Professional Documents
Culture Documents
MIXTURES
Particle Theory
All matter consists of many very
continual state of motion and the
energy and the relationship to
Compounds
Mixtures (impure)
Elements
Two or more substances mixed but
combined
not chemically combined
chemically
Can be physically separated
(constant
Homogeneous
composition)
o Substances spread evenly
Metals react
throughout
with non metals
o Cant see different parts
= ionic
o E.g. sea water
Metals react
Heterogeneous
with each other
o Not spread evenly
= covalent
throughout
E.g. H2O is a
o Includes suspensions
compounds
o E.g. dirt and water and oil
Pure
and water, salad dressing
substances
SPHERES
Lithosphere
All cold hard solid rock of planets i.e. crust, semi solid under crust, hot liquid near
centre, solid iron centre
Different minerals combined in different proportions from rocks e.g. oxides,
carbonates, sulfides which are mine to manufacture metals
E.g. quartz, calcite, olivine (all minerals)
MOST COMMON ELEMENTS = oxygen (46%), silicon (28%) and aluminum (8%)
Hydrosphere
Refers to whole planets water in any form
Most abundant compound in this sphere is water = most abundant elements are
hydrogen and oxygen
Most found in oceans and polar ice caps
MOST COMMON ELEMENTS = oxygen (86%), hydrogen (11%) and chlorine (1.9%)
Atmosphere
There are different layers we live in the troposphere
Refers to all of Earths air
Major gases = nitrogen and oxygen
MOST COMMON ELEMENTS = nitrogen (79%), oxygen (21%) and argon (nearly
1%)
Biosphere
Refers to planets living organisms
Ecosystems occupy all other spheres
Composed of cells therefore large amount of oxygen and hydrogen
Cells = complex carbon compounds carbs, fats, proteins etc.
SEPARATION TECHNIQUES
Method
Filtration
Example
Sand and water
liquids)
Used for
heterogeneous
mixtures
Dissolved solids
in liquids
Evaporation
Crystallization
Used to purify
impure salts
Sieving
Solids of different
sizes
Sedimentation
Undissolved
solids from liquids
Chromatography
Distillation
Dissolved solids
in liquids esp. if
coloured
Liquids and
dissolved solids
Salt water
Fractional
distillation
Separating liquids
that are miscible
or gases
Separating funnal
Separating
immiscible liquids
4 tetra
5 penta
6 hexa
EXAMPLES
CO carbon monoxide
CO2 carbon dioxide
PCl3 phosphorus trichloride
CCl4 carbon tetrachloride
H2O dihydrogen monoxide
H2O2 dihydrogen dioxide
Non metals
Solid, liquid (only
bromine) and gases
at room temp
Dull appearance
Brittle
Non conductors
Semi metals
Low sheen
Moderately malleable
Semi conductors of electricity
B, Si, Ge, As, Sb in pure state
wont conduct, but will when
impurity is added
TESTS USED
Property
Lustre
Conductivity of
electricity
Hardness
Malleability
Solubility in water
Test
Clean with abrasive paper
Connect power supply, globe or ammeter and material in simple circuit
and if the globe lights/ammeter reads it conducts
Scratch with steel knife to see if harder than steel
Use hammer to see if it will flatten out, shatter or form a powder
Dip sample in boiling water for 1 minute to observe
METALS
Main uses for common metals: building materials, cars, planes, machinery, electrical
wiring, appliances and household goods
EXAMPLES
o Aluminum aircraft because of low density and high strength
o Copper electrical wiring, high conductivity and ductility
o Iron cars and trains because of high tensile strength
Other factors determine the uses such as cost and chemical reactivity
Few are used in uncombined form (risk of being reactive)
NON METALS
Uses are based on their properties
EXAMPLES
o Helium lighter than air and unreactive therefore used in balloons
o Carbon (graphite) conducts electricity and is soft therefore used as an
electrode in dry cells
SEMI METALS
o Mixtures of silicon and germanium conduct electricity and are used as
semi conductors in computer chips
o
Liquids
Arranged in much less
orderly fashion
Move about much more
freely (more energy)
Forces between particles
are relatively weaker
Takes shape of container
Motion of particles =
actual free movement
therefore cannot be
compressed much
Solids have greater
density (except water)
Gases
Particles are much
further apart
Very rapid motion
No significant inter
particle forces
Expand to fill
whole volume
(rapid motion)
Big spaces
between particles
= easily
compressible
ELECTRON CONFIGURATION
1st shell 2 electrons
2nd shell 8 electrons
3rd shell (holds up to 18, but for first 20 elements, only holds 8)
4th shell 32 electrons
5th shell 50 electrons
E.g. Ca (20 atomic number) electron configuration 2, 8, 8, 2
E.g. Sc (21 atomic number) electron configuration 2, 8, 9, 2
Each electron in the first shell has a constant amount of energy as does each in the
2nd where those in outermost shells have higher energy amounts
Clear relation between reactivity and electron configuration
o Noble gases: no chemical reactions = completely stable and full outer shell
o Alkali metals: similar chemical properties (all lose one electron)
o Halogens: similar chemical properties (all gain one electron)
Chemical reactions:
o All elements undergo chemical reactions to form compounds to achieve
noble gas configuration
Valence electrons:
o Electrons in incompletely filled highest shell are called valence
o These are involved in chemical bonding
FORMATION OF IONS
e.g. Na (2, 8, 1) wants to lose one electron and Cl (2, 8, 7) wants to gain one electron
and therefore they form NaCl
PERIODIC TABLE AND IONS
e.g.
