Which solution has the lowest concentration ofhydrogen ions?
AP
BQ
CR
DS
21. Which substance is used by farmers to remove excess acidity in the soil?
A
B
C
D
Calcium nitrate
Calcium chloride
Calcium sulphate
Calcium hydroxide
A
B
C
D
Silver chloride
Zinc carbonate
Sodium nikate
Barium sulphate
A
B
C
D
'
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Lead(II) iodide
Barium chloride
Potassium iodide
Ammonium chloride
CONFIDENTIAL
acid?
24. Which salt can be prepared by reacting a metal with a dilute
A
B
C
D
Silver nitrate
Lead(ll) nitrate
CoPPer(II) sulPhate
Magnesium sulPhate
reactions?
25. Which ofthe foltowing reactions represent double decomposition
PbSOq
BaSOa
Pb(NOr, + NazSO+
IV
Ba(NO:): + Na2SO4
A
B
C
D
I and III
26. Th"
+ 2NaNO:
BaClz + 2KNO3
)
Ba(NOr2 + 2KCl )
I
II
II
and
+ 2NaNG
III
l, III and IV
ll, III
and
IV
where a
shows a reaction between sodium and oxygen
,rNa+G,
What are the values
ofa,
) d--l
Formula of Pr9d-uct
Na2O
NazO
.,
NaOz
NaOz
CONFIDENTIAL
Which of the
the Poriodic Table of Elernents'
27. Diagrarn Sshows six transition elements in
follJwing is true about the elemene?
Diagram 5
Low densitY
ofan element'
28. The following statements describe the characteristics
brown in oolour
Aqueous solution ofan ion are green or
'
.
.
Platinum
Nickel
Iron
29, Diagram 6 shows the electron anangellent of element X and Y. Which of the bonding
type and formula is true for compound for.med bctween the two elements?
Diagram 5
Formula
Bonding'tYPe
XY
ionic bond
XYz
.ionic bond
XY
XYz
covalent bond
covalent bond
l2
'
offour elements'
Element
Proton number
3
Lithium
t2
Magnesium
t9
.Potassium
20
Calcium
Table 2
Atom Y has 3 shells occupied with electrons. Element Y reacts with chlorine to form
compound T which has strong electrostatic forces.
Which of the following shows element Y and the chemical formula of T?
CompoundT
Element Y
A
B
'C
D
Lithium
YCI
Calcium
YCIu
Magaesium
YC12
Potassium
YCI
3l . The following statements are some information about the compound formed between
element P and Q.
o
.
.
Dissolve in water
High melting point
Solid at room temperature
A
B
C
D
CONFIDENTIAL
IJ
Diagram 7
and cathode of this process?
Which ofthe fotlowing is the halfequation at anode
pb2* + 2e --+ Pb
pbz* + 2e --r Pb
Pbz" + 2e
'-,
Pb
of0'l
Diagram 8
selected discharged at anode and
Which of the following pairs of ions that will be
cathode?
Anode
Cathode
No:-
Na'
oH-
oH-
NOr-
=--
Na'
H'
Reserved MARA
t4
copper(Il) sulphate solution using copper
34. Diagram 9 shows electrolysis of 0'1 mol dm-3
electrodes-
Copper ele.trode
Diagram 9
after 30 minutes?
Which of the following will be observed at anode
Iron key
Diagram l0
What is X?
A
B
C
D
Silver nitrate
Iron(II) nitrate
silver chloride
Iron(III) chloride
15
36. Diagram I
and copper as
the electrodes.
CopPer
Magnesium
Diagram 1 I
Whichofthefollowingis.thehalfequationforthereactionatnegativeterminal?
A
M{'+2e"-Mg
Mg--- Mg2* + 2e
Cu2* + 2e
Cu --- Cul*+ 2e
--
Cu
Salt solution
Ethanol
Vinegar
Sugar solution
Type of acid
pH value
0.1
0.1
Table 3
A
B
C
D
4541/l
Mis
a weak acid,
Nis
a strong acid
l6
I
tl
III
IV
I and II
I and lV
II
III
and
lll
and
lV
Substance
'
Salt + water
carbon dioxide
A
B
C
D
Zinc sulphate
Zinc carbonate
CoPPe(Il) oxide
CoPPer(II) hYdroxide
MARA
[See ne]'r
CONFIDEi'i
t7
41. Rubidium is below lithium in Group I elements'
What will happen when rubidium reacts with water?
A
B
C
D
nerjo{i1 fatt3 of
and element Y are located in Group I and Group 17 in tleis the chemrcal rormula or
Element respectively' X reacts with Y to form a compound' What
42. Element
the compound?
