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forAngularMomentumandAngularPosition
FrankRioux
DepartmentofChemistry
CollegeofSt.Benedict|St.JohnsUniversity
Theuncertaintyrelationbetweenangularmomentumandangularpositioncanbederivedfrom
themorefamiliaruncertaintyrelationbetweenlinearmomentumandposition.
p x
( 1)
Consideraparticlewithlinearmomentumpmovingonacircleofradiusr.Theparticlesangular
momentumisgivenbyequation(2).
L = m v r = p r
( 2)
Inmovingadistancexonthecircletheparticlesweepsoutanangleinradians.
=
x
r
( 3)
Equations(2)and(3)suggest,
p =
L
r
x = r
( 4)
Substitutionofequations(4)intoequation(1)yieldstheangularmomentum,angularposition
uncertaintyrelation.
L
h
4
( 5)
InadditiontotheHeisenbergrestrictionsrepresentedbyequations(1)and(5),conjugate
observablesarerelatedbyFouriertransforms.Forexample,forpositionandmomentumitis
givenbyequation(6)inatomicunits(h=2).
p x
1
exp ipx
2
( 6)
Equations(2)and(3)canbeusedwith(6)toobtaintheFouriertransformbetweenangular
momentumandangularposition.
1
exp iL
2
( 7)
Equations(6)and(7)aremathematicaldictionariestellingushowtotranslatefromxlanguageto
planguage,orlanguagetoLlanguage.Thecomplexconjugatesof(6)and(7)translateinthe
reversedirection,fromptoxandfromLto.
Theworkhorseparticleinabox(PIB)problemcanbeusedtoprovideacompellinggraphical
illustrationofthepositionmomentumuncertaintyrelation.Thepositionwavefunctionforthe
groundstateofaPIBinaboxoflengthaisgivenbelow.
2
x
sin
a
a
( 8)
TheconjugatemomentumspacewavefunctionisobtainedbythefollowingFouriertransform.
a
0
p x x dx
a
0
x
exp(ipx ) sin
( 9)
Evaluationoftheintegralinequation(9)yields,
( p a)
exp ( i p a) 1
2
( 10)
2 2
p a
Plottingthemomentumdistributionfunctionforseveralboxlengths,asisdoneinthefigure
below,clearlyrevealsthepositionmomentumuncertaintyrelation.Thegreatertheboxlength
thegreatertheuncertaintyinposition.However,asthefigureshows,thegreatertheboxlength
thenarrowerthemomentumdistribution,and,consequently,thesmallertheuncertaintyin
momentum.
( p 1)
( p 1.5)
( p 2)
10
0
p
10
Asimilarvisualizationoftheangularmomentum/angularpositionuncertaintyrelationisalso
possible.Supposeaparticleonaringispreparedinsuchawaythatitsangularwavefunctionis
representedbythefollowinggaussianfunction,
exp a 2
( 11)
wheretheparameteracontrolsthewidthoftheangulardistribution.Theconjugateangular
momentumwavefunctionisobtainedbythefollowingFouriertransform.
L d
1
2
exp iL exp a d
( 12)
Plotsof|<|>|2and|<L|>|2shownbelowfortwovaluesoftheparameteraillustratethe
angularmomentum/angularpositionuncertaintyrelation.Thelargerthevalueofa,thesmaller
theangularpositionaluncertaintyandthegreatertheangularmomentumuncertainty.Inother
words,thegreaterthevalueofathegreaterthenumberofangularmomentumeigenstates
observed.
a exp a
a 0.5
Angular Position
a 2
0.5
0.5
( L a) exp i L a d
L 5 5
Angular Momentum
( L a)
0
L
Maketheangularpositiondistributionnarrower:
a 2.5
Angular Position
a 2
0.5
0.5
Observeabroaderdistributioninangularmomentum.
Angular Momentum
( L a)
Theuncertaintyrelationbetweenangularpositionandangularmomentumasoutlinedaboveis
asimplifiedversionofthatpresentedbyS.FrankeArnoldetal.inNewJournalofPhysics6,103
(2004).