e.g. NH3
Physical change
No new substance is formed
Easily reversed e.g. changing state
Relatively small energy changes
involved e.g. evaporate alcohol
Mass is conserved (no new matter is
created)
Physical properties
Properties that relate to physical
change
E.g. boiling and melting points
Appearance
Density
Conductivity
Hardness
BONDING
Ionic
Always compounds
Solids at room temperature
High melting points
(usually over 400C)
High boiling points (usually
over 1000C)
Very high melting and
boiling points because
when you melt an ionic
solid you break up the
electrostatic forces
between ions and they are
very strong so much
energy is needed to break
them
Hard because of the
strong electrostatic forces
between ions
Brittle if enough force is
applied the ions of the
same charge can come
close together, they repel,
causing the crystal to
shatter
As solids, they DO NOT
conduct electricity the
ions are tightly bound into
an orderly array and so
there are no free moving
electrons allowing the
movement of a current
through the substance
When molten or in
aqueous solution they DO
conduct electricity when
they melt this arrangement
of ions is broken up,
allowing electrons and
therefore current to travel
freely through
Ionic compound formulas
are empirical as they show
the ratio of the atoms as
they appear in the
compound
Covalent Molecular
Can be either compounds or
elements e.g. H2 or O2
At room temperature can be in
any state
Gases = e.g. nitrogen
Liquids = water, methanol
Solids = CBr4
Low melting points (usually
below 200C) involves
disrupting the orderly
arrangement of molecules and
is therefore easier as these
forces are weaker
Low boiling points (usually
below 400C) covalent
molecules involve strong
bonds within the molecule but
the intermolecular forces are
weak, therefore it needs not
much energy to break the
forces between each molecule,
making it easy to boil
When solid they are soft
intermolecular forces are easy
to overcome therefore it is
easy to distort this solid
Pure covalent substances DO
NOT conduct electricity with as
solids or liquids (only when
impure) there are no
charged particles free to move
as the electrons are localized
in pairs and there are no ions
In aqueous solution they DO
NOT conduct electricity unless
they react with water to form
ions
Metallic
Solid at room
temperature
(except mercury)
Hard and have
high melting points
very strong
electrostatic bonds
between sea of
electrons and
positive ions
Conduct electricity
delocalized
electrons allow
current to flow
through
Consist of an
orderly giant 3D
structure (lattice)
which is an array
of positive ions
held together by a
sea of delocalized
electrons
Metallic bond =
force of attraction
between free
electrons and
metal positive ions
Metals are
malleable and
ductile allows
the layers to slide
over each other
meaning that their
shape can be
distorted and they
do not break
Giant Covalent
Solids in which the
covalent bonding
extends throughout
the whole crystal
Have the same
properties as
molecular covalent
bonded substances
Oppositely charged
ions held in a 3D
lattice by
electrostatic
attraction
1:1 ratio (each pos.
surrounded by one
neg.)