AXY
B x2Y
C XY2
D X2Y3
43. Table 4 shows the electron arrangeinents of four atoms'
Table 4
Arrange the elements in increasing order of electronegativity'
A
B
C
D
F, AI, CI,
F, CI, AI,
K, AI, CI, F
K, CI, AI, F
CONFIDENTIAL
l8
P' Q and R'
44. Table 5 shows the properties ofcompound
Compound
ProPerties
Table
I and II
I and III
II and IV
III and IV
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CONFIDENTIAL
19
of eleotrolysis of concentrated
potassium chloride
solution.
Carbon elechodes
Concentrated
potassium chloride
solution
Diagram 12
A K*+ e- ) K
B 2r{+2 > H2
C 2Cl' ) Clz+ 2eD 4OH- ) 2H2O + 02 +4e
46. What is the volume of distilled water required to be added to 25.0 cm3 of 0.5 mol dm-3
nitric acid in order to produce a solution of 0.1 mol dm-' ?
5.0 cm3
12.5 cm3
125-0 cm3
150.0 cm1
454lll
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acid and potassium hydroxide solution
47.Diagraml3 shows the titration of hydrochloric
hydrochloric acid
50 cm3 of
0.I mol
dm-3
of
Diagram 13
needed to neutralize potassium hydroxide
What is the volume ofhydrochloric acid
A
B
C
D
25 cm3
50 cm3
75
cm3
100 cm3
Copper plate
Zinc plate
Zinc sulPhale solution
Coppe(II)
sulphate solution
Diagram 14
Whatisthechemicalreaotionthattakesplaceatthepositiveterminalofthechemical
cell?
A
B
C
D
454lll
ion
Coppr atom losss electron to form oopper(Il)
ion accpt electron to form copper atom
Copper(ll)
2t
49. Table
Pair of metals
Negative terminal
R and copper
0.44
S and copper
110
T and copper
0.53
Cu
Table 6
What is t}re potential differenbe for the pair of metal S and T?
A
B
0.97 V
2.14 V
2.23 Y
2.67 Y
50.
40 cm3 of 0.5 mol dm'3 nitric acid is added to 50 cm3 of 0.2 mol drr3 sodium hydroxide'
Calculate the mass ofthe salt formed in this reaction.
[Relative atomic mass: Na; 23, O; 16, N; 14, H;1]
A
B
C
D
0.85 g
l l2g
l.7O g
2.55 g
454lll O2012
CONFIDENTIAL
4541
Chemistry
Paper 213
November
2012
2 Yz hour
Section Question
CHEMISTRY
Paper 2
&
3.
4.
5.
6.
t2
12
12
12
20
20
2.
Full
mark
l5
I
TOTAL
www,myschoolchildren,com
t7
100
Marks
SULIT
Section
148
4541D
narksl
Sodium
Aluminium
11
l3
Proton number
t4
l7
18
Table I
Based on Table 1, answer the following questions:
(a)
(D
metal
(iD
semi-metal
(iii)
non-metal
13
(b)
(c)
4541/2
marksl
Chlorine is in Group 17 in the Periodic Table. State the common name for
Group 17 elemerits.
11
nark)
ll
narkl
CONFIDENTIAL
SULIT
4s41/2
-)
(d)
(D
(iD
mark'l
ll
marhsl
12
marksl
(iiD
(e)
fl
(D
(ii)
Il
(i
454112 @
ii)
Copti*tt
markl
narkl
l(e)(ii).
RescrYcd MARA
CONFIDENTIAL
SULIT
2.
.
4541D
-\2a -.+- \.
a\iit i ,.-.,. I t /-.,..-\
i{oiiltioiit
,l I \C./ i | \\o/./
j \-_ '-r- )
L
Dirgram2
Based on Diagram 2:
State how Y ion and
(a)
Y ion:...........
X ion:...........
12 marksj
(b)
Y:,..--....
12 marks"l
I-r(-lo1
(c)
(i)
[E
ll
(ir)
mark.l
12 marks'l
(iii)
12 marks'l
4541D
SULIT
(d)
12 marksl
U narkl
4541/2
[See
ncxt PaEl
CONTIDENTIAL
SULIT
J.
4s4ll2
Diagram 3 shows the apparatus set-up for the electrolysis of 0.001 mol dm-3
hydrochloric acid solution using carbon electrodes X and Y'
Carbon electrode
Carbon electrode
Diagram
(u)
(D
(ii)
(iiD
ll
nmkl
11
narkl
X:
'....'.'.'....'....