EXAMPLES
o Diamond
Each carbon atom
is covalently
bonded to four
other carbon atoms
billions of atoms
are bonded in this
way to form a
covalent network
solid
o
Silica
SiO2 silicon wants
to form 4 covalent
bonds and oxygen
wants to form two =
each silicon atom is
bonded to four
oxygens formula
for a covalent lattice
compound shows
ratio in which the
atoms are present =
empirical formula
Diamond
HOW IT WORKS
Ionic
Covalent
EXAMPLES
Elements as covalent molecules:
H2, F2, Cl2, O2, N2 all diatomic gases
Phosphorus and sulfur exist as covalent molecules P4 and S8
Carbon exists as diamond which is a 3D lattice and as graphite (2D lattice)
Noble gases (He, Ne, Ar, Kr, Xe, Rn) all exists as monoatomic molecules
Graphite
o Form of carbon
o Covalently bonded however it conducts electricity layered structure where
each carbon only uses three electrons for bonding and the fourth is delocalized,
allowed to move freely throughout the layer free moving electrons = can
conduct
DEFINITIONS
Solution: homogeneous mixture in which
dissolved
Suspensions:
mixture where particles are large enough to be seen
heterogeneous
Colloid: mixture where size of particels are betwee suspension and solution
Diatomic molecules: more than one atom e.g. O2 N2 H2 etc, = all gases
Monoatomic molecules: exist as independent atoms e.g. all noble gases, do not need to bond
to be stable
Covalent bonds: pairs of atoms that are sharing electrons form covalent bonds
METALS
1. METALS HAVE BEEN USED FOR MANY THOUSANDS OF YEARS
Uses of metals through history and today
Metal
Copper
Historical Use
Ornaments, domestic
utensils
Modern Use
Electrical wiring, pipes
and plumbing fittings,
electroplating, jewellery
and household
decorations
Bronze
Aluminium
Building
Properties
High conductivity
Ductility
High melting point
(hard to melt),
soft and doesnt
corrode
Higher melting
point than copper
Hard and tough
(high tensile
strength)
Iron is malleable
easily rolled into
sheets
However it
corrodes
Hard, resists
corrosion, easily
cast
Low density
Good tensile
strength
High resistance to
Zinc
Lead
corrosion
Low melting point
High resistance to
corrosion
Use
Steel
Ships propellers,
casting statues
Plumbing fittings,
musical instruments,
decorations
MILD: Car bodies,
pipes, nuts and bolts
STRUCTURAL:
beams, railways,
reinforcing
HIGH-CARBON:
knives and tools e.g.
hammers
ALLOY STEELS:
electromagnets,
safes, ball bearings
STAINLESS: food
processing things,
kitchen sinks,
surgical and dental
instruments, razor
blades
Properties
Hard, easily cast,
resists corrosion
Lustrous gold
appearance, hard but
easily machined
MILD: soft, malleable
STRUCTURAL:
hard, high tensile
strength
HIGH-CARBON:
very hard
ALLOY STEELS:
hard and shock
resistant hard at high
temps, easily
de/magnetised
STAINLESS: hard,
resist corrosion
EBA - Early Bronze Age (c.3500-2000 BC) Turkey = copper and tin
MBA - Middle Bronze Age (c.2000-1600 BC) Copper mined in Egypt
LBA - Late Bronze Age (c.1600-1200 BC) Dominating battles using iron weapons
Iron used predominantly for tools and weapons. Extracted through heating it with
charcoal then softening alloys included castiron
FUTURE AGE
Activity series
Uses the reactivity of metals with oxygen, water and dilute acids to draw up a list of metals in
order of decreasing reactivity (activity series). This tells us that any metal above another in
the activity series can displace another in a reaction.
K (potassium)
Na (sodium)
Li (lithium)
Ba (barium)
Ca (calcium)
Mg (Magnesium)
Al (Aluminium)
Zn (Zinc)
Fe (Iron)
Sn (Tin)
Pb (Lead)
Cu (Copper)
Ag (Silver)
Pt (platinum)
Au (gold)
A more reactive metal (top of activity series) when reacted with a less reactive metal
will displace that metal in the equation
Therefore the less reactive metal will be left in its pure form and the more reactive
metal will take its place in the compound
Element
Potassium
Sodium
Calcium
Magnesium
Aluminum
Carbon
Zinc
Iron
Tin
Lead
Hydrogen
Copper
Silver
Gold
Platinum
Reaction with
oxygen
Violent
Tarnishes Rapidly
Moderately
Slowly in cold water
Violently
Vigorously
Moderately
No reaction when
heated
Extremely slowly in
steam
No reaction
Slowly
Very slowly
No reaction in most
acids
NOTE: do not worry about carbon or hydrogen regarding their reactions simply included to
see how reactive they are in relation to the other metals
Uses of metals based on properties
Some situations where the choice of metal is based heavily upon chemical reactivity
(particularly with oxygen, water and dilute acids) are:
Roof guttering non-reactive but expensive aluminium
Water pipes expensive but non-reactive copper
Body implants expensive but extremely inert titanium
Relationship between reactivity of metals and their position of periodic table
The reactivity of the metals decreases as you move from left to right across the table because
the atoms have more electrons that they need to lose and energy is needed to strip those
electrons away from the increasingly more positive nucleus.