Electrode Y:
12 marlcsl
(b)
(D
11
(iD
narkl
Write the half equation for the reaction that takes place at electrode
x.
ll
markl
4541D
SULIT
(c)
acid
The electrolvsis is repeated by replacing 0.001 mol dm-3 hydrochloric
solution witlr 1.0 moi dmr hydrochloric acid solution'
trtrr'hat
will
Electrode
X:
Electrode
Y:
12
(d)
narksl
One
Electrolyte
Anode
Cathode
13
(e)
narksl
Write the halfequation for the reaction that takes placeht cathode'
ll
nukT
4541D
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pH value
l0
13
Table 4
Based on Table 4, answer the following questions.
(a)
(i)
Neutal:................
(ii)
Alkaline:
12
marksl
(b)
following
ions:
(i)
Hydrogen ion
(ii)
Hydroxide ion:
12
(.)
marksl
U nark'l
(d)
p
4541i2
lSGe
narksJ
Dcxi Pagc
CONFIDENTIAL
4541/2
SULIT
(e)
Magnesium
carbonate
.F.,",,;;l-.*F;l.m.E
Diagram 4
(i)
Name salt Q.
State the
ll
mark)
lt
markl
13
marks]
solubility of salt Q.
,
Describe briefly how to prepare a solution of mlt Q from
magnesium carbonate.
4541f2
ISGC
next prge
CONr,IDENTIAL
4541D
10
SULIT
Section B
[20 rnarks]
5.
(a)
@ @:
Diagram 5.1
Based on Diagram 5.1, write the electron arrangement for atom
elements X and Y.
(b)
of
l2 marksl
Element
Proton Number
-,
Table 5
(D
(ii)
4541f2
narksl
16
narksl
Copyrigbt Rcservcd
MARA
ISGG
ncxt
PagG
CONFIDENTIAL
4s41D
l1
SULIT
(c)
Metal X is
Diagram 52 shows 0rc ractiol betni'een metal X and watcr'
a Group 1 elemenl
Water
Diagrarr
52 -
Bi
lSnwksl
6.
4541n
t2
SULIT
Diagram 5.1 shox,s two containers ofchloride sah- The sahs can be preparcd
in the school laboratory.
Lchloride
M chloride
Diagram 6.1
(a)
(D
Vntksl
(iD
dGXr).
\lhfte
[a narksl
SULIT
4541D
13
(b)
Diagrara 6.2
Describe an experiment to determine the concentration ofa
hydrochloric acid solution using titration method. A standard solution
of 0.1 mol dm-3 sodium hydroxide is provided.
.
o
.
o
o
set-up
Table of result
All
[4
454ltl
marks]
CONFIDENTIAL
454112
SULIT
Section C
[32 marks]
For
7.
to determine the
Diagram 7.1 shows the set-up of apprltul-for. an ?xPrlneT
p"tiriiJ al*"**e of an electroche#cal cell using zinc and copper as electrodas'
Copper
l-?W:-'=-!W::
.:#.{:j-#=
_-_-lrit_-_---_-_g----.
---'-E*:---':-fi:--.
After 30 minutes
-::-&----:---#-:_-----------_--------j
:;w;=t%
'-:--:-:-:::-::--1r--@::
.:---------_----------:-.
sulphate
solution
Diagam 7'l
i
(a)
min8es:
Description
Observation
Zinc elootode
Copper electrode
l3 narks)
t5
SULIT
4s4rD
as
electrodes.
Zinc I Coppr
Reading: ........
Zino / Metal Q
Reading:
Reading:
Diagram 7.2
(b)
Il
(c)
13
(d)
marksl
narksl
(0
Manipulated variable
(iD
Responding variable
(iiD
Constant variable
13
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mula]
CONFIDENTIAL
For
16
SULIT
(e)
454112
difference in this
State the operational definition for the potential
experiment.
13
4541D
@ coPYright Rescrvcd
MARA
narksl
CONFIDENTIAL
SULIT
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17
Diagram
solvents.
Clacial
ethanoic acid
Glacial
ethanoic acid
in water
in dry
propanone
Diagram 8
Based on Diagram 8, plan a laboratory experiment to investigate the solvent that
is needed for glacial ethanoic acid to show its acidic properties.
(a)
Problem statement
(b)
(c)
(d)
(e)
(0
Tabulation ofdata
experiment
|7
narksl
END OFQI]ESTIONPAPER
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@ c.opytlght Rcscrved
MARA
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