The reactivity of metals increases as you go down the group because the outer electrons
(which are lost when the metals reacts) are increasingly further from the nucleus. This means
that the nucleus exerts less of an electrostatic pull on the outer electron.
Ionisation energy
What is it: measure of the energy that is required to remove an electron from an atom. The
atom is in its gaseous state. The electron that is removed comes from the outermost shell
E.g. Na (g) e- Na+ (g)
The higher the ionisation energy, the more difficult it is to remove an electron
Generally the relationship between the periodic table and ionisation energy is:
LHS RHS ionisation energy increases
TOP BOTTOM ionisation energy decreases
The lower the ionisation energy, the more reactive is the element
The first ionisation energy measures the energy required to remove the first electron
from an atom
The second ionisation energy measures the energy required to remove the 2 nd
electron from the gaseous +1 ion
Oxidation and reduction
Whenever a metal undergoes a reaction especially with water and acids, they lose
electrons to form positive ions
1st Definition
When an atom loses electrons = oxidised
When an atom gains electrons = reduction
In any equation there is no overall loss of electrons therefore oxidation and reduction
occur simultaneously and are known as redox reactions
Agents
Oxidising Agent
Accepts electrons
Causes the oxidation of another
substance
Is always itself reduced
Has its oxidation state decreased
Reducing Agent
Donates electrons
Causes reduction of another
substance
Is always itself oxidised
Has its oxidation state increased
2nd Definition
Gain of oxygen = oxidation
Loss of oxygen = reduction
Oxidation States
Idea of oxidation state (number) is a way to track oxidation and reduction changes
that occur in chemical reactions
A set of rules have been assigned to elements, ions and compounds where they have
an oxidation state at the start and end of reaction
Rules
1. All elements in their standard states have oxidation numbers of 0
2. The charges on the ion is its oxidation number
E.g. Na+ = +1 oxidation number
O2- = -2 oxidation number
3. Certain atoms have been assigned fixed oxidation numbers e.g.
H in all of its compounds will have an oxidation number of +1
O in all of its compounds will be -2
F will always be -1 in its compounds
Cl will always be -1 in its compounds provided that oxygen isnt also present
Using these rules we can determine the other elements present. The sum of the oxidation
numbers in a compound or ion, is equal to the charge or O if the charge is neutral
Third Definition
Oxidation: increase in oxidation number
Reduction: reduction in oxidation number
Example
1) Write equation
Mg (s) + 2HCl (aq) MgCl2 (aq) + H2 (g)
2) Rewrite equation, separating the compounds into their lone ions
HCl = H+ and ClMgCl2 = Mg2+ and 2ClTherefore new equation: Mg + 2H+ + 2Cl- Mg2+ + 2Cl- + H2
3) Take note of the spectator ions (the ones that do not change after the reaction)
In this case the 2Cl- is the spectator ion, the rest have changed after the reaction
4) Write net ionic equation (equations where spectator ions are left out)
Mg (s) +2H+ (aq) Mg2+ (aq) +H2
5) Write half equations, separating the separate reactions between elements
Mg (s) 2e- Mg2+ (aq)
2H+ + 2e- H2 (g)
Therefore it is obvious that 2 electrons have been donated from magnesium to
hydrogen
6) Decide which have been oxidised and which have been reduced
In this case the magnesium has been oxidised and the hydrogen has been reduced
Oxidation
Is
Loss
Reduction
Is
Gain
Dobereiner (1829)
Newlands (1864)
Mendeleev (1869)
Ramsay (1894)
Molesley (1914)
Seaborg (1940)
Electrical Conductivity
Ionisation Energy
Atomic radius
Melting/boiling point
Valency
Electronegativity
Reactivity
decreases
Group 7 = weak intermolecular
forces = low m/bp but increases as
you go down a group (same as group
8)
Peak in group 4
Refers to the number of elements it
can combine with
Relative power of an element to
attract electrons to itself in a covalent
bond
Left right = increases (more
protons therefore more attraction and
pull power)
Top bottom = decreases
Therefore F is the most
electronegative element
Increases going down a group for
group 1
Group 7 decreases going down
No trend going across, just in
separate groups
E.g.
99% of carbon is carbon 12
0.9% is carbon 13
0.1% is carbon 14 (this is all determine by a mass spectrometer)
Average mass = (99x12) + (0.9x13) + (0.1x14)
100
= 12.011
Molecular mass
Molecular mass/weight: sum of the atomic weights of the atoms in a molecular formula
E.g.
Molecular weight of C12H22011
M.W. = (12 x Ac) + (22 x AH) + (11 x Ao)
= (12 x 12.0) + (22 x 1.01) + (11 x 16.0)
= 342.2 (but no units because mass is only relative)
Formula mass
Formula mass/weight: sum of atomic weights atoms in a compound with no discreet
molecules (e.g. ionic compound). They describe the ratio of atoms present, but are calculated
in the same way as molecular weights
E.g.
Ca3(PO4)2 is:
Ca3, P2, O8
F.W. = (3 x ACa) + (2 x AP) + (8 x A0)
= (3 x 40.1) + (2 x 31) + (8 x 16)
= 310.3
The mole
1 mole of any substance is equal to 6.022 x 1023 particles including atoms, ions, electrons,
molecules etc.
n = number of moles
m = mass (g)
mr = molar mass
n = mass
mr
Empirical formula
Empirical formula: simplest whole number ratio of all the elements in a compound
For example:
C4H10 is the molecular formula BUT C2H5 is the empirical formula
Examples
1. Find the empirical formula of a compound made up of 20g of Ca, 6g of Carbon and
24g of Oxygen
Ca = 40
C = 12
O = 16
20 : 6 : 24
40
12
16
1
2
: 1
2
(simplify ratios)
: 3
2
1 : 3
EXAMPLE
What volume of oxygen is required for the complete combustion of 11.5g of sodium?
4Na (s) + O2 (g) 2Na2O (s)
Ratio is 4:1
Number of moles of sodium = 11.5/23 = 0.5
Divide this by 4 to get number of moles of oxygen = 0.125
Therefore the volume of oxygen = n x 24.79
= 3.09875 litres
Mole calculations
1. Calculating number of moles when given atoms
E.g. 3.01 x 1024 carbon atoms find the number of moles
Divide number of atoms by Avogadros number to get number of moles
2. Finding number of moles when given grams
Number of moles = mass (g) usually given in question
Molar mass of the compound/element
E.g. How many moles are contained in 1.01g of neon gas?
N = 1.01/20.2 = 0.5
3. Calculating mass from number of moles
Mass = no. of moles x atomic weight (found on periodic table)
E.g. calculate the mass of 2.05 moles of rubidium atoms
Mass = 2.05 x 85.5 = 175g
4. Calculating mass from ratio (when given grams of wrong element)
First determine ratio between elements by looking at the coefficients of the substances in
balanced equation
Second work out number of moles in the substance that you are given the grams for
Third use the ratio to work out the moles of the other substance
Fourth use number of moles to calculate mass in g
EXAMPLE: Calculate the mass of sodium needed to react with 10g of titanium chloride
TiCl4 + 4Na Ti + 4NaCl
First It is obvious that the ratio is 1:4
Second using the 10g of titanium we can work out the number of moles of titanium chloride
Number of moles = 10/19 = 1/19
Third but its in ratio 1:4 so multiply by four to get the number of moles of the sodium
1/19 x 4 = 4/19 moles
Fourth work out mass of 4/19 moles of sodium
Mass = 4/19 x 23
= 4.8 (1dp) grams
Yield
Theoretical yield what you expect to gain from reaction
Actual yield what you actually get in reality
% yield = actual yield/theoretical yield
EXAMPLE
Part a) Calculate mass of ammonia that can be formed from 12g of Hydrogen
3H2 + N2 2NH3
Calculate mass normally by finding no. of moles and multiplying by molar mass
Found 68g to be the theoretical yield
Part b) 20g was formed in this reaction. Calculate percentage yield
20/68 x 100 = 29.4%
WATER
WATER IS DISTRIBUTED ON EARTH AS A SOLID, LIQUID AND GAS
Solute: a substance that is dissolved by a solvent in a solution
Solvent: a substance that dissolves a solute in a solution
Natural resource
Drinking and
food prep
Washing
clothes, dishes
etc.
Irrigation
Recreation
Transportation
Hydroelectricity
Alters landforms
Moving water in
rivers = canyons
Can erode rocks
by dissolving
minerals
Glaciers change
the landscapes
from mountains
to sea
Spheres
Biosphere
Liquid (as a
solvent for
nutrients)
60-90% in most
living things (5075 in humans)
Lithosphere
Solid, liquid or
chemically bound as
waters of hydration
Variable %s in
groundwater,
aquifers and rocks
Hydrosphere
Liquid and
solid
Approx. 95% in
oceans,
lakes/rivers
and icecaps
Atmosphere
Gas and liquid
Up to 5% in air,
variable
depending upon
environment
Density
DENSITY = MASS/VOLUME
EXPERIMENT
Density of water
1. Add an amount of water to beaker and weigh
2. Measure temp of water
3. Repeat in 10mL increments
What happens: as volume increases, density increases
Density of ice
1. Weigh ice cube
2. Measure 100mL of water into beaker
3. Submerge ice cube and calculate difference in volume
4. Use d = m/v to find density
THE WIDE DISTRIBUTION AND IMPORTANCE OF WATER ON EARTH IS A
CONSEQUENCE OF ITS MOLECULAR STRUCTURE AND HYDROGEN BONDING
Lewis Dot Diagrams
CH4 (methane)
NH3 (ammonia)
H2O (water)
Water
Bent
Ammonia
Pyramidal
Hydrogen Sulfide
Bent
M.p (C)
B.p. (C)
0
100
-78
-33
-86
-60
NH3
H2O
CO2
Hydrogen Bonding
Type of intermolecular force that involves a hydrogen atom bonded to an O, N or F
atom in one molecule becoming attached to an O, N or F from a different molecule
This results in an unequal sharing of electrons leading to a partial positive charge on
the H atom
These bonds are stronger than dipole-dipole and dispersion forces, but about one
tenth of that of a normal covalent bond
Ammonia
Water
Polarity
Bond can be polar or non-polar
Depends on the difference in electronegativity of the atoms in that bond
Electronegativity: measure of the ease at which an atom attracts electrons (recall that
F is the most electronegative element)
Example 1
Hydrogen fluoride
Example 2
NH3 (ammonia)
Viscosity
Reistance of a liquid
Melting/boiling point
The larger the
to flow
Two factors affect
viscosity: size and
complexity of
molecules AND
intermolecular forces
The stronger the
forces the more
resistance to flow
and therefore the
higher the viscosity
Water has a
relatively high
viscosity due to
strong hydrogen
bonding
Expansion on Freezing
Ice nearly all molecules are hydrogen bonded to each other
Each oxygen has 4 H atoms around it two covalently bonded and two hydrogen
bonded
This arrangement = open structure
When melts individual water molecules are able to move breaking up hydrogen
bonding
Less hydrogen bonding = molecules move closer water higher density than ice
(same mass occupies smaller volumes)
WATER IS AN IMPORTANT SOLVENT
Type of substance
Soluble Ionic
Compound
Soluble molecular
compound
Soluble/partially
soluble
element/compound
Covalent network
structure
Substance with large
molecules
Hydrogen Bonding
Insoluble Compounds
Carbonates, Chromates and Phosphates
except Sodium, Potassium, Lithium,
Caesium and Ammonium
Sulfides except Sodium, Potassium,
Lithium, Caesium, Beryllium, Magnesium,
Calcium, Strontium, Barium and
Ammonium
Hydroxides and Oxides except Sodium,
Potassium, Lithium, Caesium, Beryllium,
Magnesium, Calcium, Strontium and
Barium
C=n
v
Mass per
unit
volume
(g/L)
Percent by
mass (w/w)
Percent by
volume
Parts per
million
AND
n = mass
mr
Dilution Calculations
C1 x V 1 = C 2 x V 2
C1 = initial concentration
V1 = volume to be taken from the original solution and transferred into the second solution
with new concentration
C2 = new concentration
V2 = volume of solution (usually stays constant)
WATER HAS A HIGHER HEAT CAPACITY THAN MANY OTHER LIQUIDS
Specific Heat Capacity
Measure of the amount of energy (in joules J) that is needed to raise 1g of a
substance by 1C
The higher the heat capacity the more resistant a substance is to a change in
temperature
Water has a heat capacity of 4.18 JK/g
H = -mcT
(only add in the negative if you need to see whether the reaction is endo or exo thermic)
H energy released/absorbed (J)
m mass of substance (g)
C specific heat capacity (e.g. 4.18Jg-1K-1)
T change in temperature (final minus initial temperature)
Example:
What quantity of energy is required to raise the temperature of 0.5L of water from 20C to
100C?
H = mcT
H = 500g x 4.18 x 80C
= 167200J
= 167kJ
In Chemical Reactions:
e give
Breaking the bonds that hold ions together requires energy (endothermic)
Forming bonds with water (hydration) releases energy (exothermic)
So, Hsoln = heat absorbed when breaking bonds heat released when forming
bonds (in kJ/mol.)
Endo/Exothermic
Endothermic
Enthalpy/heat content of reactant < products
Heat is absorbed
H is positive
Heat from surroundings is absorbed - temperature
of surroundings will go down
Final temp initial temp = NEGATIVE
This is because the temp of surroundings go
down
Final temp < initial temp
When solute/solvent relationships are weaker
Therefore:
T is always negative
H is always positive
Exothermic
Enthalpy of reactants > products
Heat is released
H is negative
Heat is given out to the surroundings
Final temp initial temp = POSITIVE
This is because the temp of surroundings
(water) goes up
Final temp > initial temp
When solute/solvent relationship is stronger
Therefore:
T is always positive
H is always negative
Draft lost from room heat goes into air and surroundings go up rather than water
Depends on how well you read the thermometer
Insulation of cup/container
Whole experiment is dependent on weighing and measuring the temperature
therefore they are sources of error
Dissolving Solutes
Ionic Compounds
Completely dissolve and
dissociate to give ions in
solution
E.g: NaCl Na+ + Cl Therefore, NaCl is an
electrolyte and will conduct
electricity
Molecular Compounds
Those that dissolve include: glucose, sucrose
They dissolve, but dont dissociate to give
ions
C6H12O6(s) C6H12O6(aq)
Therefore no ions are released and it is a
NON-electrolyte
Thus, has no conductivity
Aquatic organisms high heat capacity of water means their environment maintains a
much more stable temperature than land
Waters prominence in the biosphere means that it has a moderating influence on
global temperatures
Thermal Pollution
Refers to human acitivity dramatically changing the temperature of waterwyas
Most commonly use of natural water bodies for industrial cooling e.g. power plants
Thermal pollution can have detrimental eggects on aquatic life:
Solubility of oxygen decreases as temperature increases
Sharp increase in temperature may directly kill fish and other organisms
High temperatures can prevent development of fish eggs
ENERGY
LIVING ORGANISMS MAKE COMPOUNDS WHICH ARE IMPORTANT SOURCES OF
ENERGY
Photosynthesis
6CO2(g) + 6H2O(l) (light and chlorophyll) C6H12O6(aq) + 6O2
Endothermic
Autotrophs make their own food by photosynethsis
Using chlorophyll, they convert light energy to chemical energy
Release
Respiration
C6H12O6 CO2 + H2O + energy
Cellular respiration releases the stored chemical energy
The amount of energy released during respiration per mole of glucose is equal to the
amount of energy absorbed during photosynthesis
Uses for respiration
Used directly for activities
Converted to protein for growth/repair of tissues
Stored as fat for energy reserves
Most is released as heat back to the environment
Carbohydrates
Photosynthesis is the production of glucose
However, photosynthesis actually makes many other carbohydrates as well
Carbohydrates contain the chemical energy that is released by living things
The general equation of a carbohydrate:
Formed when dead and decaying material was buried before complete
decomposition
Formed over millions of years due to the heat/pressure beneath the Earths surface
Energy-rich compounds known as hydrocarbons
Chemical potential energy is released when burning in oxygen
Sequence of Production
Coal
Petroleum
Natural Gas
Double Bonds
Triple Bonds
Tetravalent Carbon
Carbon has 4 valence electrons therefore forms 4 bonds with other elements to
make a full valence shell
All valence electrons are involved in bonding
This bonding leads to tetrahedral shapes when all bonds are single
Hydrocarbons are made up of carbon bonded to H, but many elements can take its
place such as halogens (Cl, F) and N, O, S
Forms of Carbon
Allotropes: forms of an element with different properties. Carbon has 4:
Arnorphous
Graphite
Diamond
Buckminsterfullerene
CnH2n+2
No. of C
1
Molecular
CH4
Methane
Empirical
CH4
Structure
C2H6
Ethane
CH3
C3H8
Propane
C3H8
C4H10
Butane
C2H5
C5H12
Pentane
(from here the prefixes are
normal hex, hept, oct etc.)
C2H12
ALKENES
General Formula:
Molecular
C2H4
Ethene
Empirical
CH2
(this is always the
same)
C3H3
Propene
CH2
C4H8
Butene
CH2
Structure
C5H10
Pentene
CH2
Combustion is Exothermic
Combustion of a material involves its combination with oxygen gas
Because combustion reactions release energy in the form of heat and light, they are
exothermic.
Examples of exothermic (many more)
Combustion reactions
Reactions between metals and water
Reactions between metals and acid
Reactions of acids and bases
Examples of endothermic
Decomposition reactions
Photosynthesis
Some precipitation reactions
Formation of synthesis gas
Activation Energy
Ignition Energy
The minimum
temperature required by
a substance to ignite.
Relationship:
The higher the activation energy, the higher the ignition temperature
In order for a fuel to ignite, a certain amount of heat energy must be applied to the
substance
Not all of the particles must be heated to this temperature to start the reaction.
Once the combustion reaction has started, the resulting release of energy provides
sufficient temperatures for neighbouring particles to ignite.
Sources of Pollution
Incomplete combustion can produce carbon monoxide and carbon (CO and C) Sulfur
Dioxide/Trioxide
Sulfur Dioxide: Sulfur is an impurity in fossil fuels, mainly coal (up to 5%). When sulfur
burns in air sulfur dioxide is produced: S(s) + O2(g) SO2(g) (or sulfur trioxide
through further oxidation of SO2)
These two gases can combine with water in the atmosphere to produce acid rain
Oxides of Nitrogen: Nitrogen and oxygen in the air can react at high temperatures
that are present inside car engines: N2(g) + O2(g) 2NO (g) causing brown haze
known as photochemical smog and respiratory problems in many people
Controlling Pollution
Incomplete
When the oxygen available is insufficient,
incomplete combustion results in other
pollutants.
As the quantity of oxygen decreases,
combustion of hydrocarbons becomes
more and more incomplete, leading to the
production of the pollutants CO and C
Incomplete Combustion (the red are the
products due to the lack of oxygen)
C5H12(l) + 4O2(g)
2CO(g) + 3C(s) +
6H2O (g)
Combustion Rates
Slow Combustion
Slow combustion:
like in slow
combustion stoves
where large lumps
of fuel take many
hours to burn
Occurs when we
use big lumps of
fuel and limit the
supply of air
This means that
burning only
occurs on the
surface of the big
lumps and its
speed is controlled
by the limited
supply of air
Fast Combustion
Fast combustion: such as
burning methane, kerosene
or heating oil in stoves or
heating appliances
Often in power stations
Coal is ground into very
small particles that are
sprayed into plentiful air
supply meaning there is a
larger surface area and a
larger amount of oxygen,
therefore speeding up the
process as more collisions
take place
In other fast combustion
processes the gaseous
nature of the mixture and
high temps ensure that fuel
is always in contact with
oxygen
Explosive Combustion
Explosive
combustion: as
in the cylinders
of petrol and
diesel engines in
vehicles
In petrol and
diesel engines,
the conditions
(often involving
large amounts of
heated air)
promote very
rapid reaction
An explosion is
just an extremely
rapid reaction,
which completes
within a few
microseconds
Spontaneous Reactions:
Once ignited they proceed without further assistance and continue to go until all of
the fuel is used up
All combustion reactions are spontaneous
Collision Theory and Reaction Rates
For a reaction to proceed to products, the reactants must collide with one another.
There must also be enough energy present (known as activation energy) and the
particles must collide in a certain relative angle or direction (referred to as steric
effect)
The rate of a reaction is the rate that reactants disappear and products form.
As the reaction proceeds and reactants are used up, the rate decreases.
Since the reacting particles must collide to react, increasing the rate of collisions
increases the rate of reaction.
Ways to increase the number of collisions and therefore the rate of the reaction:
Increasing surface area
Increasing temperature
Increasing concentration
Use of catalysts
Concentration
Measures no. of particles of a
substance per unit volume
Increasing concentration puts more
particles per unit volume
Therefore increases the chance of a
collision and speeds up the reaction
Surface area
The greater the area of the solid in a
solute/solvent reaction, the more
collisions that can occur in a given
time, so reaction rate increases
Temperature
As temperature increases, the average kinetic energy (and therefore the speed) of
particles increases
This means that the rate of collision will increase, which will cause an increase in
reaction rate
However, this effect alone does not explain the very rapid increase in the rate
In order for a reaction to take place, it is necessary for the reactant molecules to
collide AND for the colliding molecules to possess a minimum amount of kinetic
energy so that they can reach the top of the energy barrier (activation energy)
If colliding molecules have insufficient energy, they just bounce apart and stay as
reactants
If sample is heated, the kinetic energy of molecules is increased, meaning that the
molecules have more than enough energy to scale the energy barrier quickly,
increasing the rate of reaction
Catalysts
Useful when reactions have high activation energies (and is therefore very slow)
Catalyst provides a pathway of lower activation energy
The addition of a catalyst does not ultimately change the H (enthalpy change) of the
reaction
Industrial Examples:
Catalytic cracking of hydrocarbons in oil refining to convert higher boiling
point fractions into petrol cracking breaks long chains of hydrocarbons into
shorter ones and therefore speeds up the reaction
The Haber Process: The production of ammonia from nitrogen and hydrogen
gases is catalysed by an iron catalyst.
Catalytic Converter: Rhodium and platinum catalysts are coated on a ceramic
honeycomb block to remove unburnt hydrocarbons, nitric oxide and carbon
monoxide from motor vehicles.